CN104152188B - One kind of plant firpene oil fuel - Google Patents
One kind of plant firpene oil fuel Download PDFInfo
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- CN104152188B CN104152188B CN201410153832.7A CN201410153832A CN104152188B CN 104152188 B CN104152188 B CN 104152188B CN 201410153832 A CN201410153832 A CN 201410153832A CN 104152188 B CN104152188 B CN 104152188B
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- Prior art keywords
- firpene
- oil
- pinane
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- plant
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- 239000000446 fuel Substances 0.000 title claims abstract description 19
- XOKSLPVRUOBDEW-UHFFFAOYSA-N pinane Chemical compound CC1CCC2C(C)(C)C1C2 XOKSLPVRUOBDEW-UHFFFAOYSA-N 0.000 claims abstract description 40
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000000463 material Substances 0.000 claims abstract description 21
- 229930006728 pinane Natural products 0.000 claims abstract description 20
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical group CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims abstract description 11
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims abstract description 10
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims abstract description 8
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims abstract description 8
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000006227 byproduct Substances 0.000 claims abstract description 7
- 238000000034 method Methods 0.000 claims abstract description 7
- 238000004519 manufacturing process Methods 0.000 claims abstract description 5
- WUOACPNHFRMFPN-UHFFFAOYSA-N alpha-terpineol Chemical compound CC1=CCC(C(C)(C)O)CC1 WUOACPNHFRMFPN-UHFFFAOYSA-N 0.000 claims abstract description 4
- 230000036571 hydration Effects 0.000 claims abstract description 4
- 238000006703 hydration reaction Methods 0.000 claims abstract description 4
- 238000002156 mixing Methods 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 4
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 claims description 4
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 4
- 238000001914 filtration Methods 0.000 claims description 3
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 claims description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 2
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 claims description 2
- 229960004418 trolamine Drugs 0.000 claims description 2
- 239000003921 oil Substances 0.000 abstract description 28
- 239000000295 fuel oil Substances 0.000 abstract description 7
- 230000000694 effects Effects 0.000 abstract description 5
- 238000002485 combustion reaction Methods 0.000 abstract description 3
- 239000000047 product Substances 0.000 abstract description 3
- 238000010438 heat treatment Methods 0.000 abstract description 2
- 238000007599 discharging Methods 0.000 abstract 1
- 238000004134 energy conservation Methods 0.000 abstract 1
- 239000002283 diesel fuel Substances 0.000 description 5
- 239000000284 extract Substances 0.000 description 4
- 239000002803 fossil fuel Substances 0.000 description 4
- 238000011161 development Methods 0.000 description 3
- 230000018109 developmental process Effects 0.000 description 3
- 238000003912 environmental pollution Methods 0.000 description 3
- 230000008676 import Effects 0.000 description 3
- GRWFGVWFFZKLTI-IUCAKERBSA-N (-)-α-pinene Chemical compound CC1=CC[C@@H]2C(C)(C)[C@H]1C2 GRWFGVWFFZKLTI-IUCAKERBSA-N 0.000 description 2
- 239000010779 crude oil Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- WTARULDDTDQWMU-RKDXNWHRSA-N (+)-β-pinene Chemical compound C1[C@H]2C(C)(C)[C@@H]1CCC2=C WTARULDDTDQWMU-RKDXNWHRSA-N 0.000 description 1
- WTARULDDTDQWMU-IUCAKERBSA-N (-)-Nopinene Natural products C1[C@@H]2C(C)(C)[C@H]1CCC2=C WTARULDDTDQWMU-IUCAKERBSA-N 0.000 description 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- WTARULDDTDQWMU-UHFFFAOYSA-N Pseudopinene Natural products C1C2C(C)(C)C1CCC2=C WTARULDDTDQWMU-UHFFFAOYSA-N 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- XCPQUQHBVVXMRQ-UHFFFAOYSA-N alpha-Fenchene Natural products C1CC2C(=C)CC1C2(C)C XCPQUQHBVVXMRQ-UHFFFAOYSA-N 0.000 description 1
- MVNCAPSFBDBCGF-UHFFFAOYSA-N alpha-pinene Natural products CC1=CCC23C1CC2C3(C)C MVNCAPSFBDBCGF-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229930006722 beta-pinene Natural products 0.000 description 1
- 235000011089 carbon dioxide Nutrition 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 238000005474 detonation Methods 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- LCWMKIHBLJLORW-UHFFFAOYSA-N gamma-carene Natural products C1CC(=C)CC2C(C)(C)C21 LCWMKIHBLJLORW-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 239000005445 natural material Substances 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- GRWFGVWFFZKLTI-UHFFFAOYSA-N rac-alpha-Pinene Natural products CC1=CCC2C(C)(C)C1C2 GRWFGVWFFZKLTI-UHFFFAOYSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000004083 survival effect Effects 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
Landscapes
- Solid Fuels And Fuel-Associated Substances (AREA)
- Liquid Carbonaceous Fuels (AREA)
Abstract
The present invention relates to the kind of plant firpene oil fuel that New-type fuel manufactures field, comprise: containing firpene oil 65-75%, kautschin 26-34%, ignition dope 2-3%, through mixing; Containing firpene oil derive from rosin, turps and firpene produce time byproduct--long pinane material, forms through the following step process: 1) dewater: in long pinane material, add Monoethanolamine MEA BASF, addition is 0.3%; 2) neutralize: add Monoethanolamine MEA BASF, adjustment pH value to 7.0; 3) filter: removing filter residue; Kautschin derives from by product during turps hydration manufacture Terpineol 350, and ignition dope is propyl carbinol; The effect adding kautschin and propyl carbinol reduces density of the present invention, viscosity and flash-point, make it easily to light, the invention solves in turps the process problem of the long pinane material of a large amount of byproducts after extracting firpene, make it become high heating value environment-protecting clean energy product, solve fuel oil in combustion to the pollution of environment, be at present energy-conservation, reduce discharging reproducible plant fuel.
Description
Technical field
The present invention relates to New-type fuel and manufacture field, specifically a kind of plant firpene oil fuel.
Background technology
The energy is the lifeblood of national economy, the degree of dependence of the survival and development to the energy of the mankind is more and more higher, the energy of current use has 85% to be that fossil oil oil, Sweet natural gas and coal by burning non-renewable obtains, and the fossil fuel resource in the whole world just progressively moves towards exhaustion.Oil is the energy be most widely used.According to up-to-date estimation, on the earth, oil stable supplying can not more than 20 years, and dry spells is only 50 years, and energy dilemma is the huge challenge that the mankind are about to face the middle of this century.China is the relatively poor countries of petroleum resources, and reserves are only 12% of the world per capita.Along with the rapid growth of national economy, the petroleum resources of China are increasingly in short supply, and since China in 1993 becomes net import of oil state, crude oil import quantity increases year by year, and current crude oil import has accounted for national oil aggregate supply more than 50%.
While fossil oil is played a great role in human society modernization development, also bring serious ecological environmental pollution problem.Data shows, the carbonic acid gas of 70% in air, the sulfide of 80% and 70% oxynitride come from the product after combustion of fossil fuel, cause the severe contamination of air.In recent years, all there is big area, on a large scale haze weather in China various places, is degrading living environment, and serious threat people are physically and mentally healthy.
When fossil energy is gradually exhausted, energy consumption constantly increases, severe environmental pollution, advocate protection of the environment, Sustainable development and recycling economy, become the selection that people are only.People are in the urgent need to develop and useining novel, clean energy.
Nuclear energy except fossil energy, can be applied to generating maturely, but since Fukushima, Japan Nuclear power plants is due to earthquake reason, produce nuclear leakage, jeopardize the multiple country of periphery, re-recognize so people have had nuclear energy, think that it is also dangerous, and Solar use, because its utilising efficiency is low, can't large-scale application.
Therefore, the utilization of plant energy progresses into people's sight line, and it is clean energy, be a kind of form of earth plant storage sun power, plant fuel oil is topmost plant energy, and it is from plant, and plant can cyclic regeneration, not atmosphere pollution after plant fuel oil firing.
China's plant resources enriches, and can be used as setting up mass-producing plant fuel oil raw material site, utilizes deserted mountain, sand ground etc. to afforest suitable for afforestationly.China produces more than 60 ten thousand tons, rosin per year, and wherein Guangdong has more than ten ten thousand tons of rosin every year, and it makes rosin and turps, extracts the long pinane material of a large amount of byproducts after the firpene (i.e. α-pinene and beta-pinene) of high value, have pending from turps.Past is just added in the 180# heavy oil of high pollution, uses, can not make the best use of everything and contaminate environment as fuel.The applicant is through researching and developing for many years, have found a new way, after making to extract the product of firpene and so on high value from turps, remaining long pinane material, through being treated as containing firpene oil, add other component again, produce plant firpene oil fuel, as a kind of green reproducible, fossil fuel ordinary diesel oil substitute, calorific value is high, free from environmental pollution, achieves many things at one stroke.Other plant fuel oil on existing market, calorific value is low, and cost is high, difficult universal.
Summary of the invention
In order to solve the problems referred to above that prior art plant fuel oil exists, the present invention proposes a kind of plant firpene oil fuel.
The technical scheme that the present invention uses is as follows:
One kind of plant firpene oil fuel, it comprises the material of following weight percent: containing firpene oil 60-80%, kautschin 20-40%, ignition dope 1-5%, through mixing.Screening formulation: containing firpene oil 65-75%, kautschin 26-34%, ignition dope 2-3%.
Described containing firpene oil, derive from rosin, turps and firpene produce time byproduct--long pinane material, forms through the following step process.
1) dewater: by long pinane material pump delivery to the first reactor, add the one in Monoethanolamine MEA BASF, diethanolamine, trolamine, preferred Monoethanolamine MEA BASF, its effect reduces viscosity, impels profit layering, addition is 0.2-0.6%, stir 60-90 minute, then leave standstill 4-6 hour, profit natural layering, the moisture content of reactor bottom is released, then by long pinane mass transport to the second reactor on top.
2) neutralize: measure acid number, add the one in Monoethanolamine MEA BASF, diethanolamine, preferred Monoethanolamine MEA BASF, its effect reduces acid number, neutralizes, and adjustment pH value, to 6.5-7.5, then stirs 40-80 minute, leaves standstill 3-5 hour, then is delivered in the 3rd reactor.
3) filter: by the long pinane material in the 3rd reactor, deliver to pressure filter and carry out press filtration, removing filter residue, gained is containing firpene oil.
Described kautschin derives from by product during turps hydration manufacture Terpineol 350, and its content is 80-95%.
Described ignition dope is butanols, comprises propyl carbinol, isopropylcarbinol, the trimethyl carbinol, sec-butyl alcohol, content more than 93%, preferred propyl carbinol.
Above-mentioned long pinane material also can extract from trunk, branch, leaf, pulverizes, therefrom obtain liquid substance by it, and removing moisture, extracts rosin and turps, then extract firpene from turps after, remaining is long pinane material.
The invention has the beneficial effects as follows:
1) solve in turps the process problem of the long pinane material of a large amount of byproducts after extracting firpene, make it become high heating value, environmentally friendly, reproducible plant fuel, become the substitute of non-renewable fossil fuel ordinary diesel oil.
2) effect adding kautschin in formula reduces density of the present invention and flash-point, makes it easily to light, and burning completely; The effect adding propyl carbinol reduces viscosity of the present invention and flash-point, and have emulsifying effect, prevent the micro-moisture existed in the present invention from producing detonation, also make various uniform composition in the present invention be mixed into one, prevent contingent demixing phenomenon, and burning is incomplete.
3) directly long pinane material can be extracted from the trunk of plant, branch, leaf, for making plant firpene oil fuel, and the incredible amount that above-mentioned plant goes out of use every year in the wild, can utilize, will benefit future generations all ages.
4) the present invention is used kautschin, propyl carbinol etc. are the natural material of plant extract, and processing and making process of the present invention does not produce any pollutent yet.
5) plant firpene oil fuel of the present invention is than ordinary diesel oil calorific value height about 15%, and flash-point is high by 40%, and price is low by 10%, and consumption saves 24%, safe and reliable, super quality and competitive price, energy-conserving and environment-protective.
Embodiment
One kind of plant firpene oil fuel, comprises the material of following weight percent: containing firpene oil 65-75%, kautschin 26-34%, ignition dope 2-3%, through mixing.
Containing firpene oil, derive from rosin, turps and firpene produce time byproduct--long pinane material, forms through the following step process.
1) dewater: in long pinane material, add Monoethanolamine MEA BASF, addition is 0.3%, stirs 70 minutes, leave standstill 5 hours, profit natural layering, releases the moisture content of bottom.
2) neutralize: measure acid number, add Monoethanolamine MEA BASF and neutralize, adjustment pH value to 7.0, then stirs 60 minutes, leaves standstill 4 hours.
3) filter: by long pinane material, deliver to pressure filter and carry out press filtration, removing filter residue, gained is containing firpene oil.
Kautschin derives from by product during turps hydration manufacture Terpineol 350, and its content is 90-95%.Ignition dope is propyl carbinol, content more than 95%.
Each formula of the present invention and performance are as following table:
Plant firpene oil fuel of the present invention and ordinary diesel oil performance comparison table
Plant firpene oil fuel of the present invention and ordinary diesel oil combustion testing contrast table
(far reaching company project portion 3# steam oven)
Claims (2)
1. a kind of plant firpene oil fuel, is characterized in that the material comprising following weight percent: containing firpene oil 60-80%, kautschin 20-40%, ignition dope 1-5%, through mixing; Described kautschin derives from by product during turps hydration manufacture Terpineol 350, and its content is 80-95%; Described ignition dope is butanols; Described containing firpene oil, derive from byproduct-long pinane material when rosin, turps and firpene are produced, form through the following step process:
1) dewater: by long pinane material pump delivery to the first reactor, add the one in Monoethanolamine MEA BASF, diethanolamine, trolamine, addition is 0.2-0.6%, stir 60-90 minute, then 4-6 hour is left standstill, profit natural layering, releases the moisture content of reactor bottom, then by long pinane mass transport to the second reactor on top;
2) neutralize: measure acid number, add the one in Monoethanolamine MEA BASF, diethanolamine, neutralize, adjustment pH value, to 6.5-7.5, then stirs 40-80 minute, leaves standstill 3-5 hour, then is delivered in the 3rd reactor;
3) filter: by the long pinane material in the 3rd reactor, deliver to pressure filter and carry out press filtration, removing filter residue, gained is containing firpene oil.
2. a kind of plant firpene oil fuel according to claim 1, is characterized in that: described butanols comprises propyl carbinol, isopropylcarbinol, the trimethyl carbinol, sec-butyl alcohol, content more than 93%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410153832.7A CN104152188B (en) | 2014-04-16 | 2014-04-16 | One kind of plant firpene oil fuel |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410153832.7A CN104152188B (en) | 2014-04-16 | 2014-04-16 | One kind of plant firpene oil fuel |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104152188A CN104152188A (en) | 2014-11-19 |
| CN104152188B true CN104152188B (en) | 2015-09-09 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410153832.7A Expired - Fee Related CN104152188B (en) | 2014-04-16 | 2014-04-16 | One kind of plant firpene oil fuel |
Country Status (1)
| Country | Link |
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| CN (1) | CN104152188B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106906014B (en) * | 2017-03-31 | 2020-09-01 | 兰州燚能生物科技有限责任公司 | Flash point improver for biological alcohol-based light fuel |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101353603A (en) * | 2008-09-10 | 2009-01-28 | 刘鹏 | Artificially synthesized fuel oil and production method thereof |
| AU2012224533A1 (en) * | 2011-03-10 | 2013-09-12 | Shell Internationale Research Maatschappij B.V. | Improvements relating to gasoline fuel formulations |
| CN102229823B (en) * | 2011-06-10 | 2013-06-12 | 西安万德科技有限公司 | Terpene isopropyl carbonate gasoline antiknock |
| CN103122263B (en) * | 2013-01-30 | 2015-06-03 | 秦如新 | Fuel additive and clean low-carbon fuel with same |
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2014
- 2014-04-16 CN CN201410153832.7A patent/CN104152188B/en not_active Expired - Fee Related
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| CN104152188A (en) | 2014-11-19 |
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Effective date of registration: 20160818 Address after: 526020, Guangdong 40, Duanzhou Province, Zhaoqing Road Star Cui Bridge Company Patentee after: Jiang Caiqing Address before: 526020, No. 15, No. four, village two, Chu Gang Town, Duanzhou District, Guangdong, Zhaoqing Patentee before: ZHAOQING XINDIXIN BIOLOGICAL ENERGY Co.,Ltd. |
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