CN104193408B - Light reductive agent of ceramic and preparation method thereof - Google Patents
Light reductive agent of ceramic and preparation method thereof Download PDFInfo
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- CN104193408B CN104193408B CN201410392429.XA CN201410392429A CN104193408B CN 104193408 B CN104193408 B CN 104193408B CN 201410392429 A CN201410392429 A CN 201410392429A CN 104193408 B CN104193408 B CN 104193408B
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Abstract
First the present invention discloses a kind of light reductive agent of ceramic, it to be mixed with according to the mass ratio of 1:2-5 by major ingredient and flux to obtain, described major ingredient comprises the raw material of following parts by weight: quartzy 6-10, feldspar 6-10, kaolin 2-6, chalk 2-6, ironic hydroxide powder 1-5, ferric oxide 1-3, cupric oxide 0.5-1.5, water 11-25, described flux comprises the component of following parts by weight: red copper 34-38, quartz 20-24, borax 16-20, feldspar 9-12, Wingdale 6-10, kaolin 3-7, water 35-45; Secondly the present invention discloses the preparation method of above-mentioned light reductive agent, light reductive agent disclosed by the invention is adopted effectively to avoid ceramic to occur under photoenvironment reflective, effectively can improve the vision appreciation effect of the photographs on ceramic like this, strengthen the stereoscopic sensation of photographs.
Description
Technical field
The present invention relates to chemical field, light reductive agent being specifically related to a kind of ceramic and preparation method thereof.
Background technology
Now, photographic work is generally appreciate for people after directly mounting frame and recollect, but mounts the stereoeffect that frame is difficult to highlight photographic work, and this reduces the texture of photographic work undoubtedly.
Ceramic product has just been invented the Neolithic Age before 8000 by China, and nowadays, pottery is seen everywhere in the life of people, and it all has a wide range of applications in the field such as feeder, decoration.Along with the development of science and technology, ceramics has increasing intention, in order to enrich the appreciation effect of ceramics and increase photographic work, photographic work is directly presented on ceramic and views and admires for people by applicant's imagination, but the ceramic of prior art is easily reflective under light illumination, will certainly affect the appreciation effect of photographic work like this, therefore wanting photographic work can perfectly be presented on ceramic, and this just needs the reflective problem effectively solving ceramic.
Summary of the invention
Primary and foremost purpose of the present invention is to provide a kind of light reductive agent of ceramic.
For achieving the above object, the technical solution used in the present invention is: a kind of light reductive agent of ceramic, it to be mixed with according to the mass ratio of 1:2-5 by major ingredient and flux to obtain, described major ingredient comprises the raw material of following parts by weight: quartzy 6-10, feldspar 6-10, kaolin 2-6, chalk 2-6, ironic hydroxide powder 1-5, ferric oxide 1-3, cupric oxide 0.5-1.5, water 11-25, described flux comprises the component of following parts by weight: red copper 34-38, quartzy 20-24, borax 16-20, feldspar 9-12, Wingdale 6-10, kaolin 3-7, water 35-45.
The beneficial effect that technique scheme produces is: adopt light reductive agent disclosed by the invention effectively to avoid ceramic to occur under photoenvironment reflective, effectively can improve the vision appreciation effect of the image on ceramic like this, strengthen the stereoscopic sensation of image, concrete, at high temperature fire after first the surface of ceramic being coated with last layer light reductive agent of the present invention, then the surface of ceramic is carried out polishing washing process to avoid the surface of ceramic too smooth, the ceramic obtained like this can highlight the image stereoeffect on ceramic well under illumination condition, effectively avoid reflected light to the interference of image.
As further preferred version: described light reductive agent to be mixed with according to the mass ratio of 1:3 by major ingredient and flux to obtain, and described major ingredient comprises the raw material of following parts by weight: quartz 8, feldspar 8, kaolin 4, chalk 4, ironic hydroxide powder 3, ferric oxide 2, cupric oxide 1, water 18, described flux comprises the raw material of following parts by weight: red copper 36, quartz 22, borax 18, feldspar 11, Wingdale 8, kaolin 5, water 40.In fact, the various raw materials that the application prepares light reductive agent used are all bought directly from the market, although variant on its composition different of various ore country of origin, but do not affect the processing preparation of the light reductive agent described in the application, in other words the source of various raw mineral materials is without the need to particular requirement.
Another object of the present invention is to provide a kind of preparation method of light reductive agent of above-mentioned ceramic, and it comprises the following steps:
1) take quartz, feldspar, kaolin according to the above ratio, chalk, ironic hydroxide powder, ferric oxide, cupric oxide, and water, under normal temperature condition, carry out mix and blend, obtain major ingredient;
2) take red copper, quartz, borax, feldspar, Wingdale, kaolin and water according to the above ratio, under normal temperature condition, carry out mix and blend, obtain flux;
3), after being mixed according to the above ratio by the flux that major ingredient obtained for step 1 and step 2 obtain, aqueous light reductive agent is obtained.
Adopt aforesaid method to prepare light reductive agent not only easily to realize, and technique is simple, easy to control, the light reductive agent obtained is aqueous, stable performance, is directly coated in the surface of ceramic when it uses.
Embodiment
In order to further illustrate technical scheme disclosed by the invention, be described further below by way of 4 embodiments:
Embodiment 1: the preparation of light reductive agent
1) take 6g quartz, 6g feldspar, 2g kaolin, 2g chalk, 1g ironic hydroxide powder, 1g ferric oxide 0.5g cupric oxide and 11g water, mix and blend under normal temperature condition, obtains major ingredient;
2) take 34g red copper, 20g quartz, 16g borax, 9g feldspar, 6g Wingdale, 3g kaolin and 35g water, under normal temperature condition, carry out mix and blend, obtain flux;
3) mixed according to the mass ratio of 1:2 by the flux that major ingredient obtained for step 1 and step 2 obtain, obtain light reductive agent, described light reductive agent is colourless transparent liquid shape.
Embodiment 2: the preparation of light reductive agent
1) take 10g quartz, 10g feldspar, 6g kaolin, 6g chalk, 5g ironic hydroxide powder, 3g ferric oxide 1.5g cupric oxide and 25g water, mix and blend under normal temperature condition, obtains major ingredient;
2) take 38g red copper, 24g quartz, 20g borax, 12g feldspar, 10g Wingdale, 7g kaolin and 45g water, under normal temperature condition, carry out mix and blend, obtain flux;
3) flux that major ingredient obtained for step 1 and step 2 obtain is mixed according to the mass ratio of 1:5, obtain light reductive agent, described light reductive agent liquid.
Embodiment 3: the preparation of light reductive agent
1) take 8g quartz, 8g feldspar, 4g kaolin, 4g chalk, 3g ironic hydroxide powder, 2g ferric oxide 1g cupric oxide and 18g water, mix and blend under normal temperature condition, obtains major ingredient;
2) take 36g red copper, 22g quartz, 18g borax, 11g feldspar, 8g Wingdale, 5g kaolin and 40g water, under normal temperature condition, carry out mix and blend, obtain flux;
3) mixed according to the mass ratio of 1:2 by the flux that major ingredient obtained for step 1 and step 2 obtain, obtain light reductive agent, described light reductive agent is liquid.
Embodiment 4: the application of light reductive agent
1) choose Jing Dezhen home built plate ceramic products, be coated with the light reductive agent that last layer embodiment 3 prepares on the surface of this ceramic plate, then under 1000 DEG C of conditions, fire 3h, cooling;
2) surface of ceramic plate is carried out polishing washing process to avoid the surface of ceramic too smooth;
3) print photographs on the surface of ceramic plate, under being then placed in 400 DEG C of conditions, toast 15min, cooling;
4) at the surface-coated light-colored alcohol-base raw material of ceramic plate, then 3h is fired under ceramic plate being placed in 300 DEG C of conditions, cooling, described light-colored alcohol-base raw material is obtained by the component mixing preparation of following parts by weight: zirconium English powder 10, brown alundum powder 28, mullite powder 10, crystalline graphite powder 15, forsterite powder 8, lost foam paint 3, wilkinite 20,2-amino-2-methyl-1-propanol 0.1, diester 20;
5) by ceramic plate, airtight placement is after 3 days at ambient temperature, and the photographs on ceramic plate manifests, and this ceramic plate is no-reflection problem under illumination condition, can highlight the image stereoeffect on ceramic well.
Claims (3)
1. a light reductive agent for ceramic, it to be mixed with according to the mass ratio of 1:2-5 by major ingredient and flux to obtain, and described major ingredient comprises the raw material of following parts by weight: quartzy 6-10, feldspar 6-10, kaolin 2-6, chalk 2-6, ironic hydroxide powder 1-5, ferric oxide 1-3, cupric oxide 0.5-1.5, water 11-25, described flux comprises the component of following parts by weight: red copper 34-38, quartz 20-24, borax 16-20, feldspar 9-12, Wingdale 6-10, kaolin 3-7, water 35-45.
2. light reductive agent according to claim 1, is characterized in that: it to be mixed with according to the mass ratio of 1:3 by major ingredient and flux to obtain, and described major ingredient comprises the raw material of following parts by weight: quartz 8, feldspar 8, kaolin 4, chalk 4, ironic hydroxide powder 3, ferric oxide 2, cupric oxide 1, water 18, described flux comprises the raw material of following parts by weight: red copper 36, quartz 22, borax 18, feldspar 11, Wingdale 8, kaolin 5, water 40.
3. a preparation method for light reductive agent as claimed in claim 1 or 2, it comprises the following steps:
1) take quartz, feldspar, kaolin according to the above ratio, chalk, ironic hydroxide powder, ferric oxide, cupric oxide, and water, under normal temperature condition, carry out mix and blend, obtain major ingredient;
2) take red copper, quartz, borax, feldspar, Wingdale, kaolin and water according to the above ratio, under normal temperature condition, carry out mix and blend, obtain flux;
3), after being mixed according to the above ratio by the flux that major ingredient obtained for step 1 and step 2 obtain, aqueous light reductive agent is obtained.
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TWI250139B (en) * | 2003-06-27 | 2006-03-01 | R-Shin Tsai | Nano glaze with far infrared radiation functions |
CN101157542B (en) * | 2007-09-27 | 2011-10-05 | 广东金意陶陶瓷有限公司 | Production technique for ceramic title having semitransparent reflecting decorative surface |
CN101993254A (en) * | 2010-11-23 | 2011-03-30 | 大埔漳联瓷业发展有限公司 | Method for manufacturing medium-temperature ceramic matt glaze |
CN102674808B (en) * | 2012-06-11 | 2013-07-24 | 大埔县富大陶瓷有限公司 | High-toughness composite matte ceramic product and manufacturing method thereof |
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