CN106753662A - A kind of preparation technology of biomass granule fuel reducing agent - Google Patents

A kind of preparation technology of biomass granule fuel reducing agent Download PDF

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Publication number
CN106753662A
CN106753662A CN201611036715.8A CN201611036715A CN106753662A CN 106753662 A CN106753662 A CN 106753662A CN 201611036715 A CN201611036715 A CN 201611036715A CN 106753662 A CN106753662 A CN 106753662A
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CN
China
Prior art keywords
parts
granule fuel
reducing agent
biomass granule
biomass
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Pending
Application number
CN201611036715.8A
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Chinese (zh)
Inventor
李叶春
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Huaining Xinmaoyuan Biomass Fuel Co Ltd
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Huaining Xinmaoyuan Biomass Fuel Co Ltd
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Application filed by Huaining Xinmaoyuan Biomass Fuel Co Ltd filed Critical Huaining Xinmaoyuan Biomass Fuel Co Ltd
Priority to CN201611036715.8A priority Critical patent/CN106753662A/en
Publication of CN106753662A publication Critical patent/CN106753662A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L5/00Solid fuels
    • C10L5/40Solid fuels essentially based on materials of non-mineral origin
    • C10L5/44Solid fuels essentially based on materials of non-mineral origin on vegetable substances
    • C10L5/447Carbonized vegetable substances, e.g. charcoal, or produced by hydrothermal carbonization of biomass
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/02Combustion or pyrolysis
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/08Drying or removing water
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/28Cutting, disintegrating, shredding or grinding
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/32Molding or moulds
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/10Biofuels, e.g. bio-diesel
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/30Fuel from waste, e.g. synthetic alcohol or diesel

Abstract

The invention discloses a kind of biomass granule fuel reducing agent, it is made up of the raw material of following parts by weight:12 16 parts of wood chip, 15 22 parts of peanut shell, 9 18 parts of wheat stalk, 7 14 parts of castor-oil plant stalk, 16 20 parts of bagasse, 69 parts of bonding agent.Compared with prior art, the present invention can fundamentally solve the demand of fuel industry scarcity of resources, can be to greatly improving the efficiency of combustion of existing biomass granule fuel, while not increasing the content of the carbon dioxide in air, the greenhouse effects to alleviating increasingly serious have special meaning.

Description

A kind of preparation technology of biomass granule fuel reducing agent
Technical field
The present invention relates to biomass fuel reducing agent preparation field, and in particular to a kind of biomass granule fuel reducing agent Preparation technology.
Background technology
With social progress, energy resource consumption is increased rapidly, the finiteness of mineral matter fuel source reserves, non-renewable Property, the environmental pollution that particularly mineral matter using energy source is brought seriously, makes people increasingly pay attention to reproducible clean energy resource Development and utilization.In various renewable resources, biomass are can uniquely to utilize the sun on the earth in the form of fixed carbon The regenerative resource of energy, it has a large capacity and a wide range, and potentiality to be exploited is huge.It is increasingly exhausted in fossil type resource, and on the other hand it is protection The forest reserves must not be further continued for firing charcoal again in the case that, only abundant biomass resource is used, could met Demand of the fuel industry to biomass granule fuel reducing agent.
The content of the invention
The present invention is intended to provide a kind of biomass granule fuel reducing agent and its preparation technology.
The present invention provides following technical scheme:
A kind of biomass granule fuel reducing agent, is made up of the raw material of following parts by weight:Wood chip 12-16 parts, peanut shell 15-22 parts, wheat stalk 9-18 parts, 7-14 parts, bagasse 16-20 parts, bonding agent 6-9 parts of castor-oil plant stalk.
A kind of preparation technology of biomass granule fuel reducing agent, comprises the following steps:
(1) by wood chip, peanut shell, wheat stalk, castor-oil plant stalk, bagasse material collection, storage, then crushed respectively It is 80-120 mesh to granularity;
(2) by above-mentioned raw materials it is well mixed after, in the conventional distillation apparatus of feeding, routinely 500 DEG C, 600 DEG C, 700 DEG C, Under 850 DEG C or 900 DEG C of pyrolysis temperatures, carbonization obtains mixing biomass carbonized material;
(3) above-mentioned biomass carbon material is placed in activation furnace, is passed through the high-temperature vapor gas that operating pressure is 2-3atm Body flow is 20-30mL/h, the activation process 2-3h at 380-440 DEG C, is adding bonding agent, is well mixed aftershaping and dries, Fine powder is ground to form again, obtains biomass granule fuel reducing agent.
The preferred hydroxyethyl cellulose of binding agent, polyanion cellulose, modified carboxy methyl cellulose receive, compound PAC, One or more in starch.
The wood chip is selected from least one in larch, red oak.
It is the dilute sulfuric acid of 20-30%, reaction that biomass granule fuel in the step (3) after grinding adds mass concentration 20-25min, the solution for obtaining is leached with pyrolusite.
Compared with prior art, the beneficial effects of the invention are as follows:The present invention can fundamentally solve fuel industry resource Deficient demand, can be to greatly improving the efficiency of combustion of existing biomass granule fuel, while in not increasing air two The content of carbonoxide, the greenhouse effects to alleviating increasingly serious have special meaning.
Specific embodiment
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described, Obviously, described embodiment is only a part of embodiment of the invention, rather than whole embodiments.Based in the present invention Embodiment, the every other embodiment that those of ordinary skill in the art are obtained under the premise of creative work is not made, all Belong to the scope of protection of the invention.
A kind of biomass granule fuel reducing agent of embodiment 1, is made up of the raw material of following parts by weight:12 parts of wood chip, flower Raw 15 parts of shell, 9 parts of wheat stalk, 7 parts of castor-oil plant stalk, 16 parts of bagasse, 6 parts of bonding agent.
A kind of preparation technology of biomass granule fuel reducing agent, comprises the following steps:
(1) by wood chip, peanut shell, wheat stalk, castor-oil plant stalk, bagasse material collection, storage, then crushed respectively It is 80-120 mesh to granularity;
(2) by above-mentioned raw materials it is well mixed after, in the conventional distillation apparatus of feeding, routinely 500 DEG C, 600 DEG C, 700 DEG C, Under 850 DEG C or 900 DEG C of pyrolysis temperatures, carbonization obtains mixing biomass carbonized material;
(3) above-mentioned biomass carbon material is placed in activation furnace, is passed through the high-temperature vapor gas that operating pressure is 2-3atm Body flow is 20-30mL/h, the activation process 2-3h at 380-440 DEG C, is adding bonding agent, is well mixed aftershaping and dries, Fine powder is ground to form again, obtains biomass granule fuel reducing agent.
The preferred hydroxyethyl cellulose of binding agent, polyanion cellulose, modified carboxy methyl cellulose receive, compound PAC, One or more in starch.
The wood chip is selected from least one in larch, red oak.
It is the dilute sulfuric acid of 20-30%, reaction that biomass granule fuel in the step (3) after grinding adds mass concentration 20-25min, the solution for obtaining is leached with pyrolusite.
A kind of biomass granule fuel reducing agent of embodiment 2, is made up of the raw material of following parts by weight:16 parts of wood chip, flower Raw 22 parts of shell, 18 parts of wheat stalk, 14 parts of castor-oil plant stalk, 20 parts of bagasse, 9 parts of bonding agent.
A kind of preparation technology of biomass granule fuel reducing agent, comprises the following steps:
(1) by wood chip, peanut shell, wheat stalk, castor-oil plant stalk, bagasse material collection, storage, then crushed respectively It is 80-120 mesh to granularity;
(2) by above-mentioned raw materials it is well mixed after, in the conventional distillation apparatus of feeding, routinely 500 DEG C, 600 DEG C, 700 DEG C, Under 850 DEG C or 900 DEG C of pyrolysis temperatures, carbonization obtains mixing biomass carbonized material;
(3) above-mentioned biomass carbon material is placed in activation furnace, is passed through the high-temperature vapor gas that operating pressure is 2-3atm Body flow is 20-30mL/h, the activation process 2-3h at 380-440 DEG C, is adding bonding agent, is well mixed aftershaping and dries, Fine powder is ground to form again, obtains biomass granule fuel reducing agent.
The preferred hydroxyethyl cellulose of binding agent, polyanion cellulose, modified carboxy methyl cellulose receive, compound PAC, One or more in starch.
The wood chip is selected from least one in larch, red oak.
It is the dilute sulfuric acid of 20-30%, reaction that biomass granule fuel in the step (3) after grinding adds mass concentration 20-25min, the solution for obtaining is leached with pyrolusite.
A kind of biomass granule fuel reducing agent of embodiment 3, is made up of the raw material of following parts by weight:14 parts of wood chip, flower Raw 18 parts of shell, 15 parts of wheat stalk, 12 parts of castor-oil plant stalk, 18 parts of bagasse, 8 parts of bonding agent.
A kind of preparation technology of biomass granule fuel reducing agent, comprises the following steps:
(1) by wood chip, peanut shell, wheat stalk, castor-oil plant stalk, bagasse material collection, storage, then crushed respectively It is 80-120 mesh to granularity;
(2) by above-mentioned raw materials it is well mixed after, in the conventional distillation apparatus of feeding, routinely 500 DEG C, 600 DEG C, 700 DEG C, Under 850 DEG C or 900 DEG C of pyrolysis temperatures, carbonization obtains mixing biomass carbonized material;
(3) above-mentioned biomass carbon material is placed in activation furnace, is passed through the high-temperature vapor gas that operating pressure is 2-3atm Body flow is 20-30mL/h, the activation process 2-3h at 380-440 DEG C, is adding bonding agent, is well mixed aftershaping and dries, Fine powder is ground to form again, obtains biomass granule fuel reducing agent.
The preferred hydroxyethyl cellulose of binding agent, polyanion cellulose, modified carboxy methyl cellulose receive, compound PAC, One or more in starch.
The wood chip is selected from least one in larch, red oak.
It is the dilute sulfuric acid of 20-30%, reaction that biomass granule fuel in the step (3) after grinding adds mass concentration 20-25min, the solution for obtaining is leached with pyrolusite.
It is obvious to a person skilled in the art that the invention is not restricted to the details of the one exemplary embodiment, Er Qie In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be in other specific forms realized.Therefore, no matter From the point of view of which point, embodiment all should be regarded as exemplary, and be nonrestrictive, the scope of the present invention is by appended power Profit requires to be limited rather than the explanation, it is intended that all in the implication and scope of the equivalency of claim by falling Change is included in the present invention.Moreover, it will be appreciated that although the present specification is described in terms of embodiments, not each Implementation method only includes an independent technical scheme, and this narrating mode of specification is only this area for clarity Specification an as entirety, the technical scheme in each embodiment should can also be formed this by technical staff through appropriately combined Art personnel may be appreciated other embodiment.

Claims (5)

1. a kind of biomass granule fuel reducing agent, it is characterised in that be made up of the raw material of following parts by weight:Wood chip 12-16 Part, peanut shell 15-22 parts, wheat stalk 9-18 parts, 7-14 parts, bagasse 16-20 parts, bonding agent 6-9 parts of castor-oil plant stalk.
2. a kind of preparation technology of biomass granule fuel reducing agent as claimed in claim 1, it is characterised in that including following Step:
(1) by wood chip, peanut shell, wheat stalk, castor-oil plant stalk, bagasse material collection, storage, then carry out being crushed to respectively Granularity is 80-120 mesh;
(2) by above-mentioned raw materials it is well mixed after, in the conventional distillation apparatus of feeding, routinely 500 DEG C, 600 DEG C, 700 DEG C, 850 DEG C or 900 DEG C of pyrolysis temperatures under, carbonization obtains mixing biomass carbonized material;
(3) above-mentioned biomass carbon material is placed in activation furnace, is passed through the high-temperature vapor gas stream that operating pressure is 2-3atm It is 20-30mL/h to measure, the activation process 2-3h at 380-440 DEG C, is adding bonding agent, is well mixed aftershaping and dries, then grinds Fine powder is worn into, biomass granule fuel reducing agent is obtained.
3. the preparation technology of a kind of biomass granule fuel reducing agent according to claim 1 and 2, it is characterised in that:Institute State the preferred hydroxyethyl cellulose of binding agent, polyanion cellulose, modified carboxy methyl cellulose receive, in compound PAC, starch one Plant or several.
4. the preparation technology of a kind of biomass granule fuel reducing agent according to claim 1 and 2, it is characterised in that:Institute State at least one during wood chip is selected from larch, red oak.
5. the preparation technology of a kind of biomass granule fuel reducing agent according to claim 1 and 2, it is characterised in that:Institute It is the dilute sulfuric acid of 20-30% to state the biomass granule fuel after the middle grinding of step (3) and add mass concentration, reacts 20-25min, The solution for obtaining is leached with pyrolusite.
CN201611036715.8A 2016-11-23 2016-11-23 A kind of preparation technology of biomass granule fuel reducing agent Pending CN106753662A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107892968A (en) * 2017-12-06 2018-04-10 联合优发生物质能源徐州有限公司 High biomass fuel of a kind of calorific value and preparation method thereof
CN108059989A (en) * 2017-12-06 2018-05-22 联合优发生物质能源徐州有限公司 A kind of clean-burning biomass fuel of energy and preparation method thereof
CN108059990A (en) * 2017-12-06 2018-05-22 联合优发生物质能源徐州有限公司 A kind of complex biological matter fuel and preparation method thereof
CN108517235A (en) * 2018-04-29 2018-09-11 段宝荣 A kind of sawdust biomass fuel and preparation method thereof
CN109097150A (en) * 2018-08-25 2018-12-28 广州吉前化工有限公司 A kind of coal-saving comburant and preparation method thereof

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101831546A (en) * 2010-06-10 2010-09-15 中南大学 Method for preparing biomass reductant and application thereof

Patent Citations (1)

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Publication number Priority date Publication date Assignee Title
CN101831546A (en) * 2010-06-10 2010-09-15 中南大学 Method for preparing biomass reductant and application thereof

Non-Patent Citations (1)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107892968A (en) * 2017-12-06 2018-04-10 联合优发生物质能源徐州有限公司 High biomass fuel of a kind of calorific value and preparation method thereof
CN108059989A (en) * 2017-12-06 2018-05-22 联合优发生物质能源徐州有限公司 A kind of clean-burning biomass fuel of energy and preparation method thereof
CN108059990A (en) * 2017-12-06 2018-05-22 联合优发生物质能源徐州有限公司 A kind of complex biological matter fuel and preparation method thereof
CN108517235A (en) * 2018-04-29 2018-09-11 段宝荣 A kind of sawdust biomass fuel and preparation method thereof
CN108517235B (en) * 2018-04-29 2021-09-17 段宝荣 Wood chip biomass fuel and preparation method thereof
CN109097150A (en) * 2018-08-25 2018-12-28 广州吉前化工有限公司 A kind of coal-saving comburant and preparation method thereof

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Application publication date: 20170531