A kind of Cotton Fields herbicides special
Technical field
The present invention relates to a kind of weed killer herbicide, especially a kind of Cotton Fields herbicides special, belongs to field of agricultural production technologies.
Background technology
Cotton is the important economic crops of China.Cotton in China is widely distributed, has plantation from south to north, and total sowing area of Cotton in China is 75,000,000 mu of left and right.The principal element that affects output of cotton is insect pest and crop smothering.The conventional weed killer herbicide of Cotton Fields has at present: trefanocide, Acetochlor etc.Trefanocide belongs to long residual effect weed killer herbicide, easily causes the poisoning of rear stubble, and must mixed soil while using, and time-consuming work consuming, also can cause that with rear cotton knee is large; Acetochlor herbicide spectrum is narrow, and the lasting period is short, and soil moisture content is had relatively high expectations.Due to the use in a large number for years of cotton field weed killer herbicide, its drug injury problem also manifests day by day simultaneously.
Quizalotop-ethyl, chemical name: (R)-2-[4-(6-chloroquinoxalin-2-yloxy) phenoxy group] ethyl propionate, molecular formula: C
17h
13clN
2o
4; Molecular weight: 372.8.Its mechanism of action is: absorb by weeds cauline leaf, Bidirectional Conduction up and down in plant corpus, is accumulated in top and mitogenetic between two parties, suppresses cell fatty acid synthetic, makes weeds necrosis.It is a kind of novel dry land cauline leaf inorganic agent of high selectivity, has the selectivity of height between grassy weed and dicotyledonous crops, and the grassy weed in broad leaf crop field is had to good preventive effect.
Halosulfuronmethyl, molecular formula: C
13h
15clN
6o
7s, molecular weight: 434.81.Be mainly used in preventing and kill off broad leaved weed and sedge weed, as piemarker, storehouse ear, datura, artemisiifolia, Amaranthus retroflexus, flowerofanhour root or herb, knotweed, kitchen garden, black nightshade, Cassia tora, lead a cow, the rhizome of nutgrass flatsedge etc., suitable crop is as wheat and corn, paddy rice, sugarcane, lawn etc., before seedling and Miao Houjun can use.
Garlic oil is the material extracting from garlic, and main component is pi-allyl propyl disulfide compound, diallyl disulfide, diallyl trisulfide, allicin etc.There is sterilization and the anthelmintic action of wide spectrum.
Summary of the invention
The invention provides a kind of Cotton Fields herbicides special, this weed killer herbicide forms by Quizalotop-ethyl, halosulfuronmethyl and garlic oil are composite, not only grassy weed, sedge weed and broad-leaved section weeds is had to good killing action, and has alleviated chemical injury of crops.
Technical scheme of the present invention is: a kind of Cotton Fields herbicides special, it is characterized in that, comprise active ingredient and auxiliary agent, wherein active ingredient forms by Quizalotop-ethyl, halosulfuronmethyl and garlic oil are composite, wherein the mass ratio of Quizalotop-ethyl, halosulfuronmethyl and garlic oil is 10:2-3:1-2, and the content of described active ingredient is 5-65wt%.
Preferably, the mass ratio of described Quizalotop-ethyl, halosulfuronmethyl and garlic oil is 10:2.5:1.5.
Preferably, the content of described active ingredient is 14wt%.
Weed killer herbicide of the present invention can be prepared into the preparations such as aqueous emulsion, suspension emulsion, wetting powder, microemulsion.
Method for producing aqueous emulsion is: Quizalotop-ethyl, garlic oil, No. 150 industrial solvents, agricultural emulsifier NO.600 and agriculture breast NP-10 are mixed, make it to be dissolved into even oil phase; Halosulfuronmethyl, polyvinyl alcohol and propane diols are added to the water and are mixed, form even water; Under high-speed stirred, water is joined in oil phase, form the aqueous emulsion of favorable dispersibility.
Suspension emulsion preparation method is: Quizalotop-ethyl, garlic oil, No. 150 industrial solvents, No. 500, agriculture breast and Nongru-700s number are mixed, make it to be dissolved into even oil phase; Halosulfuronmethyl, polyvinyl alcohol, dodecyl sodium sulfate, organic silicone and water mixing frosted are made into aqueous suspension agent; Then the oil phase preparing and aqueous suspension agent shearing are uniformly dispersed, make suspension emulsion.
Using method: this product should, after cotton seedling, in annual gramineous weed 3-5 leaf phase dispenser, be noted to the spraying of weeds cauline leaf evenly.Strong wind sky or estimate rainfall in 1 hour, please don't dispenser.
The invention has the beneficial effects as follows:
(1) broad weed-killing spectrum of the present invention, not only grassy weed is had to good preventive effect, broad-leaved section weeds (as Amaranthus retroflexus, kitchen garden, acalypha copperleaf, field thistle etc.) and sedge weed (as the rhizome of nutgrass flatsedge) etc. are also had to good preventive effect simultaneously.
(2) the present invention, by after composite to Quizalotop-ethyl, halosulfuronmethyl and garlic oil, plays synergistic function, and herbicide effect obviously improves; Especially adding of garlic oil, its synergistic effect is obvious.
(3) the present invention, by having reduced the usage amount of Quizalotop-ethyl and halosulfuronmethyl after composite, passes through the composite of three simultaneously, has reduced key.Alleviated the resistance problem of weed in cotton field to conventional herbicide simultaneously.
(4) garlic oil of the present invention also has certain sterilization, anthelmintic action, and cotton disease is had to certain prevention effect.
Embodiment
Quizalotop-ethyl of the present invention adopts the former medicine of Quizalotop-ethyl (active constituent content >=95%), and halosulfuronmethyl adopts the former medicine of halosulfuronmethyl (active constituent content >=99%).
Embodiment 1:14wt% aqueous emulsion
Proportioning (wt%): Quizalotop-ethyl 10%, halosulfuronmethyl 2.5%, garlic oil 1.5%, No. 150 industrial solvents 8%, agricultural emulsifier NO.600 5%, agriculture breast NP-103%, polyvinyl alcohol 2wt%, ethylene glycol 3wt%, water surplus.
Preparation method: Quizalotop-ethyl, garlic oil, No. 150 industrial solvents, agricultural emulsifier NO.600 and agriculture breast NP-10 are mixed, make it to be dissolved into even oil phase; Halosulfuronmethyl, polyvinyl alcohol and propane diols are added to the water and are mixed, form even water; Under high-speed stirred, water is joined in oil phase, form the aqueous emulsion of favorable dispersibility.
Using method: this product should, after cotton seedling, in annual gramineous weed 3-5 leaf phase dispenser, be noted to the spraying of weeds cauline leaf evenly.According to 50ml/hm
2(effective ingredient consumption is consumption: 7ml/hm
2), 60L/hm adds water
2after fully stirring, carry out even spraying by this area routine techniques.
In Weifang City of Shandong Province, composite (by former medicine in Quizalotop-ethyl single spraying, halosulfuronmethyl single spraying, garlic oil single spraying, Quizalotop-ethyl and halosulfuronmethyl, the compound proportion of Quizalotop-ethyl and halosulfuronmethyl is with embodiment 1) spray as comparative example, carry out field trial.Wherein, Quizalotop-ethyl adopts 15% missible oil; Halosulfuronmethyl adopts 75% water dispersible granules (WDG).In comparative example, the discharge rate of the consumption of active ingredient, water is with embodiment 1, and the control efficiency (being weeds slips) to weeds is as shown in table 1.
The control of weeds effect of table 1 embodiment 1 and comparative example
Herbicide treatment |
Control of weeds effect % |
Embodiment 1 |
88.4 |
Quizalotop-ethyl |
65.3 |
Halosulfuronmethyl |
25.3 |
Garlic oil |
0 |
Quizalotop-ethyl and halosulfuronmethyl are composite |
68.2% |
Embodiment 2:25wt% aqueous emulsion
Proportioning (wt%): Quizalotop-ethyl 18%, halosulfuronmethyl 4%, garlic oil 3%, No. 150 industrial solvents 12%, agricultural emulsifier NO.600 7%, agriculture breast NP-104%, polyvinyl alcohol 3wt%, ethylene glycol 5wt%, water surplus.
Preparation method: with embodiment 1.
Using method: according to 30ml/hm
2consumption, all the other same embodiment.
Embodiment 3:15wt% suspension emulsion
Proportioning (wt%): Quizalotop-ethyl 10%, halosulfuronmethyl 3%, garlic oil 2%, No. 150 industrial solvents 8%, agriculture breast No. 500 6%, Nongru-700 number 2%, polyvinyl alcohol 2wt%, ethylene glycol 3wt%, dodecyl sodium sulfate 2%, organic silicone 0.2%, water surplus.
Preparation method is: Quizalotop-ethyl, garlic oil, No. 150 industrial solvents, No. 500, agriculture breast and Nongru-700s number are mixed, make it to be dissolved into even oil phase; Halosulfuronmethyl, polyvinyl alcohol, dodecyl sodium sulfate, organic silicone and water mixing frosted are made into aqueous suspension agent; Then the oil phase preparing and aqueous suspension agent shearing are uniformly dispersed, make suspension emulsion.
Embodiment 4:20wt% suspension emulsion
Proportioning (wt%): Quizalotop-ethyl 15%, halosulfuronmethyl 4%, garlic oil 2%, No. 150 industrial solvents 10%, agriculture breast No. 500 7%, Nongru-700 number 3%, polyvinyl alcohol 3wt%, ethylene glycol 5wt%, dodecyl sodium sulfate 3%, organic silicone 0.2%, water surplus.
Preparation method is with embodiment 3.
Embodiment 1-4 is as shown in table 2 to the control efficiency of weeds.
The control of weeds effect of table 2 embodiment 1-4
Herbicide treatment |
Control of weeds effect % |
Embodiment 1 |
88.4 |
Embodiment 2 |
85.7 |
Embodiment 3 |
87.2 |
Embodiment 4 |
83.9 |