CN104146580B - A kind of shading intumescent coating curtain - Google Patents

A kind of shading intumescent coating curtain Download PDF

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CN104146580B
CN104146580B CN201410397650.4A CN201410397650A CN104146580B CN 104146580 B CN104146580 B CN 104146580B CN 201410397650 A CN201410397650 A CN 201410397650A CN 104146580 B CN104146580 B CN 104146580B
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coating
pressure roller
cutter
parts
modulation
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CN104146580A (en
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许生军
李建国
奚香南
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Zhejiang Chenhong Textile Technology Co ltd
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Zhejiang Chen Hong Textile Science And Technology Ltd
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Abstract

The present invention relates to a kind of preparation method of curtain, relate in particular to a kind of shading intumescent coating curtain. It is prepared by following steps: grey cloth preparation; White slurry modulation and the first coating: adopt painting cutter pressure roller that described white slurry is rolled in grey cloth one side and obtains the first coating; Black wash modulation and the second coating: adopt painting cutter pressure roller that black wash is rolled and in the first coating, obtains the second coating; Starch adhesive modulation and the 3rd coating: adopt painting cutter pressure roller that starch adhesive is rolled and in the 3rd coating, obtains the 3rd coating; Scrape mill base modulation and cloth cover and scrape look: employing sharp knife the another side of grey cloth with described in scrape mill base and carry out cloth cover and scrape look. When halogen-free flame-retardant expanded coating Curtains exclude light prepared by the present invention, heat insulation, moistureproof, sound-absorbing, durable, burning the amount of being fuming little, do not produce poisonous and corrosive gas.

Description

A kind of shading intumescent coating curtain
Technical field
The present invention relates to a kind of preparation method of curtain, relate in particular to a kind of shading intumescent coating curtain.
Background technology
Modern window decorations are of a great variety, but most eyeball that attracts consumer is gay colours and pattern, makes us freshGorgeous color and pattern have not been novel things, have paid no attention to the pattern of its gay colours and what focus on is right peopleWhen textile product causes the security of the lives and property that the fire that produces causes, the fire quantity that textile causes in the world and deadThe fire that the rate of dying all causes than other reason is high, causes the massive losses of lives and properties, and therefore textile combustion is put into effect in weavingTechnical regulation, specifies that some textile must carry out flame-proof treatment. Now use in fire retardant some kind itself poisonous, or when burningProduce noxious material, the appearance of some Halogen antiflaming finishing agents makes its some naked lights carry out some defense reactions, but product existsThe corrosivity object and the toxic gas that when burning, send, do not meet the standard to environmental type product now.
CN102433645B (2013-6-19) discloses the production technology of flame-retarded sun-shading curtain cloth, but the screening of this inventionOptical window cord is heat insulation to have much room for improvement with sound-absorbing effect.
Summary of the invention
While the object of this invention is to provide a kind of shading, heat insulation, moistureproof, sound-absorbing, durable, burning the amount of being fuming little, do not produceGive birth to the shading intumescent coating curtain of poisonous and corrosive gas.
Above-mentioned technical purpose of the present invention is achieved by the following technical programs:
A kind of shading intumescent coating curtain, its preparation method comprises the following steps successively:
(1) grey cloth preparation;
(2) white slurry modulation and the first coating: described white slurry comprises polyurethane 8-19 part by weight, acrylic acid 21-32 part;The fire-retardant dispersion 35-40 part of phosphorus series non-halogen; Titanium dioxide dispersion 8-15 part; Foam stabilizer 10-15 part; Blowing agent 0.8-1.5 part;Ammoniacal liquor 0.5-1 part; Described white slurry pH value 9.8-10; Viscosity 2200-2500cps; Then adopt and be coated with cutter pressure roller by described white slurry stone rollerBe pressed in upper first coating that obtains of described grey cloth one side;
(3) black wash modulation and the second coating: described black wash comprises polyurethane 8-19 part by weight, acrylic acid 21-32 part;The fire-retardant dispersion 35-40 part of phosphorus series non-halogen; Titanium dioxide dispersion 8-15 part; Foam stabilizer 10-15 part; Blowing agent 0.8-1.5 part;Ammoniacal liquor 0.5-1 part; Black color paste 1-6 part; Stiffening glue 5-25 part; Described black wash pH value 9.8-10, viscosity 2200-2500cps; SoRear employing is coated with cutter pressure roller described black wash is rolled and in the first coating, obtains the second coating;
(4) starch adhesive modulation and the 3rd coating: described starch adhesive comprises polyurethane 50-60 part by weight; Phosphorus series non-halogen is fire-retardantDispersion 20-30 part; Titanium dioxide dispersion 10-15 part; Foam stabilizer 8-15 part; Blowing agent 1-2.2 part; Ammoniacal liquor 0.5-1.2 part;Described starch adhesive pH value 9.8-10, viscosity 2000-2400cps; Then adopt painting cutter pressure roller that described starch adhesive is rolled in the second coatingUpper acquisition the 3rd coating;
(5) scrape mill base modulation and cloth cover and scrape look: described in scrape mill base and comprise by weight water-based acrylic emulsion 14-28 part;Polyurethane 4-8 part; The fire-retardant dispersion 20-30 part of phosphorus series non-halogen; Defoamer 0.1-0.27 part; Bleeding agent 2-5 part; The agent of pH value stabilization0.5-1.9 part; The described mill base viscosity 20000-30000cps that scrapes; Then adopt sharp knife the another side of described grey cloth with described in scrapeMill base carries out cloth cover and scrapes look;
The formula of the fire-retardant dispersant of described phosphorus series non-halogen is acrylic acid 25-30 part by weight, aluminium hydroxide 50-55 part,APP 45-55 part, titanium dioxide 28-44 part, polyurethane 6-12 part, water 50-60 part, dispersant 0.2-0.8 part, bleeding agent0.15-0.35 part, rheology control agent 3-8 part.
The present invention, at specific multiple slurries preparation and layered coated, scrapes look at the another side of cloth cover simultaneously, meanwhile,When the burning of the fire-retardant dispersant of phosphorus series non-halogen of the present invention the amount of being fuming little, do not produce poisonous and corrosive gas, the feature of environmental protection is good; FinallyWhile forming shading, heat insulation, moistureproof, sound-absorbing, durable, burning, the amount of being fuming Halogen little, that do not produce poisonous and corrosive gas hindersCombustion intumescent coating curtain, shading and sound-absorbing effect are especially outstanding.
As preferably, described black color paste comprises a divided titanium dioxide prose style free from parallelism and aqueous black pigment; A described divided titanium dioxide prose style free from parallelismThat titanium dioxide, water, dispersant are mixed and disperse to form according to weight portion 55-65:35-45:0.5-1.
After titanium dioxide is mixed to dispersion according to the method described above, reach certain sophistication, can merge better described whiteIn slurry, black wash, mortar or starch adhesive, and increase the shading of curtain to be prepared, heat insulation, moistureproof, sound-absorbing, durability.
As preferably, described grey cloth preparation comprise turn over that cloth, weft yarn are opened sanction, margin to seam, singed, water spray, dyeing and finishing and sizing, preparationBecome the oxford of the different patterns of 300 × 600D; Described weft yarn is opened and cut out is that fabric is cut apart with a knife or scissors by weft yarn; Described margin to seam be by board itBetween, between fabric, margin to seam carries out the parallel margin to seam of weft yarn; Described sizing is included in 150-160 DEG C of whole latitude sizing.
The grey cloth obtaining through this PROCESS FOR TREATMENT, has that pattern novelty, drapability are strong, advantage is waited so long in environmental protection, service time,Cloth mask Polyamide Yarns gloss perception effect. Sizing can make embryo cloth more have glacing flatness.
More preferably, described dyeing and finishing dyestuff used comprises reactive dye and reducing dye, and described reactive dye are moral departmentReach in imperon-HF-R, LevafixEA, ProcionH-EXL, the CibacronLight type reactive dye of company extremelyFew a kind of, reducing dye is at least one in olive T, blue ARN, red R, black ES-SE, blue RSN, blue CLF, purple 2R.
Adopt the curtain color of this preparation of dyestuff soft, do not fade.
As preferably, in described white slurry, polyurethane and acrylic acid account for the half of total formulation weight; In described black wash or mortarPolyurethane and acrylic acid account for the 40-50% of total formulation weight.
As preferably, painting nose angle degree when described the first coating be 90-95 °, cutter apart from for 0.6-0.65mm, foamed slurry closeDegree is 47-48g/cm3, expansion ratio be 3.2-4 doubly, pressure roller air pressure is at 0.3-0.4MPa; Cutter head is flat cutter; Described grey cloth processThe speed of pressure roller is 15-18m/min.
In the time of coating, control and be coated with nose angle degree, cutter and pressure roller air pressure and can assist control expansion ratio, obtain high strength andThe coating of high sound-absorbing effect.
As preferably, painting nose angle degree when described the second coating be 90-95 °, cutter apart from for 0.6-0.65mm, foamed slurry closeDegree is 46-49g/cm3, expansion ratio be 3-4 doubly, pressure roller air pressure is at 0.3-0.4MPa; Described grey cloth through the speed of pressure roller is16-18m/min。
As preferably, painting nose angle degree when described the 3rd coating be 90-95 °, cutter apart from for 0.7-0.75mm, foamed slurry closeDegree is 47-48g/cm3, expansion ratio be 3-3.5 doubly, pressure roller air pressure is at 0.35-0.4MPa; Described grey cloth is through the speed of pressure rollerFor 17-22m/min.
Adopt different painting nose angle degree, cutter and pressure roller air pressure, obtain the coating of varying strength and sound-absorbing effect, make finalIntensity and the sound-absorbing effect of Curtain product play synergistic function, obtain shading, heat insulation, moistureproof, sound-absorbing, durable, while burningThe halogen-free flame-retardant expanded coating curtain that the amount of being fuming is little, do not produce poisonous and corrosive gas, shading and sound-absorbing effect are especially outstanding.
More preferably, described the first coating, the second coating, the 3rd coating cutter head used are flat cutter.
As preferably, painting nose angle degree when described cloth cover is scraped look is that 90-95 °, cutter are apart from being 38-42mm, foamed slurry densityFor 47-48g/cm3, expansion ratio be 3.2-4 doubly, pressure roller air pressure is at 0.3-0.4MPa; Cutter head is sharp knife; Described grey cloth is through overvoltageThe speed of roller is 12-16m/min.
Blow painting nose angle degree, cutter and the pressure roller air pressure of look in the another side control of cloth cover, and adopt sharp knife to scrape look, make cloth coverPositive and negative interacts, thereby obtains the curtain of shading, heat insulation, moistureproof, sound-absorbing, durable better effects if.
Described expansion ratio is the multiple increasing than foaming front volume after foaming; Described cutter is apart from being painting cutter and applying pressure rollerSuspension operation room distance; The described painting cutter degree of depth is pasting amount regulation depth.
As preferably, the stiffening glue in described black wash and/or mortar be polystyrene, acrylic acid orVinyl acetateWithPropylene Acid estersOne or more in the anionic emulsion that copolymerization forms.
As preferably, described blowing agent is a kind of or many in the sodium bicarbonate solution of pentamethylene, normal butane or 5-15%Kind; Described bleeding agent is disecoctylmaleate sodium sulfonate.
As preferably, described foam stabilizer is sodium sulfate of polyethenoxy ether of fatty alcohol, DDAO or alkaneOne or more in base alkylolamides.
As preferably, between described black wash modulation and starch adhesive modulation, also comprise mortar modulation and mortar coating, described ashSlurry comprises polyurethane 8-19 part, acrylic acid 21-32 part by weight; The fire-retardant dispersion 35-40 part of phosphorus series non-halogen; Titanium dioxide dividesProse style free from parallelism 8-15 part; Foam stabilizer 10-15 part; Blowing agent 0.8-1.5 part; Ammoniacal liquor 0.5-1 part; Black color paste 0.2-2 part; Stiffening glue 5-25 parts; Described mortar pH value 9.8-10, viscosity 2200-2500cps;
Painting nose angle degree when described mortar coating is 90-95 °, cutter apart from being 35-for 0.5-0.6mm, foamed slurry density40g/cm3, expansion ratio be 4-5 doubly, pressure roller air pressure is at 0.3-0.4MPa; Described grey cloth is 17-22m/ through the speed of pressure rollermin。
As preferably, described dispersant is polycarboxylate sodium's water treatment dispersion, described rheology control agent be silicon gel orPolyacrylamide.
More preferably, the formula of the fire-retardant dispersant of described phosphorus series non-halogen is 28 parts, acrylic acid by weight, aluminium hydroxide 52Part, 50 parts of APPs, 40 parts of titanium dioxide, 8 parts of polyurethane, 54 parts, water, 0.5 part of dispersant, 0.25 part of bleeding agent, rheology is adjusted5 parts of joint agent.
Detailed description of the invention
Embodiment mono-
Grey cloth preparation: comprise turn over that cloth, weft yarn are opened sanction, margin to seam, singed, water spray, dyeing and finishing and sizing, be prepared into 300 × 600DThe oxford of different patterns; Weft yarn is opened and cut out is that fabric is cut apart with a knife or scissors by weft yarn; Margin to seam is that margin to seam between board, between fabric is carried outThe parallel margin to seam of weft yarn; Sizing is included in 150 DEG C of whole latitude sizings;
Wherein, dyeing and finishing dyestuff used comprises reactive dye and reducing dye, and reactive dye are De Sida companyImperon-HF-R, reducing dye is at least one in olive T, blue ARN, red R, black ES-SE, blue RSN, blue CLF, purple 2R;
White slurry modulation and the first coating: white slurry comprises 8 parts of polyurethane, 21 parts, acrylic acid by weight; Phosphorus series non-halogen is fire-retardant35 parts of dispersions; 8 parts of titanium dioxide dispersion; 10 parts of foam stabilizers; 0.8 part of blowing agent; 0.5 part of ammoniacal liquor; White slurry pH value 9.8; StickyDegree 2200cps; Then adopt painting cutter pressure roller will starch in vain to roll in grey cloth one side and obtain the first coating;
Wherein, painting nose angle degree when the first coating is 90 °, cutter apart from being 47g/cm for 0.6mm, foamed slurry density3, foamingMultiplying power is that 3.2 times, pressure roller air pressure are at 0.3MPa; Cutter head is flat cutter; Grey cloth is 15m/min through the speed of pressure roller.
Black wash modulation and the second coating: black wash comprises 8 parts of polyurethane by weight, 21 parts, acrylic acid; Phosphorus series non-halogen is fire-retardant35 parts of dispersions; 8 parts of titanium dioxide dispersion; Foam stabilizer 10-15 part; 0.8 part of blowing agent; 0.5 part of ammoniacal liquor; 1 part of black color paste;5 parts, stiffening glue; Black wash pH value 9.8, viscosity 2200cps; Then adopt and be coated with cutter pressure roller black wash is rolled on the first coatingObtain the second coating;
Wherein, painting nose angle degree when the second coating is 90 °, cutter apart from being 46g/cm for 0.6mm, foamed slurry density3, foamingMultiplying power is that 3 times, pressure roller air pressure are at 0.3MPa; Grey cloth is 16m/min through the speed of pressure roller.
Mortar modulation and the 3rd coating: comprise by weight 8 parts of polyurethane, 21 parts, acrylic acid; The fire-retardant dispersion of phosphorus series non-halogen35 parts of bodies; 8 parts of titanium dioxide dispersion; 10 parts of foam stabilizers; 0.8 part of blowing agent; 0.5 part of ammoniacal liquor; 0.2 part of black color paste; Stiffening5 parts, glue; Mortar pH value 9.8, viscosity 2200cps; Then adopt painting cutter pressure roller that mortar is rolled on the second coating and obtainedThe 3rd coating;
Wherein, painting nose angle degree when the 3rd coating is 90 °, cutter apart from being 35g/cm for 0.5mm, foamed slurry density3, foamingMultiplying power is that 4 times, pressure roller air pressure are at 0.3MPa; Grey cloth is 17m/min through the speed of pressure roller.
Stiffening glue in black wash or mortar be polystyrene withAcrylateThe anionic emulsion that copolymerization forms;
Starch adhesive modulation and the 4th coating: starch adhesive comprises 50 parts of polyurethane by weight; 20 parts of the fire-retardant dispersions of phosphorus series non-halogen;10 parts of titanium dioxide dispersion; 8 parts of foam stabilizers; 1 part of blowing agent; 0.5 part of ammoniacal liquor; Starch adhesive pH value 9.8, viscosity 2000cps; ThenAdopt painting cutter pressure roller that starch adhesive is rolled on the 3rd coating and obtains the 4th coating;
Wherein, painting nose angle degree when the 4th coating is 90 °, cutter apart from being 47g/cm for 0.7mm, foamed slurry density3, foamingMultiplying power is that 3 times, pressure roller air pressure are at 0.35MPa; Grey cloth is 17m/min through the speed of pressure roller.
Black color paste in white slurry, black wash, mortar or starch adhesive comprises a divided titanium dioxide prose style free from parallelism and aqueous black pigment; Titanium dioxideDispersion is that titanium dioxide, water, dispersant are mixed and disperse to form according to weight portion 55:35:0.5.
Scrape mill base modulation and cloth cover and scrape look: scrape mill base and comprise by weight 14 parts of water-based acrylic emulsions; 4 parts of polyurethane;20 parts of the fire-retardant dispersions of phosphorus series non-halogen; 0.1 part of defoamer; 2 parts of bleeding agents; 0.5 part of pH value stabilization agent; Viscosity 20000cps; SoRear employing sharp knife carries out cloth cover and scrapes look with scraping mill base at the another side of grey cloth.
Painting nose angle degree when cloth cover is scraped look is 90 °, cutter apart from being 47g/cm for 38mm, foamed slurry density3, expansion ratio is3.2 times, pressure roller air pressure are at 0.3MPa; Cutter head is sharp knife; Grey cloth is 12m/min through the speed of pressure roller.
Blowing agent in above-mentioned each layer of slurries is by the pentamethylene of 1:1 mass mixing and normal butane; Bleeding agent is maleicDiacid di-sec-octyl sodium sulfonate; Foam stabilizer is sodium sulfate of polyethenoxy ether of fatty alcohol.
The formula of the fire-retardant dispersant of phosphorus series non-halogen is 25 parts, acrylic acid by weight, 50 parts, aluminium hydroxide, APP 45Part, 28 parts of titanium dioxide, 6 parts of polyurethane, 50 parts, water, 0.2 part of polycarboxylate sodium's water treatment dispersion, 0.15 part of bleeding agent, silicon3 parts of gels.
Embodiment bis-
Grey cloth preparation: comprise turn over that cloth, weft yarn are opened sanction, margin to seam, singed, water spray, dyeing and finishing and sizing, be prepared into 300 × 600DThe oxford of different patterns; Weft yarn is opened and cut out is that fabric is cut apart with a knife or scissors by weft yarn; Margin to seam is that margin to seam between board, between fabric is carried outThe parallel margin to seam of weft yarn; Sizing is included in 160 DEG C of whole latitude sizings;
Wherein, dyeing and finishing dyestuff used comprises reactive dye and reducing dye, and reactive dye are De Sida companyLevafixEA, reducing dye is blue ARN;
White slurry modulation and the first coating: white slurry comprises 19 parts of polyurethane, 32 parts, acrylic acid by weight; Phosphorus series non-halogen is fire-retardant40 parts of dispersions; 15 parts of titanium dioxide dispersion; 15 parts of foam stabilizers; 1.5 parts of blowing agents; 1 part of ammoniacal liquor; White slurry pH value 10; Viscosity2500cps; Then adopt painting cutter pressure roller will starch in vain to roll in grey cloth one side and obtain the first coating;
Wherein, painting nose angle degree when the first coating is 95 °, cutter apart from being 48g/cm for 0.65mm, foamed slurry density3, send outBubble multiplying power is that 4 times, pressure roller air pressure are at 0.4MPa; Cutter head is flat cutter; Grey cloth is 18m/min through the speed of pressure roller.
Black wash modulation and the second coating: black wash comprises 19 parts of polyurethane by weight, 32 parts, acrylic acid; Phosphorus series non-halogen is fire-retardant40 parts of dispersions; 15 parts of titanium dioxide dispersion; 15 parts of foam stabilizers; 1.5 parts of blowing agents; 1 part of ammoniacal liquor; 6 parts of black color pastes; Stiffening25 parts, glue; Black wash pH value 10, viscosity 2500cps; Then adopt painting cutter pressure roller that black wash is rolled on the first coating and obtainedThe second coating;
Wherein, painting nose angle degree when the second coating is 95 °, cutter apart from being 49g/cm for 0.65mm, foamed slurry density3, send outBubble multiplying power is that 4 times, pressure roller air pressure are at 0.4MPa; Grey cloth is 18m/min through the speed of pressure roller.
Mortar modulation and the 3rd coating: black wash comprises 19 parts of polyurethane by weight, 32 parts, acrylic acid; Phosphorus series non-halogen is fire-retardant40 parts of dispersions; Titanium dioxide disperses 15 parts; 15 parts of foam stabilizers; 1.5 parts of blowing agents; 1 part of ammoniacal liquor; 2 parts of black color pastes; Stiffening glue25 parts; Mortar pH value 10, viscosity 2500cps; Then adopt and be coated with cutter pressure roller mortar is rolled and obtains the on the second coatingThree coatings;
Wherein, painting nose angle degree when the 3rd coating is 95 °, cutter apart from being 40g/cm for 0.6mm, foamed slurry density3, foamingMultiplying power is that 5 times, pressure roller air pressure are at 0.4MPa; Grey cloth is 22m/min through the speed of pressure roller.
Stiffening glue in black wash or mortar be acrylic acid withAcrylateThe anionic emulsion that copolymerization forms.
Starch adhesive modulation and the 4th coating: starch adhesive comprises 60 parts of polyurethane by weight; 30 parts of the fire-retardant dispersions of phosphorus series non-halogen;15 parts of titanium dioxide dispersion; 15 parts of foam stabilizers; 2.2 parts of blowing agents; 1.2 parts of ammoniacal liquor; Starch adhesive pH value 10, viscosity 2400cps; SoRear employing is coated with cutter pressure roller starch adhesive is rolled on the 3rd coating and obtains the 4th coating;
Wherein, painting nose angle degree when the 4th coating is 95 °, cutter apart from being 48g/cm for 0.75mm, foamed slurry density3, send outBubble multiplying power is that 3.5 times, pressure roller air pressure are at 0.4MPa; Grey cloth is 22m/min through the speed of pressure roller.
Black color paste in white slurry, black wash, mortar or starch adhesive comprises a divided titanium dioxide prose style free from parallelism and aqueous black pigment; Titanium dioxideDispersion is that titanium dioxide, water, dispersant are mixed and disperse to form according to weight portion 65:45:1.
Scrape mill base modulation and cloth cover and scrape look: scrape mill base and comprise by weight 28 parts of water-based acrylic emulsions; 8 parts of polyurethane;30 parts of the fire-retardant dispersions of phosphorus series non-halogen; 0.27 part of defoamer; 5 parts of bleeding agents; 1.9 parts of pH value stabilization agent; Viscosity 30000cps; SoRear employing sharp knife carries out cloth cover and scrapes look with scraping mill base at the another side of grey cloth.
Painting nose angle degree when cloth cover is scraped look is 95 °, cutter apart from being 48g/cm for 42mm, foamed slurry density3, expansion ratio is4 times, pressure roller air pressure are at 0.4MPa; Cutter head is sharp knife; Grey cloth is 16m/min through the speed of pressure roller.
Blowing agent in above-mentioned each layer of slurries is the normal butane of 1:1 mass mixing and 5% sodium bicarbonate solution; Bleeding agentFor disecoctylmaleate sodium sulfonate; Foam stabilizer is DDAO.
The formula of the fire-retardant dispersant of phosphorus series non-halogen is 30 parts, acrylic acid by weight, 55 parts, aluminium hydroxide, APP 55Part, 44 parts of titanium dioxide, 12 parts of polyurethane, 60 parts, water, 0.8 part of polycarboxylate sodium's water treatment dispersion, 0.35 part of bleeding agent, silicon5 parts of gels.
Embodiment tri-
Grey cloth preparation: comprise turn over that cloth, weft yarn are opened sanction, margin to seam, singed, water spray, dyeing and finishing and sizing, be prepared into 300 × 600DThe oxford of different patterns; Weft yarn is opened and cut out is that fabric is cut apart with a knife or scissors by weft yarn; Margin to seam is that margin to seam between board, between fabric is carried outThe parallel margin to seam of weft yarn; Sizing is included in 155 DEG C of whole latitude sizings;
Wherein, dyeing and finishing dyestuff used comprises reactive dye and reducing dye, and reactive dye are De Sida companyProcionH-EXL, reducing dye is blue RSN and blue CLF;
White slurry modulation and the first coating: white slurry comprises 12 parts of polyurethane, 28 parts, acrylic acid by weight; Phosphorus series non-halogen is fire-retardant38 parts of dispersions; 11 parts of titanium dioxide dispersion; 12 parts of foam stabilizers; 1.2 parts of blowing agents; 0.9 part of ammoniacal liquor; White slurry pH value 9.9; StickyDegree 2400cps; Then adopt painting cutter pressure roller will starch in vain to roll in grey cloth one side and obtain the first coating;
Wherein, painting nose angle degree when the first coating is 93 °, cutter apart from being 47.5g/cm for 0.64mm, foamed slurry density3、Expansion ratio is that 3.8 times, pressure roller air pressure are at 0.36MPa; Cutter head is flat cutter; Grey cloth is 17m/min through the speed of pressure roller.
Black wash modulation and the second coating: black wash comprises 12 parts of polyurethane by weight, 28 parts, acrylic acid; Phosphorus series non-halogen is fire-retardant38 parts of dispersions; 11 parts of titanium dioxide dispersion; 12 parts of foam stabilizers; 1.2 parts of blowing agents; 0.8 part of ammoniacal liquor; 5 parts of black color pastes; FirmlyVery 21 parts, glue; Black wash pH value 9.9, viscosity 2400cps; Then adopt painting cutter pressure roller that black wash is rolled on the first coating and obtainedObtain the second coating;
Wherein, painting nose angle degree when the second coating is 94 °, cutter apart from being 48g/cm for 0.64mm, foamed slurry density3, send outBubble multiplying power is that 3.5 times, pressure roller air pressure are at 0.35MPa; Grey cloth is 17m/min through the speed of pressure roller.
Mortar modulation and the 3rd coating: black wash comprises 13 parts of polyurethane by weight, 28 parts, acrylic acid; Phosphorus series non-halogen is fire-retardant37 parts of dispersions; 11 parts of titanium dioxide dispersion; 13 parts of foam stabilizers; 1.2 parts of blowing agents; 0.8 part of ammoniacal liquor; 1.2 parts of black color pastes;18 parts, stiffening glue; Mortar pH value 9.9, viscosity 2400cps; Then adopt and be coated with cutter pressure roller mortar is rolled on the second coatingObtain the 3rd coating;
Wherein, painting nose angle degree when the 3rd coating is 94 °, cutter apart from being 38g/cm for 0.55mm, foamed slurry density3, send outBubble multiplying power is that 4.5 times, pressure roller air pressure are at 0.36MPa; Grey cloth is 19m/min through the speed of pressure roller.
Stiffening glue in black wash or mortar isVinyl acetateWithAcrylateThe anionic emulsion that copolymerization forms;
Starch adhesive modulation and the 4th coating: starch adhesive comprises 56 parts of polyurethane by weight; 27 parts of the fire-retardant dispersions of phosphorus series non-halogen;12 parts of titanium dioxide dispersion; 13 parts of foam stabilizers; 1.2 parts of blowing agents; 0.9 part of ammoniacal liquor; Starch adhesive pH value 9.9, viscosity 2300cps;Then adopt painting cutter pressure roller that starch adhesive is rolled on the 3rd coating and obtains the 4th coating;
Wherein, painting nose angle degree when the 4th coating is 94 °, cutter apart from being 47.5g/cm for 0.73mm, foamed slurry density3、Expansion ratio is that 3.3 times, pressure roller air pressure are at 0.38MPa; Grey cloth is 19m/min through the speed of pressure roller.
Black color paste in white slurry, black wash, mortar or starch adhesive comprises a divided titanium dioxide prose style free from parallelism and aqueous black pigment; Titanium dioxideDispersion is that titanium dioxide, water, dispersant are mixed and disperse to form according to weight portion 61:41:0.8.
Scrape mill base modulation and cloth cover and scrape look: scrape mill base and comprise by weight 18 parts of water-based acrylic emulsions; 6 parts of polyurethane;28 parts of the fire-retardant dispersions of phosphorus series non-halogen; 0.17 part of defoamer; 4 parts of bleeding agents; 1.3 parts of pH value stabilization agent; Viscosity 23000cps; SoRear employing sharp knife carries out cloth cover and scrapes look with scraping mill base at the another side of grey cloth.
Painting nose angle degree when cloth cover is scraped look is 93 °, cutter apart from being 47.6g/cm for 39mm, foamed slurry density3, expansion ratioBe that 3.6 times, pressure roller air pressure are at 0.36MPa; Cutter head is sharp knife; Grey cloth is 15m/min through the speed of pressure roller.
Blowing agent in above-mentioned each layer of slurries is by the pentamethylene of quality 1:1 mixing and the sodium bicarbonate solution of 5-15%; OozeAgent is disecoctylmaleate sodium sulfonate thoroughly; Foam stabilizer is alkylolamides.
The formula of the fire-retardant dispersant of phosphorus series non-halogen is 28 parts, acrylic acid by weight, 52 parts, aluminium hydroxide, APP 49Part, 39 parts of titanium dioxide, 11 parts of polyurethane, 58 parts, water, 0.6 part of polycarboxylate sodium's water treatment dispersion, bleeding agent 0.15-0.35Part, 8 parts of polyacrylamides.
Embodiment tetra-
With embodiment mono-, different is in white slurry polyurethane and acrylic acid accounts for the half of total formulation weight; Black wash or mortarMiddle polyurethane and acrylic acid account for the 40-50% of total formulation weight. The formula of the fire-retardant dispersant of phosphorus series non-halogen is acrylic acid by weight28 parts, 52 parts, aluminium hydroxide, 50 parts of APPs, 40 parts of titanium dioxide, 8 parts of polyurethane, 54 parts, water, 0.5 part of dispersant, infiltration0.25 part of agent, 5 parts of rheology control agents.
Transaudient and sound insulation test is carried out in the standard room of 10 square metres.
Experiment explanation explanation:
IIC (impact acoustical ratings), according to GB requirement, carries out the measurement of the level difference of each frequency range, directly according to ISO everyThe result that sound appraisal curve is evaluated is out sound insulation class (or weighted transmission loss), and this value does not comprise wall area, sound receiving roomThe corrections such as absorption, flanking transmission loss; Therefore sound insulation class is commonly used to describe the actual sound insulation effect between two adjacent roomReally. Impact sound insulation test according to the test of the ASTM49209 of American society association method, impact acoustical ratings according to U.S. materialThe experiment ASTME989 of association standard grading. Higher grade of IIC, and sound insulation property is better.
STC (transaudient grade) refers in laboratory or on-the-spot carries out each frequency rangeSound insulationAmount detects later again according to measuring wallAfter body is revised by the factor such as absorption, flanking transmission of sound area, sound receiving room, then according to the evaluation of ISO sound insulation appraisal curveResult out, is generally used for evaluating the sound insulation property of building element. The transaudient grade separation of transaudient level estimate method is according to U.S.The state ASTME413-04 of material experiment association standard grading. Higher grade of STC, and sound insulation property is better.
Transaudient test is 11 DEG C of room temperatures, and relative humidity is carried out for 71% time.
Table 1
1/3 multiplying power mid-band frequency 1/3 multiplying power frequency band acoustic pressure
Hertz DB (0.0002 microbar)
100 45
125 48
160 47
200 42
250 40
315 39
400 41
500 40
630 34
800 25
1000 18
1250 12
1600 8
2000 4
2500 4
3150 5
Clash into acoustical ratings (IIC) 72
Table 2
1/3 multiplying power mid-band frequency Oise insulation factor
Hertz dB
125 78.2
160 79.9
200 80.6
250 69.1
315 70.2 7 -->
400 73.6
500 78.6
630 81.2
800 82.6
1000 84.5
1250 88.7
1600 92.1
2000 93.7
2500 92.1
3150 91.9
4000 91.4
Transaudient grade (STC) 82
As can be seen from Table 2, material of the present invention can effectively completely cut off high frequency noise and low frequency noise. And ordinary cityPlane materiel material does not only possess this function, and transaudient grade is generally below 50.
Can draw from table 1 and table 2, the sound-absorbing effect of halogen-free flame-retardant expanded coating curtain of the present invention is better than common greatlyMarket material.
In addition, to anti-flammability, test adopts flaming combustion and flameless combustion to test its burning time, with ordinary city plane materiel materialContrast. The flaming combustion time is long and the internally fired nonflame time is short, illustrates that its anti-flammability is strong. After tested, anti-flammability of the present inventionBe better than ordinary city plane materiel material.
The amount of being fuming while simultaneously collecting burning is carried out smog test, and the present invention's amount of being fuming is less than ordinary city plane materiel material.
This specific embodiment is only explanation of the invention, and it is not limitation of the present invention, art technology peopleMember is reading after this description and can make to the present embodiment the amendment that there is no creative contribution as required, but as long as at thisWithin the scope of the claim of invention, be all subject to the protection of Patent Law.

Claims (8)

1. a shading intumescent coating curtain, is characterized in that: its preparation method comprises the following steps successively:
(1) grey cloth preparation;
(2) white slurry modulation and the first coating: described white slurry comprises polyurethane 8-19 part by weight, acrylic acid 21-32 part; Phosphorus systemHalogen-free flameproof dispersant 35-40 part; Titanium dioxide dispersion 8-15 part; Foam stabilizer 10-15 part; Blowing agent 0.8-1.5 part; Ammoniacal liquor0.5-1 part; Described white slurry pH value 9.8-10; Viscosity 2200-2500cps; Then adopt painting cutter pressure roller that described white slurry is rolledUpper first coating that obtains of described grey cloth one side;
(3) black wash modulation and the second coating: described black wash comprises polyurethane 8-19 part by weight, acrylic acid 21-32 part; Phosphorus systemHalogen-free flameproof dispersant 35-40 part; Titanium dioxide dispersion 8-15 part; Foam stabilizer 10-15 part; Blowing agent 0.8-1.5 part; Ammoniacal liquor0.5-1 part; Black color paste 1-6 part; Stiffening glue 5-25 part; Described black wash pH value 9.8-10, viscosity 2200-2500cps; Then adoptWith being coated with cutter pressure roller, described black wash is rolled and in the first coating, obtains the second coating;
(4) starch adhesive modulation and the 3rd coating: described starch adhesive comprises polyurethane 50-60 part by weight; The fire-retardant dispersion of phosphorus series non-halogenAgent 20-30 part; Titanium dioxide dispersion 10-15 part; Foam stabilizer 8-15 part; Blowing agent 1-2.2 part; Ammoniacal liquor 0.5-1.2 part; DescribedStarch adhesive pH value 9.8-10, viscosity 2000-2400cps; Then adopt painting cutter pressure roller that described starch adhesive is rolled in the second coating and obtainedObtain the 3rd coating;
(5) scrape mill base modulation and cloth cover and scrape look: described in scrape mill base and comprise by weight water-based acrylic emulsion 14-28 part; Poly-ammoniaEster 4-8 part; The fire-retardant dispersant 20-30 of phosphorus series non-halogen part; Defoamer 0.1-0.27 part; Bleeding agent 2-5 part; PH value stabilization agent 0.5-1.9 part; The described mill base viscosity 20000-30000cps that scrapes; Then adopt sharp knife the another side of described grey cloth with described in scrape mill baseCarry out cloth cover and scrape look;
The formula of the fire-retardant dispersant of described phosphorus series non-halogen is acrylic acid 25-30 part by weight, aluminium hydroxide 50-55 part, poly-phosphorusAcid ammonium 45-55 part, titanium dioxide 28-44 part, polyurethane 6-12 part, water 50-60 part, dispersant 0.2-0.8 part, bleeding agent0.15-0.35 part, rheology control agent 3-8 part.
2. a kind of shading intumescent coating curtain according to claim 1, is characterized in that: described black color paste comprises titanium whitePowder dispersion and aqueous black pigment; A described divided titanium dioxide prose style free from parallelism be by titanium dioxide, water, dispersant according to weight portion 55-65:Disperse to form 35-45:0.5-1 mix.
3. a kind of shading intumescent coating curtain according to claim 2, is characterized in that: painting cutter when described the first coatingAngle is 90-95 °, cutter apart from being 47-48g/cm for 0.6-0.65mm, foamed slurry density3, expansion ratio be 3.2-4 doubly, pressure rollerAir pressure is at 0.3-0.4MPa; Cutter head is flat cutter; Described grey cloth is 15-18m/min through the speed of pressure roller.
4. a kind of shading intumescent coating curtain according to claim 3, is characterized in that: painting cutter when described the second coatingAngle is 90-95 °, cutter apart from being 46-49g/cm for 0.6-0.65mm, foamed slurry density3, expansion ratio be 3-4 doubly, pressure roller gasBe pressed in 0.3-0.4MPa; Described grey cloth is 16-18m/min through the speed of pressure roller.
5. a kind of shading intumescent coating curtain according to claim 4, is characterized in that: painting cutter when described the 3rd coatingAngle is 90-95 °, cutter apart from being 47-48g/cm for 0.7-0.75mm, foamed slurry density3, expansion ratio be 3-3.5 doubly, pressure rollerAir pressure is at 0.35-0.4MPa; Described grey cloth is 17-22m/min through the speed of pressure roller.
6. a kind of shading intumescent coating curtain according to claim 5, is characterized in that: painting cutter when described cloth cover is scraped lookAngle is 90-95 °, cutter apart from being 47-48g/cm for 38-42mm, foamed slurry density3, expansion ratio be 3.2-4 doubly, pressure roller gasBe pressed in 0.3-0.4MPa; Cutter head is sharp knife; Described grey cloth is 12-16m/min through the speed of pressure roller.
7. according to a kind of shading intumescent coating curtain described in claim 1-6 any one, it is characterized in that: adjust at described black washBetween system and starch adhesive modulation, also comprise mortar modulation and mortar coating, described mortar comprises polyurethane 8-19 part, third by weightOlefin(e) acid 21-32 part; The fire-retardant dispersant 35-40 of phosphorus series non-halogen part; Titanium dioxide dispersion 8-15 part; Foam stabilizer 10-15 part; FoamingAgent 0.8-1.5 part; Ammoniacal liquor 0.5-1 part; Black color paste 0.2-2 part; Stiffening glue 5-25 part; Described mortar pH value 9.8-10, viscosity2200-2500cps;
Painting nose angle degree when described mortar coating is 90-95 °, cutter apart from being 35-40g/cm for 0.5-0.6mm, foamed slurry density3、Expansion ratio be 4-5 doubly, pressure roller air pressure is at 0.3-0.4MPa; Described grey cloth is 17-22m/min through the speed of pressure roller.
8. according to a kind of shading intumescent coating curtain described in claim 1-6 any one, it is characterized in that: described phosphorus series non-halogenDispersant in fire-retardant dispersant is polycarboxylate sodium's water treatment dispersion, and described rheology control agent is silicon gel or polyacrylamideAmine.
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CN105239395A (en) * 2015-09-29 2016-01-13 杭州华辰植绒股份有限公司 Color scraped cloth scraping and preparation method thereof
CN105525506A (en) * 2015-12-29 2016-04-27 苏州宇希新材料科技有限公司 Preparation method of textile heat insulation coating
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JP2019126984A (en) * 2018-01-25 2019-08-01 大日本印刷株式会社 Heat-insulating decorative sheet, and decorative member using the same
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