CN107652617A - A kind of toy for children special environment protection plastics and preparation method thereof - Google Patents
A kind of toy for children special environment protection plastics and preparation method thereof Download PDFInfo
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- CN107652617A CN107652617A CN201711165118.XA CN201711165118A CN107652617A CN 107652617 A CN107652617 A CN 107652617A CN 201711165118 A CN201711165118 A CN 201711165118A CN 107652617 A CN107652617 A CN 107652617A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Epoxy Resins (AREA)
- Toys (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention relates to a kind of toy for children special environment protection plastics and preparation method thereof, raw material constituent is made up of following ratio in parts by weight：10 20 parts of acrylonitrile, 6 12 parts of butadiene, 15 20 parts of styrene, 8 15 parts of polyvinyl chloride, 48 parts of silicone oil, 35 parts of sorbic acid, 10 15 parts of epoxy resin, 6 10 parts of phenolic resin, 34 parts of titanium dioxide, 20 25 parts of ethanol.Material of the present invention is easy to get, and resistance to compression effect is good, has certain anti-impact force, and Stability Analysis of Structures, dispersion effect are good, high temperature resistant, ageing-resistant, has good antioxygenic property and chemical stability, service life length is nontoxic, green.
Description
Technical field
The present invention relates to plastic applications, and in particular to a kind of toy for children special environment protection plastics and preparation method thereof.
Background technology
Plastics are essential product in life, and toy for children is also what is be made by plastic products mostly, but
It is for the plastics in existing market, mostly containing substantial amounts of carcinogen, stability is weaker, once after long-time use,
The leakage of harmful substance has occurred, for children, has influenceed huge, can be used for so there is an urgent need to one kind now
The environmentally-friendly plastic that child uses.
The content of the invention
A kind of toy for children special environment protection plastics and its system are provided the invention aims to overcome the shortcomings of the above
Preparation Method.
Technical scheme includes：A kind of toy for children special environment protection plastics and preparation method thereof, raw material composition into
Divide and be made up of in parts by weight following ratio：Acrylonitrile 10-20 parts, butadiene 6-12 parts, styrene 15-20 parts, polyvinyl chloride
8-15 parts, silicone oil 4-8 parts, sorbic acid 3-5 parts, epoxy resin 10-15 parts, phenolic resin 6-10 parts, titanium dioxide 3-4 parts, ethanol
20-25 parts.
Further improvement of the present invention is：Its preparation method is as follows：
A, acrylonitrile and butadiene and styrene are subjected to mixing copolymerization, temperature is set to 120-140 DEG C, and pressure is set to 1.1-
1.4MPa, obtain mixture A；
B, polyvinyl chloride and silicone oil are mixed, adds sorbic acid thickness and stir, stir speed (S.S.) 430-480r/
Min, it is ultrasonically treated after adding mixture A, frequency is set to 2500-3000HZ, and temperature is set to 35-40 DEG C, after 15-20min
Obtain mixture B；
C, epoxy resin and phenolic resin are added in ethanol and carries out polycondensation, using titanium dioxide as catalyst, temperature is set to 95-110
DEG C, pressure 1.1-1.2MPa, add mixture B and be stirred, stir speed (S.S.) 360-400r/min, carried out after stirring
Centrifugal treating, frequency are set to 7500-8000HZ, and thick solid is taken out after 10-15min, carry out extrusion forming, are pressurized as 230-
250N/cm2, obtain product.
Beneficial effects of the present invention：Material of the present invention is easy to get, and resistance to compression effect is good, has certain anti-impact force, and structure is steady
It is fixed, dispersion effect is good, high temperature resistant, ageing-resistant, there is good antioxygenic property and chemical stability, service life is grown, nontoxic
It is harmless, it is green.
Embodiment：
In order to deepen the understanding of the present invention, below in conjunction with embodiment, the invention will be further described, and the embodiment is only used
In explaining the present invention, it is not intended to limit the scope of the present invention..
Embodiment 1
A kind of toy for children special environment protection plastics and preparation method thereof, raw material constituent is in parts by weight by following ratio group
Into：18 parts of acrylonitrile, 10 parts of butadiene, 17 parts of styrene, 13 parts of polyvinyl chloride, 6 parts of silicone oil, 4 parts of sorbic acid, epoxy resin 12
Part, 8 parts of phenolic resin, 4 parts of titanium dioxide, 23 parts of ethanol.
Its preparation method is as follows：
A, acrylonitrile and butadiene and styrene are subjected to mixing copolymerization, temperature is set to 130 DEG C, and pressure is set to 1.2MPa, obtains
Mixture A；
B, polyvinyl chloride and silicone oil are mixed, adds sorbic acid thickness and stir, stir speed (S.S.) 460r/min, add
It is ultrasonically treated after entering mixture A, frequency is set to 2800HZ, and temperature is set to 38 DEG C, and mixture B is obtained after 17min；
C, epoxy resin and phenolic resin are added in ethanol and carries out polycondensation, using titanium dioxide as catalyst, temperature is set to 105 DEG C,
Pressure is 1.2MPa, adds mixture B and is stirred, stir speed (S.S.) 380r/min, centrifugal treating is carried out after stirring, frequency
Rate is set to 7800HZ, and thick solid is taken out after 14min, carries out extrusion forming, is pressurized as 240N/cm2, obtain product.
Embodiment 2
A kind of toy for children special environment protection plastics and preparation method thereof, raw material constituent is in parts by weight by following ratio group
Into：20 parts of acrylonitrile, 6 parts of butadiene, 20 parts of styrene, 8 parts of polyvinyl chloride, 8 parts of silicone oil, 3 parts of sorbic acid, epoxy resin 15
Part, 6 parts of phenolic resin, 4 parts of titanium dioxide, 20 parts of ethanol.
Its preparation method is as follows：
A, acrylonitrile and butadiene and styrene are subjected to mixing copolymerization, temperature is set to 140 DEG C, and pressure is set to 1.1MPa, obtains
Mixture A；
B, polyvinyl chloride and silicone oil are mixed, adds sorbic acid thickness and stir, stir speed (S.S.) 480r/min, add
It is ultrasonically treated after entering mixture A, frequency is set to 3000HZ, and temperature is set to 40 DEG C, and mixture B is obtained after 15min；
C, epoxy resin and phenolic resin are added in ethanol and carries out polycondensation, using titanium dioxide as catalyst, temperature is set to -110 DEG C,
Pressure is 1.1MPa, adds mixture B and is stirred, stir speed (S.S.) 400r/min, centrifugal treating is carried out after stirring, frequency
Rate is set to 7500HZ, and thick solid is taken out after 15min, carries out extrusion forming, is pressurized as 230N/cm2, obtain product.
Embodiment 3
A kind of toy for children special environment protection plastics and preparation method thereof, raw material constituent is in parts by weight by following ratio group
Into：10 parts of acrylonitrile, 12 parts of butadiene, 15 parts of styrene, 15 parts of polyvinyl chloride, 4 parts of silicone oil, 5 parts of sorbic acid, epoxy resin 10
Part, 10 parts of phenolic resin, 3 parts of titanium dioxide, 25 parts of ethanol.
Its preparation method is as follows：
A, acrylonitrile and butadiene and styrene are subjected to mixing copolymerization, temperature is set to 120 DEG C, and pressure is set to 1.4MPa, obtains
Mixture A；
B, polyvinyl chloride and silicone oil are mixed, adds sorbic acid thickness and stir, stir speed (S.S.) 430r/min, add
It is ultrasonically treated after entering mixture A, frequency is set to 3000HZ, and temperature is set to 35 DEG C, and mixture B is obtained after 20min；
C, epoxy resin and phenolic resin are added in ethanol and carries out polycondensation, using titanium dioxide as catalyst, temperature is set to 95 DEG C, pressure
Power is 1.2MPa, adds mixture B and is stirred, stir speed (S.S.) 360r/min, centrifugal treating, frequency is carried out after stirring
8000HZ is set to, thick solid is taken out after 10min, extrusion forming is carried out, is pressurized as 250N/cm2, obtain product.
Embodiment 4
A kind of toy for children special environment protection plastics and preparation method thereof, raw material constituent is in parts by weight by following ratio group
Into：12 parts of acrylonitrile, 10 parts of butadiene, 18 parts of styrene, 13 parts of polyvinyl chloride, 5 parts of silicone oil, 4 parts of sorbic acid, epoxy resin 13
Part, 9 parts of phenolic resin, 3 parts of titanium dioxide, 21 parts of ethanol.
Its preparation method is as follows：
A, acrylonitrile and butadiene and styrene are subjected to mixing copolymerization, temperature is set to 125 DEG C, and pressure is set to 1.2MPa, obtains
Mixture A；
B, polyvinyl chloride and silicone oil are mixed, adds sorbic acid thickness and stir, stir speed (S.S.) 450r/min, add
It is ultrasonically treated after entering mixture A, frequency is set to 2500HZ, and temperature is set to 39 DEG C, and mixture B is obtained after 18min；
C, epoxy resin and phenolic resin are added in ethanol and carries out polycondensation, using titanium dioxide as catalyst, temperature is set to 100 DEG C,
Pressure is 1.1MPa, adds mixture B and is stirred, stir speed (S.S.) 380r/min, centrifugal treating is carried out after stirring, frequency
Rate is set to 7600HZ, and thick solid is taken out after 13min, carries out extrusion forming, is pressurized as 240N/cm2, obtain product.
In above example, embodiment 1 is most preferred embodiment, and stability is strong, and peace ring is nontoxic, and pressure-resistant effect is good, above-mentioned step
Acrylonitrile and butadiene and styrene are carried out into mixing copolymerization in rapid A can form novel plastics raw material, and pressure-resistant effect is good, stable
Property is strong.
Explanation embodiments of the present invention are the foregoing is only, are not intended to limit the invention, for the technology of this area
For personnel, within the spirit and principles of the invention, any modification, equivalent substitution and improvements made etc., it should be included in
Within protection scope of the present invention.
Claims (2)
- A kind of 1. toy for children special environment protection plastics and preparation method thereof, it is characterised in that：Raw material constituent is in parts by weight It is made up of following ratio：Acrylonitrile 10-20 parts, butadiene 6-12 parts, styrene 15-20 parts, polyvinyl chloride 8-15 parts, silicone oil 4- 8 parts, sorbic acid 3-5 parts, epoxy resin 10-15 parts, phenolic resin 6-10 parts, titanium dioxide 3-4 parts, ethanol 20-25 parts.
- A kind of 2. toy for children special environment protection plastics according to claim 1 and preparation method thereof, it is characterised in that：It is made Preparation Method is as follows：A, acrylonitrile and butadiene and styrene are subjected to mixing copolymerization, temperature is set to 120-140 DEG C, and pressure is set to 1.1- 1.4MPa, obtain mixture A；B, polyvinyl chloride and silicone oil are mixed, adds sorbic acid thickness and stir, stir speed (S.S.) 430-480r/ Min, it is ultrasonically treated after adding mixture A, frequency is set to 2500-3000HZ, and temperature is set to 35-40 DEG C, after 15-20min Obtain mixture B；C, epoxy resin and phenolic resin are added in ethanol and carries out polycondensation, using titanium dioxide as catalyst, temperature is set to 95-110 DEG C, pressure 1.1-1.2MPa, add mixture B and be stirred, stir speed (S.S.) 360-400r/min, carried out after stirring Centrifugal treating, frequency are set to 7500-8000HZ, and thick solid is taken out after 10-15min, carry out extrusion forming, are pressurized as 230- 250N/cm2, obtain product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711165118.XA CN107652617A (en) | 2017-11-21 | 2017-11-21 | A kind of toy for children special environment protection plastics and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711165118.XA CN107652617A (en) | 2017-11-21 | 2017-11-21 | A kind of toy for children special environment protection plastics and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107652617A true CN107652617A (en) | 2018-02-02 |
Family
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711165118.XA Withdrawn CN107652617A (en) | 2017-11-21 | 2017-11-21 | A kind of toy for children special environment protection plastics and preparation method thereof |
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| CN (1) | CN107652617A (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103965576A (en) * | 2014-05-12 | 2014-08-06 | 宁波高新区卓尔化工科技有限公司 | Antibacterial toy plastic and preparation method thereof |
| CN104140636A (en) * | 2014-08-10 | 2014-11-12 | 宁国市宁盛橡塑制品有限公司 | High-hardness impact-resistant heat-insulation foamed plastic |
| CN105385060A (en) * | 2015-11-13 | 2016-03-09 | 安徽广源科技发展有限公司 | High-fire-retardant polyvinyl chloride environmental-friendly plastic |
| CN106380748A (en) * | 2016-11-08 | 2017-02-08 | 郑州诚合信息技术有限公司 | Antibacterial toy plastic and preparation method thereof |
| CN106700408A (en) * | 2016-12-12 | 2017-05-24 | 天长市康宁塑胶科技有限公司 | High-temperature-resistant toughening modified plastic material |
-
2017
- 2017-11-21 CN CN201711165118.XA patent/CN107652617A/en not_active Withdrawn
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103965576A (en) * | 2014-05-12 | 2014-08-06 | 宁波高新区卓尔化工科技有限公司 | Antibacterial toy plastic and preparation method thereof |
| CN104140636A (en) * | 2014-08-10 | 2014-11-12 | 宁国市宁盛橡塑制品有限公司 | High-hardness impact-resistant heat-insulation foamed plastic |
| CN105385060A (en) * | 2015-11-13 | 2016-03-09 | 安徽广源科技发展有限公司 | High-fire-retardant polyvinyl chloride environmental-friendly plastic |
| CN106380748A (en) * | 2016-11-08 | 2017-02-08 | 郑州诚合信息技术有限公司 | Antibacterial toy plastic and preparation method thereof |
| CN106700408A (en) * | 2016-12-12 | 2017-05-24 | 天长市康宁塑胶科技有限公司 | High-temperature-resistant toughening modified plastic material |
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| PB01 | Publication | ||
| PB01 | Publication | ||
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| WW01 | Invention patent application withdrawn after publication | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20180202 |