CN104140636A - High-hardness impact-resistant heat-insulation foamed plastic - Google Patents
High-hardness impact-resistant heat-insulation foamed plastic Download PDFInfo
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- CN104140636A CN104140636A CN201410390735.XA CN201410390735A CN104140636A CN 104140636 A CN104140636 A CN 104140636A CN 201410390735 A CN201410390735 A CN 201410390735A CN 104140636 A CN104140636 A CN 104140636A
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Abstract
The invention discloses a high-hardness impact-resistant heat-insulation foamed plastic which comprises the following raw materials in parts by weight: 57-60 parts of ABS (acrylonitrile butadiene styrene) resin, 32-35 parts of EVA (ethylene vinyl acetate) resin, 22-26 parts of epoxy resin, 15-18 parts of phenolic resin, 3-3.6 parts of nylon 66 fibers, 2.5-2.9 parts of glass fibers, 2.4-2.7 parts of a silane coupling agent A-172, 15-18 parts of a foamer K, 3-6 parts of supercritical nitrogen gas, 9-12 parts of supercritical carbon dioxide, 3-6 parts of a polyethylene-octene copolymer elastomer (POE), 2.1-2.4 parts of diisononyl phthalate (DINP), 3.7-4 parts of epoxy octyl stearate, 7-10 parts of fumed silica, 25-28 parts of wollastonite powder, 17-21 parts of augite powder, 10-13 parts of mica powder, 0.7-2.1 parts of an antioxidant RD and 2.4-2.8 parts of an antioxidant 4010NA.
Description
Technical field
The present invention relates to expanded plastic technical field, relate in particular to the shock-resistant heat insulation expanded plastic of a kind of high rigidity.
Background technology
Expanded plastic, is obtained by plastic foamed moulding.Foaming is to make plastics produce the process of microvoid structure.Nearly all thermoset and thermoplastics can be made porous plastics, and conventional resin has polystyrene, urethane, polyvinyl chloride, polyethylene, urea formaldehyde, phenolic aldehyde etc.Existing expanded plastic is often used for heat insulation, but effect is unsatisfactory, and the impact resistance of expanded plastic and hardness are difficult to reach unified.
Summary of the invention
The technical problem that basic background technology exists, the present invention proposes the shock-resistant heat insulation expanded plastic of a kind of high rigidity, and impact resistance and hardness reach unified, and heat-proof quality is excellent, also has outstanding compression and tensile property.
The shock-resistant heat insulation expanded plastic of a kind of high rigidity that the present invention proposes, its raw material comprises by weight:
Preferably, in ABS resin, vinyl cyanide, divinyl and cinnamic weight ratio are 29-32:27-28:47-49.
Preferably, in EVA resin, the content of vinyl acetate between to for plastic is 12-16wt%.
Preferably, the shore hardness of polyethylene-octene copolymer elastomerics POE is 72-80HA.
Preferably, its raw material comprises by weight:
It is major ingredient that ABS resin, EVA resin, epoxy resin, resol are take in the present invention, makes the present invention have excellent hardness and the outstanding performance such as heat-resisting, shock-resistant, fire-retardant; Add diisononyl phthalate DINP, octyl epoxy stearate to mix with major ingredient, when improving system mobility, material is better disperseed, realized the comprehensive raising of heat-resisting effect and mechanical property, and octyl epoxy stearate is also as stablizer, with antioxidant RD, antioxidant 4010NA combined action, significantly improve oxidation resistance of the present invention, not hardening in life-time service process, do not rupture, without shrinking perk phenomenon, not affecting viscosity, extend work-ing life of the present invention; Coordinate and add polyethylene-octene copolymer elastomerics POE as toughner, by different particle diameters and different toughening mechanism, toughening effect is significantly strengthened, increasing substantially the stable on heating while, have and there is good processing characteristics and impact resistance; And nylon 66 fiber and glass fibre are used in conjunction with, significantly improved stretch-proof performance of the present invention, simultaneously with gas-phase silica, wollastonite powder, pyroxene powder, mica powder combined action, greatly improved wear resisting property of the present invention, and by the characteristic of silane coupling A-172, make inorganic raw material and form an integral body with major ingredient; Whipping agent K, overcritical nitrogen, supercritical co mix with major ingredient and mating reaction, make the bubble in the present invention even, and have reduced thermal conductivity, have improved heat-proof quality, have also greatly improved compression ability.
Embodiment
Below, by specific embodiment, technical scheme of the present invention is elaborated, in embodiment 1-4, the raw material of the shock-resistant heat insulation expanded plastic of a kind of high rigidity that the present invention proposes is composition as shown in the table by weight.
Wherein, in embodiment 1, the vinyl cyanide of ABS resin, divinyl and vinylbenzene weight ratio are 29:28:47, and the shore hardness of polyethylene-octene copolymer elastomerics POE is 72HA; In embodiment 2, the vinyl cyanide of ABS resin, divinyl and vinylbenzene weight ratio are 32:27:49, and the vinyl acetate content of EVA resin is 12wt%; In embodiment 3, the vinyl acetate content of EVA resin is 16wt%, and the shore hardness of polyethylene-octene copolymer elastomerics POE is 80HA; In embodiment 4, the vinyl cyanide of ABS resin, divinyl and vinylbenzene weight ratio are 30:27.5:48, and the vinyl acetate content of EVA resin is 14wt%, and the shore hardness of polyethylene-octene copolymer elastomerics POE is 75HA.
The shock-resistant heat insulation expanded plastic of the high rigidity of embodiment 1-4 gained is carried out to performance test, and result is as shown in the table:
| Test item | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Standard |
| Thermal conductivity [W/ (mh)] | 0.020 | 0.018 | 0.022 | 0.016 | ＜0.028 |
| 10% compressive strength (MPa) | 4.7 | 5.0 | 4.5 | 5.2 | ＞1 |
| Tensile strength (MPa) | 8.7 | 9.3 | 8.2 | 9.8 | ＞5.5 |
| Shore hardness (HA) | 72 | 70 | 73 | 69 | / |
The above; it is only preferably embodiment of the present invention; but protection scope of the present invention is not limited to this; anyly be familiar with those skilled in the art in the technical scope that the present invention discloses; according to technical scheme of the present invention and inventive concept thereof, be equal to replacement or changed, within all should being encompassed in protection scope of the present invention.
Claims (5)
1. the shock-resistant heat insulation expanded plastic of high rigidity, is characterized in that, its raw material comprises by weight:
2. the shock-resistant heat insulation expanded plastic of high rigidity as claimed in claim 1, is characterized in that, in ABS resin, vinyl cyanide, divinyl and cinnamic weight ratio are 29-32:27-28:47-49.
3. the shock-resistant heat insulation expanded plastic of high rigidity as claimed in claim 2, is characterized in that, in EVA resin, the content of vinyl acetate between to for plastic is 12-16wt%.
4. the shock-resistant heat insulation expanded plastic of high rigidity as claimed in claim 3, is characterized in that, the shore hardness of polyethylene-octene copolymer elastomerics POE is 72-80HA.
5. heat insulation expanded plastic as shock-resistant in high rigidity as described in claim 1-4 any one, is characterized in that, its raw material comprises by weight:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410390735.XA CN104140636A (en) | 2014-08-10 | 2014-08-10 | High-hardness impact-resistant heat-insulation foamed plastic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201410390735.XA CN104140636A (en) | 2014-08-10 | 2014-08-10 | High-hardness impact-resistant heat-insulation foamed plastic |
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| CN104140636A true CN104140636A (en) | 2014-11-12 |
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| CN201410390735.XA Pending CN104140636A (en) | 2014-08-10 | 2014-08-10 | High-hardness impact-resistant heat-insulation foamed plastic |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105176062A (en) * | 2015-11-02 | 2015-12-23 | 淄博夸克医药技术有限公司 | High-hardness impact-resisting heat-insulation foaling plastic |
| CN105566732A (en) * | 2015-11-30 | 2016-05-11 | 常州碳润新材料科技有限公司 | Automotive high-foam sound-insulation material and method for preparing same |
| CN105566733A (en) * | 2015-11-30 | 2016-05-11 | 常州碳润新材料科技有限公司 | Automotive graphene EVA (ethylene vinyl acetate copolymer) high-foam sound-insulation material and method for preparing same |
| CN107476371A (en) * | 2017-09-22 | 2017-12-15 | 江苏紫石机械制造有限公司 | One kind grab bucket |
| CN107652617A (en) * | 2017-11-21 | 2018-02-02 | 马鞍山松鹤信息科技有限公司 | A kind of toy for children special environment protection plastics and preparation method thereof |
| CN107653922A (en) * | 2017-09-22 | 2018-02-02 | 江苏紫石机械制造有限公司 | A kind of grab bucket with stress buffer characteristic |
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| US20070090560A1 (en) * | 2005-10-25 | 2007-04-26 | L&L Products, Inc. | Shaped expandable material |
| CN101712780A (en) * | 2009-08-25 | 2010-05-26 | 上海普利特复合材料股份有限公司 | Low-density, high-rigidity and high-tenacity polypropylene nano composite material and preparation method thereof |
| CN103030924A (en) * | 2012-12-11 | 2013-04-10 | 四川大学 | Fiber material modified melamine formaldehyde foam and preparation method thereof |
| CN103052676A (en) * | 2010-08-03 | 2013-04-17 | 费罗公司 | Polymer composite foams |
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Patent Citations (4)
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| US20070090560A1 (en) * | 2005-10-25 | 2007-04-26 | L&L Products, Inc. | Shaped expandable material |
| CN101712780A (en) * | 2009-08-25 | 2010-05-26 | 上海普利特复合材料股份有限公司 | Low-density, high-rigidity and high-tenacity polypropylene nano composite material and preparation method thereof |
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Non-Patent Citations (1)
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| 周殿明: "《塑料制品成型材料》", 31 October 2011, article "1.1.10 乙烯-醋酸乙烯共聚物", pages: 43-44 * |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105176062A (en) * | 2015-11-02 | 2015-12-23 | 淄博夸克医药技术有限公司 | High-hardness impact-resisting heat-insulation foaling plastic |
| CN105566732A (en) * | 2015-11-30 | 2016-05-11 | 常州碳润新材料科技有限公司 | Automotive high-foam sound-insulation material and method for preparing same |
| CN105566733A (en) * | 2015-11-30 | 2016-05-11 | 常州碳润新材料科技有限公司 | Automotive graphene EVA (ethylene vinyl acetate copolymer) high-foam sound-insulation material and method for preparing same |
| CN105566732B (en) * | 2015-11-30 | 2018-06-19 | 常州碳润新材料科技有限公司 | A kind of automobile-used high-foaming acoustic material and preparation method thereof |
| CN107476371A (en) * | 2017-09-22 | 2017-12-15 | 江苏紫石机械制造有限公司 | One kind grab bucket |
| CN107653922A (en) * | 2017-09-22 | 2018-02-02 | 江苏紫石机械制造有限公司 | A kind of grab bucket with stress buffer characteristic |
| CN107652617A (en) * | 2017-11-21 | 2018-02-02 | 马鞍山松鹤信息科技有限公司 | A kind of toy for children special environment protection plastics and preparation method thereof |
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Application publication date: 20141112 |