CN104170834B - A kind of Avermectin Imidacloprid granule for pest control - Google Patents
A kind of Avermectin Imidacloprid granule for pest control Download PDFInfo
- Publication number
- CN104170834B CN104170834B CN201410362820.5A CN201410362820A CN104170834B CN 104170834 B CN104170834 B CN 104170834B CN 201410362820 A CN201410362820 A CN 201410362820A CN 104170834 B CN104170834 B CN 104170834B
- Authority
- CN
- China
- Prior art keywords
- avermectin
- imidacloprid
- granule
- pest control
- percentage
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000005906 Imidacloprid Substances 0.000 title claims abstract description 131
- YWTYJOPNNQFBPC-UHFFFAOYSA-N imidacloprid Chemical compound [O-][N+](=O)\N=C1/NCCN1CC1=CC=C(Cl)N=C1 YWTYJOPNNQFBPC-UHFFFAOYSA-N 0.000 title claims abstract description 131
- 229940056881 imidacloprid Drugs 0.000 title claims abstract description 131
- 239000005660 Abamectin Substances 0.000 title claims abstract description 119
- RRZXIRBKKLTSOM-XPNPUAGNSA-N avermectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 RRZXIRBKKLTSOM-XPNPUAGNSA-N 0.000 title claims abstract description 111
- 239000008187 granular material Substances 0.000 title claims abstract description 97
- 241000607479 Yersinia pestis Species 0.000 title claims abstract description 57
- 239000011230 binding agent Substances 0.000 claims abstract description 28
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 17
- 239000003381 stabilizer Substances 0.000 claims abstract description 6
- 238000004040 coloring Methods 0.000 claims abstract description 5
- 239000005648 plant growth regulator Substances 0.000 claims abstract description 5
- 235000010777 Arachis hypogaea Nutrition 0.000 claims description 38
- 235000020232 peanut Nutrition 0.000 claims description 35
- 235000017060 Arachis glabrata Nutrition 0.000 claims description 34
- 235000018262 Arachis monticola Nutrition 0.000 claims description 34
- 239000000203 mixture Substances 0.000 claims description 30
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 16
- 239000004576 sand Substances 0.000 claims description 14
- 230000000361 pesticidal effect Effects 0.000 claims description 9
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims description 8
- 229930006000 Sucrose Natural products 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 7
- 239000003966 growth inhibitor Substances 0.000 claims description 6
- JUQPZRLQQYSMEQ-UHFFFAOYSA-N CI Basic red 9 Chemical compound [Cl-].C1=CC(N)=CC=C1C(C=1C=CC(N)=CC=1)=C1C=CC(=[NH2+])C=C1 JUQPZRLQQYSMEQ-UHFFFAOYSA-N 0.000 claims description 5
- 239000005974 Chlormequat Substances 0.000 claims description 5
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 5
- 229920002472 Starch Polymers 0.000 claims description 5
- RZUBARUFLYGOGC-MTHOTQAESA-L acid fuchsin Chemical compound [Na+].[Na+].[O-]S(=O)(=O)C1=C(N)C(C)=CC(C(=C\2C=C(C(=[NH2+])C=C/2)S([O-])(=O)=O)\C=2C=C(C(N)=CC=2)S([O-])(=O)=O)=C1 RZUBARUFLYGOGC-MTHOTQAESA-L 0.000 claims description 5
- 229940052223 basic fuchsin Drugs 0.000 claims description 5
- JUZXDNPBRPUIOR-UHFFFAOYSA-N chlormequat Chemical group C[N+](C)(C)CCCl JUZXDNPBRPUIOR-UHFFFAOYSA-N 0.000 claims description 5
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 5
- 239000008107 starch Substances 0.000 claims description 5
- 235000019698 starch Nutrition 0.000 claims description 5
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 claims description 5
- 229920001285 xanthan gum Polymers 0.000 claims description 4
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 3
- 229930191978 Gibberellin Natural products 0.000 claims description 3
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 3
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 3
- 229920003064 carboxyethyl cellulose Polymers 0.000 claims description 3
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 3
- -1 carclazyte Chemical compound 0.000 claims description 3
- IXORZMNAPKEEDV-UHFFFAOYSA-N gibberellic acid GA3 Natural products OC(=O)C1C2(C3)CC(=C)C3(O)CCC2C2(C=CC3O)C1C3(C)C(=O)O2 IXORZMNAPKEEDV-UHFFFAOYSA-N 0.000 claims description 3
- 239000003448 gibberellin Substances 0.000 claims description 3
- 229920000609 methyl cellulose Polymers 0.000 claims description 3
- 239000001923 methylcellulose Substances 0.000 claims description 3
- 235000010981 methylcellulose Nutrition 0.000 claims description 3
- 229910021536 Zeolite Inorganic materials 0.000 claims description 2
- 239000003818 cinder Substances 0.000 claims description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 2
- 239000005720 sucrose Substances 0.000 claims description 2
- 239000010457 zeolite Substances 0.000 claims description 2
- 241001553178 Arachis glabrata Species 0.000 claims 1
- 238000002360 preparation method Methods 0.000 abstract description 59
- 239000002917 insecticide Substances 0.000 abstract description 8
- 230000000857 drug effect Effects 0.000 abstract description 6
- 231100000053 low toxicity Toxicity 0.000 abstract description 5
- 238000005516 engineering process Methods 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 239000002689 soil Substances 0.000 description 56
- 239000003814 drug Substances 0.000 description 51
- 238000002156 mixing Methods 0.000 description 44
- 238000000034 method Methods 0.000 description 41
- 230000008569 process Effects 0.000 description 41
- 244000105624 Arachis hypogaea Species 0.000 description 38
- 238000012360 testing method Methods 0.000 description 30
- 230000003449 preventive effect Effects 0.000 description 27
- 238000007599 discharging Methods 0.000 description 22
- 239000007788 liquid Substances 0.000 description 22
- 239000000843 powder Substances 0.000 description 22
- 241000238631 Hexapoda Species 0.000 description 14
- 239000003153 chemical reaction reagent Substances 0.000 description 13
- 239000000463 material Substances 0.000 description 13
- 241000196324 Embryophyta Species 0.000 description 12
- 238000012216 screening Methods 0.000 description 12
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 11
- 235000011613 Pinus brutia Nutrition 0.000 description 11
- 241000018646 Pinus brutia Species 0.000 description 11
- 238000003556 assay Methods 0.000 description 11
- 230000006378 damage Effects 0.000 description 11
- 238000001035 drying Methods 0.000 description 11
- 238000004806 packaging method and process Methods 0.000 description 11
- 239000002245 particle Substances 0.000 description 11
- 238000010298 pulverizing process Methods 0.000 description 11
- 238000003756 stirring Methods 0.000 description 11
- 230000007306 turnover Effects 0.000 description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- 239000011248 coating agent Substances 0.000 description 9
- 230000000749 insecticidal effect Effects 0.000 description 9
- IBSREHMXUMOFBB-JFUDTMANSA-N 5u8924t11h Chemical compound O1[C@@H](C)[C@H](O)[C@@H](OC)C[C@@H]1O[C@@H]1[C@@H](OC)C[C@H](O[C@@H]2C(=C/C[C@@H]3C[C@@H](C[C@@]4(O3)C=C[C@H](C)[C@@H](C(C)C)O4)OC(=O)[C@@H]3C=C(C)[C@@H](O)[C@H]4OC\C([C@@]34O)=C/C=C/[C@@H]2C)/C)O[C@H]1C.C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 IBSREHMXUMOFBB-JFUDTMANSA-N 0.000 description 8
- 241000218475 Agrotis segetum Species 0.000 description 8
- 241000241125 Gryllotalpa gryllotalpa Species 0.000 description 8
- 229950008167 abamectin Drugs 0.000 description 8
- 201000010099 disease Diseases 0.000 description 8
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 8
- 241000243785 Meloidogyne javanica Species 0.000 description 7
- 230000000694 effects Effects 0.000 description 6
- 238000009472 formulation Methods 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 208000024891 symptom Diseases 0.000 description 5
- 235000003276 Apios tuberosa Nutrition 0.000 description 4
- 235000010744 Arachis villosulicarpa Nutrition 0.000 description 4
- DUEPRVBVGDRKAG-UHFFFAOYSA-N carbofuran Chemical compound CNC(=O)OC1=CC=CC2=C1OC(C)(C)C2 DUEPRVBVGDRKAG-UHFFFAOYSA-N 0.000 description 4
- BTCSSZJGUNDROE-UHFFFAOYSA-N gamma-aminobutyric acid Chemical compound NCCCC(O)=O BTCSSZJGUNDROE-UHFFFAOYSA-N 0.000 description 4
- 230000002045 lasting effect Effects 0.000 description 4
- 239000000725 suspension Substances 0.000 description 4
- 239000004255 Butylated hydroxyanisole Substances 0.000 description 3
- 239000004322 Butylated hydroxytoluene Substances 0.000 description 3
- 239000003905 agrochemical Substances 0.000 description 3
- 230000012010 growth Effects 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- OGNSCSPNOLGXSM-UHFFFAOYSA-N (+/-)-DABA Natural products NCCC(N)C(O)=O OGNSCSPNOLGXSM-UHFFFAOYSA-N 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 235000013399 edible fruits Nutrition 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 229960003692 gamma aminobutyric acid Drugs 0.000 description 2
- 230000002147 killing effect Effects 0.000 description 2
- 238000009335 monocropping Methods 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 210000002784 stomach Anatomy 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- XLNZEKHULJKQBA-UHFFFAOYSA-N terbufos Chemical compound CCOP(=S)(OCC)SCSC(C)(C)C XLNZEKHULJKQBA-UHFFFAOYSA-N 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- 241000238876 Acari Species 0.000 description 1
- 241000241395 Anomala corpulenta Species 0.000 description 1
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
- 206010053759 Growth retardation Diseases 0.000 description 1
- 241000346653 Holotrichia parallela Species 0.000 description 1
- 241000244206 Nematoda Species 0.000 description 1
- 206010033799 Paralysis Diseases 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000003958 fumigation Methods 0.000 description 1
- 231100000001 growth retardation Toxicity 0.000 description 1
- 239000003630 growth substance Substances 0.000 description 1
- 238000003306 harvesting Methods 0.000 description 1
- 231100000086 high toxicity Toxicity 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000001665 lethal effect Effects 0.000 description 1
- 244000144972 livestock Species 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- 230000007830 nerve conduction Effects 0.000 description 1
- 230000036403 neuro physiology Effects 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 244000045947 parasite Species 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000009331 sowing Methods 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 230000009885 systemic effect Effects 0.000 description 1
Abstract
The present invention relates to technical field of insecticide, particularly relate to a kind of Avermectin Imidacloprid granule for pest control, the percentage by weight of the component that this granule comprises and each component is as follows: Avermectin 1.0 ~ 2.5%, Imidacloprid 1.0 ~ 2.5%, stabilizing agent 0.5 ~ 2.0%, binding agent 0.1 ~ 0.4%, colouring agent 0.05 ~ 0.2%, plant growth regulator 0.2 ~ 0.5%, carrier 91.9 ~ 97.1%; Avermectin Imidacloprid granule drug effect of the present invention is long, residual quantity is low, safety, low toxicity, low-risk, preparation technology simple, and condition is easily controlled, and is suitable for suitability for industrialized production.
Description
Technical field
The present invention relates to technical field of insecticide, particularly relate to a kind of Avermectin Imidacloprid granule for pest control and preparation method thereof, application process.
Background technology
In recent years, with the adjustment of agricultural structure, peanut progressively expands in the cultivated area of China, and the area of continuous cropping plantation is also increasing, and continuous cropping plantation causes the generation of peanut soil pest to increase the weight of year by year; And in peanut cultivation process, because its seed and fruit is all in soil, for soil insect provides abundant foodstuff and nutrition, so soil insect harm is serious during peanut growth, from being seeded into the whole cultivation of results, be all subject to the harm of soil insect, and this harm increases the weight of day by day, become the key factor affecting peanut growth, especially the soil insect such as mole cricket, grub, black cutworm, root-knot nematode occurs the most serious; According to statistics, peanut generally causes the underproduction 20% ~ 40% because soil insect endangers, and the serious underproduction 70% ~ 80%, even has no harvest, and cause Quality of Peanuts to decline and be unable to estimate especially, soil insect has become the key factor affecting peanut yield, quality and benefits.
At present, the agricultural chemicals of control peanut soil pest is mostly high toxicity agricultural chemicals terbufos, chlopyrifos, carbofuran etc., and this type of agricultural chemicals Long-Time Service causes the problems such as pest resistance to insecticide increase, residue of pesticide, environmental pollution, the benign cycle of the destruction ecological balance.In view of produce in the urgent need to the mankind to environmental concern and the demand to green product, make to select and seek efficient, low toxicity, nuisanceless, efficiency time long, become the task of top priority to the specific insecticide of soil insect.
Summary of the invention
The object of the invention is to overcome the deficiencies in the prior art, there is provided a kind of Avermectin Imidacloprid granule for pest control, Avermectin Imidacloprid granule of the present invention is a kind of efficient, low toxicity, nuisanceless, efficiency time long, to the specific granule of control soil insect.
The present invention is achieved through the following technical solutions.
For an Avermectin Imidacloprid granule for pest control, it is characterized in that: the percentage by weight of the component that this granule comprises and each component is as follows:
The percentage by weight sum of all components is 100%;
Preferably, described a kind of Avermectin Imidacloprid granule for pest control, is characterized in that: the percentage by weight of the component that this granule comprises and each component is as follows:
The percentage by weight sum of all components is 100%;
Wherein, Avermectin and Imidacloprid composition Pesticidal combination, the percentage by weight that Pesticidal combination accounts for granule is 2.5 ~ 4.5%.
Preferably, described Pesticidal combination accounts for the percentage by weight of granule is 2.5 ~ 3.5%.
More preferably, described Pesticidal combination accounts for the percentage by weight of granule is 3%.
Described plant growth regulator is at least one in white sugar, gibberellin, growth inhibitor, chlormequat; The selection of plant growth regulator: the field test results according to each growth regulator is determined, optimal selection is white sugar.
Described binding agent is at least one in starch, sucrose, polyvinyl alcohol, xanthans, carboxymethyl cellulose, carboxyethyl cellulose, Methyl cellulose; The selection of binding agent: select adhesive according to the expulsion rate in product item index, optimum binding agent is polyvinyl alcohol.
Described colouring agent is at least one in basic fuchsin, acid fuchsin, alkaline purple, acid purple; The selection of colouring agent: physical property per sample and the Ministry of Chemical Industry's defined are determined for the color of preparation, and optimal selection is basic fuchsin.
Described carrier is at least one in white carbon, river sand, cinder, carclazyte, zeolite; The selection of carrier: according to the outward appearance of granule, and company's survey report, and carrier is ready availability, optimum carrier is chosen as river sand.
Described stabilizing agent is at least one in triphenyl phosphate, BHT, BHA; The physical property of the selection of stabilizing agent and two kinds of effective ingredient Avermectin and Imidacloprid is closely bound up, and Imidacloprid is stable in neutrality with micro acid medium, slowly decomposes in alkaline medium; Avermectin is to thermally-stabilised, unstable to light, strong acid, highly basic, so BHA and BHT elected as by optimum stabilizing agent.
Preferably, a kind of Avermectin Imidacloprid granule for pest control is for preventing and treating peanut soil pest.
For a preparation method for the Avermectin Imidacloprid granule of pest control, it is characterized in that, comprise the steps:
Step one, the female powder of preparation Avermectin Imidacloprid: former for Avermectin medicine, the former medicine of Imidacloprid, plant growth regulator, stabilizing agent are put into mixing screw by proportioning and be uniformly mixed 15 ~ 20min, the rotating speed of adjustment sorter and batcher, then open airslide disintegrating mill and carry out air-flow crushing, material after pulverizing enters Agravicmixer, again mix 20 ~ 30min, qualified rear discharging, for subsequent use after testing;
Step 2, preparation binder liquid: a certain amount of water is put into mixing screw and is heated to 80 DEG C, then add colouring agent, binding agent successively by proportioning, stir 1 hour, place for subsequent use;
Step 3, the preparation of product: add the binder liquid prepared again after carrier being put into mixer by proportioning, after mixing 10 ~ 15min, drop into the female powder of the A Wei Imidacloprid prepared again and carry out dressing mixing 15 ~ 20min, then drying, screening operation is entered successively, through discharging after the assay was approved, warehouse-in, packaging.
A kind of application process of the Avermectin Imidacloprid granule for pest control, it is characterized in that: first turn over whole soil, make soil particle pine evenly thin, then mix with 10 kilograms of moistening thin sand and soils by 1500 ~ 2000 grams/acre of pharmaceutical quantities, impose in plantation ditch, plant after covering a small amount of soil.
A kind of Avermectin Imidacloprid granule for pest control is for preventing and treating mole cricket, grub, black cutworm, root-knot nematode damage by disease and insect.
Avermectin white or yellow crystal, vapour pressure < 200nPa, fusing point 150-155 DEG C, stable under usual storage requirement, to thermally-stabilised, to light, strong acid, highly basic instability; Be the natural products be separated from edaphon, have insects and mites and tag and stomach poison function have faint fumigation action, without systemic action.Its mechanism of action and general insecticide disturb neurophysiology movable unlike it, stimulate release γ-aminobutyric acid, and γ-aminobutyric acid has inhibitory action to arthropodan nerve conduction, if namely there is paralysis symptom after becoming mite to contact with medicament with larva with insect in mite class, inertia does not take food, dead after 2-4 days; Because not causing insect rapid dehydration, so its lethal effect is slower.Though have direct killing effect to predatism and parasite, because plant surface is residual few, therefore little to the damage of beneficial insect, obvious to root nematode effect.
Imidacloprid white crystal, chemical name: 1-(6-chloro-3-pyridyl ylmethyl)-4,5-dihydro-N-Nitroimidazoline-2-base amine, has wide spectrum, efficient, low toxicity, low-residual, to human body and the livestock feature such as safely, and have tag, stomach toxicity and the multiple drug effect of interior suction.After contacting pests medicament, nervous centralis normal conduction is obstructed, and makes it benumb death; Quick-acting is good, and namely medicine has higher preventive effect one day after, and residual life is long, and drug effect and temperature are just becoming ratio, and temperature is high, good disinsection effect.
Beneficial effect of the present invention is:
(1) obviously, prevention effect is good, and the lasting period is long for two kinds of active principle Avermectin of the present invention and Imidacloprid synergistic function, reduces spraying times and formulation rate, reduces drug cost.
(2) traditional Pesticidal combination is at least 10%, and cost of material is high, and the consumption of Pesticidal combination of the present invention is less than within 5%, can reduce cost of material, and preventing disease and pest effect is than traditional product excellent effect.
(3) the present invention adopts granule on preparation, and product is easy to transport; Easy to use; Because of its not with an organic solvent, free from environmental pollution.
(4) the Avermectin Imidacloprid granule drug effect for pest control of the present invention is long, residual quantity is low, safety, low toxicity, low-risk.
(5) the Avermectin Imidacloprid Preparation Technology of Granules for pest control of the present invention is simple, and condition is easily controlled, and is suitable for suitability for industrialized production.
(6) the Avermectin Imidacloprid granule for pest control of the present invention is only used and is once just had good killing effect to damage by disease and insect such as mole cricket, grub, black cutworm, root-knot nematodes.
Embodiment
Below in conjunction with embodiment, the present invention is further illustrated.
Embodiment 1
For an Avermectin Imidacloprid granule for pest control, it is characterized in that: the percentage by weight of the component that this granule comprises and each component is as follows:
For a preparation method for the Avermectin Imidacloprid granule of pest control, comprise the steps:
Step one, the female powder of preparation Avermectin Imidacloprid: former for Avermectin medicine, the former medicine of Imidacloprid, white sugar, triphenyl phosphate are put into mixing screw by proportioning and be uniformly mixed 17min, the rotating speed of adjustment sorter and batcher, then open airslide disintegrating mill and carry out air-flow crushing, material after pulverizing enters Agravicmixer, again mix 20min, qualified rear discharging, for subsequent use after testing;
Step 2, preparation binder liquid: a certain amount of water is put into mixing screw and is heated to 80 DEG C, then add basic fuchsin, starch successively by proportioning, stir 1 hour, place for subsequent use;
Step 3, the preparation of product: add the binder liquid prepared again after carrier being put into mixer by proportioning, after mixing 10min, drop into the female powder of the A Wei Imidacloprid prepared again and carry out dressing mixing 16min, then drying, screening operation is entered successively, through discharging after the assay was approved, warehouse-in, packaging.
A kind of application process of the Avermectin Imidacloprid granule for pest control, it is characterized in that: first turn over whole soil, make soil particle pine evenly thin, then mix with 10 kilograms of moistening thin sand and soils by 1500 grams/acre of pharmaceutical quantities, impose in plantation ditch, plant after covering a small amount of soil.
Embodiment 2
For an Avermectin Imidacloprid granule for pest control, it is characterized in that: the percentage by weight of the component that this granule comprises and each component is as follows:
For a preparation method for the Avermectin Imidacloprid granule of pest control, comprise the steps:
Step one, the female powder of preparation Avermectin Imidacloprid: former for Avermectin medicine, the former medicine of Imidacloprid, growth inhibitor, BHT are put into mixing screw by proportioning and be uniformly mixed 19min, the rotating speed of adjustment sorter and batcher, then open airslide disintegrating mill and carry out air-flow crushing, material after pulverizing enters Agravicmixer, again mix 24min, qualified rear discharging, for subsequent use after testing;
Step 2, preparation binder liquid: a certain amount of water is put into mixing screw and is heated to 80 DEG C, then add alkaline purple, starch successively by proportioning, stir 1 hour, place for subsequent use;
Step 3, the preparation of product: add the binder liquid prepared again after carrier being put into mixer by proportioning, after mixing 13min, drop into the female powder of the A Wei Imidacloprid prepared again and carry out dressing mixing 15min, then drying, screening operation is entered successively, through discharging after the assay was approved, warehouse-in, packaging.
A kind of application process of the Avermectin Imidacloprid granule for pest control, it is characterized in that: first turn over whole soil, make soil particle pine evenly thin, then mix with 10 kilograms of moistening thin sand and soils by 1600 grams/acre of pharmaceutical quantities, impose in plantation ditch, plant after covering a small amount of soil.
Embodiment 3
For an Avermectin Imidacloprid granule for pest control, the percentage by weight of its component comprised and each component is as follows:
For a preparation method for the Avermectin Imidacloprid granule of pest control, comprise the steps:
Step one, the female powder of preparation Avermectin Imidacloprid: former for Avermectin medicine, the former medicine of Imidacloprid, chlormequat, BHA are put into mixing screw by proportioning and be uniformly mixed 15min, the rotating speed of adjustment sorter and batcher, then open airslide disintegrating mill and carry out air-flow crushing, material after pulverizing enters Agravicmixer, again mix 22min, qualified rear discharging, for subsequent use after testing;
Step 2, preparation binder liquid: a certain amount of water is put into mixing screw and is heated to 80 DEG C, then add acid fuchsin, xanthans successively by proportioning, stir 1 hour, place for subsequent use;
Step 3, the preparation of product: add the binder liquid prepared again after carrier being put into mixer by proportioning, after mixing 10min, drop into the female powder of the A Wei Imidacloprid prepared again and carry out dressing mixing 15min, then drying, screening operation is entered successively, through discharging after the assay was approved, warehouse-in, packaging.
A kind of application process of the Avermectin Imidacloprid granule for pest control, it is characterized in that: first turn over whole soil, make soil particle pine evenly thin, then mix with 10 kilograms of moistening thin sand and soils by 1650 grams/acre of pharmaceutical quantities, impose in plantation ditch, plant after covering a small amount of soil.
Embodiment 4
For an Avermectin Imidacloprid granule for pest control, the percentage by weight of its component comprised and each component is as follows:
For a preparation method for the Avermectin Imidacloprid granule of pest control, comprise the steps:
Step one, the female powder of preparation Avermectin Imidacloprid: former for Avermectin medicine, the former medicine of Imidacloprid, gibberellin, BHT are put into mixing screw by proportioning and be uniformly mixed 18min, the rotating speed of adjustment sorter and batcher, then open airslide disintegrating mill and carry out air-flow crushing, material after pulverizing enters Agravicmixer, again mix 20min, qualified rear discharging, for subsequent use after testing;
Step 2, preparation binder liquid: a certain amount of water is put into mixing screw and is heated to 80 DEG C, then add acid purple, polyvinyl alcohol successively by proportioning, stir 1 hour, place for subsequent use;
Step 3, the preparation of product: add the binder liquid prepared again after carrier being put into mixer by proportioning, after mixing 13min, drop into the female powder of the A Wei Imidacloprid prepared again and carry out dressing mixing 17min, then drying, screening operation is entered successively, through discharging after the assay was approved, warehouse-in, packaging.
A kind of application process of the Avermectin Imidacloprid granule for pest control, it is characterized in that: first turn over whole soil, make soil particle pine evenly thin, then mix with 10 kilograms of moistening thin sand and soils by 1550 grams/acre of pharmaceutical quantities, impose in plantation ditch, plant after covering a small amount of soil.
Embodiment 5
For an Avermectin Imidacloprid granule for pest control, the percentage by weight of its component comprised and each component is as follows:
For a preparation method for the Avermectin Imidacloprid granule of pest control, comprise the steps:
Step one, the female powder of preparation Avermectin Imidacloprid: former for Avermectin medicine, the former medicine of Imidacloprid, growth inhibitor, triphenyl phosphate are put into mixing screw by proportioning and be uniformly mixed 17min, the rotating speed of adjustment sorter and batcher, then open airslide disintegrating mill and carry out air-flow crushing, material after pulverizing enters Agravicmixer, again mix 25min, qualified rear discharging, for subsequent use after testing;
Step 2, preparation binder liquid: a certain amount of water is put into mixing screw and is heated to 80 DEG C, then add acid fuchsin, carboxymethyl cellulose successively by proportioning, stir 1 hour, place for subsequent use;
Step 3, the preparation of product: add the binder liquid prepared again after carrier being put into mixer by proportioning, after mixing 15min, drop into the female powder of the A Wei Imidacloprid prepared again and carry out dressing mixing 19min, then drying, screening operation is entered successively, through discharging after the assay was approved, warehouse-in, packaging.
A kind of application process of the Avermectin Imidacloprid granule for pest control, it is characterized in that: first turn over whole soil, make soil particle pine evenly thin, then mix with 10 kilograms of moistening thin sand and soils by 1750 grams/acre of pharmaceutical quantities, impose in plantation ditch, plant after covering a small amount of soil.
Embodiment 6
For an Avermectin Imidacloprid granule for pest control, the percentage by weight of its component comprised and each component is as follows:
For a preparation method for the Avermectin Imidacloprid granule of pest control, comprise the steps:
Step one, the female powder of preparation Avermectin Imidacloprid: former for Avermectin medicine, the former medicine of Imidacloprid, chlormequat, BHA are put into mixing screw by proportioning and be uniformly mixed 16min, the rotating speed of adjustment sorter and batcher, then open airslide disintegrating mill and carry out air-flow crushing, material after pulverizing enters Agravicmixer, again mix 22min, qualified rear discharging, for subsequent use after testing;
Step 2, preparation binder liquid: a certain amount of water is put into mixing screw and is heated to 80 DEG C, then add alkaline purple, carboxyethyl cellulose successively by proportioning, stir 1 hour, place for subsequent use;
Step 3, the preparation of product: add the binder liquid prepared again after carrier being put into mixer by proportioning, after mixing 12min, drop into the female powder of the A Wei Imidacloprid prepared again and carry out dressing mixing 16min, then drying, screening operation is entered successively, through discharging after the assay was approved, warehouse-in, packaging.
A kind of application process of the Avermectin Imidacloprid granule for pest control, it is characterized in that: first turn over whole soil, make soil particle pine evenly thin, then mix with 10 kilograms of moistening thin sand and soils by 1850 grams/acre of pharmaceutical quantities, impose in plantation ditch, plant after covering a small amount of soil.
Embodiment 7
For an Avermectin Imidacloprid granule for pest control, the percentage by weight of its component comprised and each component is as follows:
For a preparation method for the Avermectin Imidacloprid granule of pest control, comprise the steps:
Step one, the female powder of preparation Avermectin Imidacloprid: former for Avermectin medicine, the former medicine of Imidacloprid, white sugar, BHA are put into mixing screw by proportioning and be uniformly mixed 15min, the rotating speed of adjustment sorter and batcher, then open airslide disintegrating mill and carry out air-flow crushing, material after pulverizing enters Agravicmixer, again mix 24min, qualified rear discharging, for subsequent use after testing;
Step 2, preparation binder liquid: a certain amount of water is put into mixing screw and is heated to 80 DEG C, then add basic fuchsin, Methyl cellulose successively by proportioning, stir 1 hour, place for subsequent use;
Step 3, the preparation of product: add the binder liquid prepared again after carrier being put into mixer by proportioning, after mixing 15min, drop into the female powder of the A Wei Imidacloprid prepared again and carry out dressing mixing 18min, then drying, screening operation is entered successively, through discharging after the assay was approved, warehouse-in, packaging.
A kind of application process of the Avermectin Imidacloprid granule for pest control, it is characterized in that: first turn over whole soil, make soil particle pine evenly thin, then mix with 10 kilograms of moistening thin sand and soils by 1700 grams/acre of pharmaceutical quantities, impose in plantation ditch, plant after covering a small amount of soil.
Embodiment 8
For an Avermectin Imidacloprid granule for pest control, the percentage by weight of its component comprised and each component is as follows:
For a preparation method for the Avermectin Imidacloprid granule of pest control, comprise the steps:
Step one, the female powder of preparation Avermectin Imidacloprid: former for Avermectin medicine, the former medicine of Imidacloprid, chlormequat, BHT are put into mixing screw by proportioning and be uniformly mixed 20min, the rotating speed of adjustment sorter and batcher, then open airslide disintegrating mill and carry out air-flow crushing, material after pulverizing enters Agravicmixer, again mix 20min, qualified rear discharging, for subsequent use after testing;
Step 2, preparation binder liquid: a certain amount of water is put into mixing screw and is heated to 80 DEG C, then add acid purple, xanthans successively by proportioning, stir 1 hour, place for subsequent use;
Step 3, the preparation of product: add the binder liquid prepared again after carrier being put into mixer by proportioning, after mixing 14min, drop into the female powder of the A Wei Imidacloprid prepared again and carry out dressing mixing 19min, then drying, screening operation is entered successively, through discharging after the assay was approved, warehouse-in, packaging.
A kind of application process of the Avermectin Imidacloprid granule for pest control, it is characterized in that: first turn over whole soil, make soil particle pine evenly thin, then mix with 10 kilograms of moistening thin sand and soils by 1600 grams/acre of pharmaceutical quantities, impose in plantation ditch, plant after covering a small amount of soil.
Embodiment 9
For an Avermectin Imidacloprid granule for pest control, the percentage by weight of its component comprised and each component is as follows:
For a preparation method for the Avermectin Imidacloprid granule of pest control, comprise the steps:
Step one, the female powder of preparation Avermectin Imidacloprid: former for Avermectin medicine, the former medicine of Imidacloprid, white sugar, triphenyl phosphate are put into mixing screw by proportioning and be uniformly mixed 19min, the rotating speed of adjustment sorter and batcher, then open airslide disintegrating mill and carry out air-flow crushing, material after pulverizing enters Agravicmixer, again mix 23min, qualified rear discharging, for subsequent use after testing;
Step 2, preparation binder liquid: a certain amount of water is put into mixing screw and is heated to 80 DEG C, then add acid fuchsin, starch successively by proportioning, stir 1 hour, place for subsequent use;
Step 3, the preparation of product: add the binder liquid prepared again after carrier being put into mixer by proportioning, after mixing 15min, drop into the female powder of the A Wei Imidacloprid prepared again and carry out dressing mixing 19min, then drying, screening operation is entered successively, through discharging after the assay was approved, warehouse-in, packaging.
A kind of application process of the Avermectin Imidacloprid granule for pest control, it is characterized in that: first turn over whole soil, make soil particle pine evenly thin, then mix with 10 kilograms of moistening thin sand and soils by 1900 grams/acre of pharmaceutical quantities, impose in plantation ditch, plant after covering a small amount of soil.
Embodiment 10
For an Avermectin Imidacloprid granule for pest control, the percentage by weight of its component comprised and each component is as follows:
For a preparation method for the Avermectin Imidacloprid granule of pest control, comprise the steps:
Step one, the female powder of preparation Avermectin Imidacloprid: former for Avermectin medicine, the former medicine of Imidacloprid, growth inhibitor, BHA are put into mixing screw by proportioning and be uniformly mixed 17min, the rotating speed of adjustment sorter and batcher, then open airslide disintegrating mill and carry out air-flow crushing, material after pulverizing enters Agravicmixer, again mix 25min, qualified rear discharging, for subsequent use after testing;
Step 2, preparation binder liquid: a certain amount of water is put into mixing screw and is heated to 80 DEG C, then add alkaline purple, polyvinyl alcohol successively by proportioning, stir 1 hour, place for subsequent use;
Step 3, the preparation of product: add the binder liquid prepared again after carrier being put into mixer by proportioning, after mixing 15min, drop into the female powder of the A Wei Imidacloprid prepared again and carry out dressing mixing 16min, then drying, screening operation is entered successively, through discharging after the assay was approved, warehouse-in, packaging.
A kind of application process of the Avermectin Imidacloprid granule for pest control, it is characterized in that: first turn over whole soil, make soil particle pine evenly thin, then mix with 10 kilograms of moistening thin sand and soils by 1850 grams/acre of pharmaceutical quantities, impose in plantation ditch, plant after covering a small amount of soil.
To the performance test of the Avermectin Imidacloprid granule of embodiments of the invention 1 ~ 10
Avermectin Imidacloprid granule is to the indoor compounded formula screening of grub
Table 1 Avermectin and Imidacloprid different ratio grub toxicity index and co-toxicity coefficient analysis result
Can learn from table 1, in five reagent agent proportionings, Avermectin and Imidacloprid weight ratio all show as synergistic effect when being 1.5/4.5,1.5/3.0,1.5/1.5,3.0/1.5,4.5/1.5, when wherein weight ratio is 1.5/1.5, co-toxicity coefficient is maximum in five test proportionings, and synergy is the most remarkable.
Avermectin Imidacloprid granule is to peanut Security test
Table 2 Avermectin Imidacloprid granule is to 20 days results after the various medicine of peanut
Can learn from table 2: reagent agent Avermectin Imidacloprid granule 300,600,1200gai/667m
2do not affect the growth of three peanut varieties under dosage, also do not observe the symptom of chemical damage such as the change of leaf look, leaf distortion, growth retardation, it is safe for illustrating that Avermectin Imidacloprid granule uses on peanut.
The test of Avermectin Imidacloprid granule control peanut grub
Table 3 Avermectin Imidacloprid granule is to the result of the test of peanut grub
Result of the test (table 3) shows, test medicine Avermectin Imidacloprid granule quick-acting is poor, 20d after medicine, its preparation consumption 1000,1500,2000 grams/acre process is respectively 58.67%, 65.18%, 72.31% to the insecticidal effect of peanut grub.40d after medicine, the insecticidal effect of its basic, normal, high dosage process to peanut grub is respectively 75.94%, 94.10%, 100.00%, three process preventive effect significant differences; Middle and high dosage process preventive effect with contrast medicament 0.5% Abamectin preparation consumption 4000 grams/acre and process the equal significant difference of preventive effect that (73.81%) and 600 grams per liter Imidacloprid suspended seed coating agent formulation consumptions 30 milliliters/mu process (74.12%).
To sum up analyze visible, Avermectin Imidacloprid granule quick-acting is poor, but the lasting period is long, only dispenser in sowing time can have good insecticidal effect to peanut grub (mixed population such as Holotrichia parallela, anomala corpulenta) 1 time, also better to the fruit retention effect of peanut pod.The dispenser of Avermectin Imidacloprid granule is convenient, and has no symptom of chemical damage within the scope of test dose, to peanut safety, is the outstanding insecticide of control peanut grub, can registers use; Field recommends preparation consumption to be 1500-2000 gram/acre.
The test of Avermectin Imidacloprid granule control peanut black cutworm
Table 4 Avermectin Imidacloprid granule is to the result of the test of peanut black cutworm
Result of the test (table 4) shows, reagent agent Avermectin Imidacloprid granule quick-acting is poor, 20d after medicine, its preparation consumption 1000,1500,2000 grams/acre process is respectively 59.84%, 62.34%, 70.77%% to the insecticidal effect of peanut black cutworm, middle and high dosage process and in, low dosage process preventive effect is suitable between two, without significant difference; Reagent agent respectively processes preventive effect and contrasts medicament 0.5% Abamectin preparation consumption 4000 grams/acre and process (75.54%) and 600 grams per liter Imidacloprid suspended seed coating agent formulation consumptions 30 milliliters/mu to process the preventive effect of (64.28%) all suitable, without significant difference.40d after medicine, the insecticidal effect of its basic, normal, high dosage process is respectively 83.19%, 90.25%, 92.13%, and middle and high dosage process preventive effect is suitable, and higher than low dosage process preventive effect; High dose process preventive effect with contrast medicament 0.5% Abamectin preparation consumption 4000 grams/acre and process the preventive effect significant difference that (63.04%) and 600 grams per liter Imidacloprid suspended seed coating agent formulation consumptions 30 milliliters/mu process (66.19%); Median dose process preventive effect and the preventive effect significant difference contrasting medicament 600 grams per liter Imidacloprid suspension seed-coating agent.
To sum up analyze visible, Avermectin Imidacloprid granule has good insecticidal effect to peanut black cutworm, and quick-acting is poor, but lasting effect is better, and along with the prolongation of spraying time, drug effect improves gradually.And symptom of chemical damage is had no within the scope of test dose, to peanut safety, be the good insecticide of control peanut black cutworm, can use be registered; Field recommends preparation consumption to be 1500-2000 gram/acre.
The test of Avermectin Imidacloprid granule control peanut mole cricket
Table 5 Avermectin Imidacloprid granule is to the result of the test of peanut mole cricket
Result of the test (table 5) shows, reagent agent Avermectin Imidacloprid granule quick-acting is poor, 20d after medicine, its preparation consumption 1000,1500,2000 grams/acre process is respectively 61.44%, 63.53%, 74.23% to the insecticidal effect of peanut mole cricket, in, the preventive effect of low dosage process and contrast medicament 0.5% Abamectin preparation consumption 4000 grams/acre of process (65.80%) is suitable; To process the preventive effect of (71.46%) suitable with contrasting medicament 600 grams per liter Imidacloprid suspended seed coating agent formulation consumption 30 milliliters/mu, without significant difference for high dose process preventive effect.40d after medicine, the insecticidal effect of its basic, normal, high dosage process is respectively 80.76%, 88.27%, 93.18%, the equal significant difference of preventive effect of high, medium and low dosage process contrast medicament 0.5% Abamectin 4000 grams/acre of process (69.52%) and 600 grams per liter Imidacloprid suspended seed coating agent formulation consumptions, 30 milliliters of/mu of process (72.02%).
To sum up analyze visible, Avermectin Imidacloprid granule has good insecticidal effect to peanut mole cricket, quick-acting is poor, but lasting effect is better, along with the prolongation of spraying time, drug effect improves gradually, the dispenser of Avermectin Imidacloprid granule is convenient, and within the scope of test dose, has no symptom of chemical damage, to peanut safety, be the good insecticide of control peanut mole cricket, can use be registered; Field recommends preparation consumption to be 1500-2000 gram/acre.
Avermectin Imidacloprid granule prevents and treats the test of groundnut root knot nematode disease
Table 6, Avermectin Imidacloprid granule groundnut root knot nematode disease result of the test
Result of the test (table 6) shows, after dispenser 2 months, is 62.63%-84.54% for medicine reagent Avermectin Imidacloprid granule preventive effect.In 0.05 level, the preventive effect of high dose (2000 grams/acre) reagent agent Avermectin Imidacloprid granule is significantly higher than the preventive effect contrasting medicament 0.5% Abamectin (4000 grams/acre), contrast medicament 600 grams per liter Imidacloprid suspension seed-coating agent (30ml/30 jin seed), contrast medicament 3% carbofuran granule (3000 grams/acre) and low dosage (1000 grams/acre) reagent agent 3% Avermectin Imidacloprid granule; The preventive effect of middle dosage reagent agent is significantly higher than the preventive effect of contrast medicament 600 grams per liter Imidacloprid suspension seed-coating agent, contrast medicament 3% carbofuran granule and low dosage reagent agent preventive effect, contrast medicament 0.5% Abamectin; The preventive effect of low dosage reagent agent is significantly higher than contrast medicament 600 grams per liter Imidacloprid suspension seed-coating agent; With the preventive effect contrasting medicament 3% carbofuran granule and contrast medicament 0.5% Abamectin quite, significantly lower than the preventive effect of high dose, middle dosage reagent agent.In 0.01 level, the significance of difference between the preventive effect of each dosage reagent agent, they with the significance of difference respectively contrasted between pharmacy control efficacy all to have similar trend during 0.05 level.Under the dosage for examination, do not observe poisoning phenomenon.Therefore, Avermectin Imidacloprid granule can prevent and treat groundnut root knot nematode disease effectively, significantly can reduce the disease index of groundnut root knot nematode disease, and using dosage is 1500-2000 gram/acre.
The above embodiment, just better embodiment of the present invention, be not limit the scope of the present invention, therefore all equivalences done according to structure, feature and the principle described in the present patent application the scope of the claims change or modify, and all should comprise in patent claim of the present invention.
Claims (7)
1. the Avermectin Imidacloprid granule for pest control is used for a control of grubs, it is characterized in that: the percentage by weight of the component that this granule comprises and each component is as follows:
The percentage by weight sum of all components is 100%;
Wherein, Avermectin and Imidacloprid composition Pesticidal combination, the percentage by weight that Pesticidal combination accounts for granule is 2.5 ~ 4.5%; The weight ratio of Avermectin and Imidacloprid is 1.5/3.0,1.5/1.5,3.0/1.5 or 4.5/1.5;
Described plant growth regulator is at least one in white sugar, gibberellin, growth inhibitor;
Described binding agent is at least one in starch, sucrose, polyvinyl alcohol, xanthans, carboxymethyl cellulose, carboxyethyl cellulose, Methyl cellulose.
2. a kind of Avermectin Imidacloprid granule for pest control according to claim 1 is used for control of grubs, it is characterized in that: described growth inhibitor is chlormequat.
3. a kind of Avermectin Imidacloprid granule for pest control according to claim 1 is used for control of grubs, it is characterized in that: the percentage by weight of the component that this granule comprises and each component is as follows:
The percentage by weight sum of all components is 100%.
4. a kind of Avermectin Imidacloprid granule for pest control according to claim 1 is used for control of grubs, it is characterized in that: the percentage by weight that described Pesticidal combination accounts for granule is 2.5 ~ 3.5%.
5. a kind of Avermectin Imidacloprid granule for pest control according to claim 1 is used for control of grubs, it is characterized in that: described colouring agent is at least one in basic fuchsin, acid fuchsin, alkaline purple, acid purple.
6. a kind of Avermectin Imidacloprid granule for pest control according to claim 1 is used for control of grubs, it is characterized in that: described stabilizing agent is at least one in triphenyl phosphate, BHT, BHA; Described carrier is at least one in white carbon, river sand, cinder, carclazyte, zeolite.
7. a kind of Avermectin Imidacloprid granule for pest control according to claim 1 is used for control of grubs, it is characterized in that: for preventing and treating peanut underground grub.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410362820.5A CN104170834B (en) | 2014-07-28 | 2014-07-28 | A kind of Avermectin Imidacloprid granule for pest control |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410362820.5A CN104170834B (en) | 2014-07-28 | 2014-07-28 | A kind of Avermectin Imidacloprid granule for pest control |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104170834A CN104170834A (en) | 2014-12-03 |
| CN104170834B true CN104170834B (en) | 2016-04-20 |
Family
ID=51952406
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410362820.5A Active CN104170834B (en) | 2014-07-28 | 2014-07-28 | A kind of Avermectin Imidacloprid granule for pest control |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104170834B (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104814030A (en) * | 2015-04-16 | 2015-08-05 | 山东省花生研究所 | Peanut pest and disease preventing compound synergist |
| GB2541374B (en) * | 2015-08-11 | 2020-04-22 | Rotam Agrochem Int Co Ltd | Synergistic insecticidal composition |
| CN106305780A (en) * | 2016-08-18 | 2017-01-11 | 广西鑫雅皇庭园林工程有限责任公司 | Pesticide for Hibiscus root-knot nematode disease |
| CN107027800A (en) * | 2017-05-26 | 2017-08-11 | 河北威远生化农药有限公司 | A kind of Pesticidal combination containing avermectin B2a |
| CN107279172A (en) * | 2017-06-29 | 2017-10-24 | 山东大农药业有限公司 | A kind of granule containing AVM and imidacloprid |
| CN112425606A (en) * | 2019-08-26 | 2021-03-02 | 北京市农林科学院 | Insecticidal composition for synergistic control of Aphis vinosa |
| CN114766501A (en) * | 2022-04-27 | 2022-07-22 | 四川眉山凯尔化工有限公司 | Process for preparing multifunctional biological insecticide |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1291651C (en) * | 2005-08-11 | 2006-12-27 | 西北农林科技大学无公害农药研究服务中心 | Liquid formulation containing imidacloprid for trunk injection |
| CN1961670A (en) * | 2005-11-11 | 2007-05-16 | 周弘 | Coated coccid killing medicinal liquid used for plant shooting and leaf surface and mixing preparation method thereof |
| CN1985596A (en) * | 2005-12-20 | 2007-06-27 | 云南农业大学 | Water-base microemulsion preparation of re-compounded imidacloprid and abamectin |
| CN1810117A (en) * | 2006-02-21 | 2006-08-02 | 史锡洪 | Wettable powder of 1.8% concentration of abamectin and imidacloprid and its prepn |
| CN101703066A (en) * | 2009-09-27 | 2010-05-12 | 广西田园生化股份有限公司 | Ultralow-volume compound medicament for preventing and controlling cotton aphids |
| CN103918700B (en) * | 2014-03-28 | 2016-02-24 | 海南力智生物工程有限责任公司 | A kind of desinsection particle and its preparation method and application |
-
2014
- 2014-07-28 CN CN201410362820.5A patent/CN104170834B/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN104170834A (en) | 2014-12-03 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104170834B (en) | A kind of Avermectin Imidacloprid granule for pest control | |
| CN102515936A (en) | Granular formulation for paddy pesticide fertilizer and preparation method thereof | |
| CN102805097A (en) | Granules containing monosultap and thiamethoxam | |
| CN101983564A (en) | Suspended seed coating agent for treatment of seeds | |
| CN104686537A (en) | Compound nematode killing composition containing abamectin and amino-oligosaccharin and preparation method of composition | |
| CN105613490A (en) | Attractant for grub imagoes | |
| CN111454092A (en) | Broad-spectrum intelligent controlled-release pesticide fertilizer granule and preparation method and application thereof | |
| CN103030475A (en) | Sugarcane pesticide fertilizer granule containing thiamethoxam and preparation method thereof | |
| CN104938528B (en) | A kind of termite-killing trapping medicament and preparation method | |
| CN105272630A (en) | Method for preparing fertilizer capable of controlling soil crop pests | |
| CN102771503A (en) | Granule containing chitin | |
| CN103749555A (en) | Toxic bait pesticide | |
| CN102972430A (en) | Insecticidal composition containing thiamethoxam and acetamiprid | |
| CN105330398A (en) | Paddy field pesticide fertilizer particle containing pyrazosulfuron and thiamethoxam, and preparation method thereof | |
| CN108684703A (en) | A kind of compounding granule containing diazinon, phoxim | |
| CN104186547B (en) | A kind of granular pesticide containing humic acid and clothianidin | |
| CN106614642B (en) | Seed treatment agent composition and application thereof | |
| CN101444203A (en) | Compound formulation for paddy pest control | |
| CN101485329A (en) | Agricultural chemical composition for disinsection and use thereof | |
| CN105994414A (en) | Corn seed coating agent capable of effectively removing weeds in corn fields | |
| CN105010315A (en) | Dispersable oil suspending agent containing acetamiprid and carbosulfan and application | |
| CN105265497A (en) | Preparation method for fertilizer-mixing biological disinsection additive | |
| CN105432651A (en) | Suspended seed coating containing fluopyram, fludioxonil and thiamethoxam | |
| CN102334488B (en) | Insect-killing and disease-preventing suspension seed coating formulation | |
| CN102283245A (en) | Suspending seed coating agent |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CP03 | Change of name, title or address |
Address after: No.16, Weisan Road, Shangyu economic and Technological Development Zone, Hangzhou Bay, Shaoxing, Zhejiang Province Patentee after: Zhejiang Tianyi Biotechnology Co.,Ltd. Address before: 312369, No. three, No. 16, Shangyu Industrial Park, Hangzhou Bay, Shaoxing, Zhejiang, Shangyu Patentee before: ZHEJIANG TIANYI AGROCHEMICAL CO.,LTD. |
|
| CP03 | Change of name, title or address | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Avermectin and imidacloprid granules for pest control Effective date of registration: 20221204 Granted publication date: 20160420 Pledgee: Zhejiang Shangyu Rural Commercial Bank Co.,Ltd. Yiting Sub branch Pledgor: Zhejiang Tianyi Biotechnology Co.,Ltd. Registration number: Y2022330003414 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20231101 Granted publication date: 20160420 Pledgee: Zhejiang Shangyu Rural Commercial Bank Co.,Ltd. Yiting Sub branch Pledgor: Zhejiang Tianyi Biotechnology Co.,Ltd. Registration number: Y2022330003414 |
|
| PC01 | Cancellation of the registration of the contract for pledge of patent right |