CN104179319A - Colorized GRC product prepared from multi-grading waste glass and preparation method thereof - Google Patents
Colorized GRC product prepared from multi-grading waste glass and preparation method thereof Download PDFInfo
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- CN104179319A CN104179319A CN201410396972.7A CN201410396972A CN104179319A CN 104179319 A CN104179319 A CN 104179319A CN 201410396972 A CN201410396972 A CN 201410396972A CN 104179319 A CN104179319 A CN 104179319A
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
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Abstract
The invention discloses a colorized GRC product prepared from multi-grading waste glass and a preparation method thereof. The colorized GRC product comprises waste glass composite colorized decorative surface layer and a waste glass composite structural layer. The preparation method comprises the following steps: recycled waste glass is classified according to color, levigated and added to a GRC surface layer so as to prepare the decorative surface layers with specified colors; at the same time, the waste glass with various colors are prepared into fine aggregate and coarse aggregate according to grading so as to prepare the structural layer. According to the invention, the waste glass is adopted to replace aggregate, so that the waste is efficiently utilized, the colorized glass is used as different color tone to replace pigments and to be added to the GRC product, the defects that the pigments are not uniformly distributed and the pollution is serious in the later period are overcome, the artistry of GRC decoration is improved, and various properties of fiber reinforced cement can be improved. The technology is simple, higher economical and environmental benefits are obtained, and high value-added resource utilization is realized.
Description
Technical field
The invention belongs to architectural decoration material field, particularly a kind of multistage cullet of joining is prepared extremely preparation method of colored GRC goods.
Background technology
Glass, as the huge article of consumption figure in daily life, if effectively do not reclaimed and utilize, will become the major pollutants of municipal refuse, has not only wasted resource but also welding.The current cullet recovery utilization rate of China only has 13%, and a large amount of cullet does not also obtain effective recycling.If again as the raw material of burning glass, it is had relatively high expectations to color, kind using cullet, benefit is also not obvious.At present at home, the cullet producing in life, has sub-fraction to arrive waste product gathering station by variety of way and is recycled, and remaining major part is all by environmental sanitation department landfill disposal.Landfill disposal not only makes the resource of a large amount of reproducible utilizations waste, and also will spend a large amount of disposal costs.
In the manufacturing process of GRC goods, a large amount of quartz sand serves as aggregate to be risen and fills and supporting role, and up to 1:1, and quartz sand per kilogram needs 670 yuan of left and right, is main material cost with cement additive ratio.Owing to having added multiple organic or inorganic pigment for playing decorative effect in surface layer, be accompanied by and expose to the weather in actual applications, often there is aberration and fade, greatly affect decorative effect.And cullet is wide in variety, color is abundant.Colored cullet recycling after certain processing is processed, in the production of colored fiber refinforced cement goods, is substituted and is not only conducive to the saving of resource and the consumption of the energy, and can realize the variation of builing industry product and then the reduction of cost.
Owing to containing the amorphous Si O of 70% left and right in glass
2, it has been generally acknowledged that and should not join in cement products, because the SiO in glass aggregate
2may with cement slurry in alkali metal ion generation alkali.And by different from raw glass particle Abrasive glass dust end, there is good activity, so thin glass powder is combined and can be effectively suppressed alkali with raw glass particle.
Summary of the invention
The object of the invention is to cullet recycling problem and the effective combination of GRC decorated articles, the different demands to color, fines and coarse aggregate according to GRC goods surface layer and deck, provide the multistage cullet of joining to prepare colored GRC goods.
The object of the invention is achieved by the following technical programs:
A kind of multistage cullet of joining is prepared colored GRC goods, comprises the composite coloured architectural surface of cullet and cullet composite construction layer.
In the present invention, preferred, the composite coloured architectural surface of cullet refers to the polychromy surface layer being prepared from by the toner in the alternative GRC surface layer of the thin cullet of colour and quartz sand; Described cullet composite construction layer refers to the deck being prepared from by the sand in variegated thin cullet and the alternative GRC deck of variegated thick cullet and quartz sand.
In the present invention, preferred, the particle size range of the described thin cullet of colour is at 0.037 mm ~ 1 mm; The particle size range of described variegated thin cullet is at 0.037 mm ~ 1 mm; The particle size range of described variegated thick cullet is at 1 mm ~ 4.75 mm.
In the present invention, preferably, thin cullet preparation method is as follows for described colour: select the one in sheet glass, bottle glass, medical glass, ware glass, bulb glass, ornamental glass, press color classification (green, brown, blue, purple, redness, yellow, white are transparent), after fragmentation, cleaning, respectively the cullet of particular color and absolute ethyl alcohol are put into the common ball milling 12 ~ 48h of ball mill, obtain the colour thin cullet of particle size range at 0.037 mm ~ 1 mm through screening;
In the present invention, preferably, described variegated thin cullet and variegated thick cullet preparation method are as follows: one or more in sheet glass, bottle glass, medical glass, ware glass, bulb glass, ornamental glass, after fragmentation, cleaning, put into the common ball milling 8 ~ 20h of ball mill with absolute ethyl alcohol, obtain the variegated thin cullet of particle size range at 0.037 mm ~ 1 mm through screening, particle size range is at the variegated thick cullet of 1 mm ~ 4.75 mm.
Multistagely described in the present invention join the preparation method that cullet is prepared colored GRC goods, comprise the following steps:
(1) cement, colored thin cullet, anti-crack fiber, polymer, Admixture and water are mixed according to following weight per distribution ratio, make the composite coloured architectural surface mortar of cullet after stirring, surface layer raw material weight per distribution ratio is as follows:
Cement 20 ~ 55%
Colored thin cullet 15 ~ 50%
Anti-crack fiber 0 ~ 2%
Polymer 0 ~ 2.5%
Admixture 0 ~ 6%
Water 10.5 ~ 20%
Described anti-crack fiber is selected one or several in PVA fiber, PU fiber, PP fiber, nylon fiber, wood fiber, paper pulp fiber;
Described polymer is selected the one in redispersable latex powder, poly-acrylic emulsion, benzene emulsion, Silicone acrylic emulsion;
(2) the composite coloured architectural surface mortar of cullet step 1 being configured, adopt and spray or brush or laying vibratory drilling method, in the mould with decorative effect, make the composite coloured architectural surface of cullet, architectural surface thickness is 3-5mm, spontaneous curing 10-60 minute;
(3) cement, variegated thin cullet, variegated thick cullet, polymer, fiber, Admixture, active material, water are mixed according to following weight per distribution ratio, stir and make cullet composite construction layer mortar, deck raw material weight per distribution ratio is as follows:
Cement 25 ~ 50%
Variegated thin cullet 3 ~ 10%
Variegated thick cullet 20 ~ 50%
Polymer 0 ~ 2.5%
Fiber 3 ~ 5%
Admixture 0 ~ 2%
Active material 4 ~ 10%
Water 11 ~ 18%
Described polymer is selected the one in redispersable latex powder, poly-acrylic emulsion, benzene emulsion, Silicone acrylic emulsion;
Described fiber is one or more in glass fiber, steel fibre, carbon fiber, basalt fibre;
Described active material is a kind of or its mixture in metakaolin, flyash, breeze, stone flour, silicon ash;
(4) cullet composite construction layer mortar step 3 being configured, by spraying or brush or be routed in the mould with the composite coloured architectural surface of cullet that step 2 obtains, adopt scraper plate that slurry is struck off, then use pressure roller to carry out roll-in closely knit, make cullet composite construction layer;
(5) mesh reinforcements is routed in mould, carries out roll extrusion with pressure roller, make it to be absorbed in cullet composite construction layer;
(6) maintenance under the product normal temperature of step 5 forming or steam, after 4 ~ 24 hours, is carried out to the demoulding;
(7) after the demoulding, brush or gunning concrete surface protectant at product surface, after being fully dried, can be made into the multistage cullet of joining and prepare colored GRC goods.
In the present invention, preferred, described Admixture is a kind of or its mixture in water reducing agent, early strength admixture, antifreezing agent, expansion agent, retarding agent; Described water reducing agent is the one in naphthalenesulfonate formaldehyde condensation compound, sulfonated melamine compound condensation product, polycarboxylate water-reducer; Described early strength admixture is selected the one in sulfate, nitrite, triethanolamine; Described antifreezing agent is selected the one in calcium chloride, potash, natrium nitrosum; Described expansion agent is selected one or more in aluminium sulfate, calcium chloride, magnesia class; Described retarding agent is selected the one in wooden calcium, molasses, citric acid.
In the present invention, preferred, the one in acrylic type, silicon the third type, organosilicon type, silicon fluoride type, fluorine carbon type is selected in described concrete surface protecting agent.
Beneficial effect of the present invention is:
1, the multistage cullet of joining is prepared colored GRC goods employing cullet replacement quartz sand, embody the approach of high added value processing cullet, for the recycling of solid waste provides higher economic and social benefit, significantly reduce the cost of product simultaneously.
2, the multistage cullet of joining is prepared colored GRC goods and is adopted colored cullet to replace toner, has overcome the dispersion inequality that organic and inorganic dyestuff in use exists, the problem of stability deficiency, the problems such as fading of causing and aberration that having avoided exposes to the weather.
3, thin cullet and thick cullet are prepared according to a certain ratio to the deck of cement products, can effectively be solved glass product and occur the problem of alkali in cement.
Brief description of the drawings
To be that the embodiment of the present invention is multistage join the generalized section that cullet is prepared colored GRC goods to Fig. 1.
In figure, 1, the architectural surface of colored cullet composite fibre refinforced cement; 2, the deck of cullet composite fibre refinforced cement.
Brief description of the drawings
Fig. 1 is colorful cover-coat enamel GRC decorative building material structural representation by the embodiment of the present invention is obtained;
In figure: 1, GRC matrix, 2, intermediate layer, 3, colorful cover coat.
detailed description of the invention:
embodiment 1
(1) green sheet glass is carried out to fragmentation, cleaning, then the cullet after fragmentation and absolute ethyl alcohol is put into ball mill ball milling 18h jointly, sieve and obtain the thin cullet of green that particle diameter is 0.18 mm;
(2) sheet glass, ware glass and ornamental glass are carried out after fragmentation, cleaning, put into the common ball milling 10h of ball mill with absolute ethyl alcohol, obtaining through screening variegated thin cullet and particle diameter that particle diameter is 0.21 mm is the variegated thick cullet of 3.35 mm.
(3) by cement 50 kg(50%), particle diameter is thin cullet 25.5 kg(25.5% of green of 0.18 mm), PP fiber 2 kg(2%), polymer dispersion powder 1.5 kg(1.5%), naphthalenesulfonate formaldehyde condensation compound water reducing agent 0.5 kg(0.5%), early strength admixture sulfate 1 kg(1%), antifreezing agent calcium chloride 0.5 kg(0.5%), expansion agent aluminium sulfate 4 kg(4%) and water 15 kg(15%) mix according to percentage by weight, stir and make green keynote surface layer mortar.
(4), by the green keynote surface layer mortar configuring, adopt gunite in grinding tool, to make decorative layer, spontaneous curing 10 minutes.
(5) by cement 25kg(25%), particle diameter is variegated thin cullet 10 kg(10% of 0.21 mm), particle diameter is variegated raw glass 43 kg(43% of 3.35 mm), redispersable latex powder 1 kg(1%), glass fiber 3 kg(3%), naphthalenesulfonate formaldehyde condensation compound water reducing agent 0.6 kg(0.6%), early strength admixture sulfate 1 kg(1%), antifreezing agent calcium chloride 0.4 kg(0.4%), breeze 5 kg(5%) and water 11kg(11%) mix according to percentage by weight, stir and make deck mortar.
(6) by the cullet composite construction layer mortar configuring, by being ejected in the mould with the composite coloured architectural surface of cullet, adopt scraper plate that slurry is struck off, then use pressure roller to carry out roll-in closely knit, make cullet composite construction layer;
(7) mesh reinforcements is routed in mould, carries out roll extrusion with pressure roller, make it to be absorbed in cullet composite construction layer;
(8) the product normal temperature maintenance of forming, after 4 hours, is carried out to the demoulding;
(9) after the demoulding, brush the agent of acrylic type concrete surface protecting at product surface, after being fully dried, can be made into the multistage cullet of joining and prepare colored GRC goods.
embodiment 2
(1) blue ornamental glass is carried out to fragmentation, cleaning, then the cullet after fragmentation and absolute ethyl alcohol is put into ball mill ball milling 24h jointly, sieve and obtain the thin cullet of blueness that particle diameter is 0.15 mm;
(2) medical glass, bottle glass and ornamental glass are carried out after fragmentation, cleaning, put into the common ball milling 12h of ball mill with absolute ethyl alcohol, obtaining through screening variegated thin cullet and particle diameter that particle diameter is 0.35 mm is the variegated thick cullet of 4.0 mm.
(3) by cement 55 kg(55%), particle diameter is the thin cullet 15kg(15% of blueness of 0.15 mm), PVA fiber 2 kg(2%), poly-acrylic emulsion 2.5 kg(2.5%), sulfonated melamine compound condensation product water reducing agent 1.5 kg(1.5%), early strength admixture nitrous acid hydrochlorate 0.5 kg(0.5%), antifreezing agent potash 1.2 kg(1.2%), expansion agent calcium chloride 2.3 kg(2.3%) and water 20 kg(20%) according to percentage by weight mixing, stir and make blue keynote surface layer mortar.
(4), by the blue keynote surface layer mortar configuring, adopt spread coating in grinding tool, to make decorative layer, spontaneous curing 20 minutes.
(5) by cement 50 kg(50%), particle diameter is variegated thin cullet 3 kg(3% of 0.35 mm), particle diameter is variegated thick cullet 20 kg(20% of 4.0 mm), poly-acrylic emulsion 1 kg(1%), glass fiber 3kg(3%), steel fibre 2kg(2%), sulfonated melamine compound condensation product water reducing agent 0.5 kg(0.5%), early strength admixture nitrous acid acid 0.5 kg(0.5%), antifreezing agent potash 0.5 kg(0.5%), expansion agent calcium chloride 0.5 kg(0.5%), stone flour 7 kg(7%) and water 12% mix according to percentage by weight, stir and make deck mortar.
(6) by the cullet composite construction layer mortar configuring, by brushing to having in the mould of the composite coloured architectural surface of cullet, adopt scraper plate that slurry is struck off, then use pressure roller to carry out roll-in closely knit, make cullet composite construction layer;
(7) mesh reinforcements is routed in mould, carries out roll extrusion with pressure roller, make it to be absorbed in cullet composite construction layer;
(8) the product normal temperature maintenance of forming, after 24 hours, is carried out to the demoulding;
(9) after the demoulding in the third type concrete surface protecting agent of product surface spray coating silicon, can be made into the multistage cullet of joining after fully dry and prepare colored GRC goods.
case study on implementation 3
(1) brown bottle glass is carried out to fragmentation, cleaning, then the cullet after fragmentation and absolute ethyl alcohol is put into ball mill ball milling 36h jointly, sieve and obtain the brown thin cullet that particle diameter is 0.09 mm;
(2) sheet glass, bottle glass, ware glass and bulb glass are carried out after fragmentation, cleaning, put into the common ball milling 8h of ball mill with absolute ethyl alcohol, obtaining through screening variegated thin cullet and particle diameter that particle diameter is 1 mm is the variegated thick cullet of 4.75 mm.
(3) by cement 20 kg(20%), particle diameter is brown thin cullet 50 kg(50% of 0.09 mm), PU fiber 1.5 kg(1.5%), benzene emulsion 2.5 kg(2.5%), polycarboxylate water-reducer 2.5 kg(2.5%), early strength admixture triethanolamine 2 kg(2%), antifreezing agent natrium nitrosum 0.5 kg(0.5%), expansion agent magnesia 1kg(1%) and water 20 kg(20%) mix according to percentage by weight, stir and make brown keynote surface layer mortar.
(4), by the brown keynote surface layer mortar configuring, adopt laying vibratory drilling method in grinding tool, to make decorative layer, spontaneous curing 30 minutes.
(5) by cement 25kg(25%), particle diameter is variegated thin cullet 4 kg(4% of 1 mm), particle diameter is variegated raw glass 50 kg(50% of 4.75 mm), benzene emulsion 1kg(1%), glass fiber 2kg(2%), carbon fiber 1kg(1%), polycarboxylate water-reducer 0.5kg(0.5%), early strength admixture triethanolamine 0.5 kg(0.5%), antifreezing agent natrium nitrosum 0.5 kg(0.5%), expansion agent magnesia 0.5kg(0.5%), silicon ash 4 kg(4%) and water 11kg(11%) according to percentage by weight mixing, stir and make deck mortar.
(6) by the cullet composite construction layer mortar configuring, be routed in the mould with the composite coloured architectural surface of cullet, adopt scraper plate that slurry is struck off, then use pressure roller to carry out roll-in closely knit, make cullet composite construction layer;
(7) mesh reinforcements is routed in mould, carries out roll extrusion with pressure roller, make it to be absorbed in cullet composite construction layer;
(8) maintenance under the product steam of forming, after 12 hours, is carried out to the demoulding;
(9) after the demoulding, brush organosilicon concrete surface protectant at product surface, after being fully dried, can be made into the multistage cullet of joining and prepare colored GRC goods.
case study on implementation 4
(1) purple bulb glass is carried out to fragmentation, cleaning, then the cullet after fragmentation and absolute ethyl alcohol are put into ball mill ball milling 48h jointly, sieve and obtain the thin cullet of purple that particle diameter is 0.037 mm;
(2) medical glass, sheet glass, bottle glass, ware glass and bulb glass are carried out after fragmentation, cleaning, put into the common ball milling 15h of ball mill with absolute ethyl alcohol, obtaining through screening variegated thin cullet and particle diameter that particle diameter is 0.25 mm is the variegated thick cullet of 2.80 mm.
(3) by cement 45 kg(45%), particle diameter is thin cullet 40 kg(40% of purple of 0.037 mm), Silicone acrylic emulsion 1.5 kg(1.5%), sulfonate sodium formaldehyde condensation products 0.5 kg(0.5%), retarding agent wood calcium 1 kg(1%), antifreezing agent calcium chloride 0.5 kg(0.5%), expansion agent aluminium sulfate 1 kg(1%) and water 10.5 kg(10.5%) according to percentage by weight mixing, stir and make purple keynote surface layer mortar.
(4), by the purple keynote surface layer mortar configuring, adopt gunite in grinding tool, to make decorative layer, spontaneous curing 40 minutes.
(5) by cement 30 kg(30%), particle diameter is variegated thin cullet 6 kg(6% of 0.25 mm), particle diameter is the variegated raw glass 29kg(29% of 2.8 mm), Silicone acrylic emulsion 2 kg(2%), glass fiber 2kg(2%), basalt fibre 2kg (2%), sulfonate sodium formaldehyde condensation products 0.2 kg(0.2%), retarding agent wood calcium 0.3kg(0.3%), antifreezing agent calcium chloride 0.3 kg(0.3%), expansion agent aluminium sulfate 0.2kg(0.2%), flyash 10 kg(10%) and water 18kg(18%) mix according to percentage by weight, stir and make deck mortar.
(6) by the cullet composite construction layer mortar configuring, by spraying or brushing or be routed in the mould with the composite coloured architectural surface of cullet, adopt scraper plate that slurry is struck off, then use pressure roller to carry out roll-in closely knit, make cullet composite construction layer;
(7) mesh reinforcements is routed in mould, carries out roll extrusion with pressure roller, make it to be absorbed in cullet composite construction layer;
(8) maintenance under the product steam of forming, after 24 hours, is carried out to the demoulding;
(9) after the demoulding, brush the agent of silicon fluoride type concrete surface protecting at product surface, after being fully dried, can be made into the multistage cullet of joining and prepare colored GRC goods.
case study on implementation 5
(1) red ornamental glass is carried out to fragmentation, cleaning, then the cullet after fragmentation and absolute ethyl alcohol are put into ball mill ball milling 12h jointly, sieve and obtain the thin cullet of redness that particle diameter is 1 mm;
(2) medical glass, sheet glass, bottle glass, ware glass and bulb glass are carried out after fragmentation, cleaning, put into the common ball milling 20h of ball mill with absolute ethyl alcohol, obtaining through screening variegated thin cullet and particle diameter that particle diameter is 0.037 mm is the variegated thick cullet of 1 mm.
(3) by cement 40 kg(40%), particle diameter is thin cullet 38 kg(38% of redness of 1 mm), nylon fiber 2 kg(2%), sulfonate sodium formaldehyde condensation products 0.5 kg(0.5%), early strength admixture sulfate 1 kg(1%), retarding agent molasses 1.5 kg(1.5%), expansion agent aluminium sulfate 2kg(2%) and water 15 kg(15%) mix according to percentage by weight, stir and make red keynote surface layer mortar.
(4), by the red keynote surface layer mortar configuring, adopt gunite in grinding tool, to make decorative layer, spontaneous curing 50 minutes.
(5) by cement 34 kg(34%), particle diameter is variegated thin cullet 8 kg(8% of 0.037 mm), particle diameter variegated raw glass 33 kg(33% that are 1mm), glass fiber 4 kg(4%), sulfonate sodium formaldehyde condensation products 0.5 kg(0.5%), early strength admixture sulfate 0.5 kg(0.5%), retarding agent molasses 0.5 kg(0.5%), expansion agent aluminium sulfate 0.5kg(0.5%), metakaolin 6 kg(6%) and water 13kg(13%) mix according to percentage by weight, stir and make deck mortar.
(6) by the cullet composite construction layer mortar configuring, by being ejected in the mould with the composite coloured architectural surface of cullet, adopt scraper plate that slurry is struck off, then use pressure roller to carry out roll-in closely knit, make cullet composite construction layer;
(7) mesh reinforcements is routed in mould, carries out roll extrusion with pressure roller, make it to be absorbed in cullet composite construction layer;
(8) the product normal temperature maintenance of forming, after 8 hours, is carried out to the demoulding;
(9) after the demoulding in the agent of product surface spray coating fluorine carbon type concrete surface protecting, can be made into the multistage cullet of joining after fully dry and prepare colored GRC goods.
case study on implementation 6
(1) Transparent color ware glass is carried out to fragmentation, cleaning, then the cullet after fragmentation and absolute ethyl alcohol are put into ball mill ball milling 40h jointly, sieve and obtain the thin cullet of Transparent color that particle diameter is 0.075 mm;
(2) medical glass, sheet glass, bottle glass, ware glass and bulb glass are carried out after fragmentation, cleaning, put into the common ball milling 15h of ball mill with absolute ethyl alcohol, obtaining through screening variegated thin cullet and particle diameter that particle diameter is 0.25 mm is the variegated thick cullet of 2.80 mm.
(3) by cement 38 kg(38%), particle diameter is thin cullet 42 kg(42% of Transparent color of 0.075 mm), wood fiber 1 kg(1%), poly-acrylic emulsion 1 kg(1%) and water 18 kg(18%) according to percentage by weight mixing, stir and make Transparent color keynote surface layer mortar.
(4), by the purple keynote surface layer mortar configuring, adopt gunite in grinding tool, to make decorative layer, spontaneous curing 60 minutes.
(5) by cement 28kg(28%), particle diameter is variegated thin cullet 7 kg(7% of 0.25 mm), particle diameter is variegated raw glass 36 kg(36% of 2.8 mm), poly-acrylic emulsion 1 kg(1%), glass fiber 4 kg(4%), breeze 8 kg(8%) and water 16kg(16%) according to percentage by weight mixing, stir and make deck mortar.
(6) by the cullet composite construction layer mortar configuring, by brushing to having in the mould of the composite coloured architectural surface of cullet, adopt scraper plate that slurry is struck off, then use pressure roller to carry out roll-in closely knit, make cullet composite construction layer;
(7) mesh reinforcements is routed in mould, carries out roll extrusion with pressure roller, make it to be absorbed in cullet composite construction layer;
(8) maintenance under the product steam of forming, after 4 hours, is carried out to the demoulding;
(9) after the demoulding, brush the agent of fluorine carbon type concrete surface protecting at product surface, after being fully dried, can be made into the multistage cullet of joining and prepare colored GRC goods.
case study on implementation 7
(1) amber light bulb glass is carried out to fragmentation, cleaning, then the cullet after fragmentation and absolute ethyl alcohol are put into ball mill ball milling 40h jointly, sieve and obtain the thin cullet of yellow that particle diameter is 0.5mm;
(2) medical glass, sheet glass, bottle glass, ware glass and bulb glass are carried out after fragmentation, cleaning, put into the common ball milling 15h of ball mill with absolute ethyl alcohol, obtaining through screening variegated thin cullet and particle diameter that particle diameter is 0.25 mm is the variegated thick cullet of 2.80 mm.
(3) by cement 46kg(46%), particle diameter is thin cullet 36 kg(36% of yellow of 0.5 mm), paper pulp fiber 0.5 kg(0.5%), benzene emulsion 0.5 kg(0.5%), sulfonate sodium formaldehyde condensation products 0.5 kg(0.5%), early strength admixture sulfate 0.5 kg(0.5%), antifreezing agent calcium chloride 0.5 kg(0.5%), retarding agent citric acid 0.5 kg(0.5%) and water 15 kg(15%) mix according to percentage by weight, stir and make yellow keynote surface layer mortar.
(4), by the purple keynote surface layer mortar configuring, adopt gunite in grinding tool, to make decorative layer, spontaneous curing 15 minutes.
(5) by cement 35 kg(35%), particle diameter is variegated thin cullet 4 kg(4% of 0.25 mm), particle diameter is the variegated raw glass 35kg(35% of 2.8 mm), benzene emulsion 1 kg(1%), glass fiber 3 kg(3%), carbon fiber 2kg(2%), sulfonate sodium formaldehyde condensation products 0.2 kg(0.2%), early strength admixture sulfate 0.2 kg(0.2%), antifreezing agent calcium chloride 0.3 kg(0.3%), retarding agent citric acid 0.3 kg(0.3%), breeze 7 kg(7%) and water 12kg(12%) mix according to percentage by weight, stir and make deck mortar.
(6) by the cullet composite construction layer mortar configuring, by brushing to having in the mould of the composite coloured architectural surface of cullet, adopt scraper plate that slurry is struck off, then use pressure roller to carry out roll-in closely knit, make cullet composite construction layer;
(7) mesh reinforcements is routed in mould, carries out roll extrusion with pressure roller, make it to be absorbed in cullet composite construction layer;
(8) the product normal temperature maintenance of forming, after 4 hours, is carried out to the demoulding;
(9) after the demoulding in the third type concrete surface protecting agent of product surface spray coating silicon, can be made into the multistage cullet of joining after fully dry and prepare colored GRC goods.
case study on implementation 8
(1) white medical glass is carried out to fragmentation, cleaning, then the cullet after fragmentation and absolute ethyl alcohol are put into ball mill ball milling 40h jointly, sieve and obtain the thin cullet of white that particle diameter is 0.7mm;
(2) medical glass, sheet glass, bottle glass, ware glass and bulb glass are carried out after fragmentation, cleaning, put into the common ball milling 15h of ball mill with absolute ethyl alcohol, obtaining through screening variegated thin cullet and particle diameter that particle diameter is 0.25 mm is the variegated thick cullet of 2.80 mm.
(3) by cement 40 kg(40%), particle diameter thin cullet 40 kg(40% of white that are 0.7mm), nylon fiber 1.5 kg(1.5%), Silicone acrylic emulsion 1.5 kg(1.5%), sulfonate sodium formaldehyde condensation products 1.5 kg(1.5%), early strength admixture sulfate 1 kg(1%), antifreezing agent calcium chloride 1.5 kg(1.5%), expansion agent aluminium sulfate 1 kg(1%) and water 12 kg(12%) mix according to percentage by weight, stir and make white color tone surface layer mortar.
(4), by the purple keynote surface layer mortar configuring, adopt gunite in grinding tool, to make decorative layer, spontaneous curing 15 minutes.
(5) by cement 33.5 kg(33.5%), particle diameter is variegated thin cullet 7 kg(7% of 0.25 mm), particle diameter is variegated raw glass 34 kg(34% of 2.8 mm), Silicone acrylic emulsion 1 kg(1%), glass fiber 4 kg(4%), sulfonate sodium formaldehyde condensation products 0.1kg(0.1%), early strength admixture sulfate 0.2kg(0.2%), antifreezing agent calcium chloride 0.1 kg(0.1%), expansion agent aluminium sulfate 0.1 kg(0.1%), metakaolin 5 kg(5%) and water 15kg(15%) mix according to percentage by weight, stir and make deck mortar.
(6) by the cullet composite construction layer mortar configuring, by being ejected in the mould with the composite coloured architectural surface of cullet, adopt scraper plate that slurry is struck off, then use pressure roller to carry out roll-in closely knit, make cullet composite construction layer;
(7) mesh reinforcements is routed in mould, carries out roll extrusion with pressure roller, make it to be absorbed in cullet composite construction layer;
(8) maintenance under the product normal temperature of forming or steam, after 8 hours, is carried out to the demoulding;
(9) after the demoulding in the agent of product surface spray coating organosilicon type concrete surface protecting, can be made into the multistage cullet of joining after fully dry and prepare colored GRC goods.
C) interlayer surfaces that the glaze by the mode of spraying, brushing or pouring glaze, step a being obtained is evenly coated on step b acquisition forms glaze layer, is dried 30 ~ 60 min at 60 ~ 80 DEG C; Repeat, after 3 ~ 5 times, GRC building materials to be preheated to 300 ~ 500
oc, to the glaze layer of interlayer surfaces with selective thermal treatment technology Fast Heating 10-300 s, then in 300 ~ 500
oafter C annealing 60 ~ 120 min, but to room temperature, glaze layer forms colorful cover coat in interlayer surfaces, obtains colorful cover-coat enamel GRC decorative building material.
In the present invention, preferred, described selective thermal treatment technology is by electrical heating or flame heating.
In the present invention, preferred, described electrical heating is silicon molybdenum or Elema heating, and heating-up temperature is 1000 ~ 1500
oc; Described flame is heated to be the one in oxyhydrogen flame, acetylene oxygen flame or methane oxygen flame, and flame temperature is 1500 ~ 2500
oc.
In the present invention, preferred, described glass dust is the one in silicate, borosilicate or plumbite.
In the present invention, preferred, described cementing agent is the one in silicate of soda, gum arabic, polyvinyl alcohol or cellulose.
In the present invention, preferred, described inorganic pigment is the one in cobalt chloride, iron chloride, Cu oxide, cadmium sulfide, manganese chloride, antimony trisulfide.
In the present invention, preferred, described intermediate layer thickness is 5 ~ 50 μ m, and described colorful cover coat thickness is 0.1 ~ 1 mm.
Beneficial effect of the present invention is:
(1) the colorful cover coat of GRC building material surface of the present invention has better mechanical stability, ageing-resistant, resistance to chemical corrosion than traditional organic group coating; Fine and close colorful cover coat can prevent that again liquid and gas permeation from entering GRC building material surface.
(2) colorful cover coat gives GRC goods special decorative effect, and smooth surface and glossiness are high, by adding inorganic pigment, can form abundant color, and beautiful in colour, pattern enriches, and plays good decoration function.
(3) preparation method provided by the invention only carries out selective thermal processing to GRC building material surface; make surperficial glaze Flashmelt; through cooling, annealing after obtain complete, continuous, flawless cover coat; thereby reduce the damage of overall heating to GRC intrinsic performance; simultaneously can energy conservation, reduce production costs, be beneficial to large-scale production.
Detailed description of the invention
Below by specific embodiment, the present invention will be further described.
embodiment 1:
(1) weighing 50 g silicate glass powder is scattered in 50 g distilled water, and add 0.025 g silicate of soda suspending agent and 0.5 g cobalt chloride colorant, above powder mixed and carry out mechanical ball and grind 12 h, obtaining suspending stabilized, finely dispersed glaze after mixture slurry is crossed to 400 mesh sieves.
(2) glaze obtaining is formed to the uniform glaze layer of one deck by the mode of spraying on the surface of GRC matrix, and be placed in 60 DEG C of dry 30 min, dried GRC building materials are preheated to 400 DEG C, oxyhydrogen flame with 1500 DEG C of flame temperatures is evenly ejected into GRC matrix surface, the time of staying is 10 s, make glaze layer rapid melting and be combined with GRC matrix phase, obtaining the approximately 10 thick intermediate layers of μ m.
(3) the glaze slurry by the mode of spraying, step 1 being obtained is evenly coated on the interlayer surfaces formation glaze layer that step 2 obtains, dry 30 ~ 60 min at 60 ~ 80 DEG C, this glazing process circulation 3 times, obtain uniform glaze layer, dried GRC building materials are preheated to 400 DEG C, the oxyhydrogen flame of 1500 DEG C of flame temperatures is evenly ejected into interlayer surfaces glaze layer, and stopping the retention time is 10 s, makes surperficial glaze that optionally Flashmelt occur; When high temperature heat source leaves after melting zone, melten glass is cooling and anneal after 60 min under 400 DEG C of conditions, cools to room temperature with the furnace, and glaze layer forms in interlayer surfaces the colorful cover coat that about 0.1mm is thick, obtains sky blue cover-coat enamel GRC decorative building material.
embodiment 2:
(1) weighing 50 g borosilicate glass powder is scattered in 100 g distilled water, and add 0.05 g polyvinyl alcohol and 1.0 g iron chloride, above powder mixed and carry out mechanical ball and grind 24 h, obtaining suspending stabilized, finely dispersed glaze after mixture slurry is crossed to 600 mesh sieves.
(2) glaze obtaining is formed to the uniform glaze layer of one deck by the mode of brushing on the surface of GRC matrix, and be placed in 80 DEG C of dry 30 min, dried GRC building materials are preheated to 500 DEG C, acetylene oxygen even flame with 2000 DEG C of flame temperatures is ejected into GRC matrix surface, the time of staying is 5 s, make glaze rapid melting and be combined with GRC matrix phase, obtaining the approximately 20 thick intermediate layers of μ m.
(3) the glaze slurry by the mode of brushing, step 1 being obtained is evenly coated on the interlayer surfaces formation glaze layer that step 2 obtains, dry 30 ~ 60 min at 60 ~ 80 DEG C, this glazing process circulation 5 times, form uniform glaze layer in interlayer surfaces, dried GRC goods are preheated to 500 DEG C, the acetylene oxygen even flame of flame temperature 2000 oC is ejected into the glaze layer of interlayer surfaces, stopping the retention time is 50 s, makes surperficial glaze that optionally Flashmelt occur; When high temperature heat source leaves after melting zone, melten glass is cooling and anneal after 90 min under 500 DEG C of conditions, cools to room temperature with the furnace, and glaze layer forms in interlayer surfaces the colorful cover coat that about 1mm is thick, obtains brown cover-coat enamel GRC decorative building material.
embodiment 3:
(1) weighing 50 g lead silicate glass powder is scattered in 25 g distilled water, and add 0.1 g gum arabic suspending agent and 2.5 g Cu oxide colorants, above powder mixed and carry out mechanical ball and grind 48 h, obtaining suspending stabilized, finely dispersed glaze after mixture slurry is crossed to 200 mesh sieves.
(2) glaze obtaining is formed to the uniform glaze of one deck by the mode of drenching glaze on the surface of GRC matrix, and be placed in 70 DEG C of dry 40 min, dried GRC building materials are preheated to 300 DEG C, the Elema of heating-up temperature 1000oC is carried out to surface heating to the glaze of GRC matrix surface, the time of staying is 7 s, make glaze rapid melting and be combined with GRC matrix phase, obtaining the approximately 30 thick intermediate layers of μ m.
(3) the glaze slurry by the mode of pouring glaze, step 1 being obtained is evenly coated on the interlayer surfaces formation glaze layer that step 2 obtains, dry 30 ~ 60 min at 60 ~ 80 DEG C, this glazing process circulation 5 times, obtain uniform glaze layer, dried GRC goods are preheated to 300 DEG C, the Elema of 1000 DEG C of heating-up temperatures is carried out to surface heating to the glaze of interlayer surfaces, and stopping the retention time is 100 s, makes surperficial glaze that optionally Flashmelt occur; When high temperature heat source leaves after melting zone, melten glass is cooling and anneal after 120 min under 300 DEG C of conditions, cools to room temperature with the furnace, and glaze layer forms in interlayer surfaces the colorful cover coat that about 0.8mm is thick, obtains peacock green cover-coat enamel GRC decorative building material.
embodiment 4:
(1) weighing 50 g lead silicate glass powder is scattered in 100 g distilled water, and add 0.1 g gum arabic suspending agent and 2.0 g cadmium sulfides, above powder mixed and carry out mechanical ball and grind 48 h, obtaining suspending stabilized, finely dispersed glaze after mixture slurry is crossed to 400 mesh sieves.
(2) glaze obtaining is formed to the uniform glaze of one deck by the mode of spraying on the surface of GRC matrix, and be placed in 60 DEG C of dry 60 min, dried GRC building materials are preheated to 400 DEG C, the Si-Mo rod of 1500 DEG C of heating-up temperatures is carried out to surface heating to sample, the time of staying is 8 s, make glaze rapid melting and be combined with GRC matrix phase, obtaining the approximately 10 thick intermediate layers of μ m.
(3) the glaze slurry by the mode of spraying, step 1 being obtained is evenly coated on the interlayer surfaces formation glaze layer that step 2 obtains, dry 30 ~ 60 min at 60 ~ 80 DEG C, this glazing process circulation 3 times, obtain uniform glaze layer, dried GRC building materials are preheated to 400 DEG C, the Si-Mo rod of 1500 DEG C of heating-up temperatures is carried out to surface heating to the glaze of interlayer surfaces, and stopping the retention time is 300 s, makes surperficial glaze that optionally Flashmelt occur; When high temperature heat source leaves after melting zone, melten glass is cooling and anneal after 90 min under 400 DEG C of conditions, cools to room temperature with the furnace, and glaze layer forms in interlayer surfaces the colorful cover coat that about 0.4mm is thick, obtains orange-yellow cover-coat enamel GRC decorative building material.
embodiment 5:
(1) weighing 50 g silicate glass powder is scattered in 100 g distilled water, and add 0.025 g cellulose suspending agent and 1.5 g manganese chlorides, above powder mixed and carry out mechanical ball and grind 24 h, obtaining suspending stabilized, finely dispersed glaze after mixture slurry is crossed to 400 mesh sieves.
(2) glaze obtaining is formed to the uniform glaze of one deck by the mode of spraying on the surface of GRC matrix, and be placed in 60 DEG C of dry 60 min, dried GRC building materials are preheated to 400 DEG C, the methane oxygen even flame of 2500 DEG C of flame temperatures is ejected into GRC matrix surface, the time of staying is 9s, make glaze rapid melting and be combined with GRC matrix phase, obtaining the approximately 5 thick intermediate layers of μ m.
(3) the glaze slurry by the mode of spraying, step 1 being obtained is evenly coated on the interlayer surfaces formation glaze layer that step 2 obtains, dry 30 ~ 60 min at 60 ~ 80 DEG C, this glazing process circulation 5 times, obtain uniform glaze layer, dried GRC building materials are preheated to 400 DEG C, the methane oxygen even flame of 2500 DEG C of flame temperatures is sprayed to the glaze layer of interlayer surfaces, stopping the retention time is 100 s, makes surperficial glaze that optionally Flashmelt occur; When high temperature heat source leaves after melting zone, melten glass is cooling and anneal after 120 min under 400 DEG C of conditions, cools to room temperature with the furnace, and glaze layer forms in interlayer surfaces the colorful cover coat that about 0.8mm is thick, obtains darkviolet cover-coat enamel GRC decorative building material.
embodiment 6:
(1) weigh 50 g silicate glass powder and be scattered in 80 g distilled water, and add 0.03 g cellulose and 2g antimony trisulfide, above powder is mixed and carry out mechanical ball and grind 36h.After being crossed to 300 mesh sieves, mixture slurry obtains suspending stabilized, finely dispersed glaze.
(2) glaze obtaining is formed to the uniform glaze of one deck by the mode of brushing on the surface of GRC matrix, and be placed in 70 DEG C of dry 50 min, dried GRC building materials are preheated to 400 DEG C, the Si-Mo rod of 1200 DEG C of heating-up temperatures is carried out to surface heating to sample, the time of staying is 6 s, make glaze rapid melting and be combined with GRC matrix phase, obtaining the approximately 50 thick intermediate layers of μ m.
(3) the glaze slurry by the mode of brushing, step 1 being obtained is evenly coated on the interlayer surfaces formation glaze layer that step 2 obtains, dry 30 ~ 60 min at 60 ~ 80 DEG C, this glazing process circulation 4 times, obtain uniform glaze layer, dried GRC building materials are preheated to 400 DEG C, the Si-Mo rod of 1200 DEG C of heating-up temperatures is carried out to surface heating to glaze, and stopping the retention time is 200 s, makes the glaze of interlayer surfaces that optionally Flashmelt occur; When high temperature heat source leaves after melting zone, melten glass is cooling and anneal after 120 min under 300 DEG C of conditions, cools to room temperature with the furnace, and glaze layer forms in interlayer surfaces the colorful cover coat that about 0.7mm is thick, obtains darkviolet cover-coat enamel GRC decorative building material.
Above embodiment only, for explanation technological thought of the present invention, can not limit protection scope of the present invention with this, every technological thought proposing according to the present invention, and any change of doing on technical scheme basis, within all falling into protection domain of the present invention.
Claims (8)
1. the multistage cullet of joining is prepared colored GRC goods, it is characterized in that, comprises the composite coloured architectural surface of cullet (1) and cullet composite construction layer (2).
2. the multistage cullet of joining according to claim 1 is prepared colored GRC goods, it is characterized in that, the composite coloured architectural surface of described cullet (1) refers to the polychromy surface layer being prepared from by the toner in the alternative GRC surface layer of the thin cullet of colour and quartz sand; Described cullet composite construction layer (2) refers to the deck being prepared from by the sand in variegated thin cullet and the alternative GRC deck of variegated thick cullet and quartz sand.
3. the multistage cullet of joining according to claim 2 is prepared colored GRC goods, it is characterized in that, the thin cullet particle diameter of described colour is 0.037 mm ~ 1 mm; Described variegated thin cullet particle diameter is 0.037 mm ~ 1 mm; Described variegated thick cullet particle diameter is 1 mm ~ 4.75 mm.
4. the multistage cullet of joining according to claim 3 is prepared colored GRC goods, it is characterized in that, the thin cullet of described colour obtains by the following method: by the one in sheet glass, bottle glass, medical glass, ware glass, bulb glass, ornamental glass, press after color classification, after fragmentation, cleaning, respectively the cullet of particular color and absolute ethyl alcohol are put into ball mill ball milling 12 ~ 48h, obtain the colour thin cullet of particle size range at 0.037 mm ~ 1 mm through screening.
5. the multistage cullet of joining according to claim 3 is prepared colored GRC goods, it is characterized in that, described variegated thin cullet and variegated thick cullet obtain by the following method: by one or more in sheet glass, bottle glass, medical glass, ware glass, bulb glass, ornamental glass, after fragmentation, cleaning, put into the common ball milling 8 ~ 20h of ball mill with absolute ethyl alcohol, through screening, particle diameter is the variegated thin cullet of being of 0.037 mm ~ 1 mm, and particle diameter is the variegated thick cullet of being of 1 mm ~ 4.75 mm.
6. multistagely as described in any one in claim 1-5 join the preparation method that cullet is prepared colored GRC goods, it is characterized in that, comprise the following steps:
(1) cement, colored thin cullet, anti-crack fiber, polymer, Admixture and water are mixed according to following weight per distribution ratio, make the composite coloured architectural surface mortar of cullet after stirring, raw material weight per distribution ratio is as follows:
Cement 20% ~ 55%
Colored thin cullet 15 ~ 50%
Anti-crack fiber 0 ~ 2%
Polymer 0 ~ 2.5%
Admixture 0 ~ 6%
Water 10.5 ~ 20%
Described anti-crack fiber is one or several in PVA fiber, PU fiber, PP fiber, nylon fiber, wood fiber, paper pulp fiber;
Described polymer is the one in redispersable latex powder, poly-acrylic emulsion, benzene emulsion, Silicone acrylic emulsion;
(2) the composite coloured architectural surface mortar of cullet step 1 being obtained, adopts and sprays or brush or lay vibratory drilling method, and by prepare the composite coloured architectural surface of cullet with the mould of decorative effect, architectural surface thickness is 3-5mm, spontaneous curing 10-60min;
(3) cement, variegated thin cullet, variegated thick cullet, polymer, fiber, Admixture, active material, water are mixed according to following weight per distribution ratio, stir and make cullet composite construction layer mortar, raw material weight per distribution ratio is as follows:
Cement 25 ~ 50%
Variegated thin cullet 3 ~ 10%
Variegated thick cullet 20 ~ 50%
Polymer 0 ~ 2.5%
Fiber 3 ~ 5%
Admixture 0 ~ 2%
Active material 4 ~ 10%
Water 11 ~ 18%
Described polymer is the one in redispersable latex powder, poly-acrylic emulsion, benzene emulsion, Silicone acrylic emulsion;
Described fiber is one or more in glass fiber, steel fibre, carbon fiber, basalt fibre;
Described active material is one or more in metakaolin, flyash, breeze, stone flour, silicon ash;
(4) cullet composite construction layer mortar step 3 being obtained, by spraying or brush or be routed in the mould with the composite coloured architectural surface of cullet that step 2 obtains, adopt scraper plate that slurry is struck off, then use pressure roller to carry out roll-in closely knit, make cullet composite construction layer;
(5) mesh reinforcements is routed in mould, carries out roll extrusion with pressure roller, it is absorbed in cullet composite construction layer;
(6) mould step 5 being obtained maintenance under normal temperature or steam, after 4 ~ 24 hours, is carried out the demoulding;
(7) after the demoulding, brush or gunning concrete surface protectant at product surface, after being dried, can obtain the multistage cullet of joining and prepare colored GRC goods.
7. the multistage preparation method that cullet is prepared colored GRC goods that joins according to claim 6, is characterized in that,
Described Admixture is one or more in water reducing agent, early strength admixture, antifreezing agent, expansion agent, retarding agent;
Described water reducing agent is the one in naphthalenesulfonate formaldehyde condensation compound, sulfonated melamine compound condensation product, polycarboxylate water-reducer;
Described early strength admixture is the one in sulfate, nitrite, triethanolamine;
Described antifreezing agent is the one in calcium chloride, potash, natrium nitrosum;
Described expansion agent is one or more in aluminium sulfate, calcium chloride, magnesia class;
Described retarding agent is the one in wooden calcium, molasses, citric acid.
8. the multistage preparation method that cullet is prepared colored GRC goods that joins according to claim 7, is characterized in that, described concrete surface protecting agent is the one in acrylic type, silicon the third type, organosilicon type, silicon fluoride type, fluorine carbon type.
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104496318A (en) * | 2014-12-20 | 2015-04-08 | 王小波 | Compression-resistant fireproof plaster mortar and preparation method thereof |
| CN105000850A (en) * | 2015-08-14 | 2015-10-28 | 福州皇家地坪有限公司 | Glass artistic floor |
| CN107902975A (en) * | 2017-12-22 | 2018-04-13 | 南京倍立达新材料系统工程股份有限公司 | A kind of dust-proof stain resistant fiber reinforced cement product and preparation method |
| CN108147743A (en) * | 2017-12-28 | 2018-06-12 | 湖南大学 | A kind of self-compaction glass decoration method for preparing mortar sterilized |
| CN108689664A (en) * | 2018-07-01 | 2018-10-23 | 王丹 | A kind of environment-friendly concrete and preparation method thereof |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN87104465A (en) * | 1987-06-24 | 1988-05-25 | 重庆建筑工程学院 | Use waste glass sintered into granite-like decorative plate |
| KR20010074041A (en) * | 2001-01-08 | 2001-08-04 | 박승범 | Manufacturing Methods of Concrete Interlocking Block and Permeable Concrete Interlocking Block for Roadway and Sidewalk Using Crushed Aggregates from Waste Glasses and Blast Furnace Cement. |
| CN101066837A (en) * | 2007-05-24 | 2007-11-07 | 江苏奥博晶瓷科技有限公司 | Environment friendly heat resistant opal crystalline glass and its prepn process |
| CN101644099A (en) * | 2008-08-05 | 2010-02-10 | 许春雷 | Artificial panel |
-
2014
- 2014-08-14 CN CN201410396972.7A patent/CN104179319B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN87104465A (en) * | 1987-06-24 | 1988-05-25 | 重庆建筑工程学院 | Use waste glass sintered into granite-like decorative plate |
| KR20010074041A (en) * | 2001-01-08 | 2001-08-04 | 박승범 | Manufacturing Methods of Concrete Interlocking Block and Permeable Concrete Interlocking Block for Roadway and Sidewalk Using Crushed Aggregates from Waste Glasses and Blast Furnace Cement. |
| CN101066837A (en) * | 2007-05-24 | 2007-11-07 | 江苏奥博晶瓷科技有限公司 | Environment friendly heat resistant opal crystalline glass and its prepn process |
| CN101644099A (en) * | 2008-08-05 | 2010-02-10 | 许春雷 | Artificial panel |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104496318A (en) * | 2014-12-20 | 2015-04-08 | 王小波 | Compression-resistant fireproof plaster mortar and preparation method thereof |
| CN105000850A (en) * | 2015-08-14 | 2015-10-28 | 福州皇家地坪有限公司 | Glass artistic floor |
| CN109476547A (en) * | 2016-05-24 | 2019-03-15 | 2581776 安大略公司 | Lightweight concrete formulation |
| CN107902975A (en) * | 2017-12-22 | 2018-04-13 | 南京倍立达新材料系统工程股份有限公司 | A kind of dust-proof stain resistant fiber reinforced cement product and preparation method |
| CN107902975B (en) * | 2017-12-22 | 2020-09-22 | 南京倍立达新材料系统工程股份有限公司 | Dustproof contamination-resistant fiber reinforced cement product and preparation method thereof |
| CN108147743A (en) * | 2017-12-28 | 2018-06-12 | 湖南大学 | A kind of self-compaction glass decoration method for preparing mortar sterilized |
| CN108689664A (en) * | 2018-07-01 | 2018-10-23 | 王丹 | A kind of environment-friendly concrete and preparation method thereof |
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