CN104122266B - Solar silicon wafers high-speed line scanning photoluminescence imaging detection device - Google Patents

Solar silicon wafers high-speed line scanning photoluminescence imaging detection device Download PDF

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CN104122266B
CN104122266B CN201310155633.5A CN201310155633A CN104122266B CN 104122266 B CN104122266 B CN 104122266B CN 201310155633 A CN201310155633 A CN 201310155633A CN 104122266 B CN104122266 B CN 104122266B
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laser
module
line scanning
silicon chip
silicon
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CN104122266A (en
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陈利平
李波
裴世铀
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Zhongdao Optoelectronic Equipment Co ltd
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SUZHOU ZHONGDAO PHOTOELECTRIC EQUIPMENT CO Ltd
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Abstract

nullThe invention discloses a kind of solar silicon wafers high-speed line scanning photoluminescence imaging detection device,Including frame、Silicon wafer conveying mechanism、Generating device of laser、Fluorescence imaging module and image acquisition and processing module,Described generating device of laser、At least one fluorescence imaging module and image acquisition and processing module are fixedly arranged in frame respectively,Silicon wafer conveying mechanism can carry silicon chip to be detected and arrive detection position,Generating device of laser can launch the silicon chip to be detected of laser rays the irradiating and detecting position being perpendicular to the silicon chip direction of motion,Fluorescence imaging module can detect and be messaging in image acquisition and processing module to the fluorescence signal that the silicon chip of detection position sends and is analyzed and processes,The present invention greatly improves photoluminescence imaging technique and silicon materials detects the signal to noise ratio of speed and final image,Be suitable on product line detects application in real time.

Description

Solar silicon wafers high-speed line scanning photoluminescence imaging detection device
Technical field
The present invention relates to a kind of solar silicon wafers detecting system, photic particularly to a kind of solar silicon wafers high-speed line scanning Fluorescence imaging detection equipment.
Background technology
Solar silicon wafers photoluminescence imaging (PL, Photoluminescence imaging) detection technique is in recent years A kind of quickly silicon materials detection technique occurred along with the development of photovoltaic industry.This technology uses high power laser to excite Light source, by high-pass filter by same for fluorescence separation by laser, then uses the highly sensitive camera of near-infrared to carry out fluoroscopic image Gather.This technology can carry out fast imaging to fluorescent, it is possible to meets the requirement of quickly detection, is suitable for the real-time inspection producing on line Survey application.PL can be used for the silicon ingot to different phase, silicon chip detection, operation stage includes: the section of silicon ingot, silicon chip, making herbs into wool silicon chip, Diffusion silicon chip, cleaning silicon chip, PECVD silicon chip and resultant battery sheet.Application PL technology can detect that the defect kind of sample has: black Core, black surround, crystal boundary, hidden split, diffusion problem, edge isolation problem, electric leakage, Sintering Problem and contact resistance problem etc..
The photoluminescence of solar energy original silicon chip extremely inefficient (< 10^-8), in early days in order to detect this series products, typically selects Select near-infrared response enhanced type silicon CCD and strengthen laser excitation power simultaneously.But detection sample is similarly silicon materials, detector Sensitivity curve only seldom partly overlaps with the fluorescence spectrum of silicon chip, is therefore difficult to promote detection efficient, thus limits inspection Degree of testing the speed and the lifting of signal to noise ratio.
Use InGaAs image detector detection silicon materials fluorescence, started from the earliest in 2005 first by photoluminescence imaging Introducing the T.Trupke of solar silicon wafers detection field, feature is the fluorescence light that its sensitivity spectrum can be completely covered silicon materials Spectrum, therefore, it is possible to realize quickly detection, but owing to face battle array InGaAs camera price is the highest and the problem such as lack of resolution, limits Its extensive commercial application.Comparatively speaking, line scanning InGaAs detector comparative maturity, in resolution and in price There is bigger advantage.Line scanning InGaAs detector the most how is applied to build solar silicon wafers photoluminescence image checking system System becomes the hot technology in industry.
Summary of the invention
In order to make up above deficiency, the invention provides a kind of solar silicon wafers high-speed line scanning photoluminescence image checking Equipment, this solar silicon wafers high-speed line scanning photoluminescence imaging detection device greatly improves photoluminescence imaging technique pair The detection speed of silicon materials and the signal to noise ratio of final image, be suitable on product line detects application in real time, saves production cost.
The present invention is to solve that its technical problem be the technical scheme is that a kind of solar silicon wafers high-speed line scanning light Cause fluorescence imaging detection equipment, including frame, silicon wafer conveying mechanism, generating device of laser, fluorescence imaging module and image acquisition- Processing module, described generating device of laser, at least one fluorescence imaging module and image acquisition-processing module are fixedly arranged on machine respectively On frame, silicon wafer conveying mechanism can carry silicon chip to be detected and arrive detection position, and generating device of laser can be launched and is perpendicular to silicon The laser rays of the sheet direction of motion the silicon chip to be detected of irradiating and detecting position, fluorescence imaging module can be to the silicon chip of detection position The fluorescence signal sent carries out detecting and be messaging in image acquisition-processing module and is analyzed and processes.
As a further improvement on the present invention, described generating device of laser includes laser rays lighting module and optical fiber coupling half Conductor laser, laser rays lighting module is connected by fiber output head with fiber coupled laser diode, and laser rays shines The laser shaping that fiber output head can be exported by bright module is uniform laser line ultra-fine, high.
As a further improvement on the present invention, described laser rays lighting module includes the sphere being arranged in order along radiation direction Collimation lens set, dichroic mirror, cylindrical lens array, negative cylindrical mirror, the first positive cylindrical mirror, the second positive cylindrical mirror, cylindrical mirror group, its In negative cylindrical mirror, cylindrical mirror group and cylindrical lens array, the first positive cylindrical mirror, the second positive cylindrical mirror type direction, face vertical.
As a further improvement on the present invention, described laser rays lighting module and fluorescence imaging module are placed in not having light In the darkroom of line, this darkroom sidewall is provided with the slit driving silicon chip turnover darkroom for silicon wafer conveying mechanism.
As a further improvement on the present invention, described laser rays lighting module and fluorescence imaging module are positioned at silicon chip conveyer Structure homonymy or heteropleural.
As a further improvement on the present invention, described fluorescence imaging module includes the line scanning InGaAs being arranged in order setting Camera, imaging lens and optical filter.
As a further improvement on the present invention, the line scanning InGaAs image that described line scanning InGaAs camera is configured is visited Survey device pixels tall more than pixel wide.
As a further improvement on the present invention, described fluorescence imaging module is additionally provided with the filter for switching different optical filter Mating plate switching device.
As a further improvement on the present invention, being additionally provided with silicon chip minority carrier life measurement module, this silicon chip minority carrier life is measured Fluorescent image can be calibrated by module.
The method have the benefit that: the present invention passes through high power laser homogenization narrow linewidth line lighting module to sample The efficient of fluorescence signal is detected by efficiently excite and the line scanning InGaAs image detector of product, greatly improves photoluminescence Silicon materials are detected the signal to noise ratio of speed and final image by imaging technique, and be suitable on product line detects application in real time.
Accompanying drawing explanation
Fig. 1 is the structural principle schematic diagram of the present invention;
Fig. 2 is the axonometric chart of the present invention;
Fig. 3 is the laser rays lighting module principle front view of the present invention;
Fig. 4 is A portion enlarged drawing in Fig. 3;
Fig. 5 is B portion enlarged drawing in Fig. 4;
Fig. 6 is the laser rays lighting module principle left view of the present invention;
Fig. 7 is C portion enlarged drawing in Fig. 6;
Fig. 8 is the fluorescence imaging module principle schematic diagram of the present invention;
Fig. 9 is that line of the present invention scans InGaAs image detection array schematic diagram;
Figure 10 is the switching device of optical fiber structural principle schematic diagram of the present invention;
Figure 11 is that the present invention uses multiple fluorescence imaging module to carry out sample detecting schematic diagram;
Figure 12 is that the present invention uses laser rays lighting module and fluorescence imaging module to be positioned at the knot of silicon wafer conveying mechanism heteropleural Structure principle schematic;
Figure 13 is that minority carrier life time measurement module carries out calibrating principle schematic diagram to photoluminescence imaging.
Detailed description of the invention
Embodiment: a kind of solar silicon wafers high-speed line scanning photoluminescence imaging detection device, including frame, silicon chip transmission Mechanism 1, generating device of laser, fluorescence imaging module 3 and image acquisition-processing module 4, described generating device of laser, at least Individual fluorescence imaging module 3 and image acquisition-processing module 4 are fixedly arranged in frame respectively, and silicon wafer conveying mechanism 1 can carry to be checked Surveying silicon chip and arrive detection position, generating device of laser can launch laser rays the irradiating and detecting position being perpendicular to the silicon chip direction of motion The silicon chip to be detected put, the fluorescence signal that the silicon chip of detection position sends can be detected and deliver a letter by fluorescence imaging module 3 It is analyzed in image acquisition-processing module 4 and processes, generating device of laser Output of laser line, and it is radiated on silicon chip excitation Sample makes its homogeneous radiation go out fluorescence, and the direction of laser rays is vertical with the silicon wafer linear direction of motion, and fluorescence imaging module 3 is directed at this Laser rays the fluorescence signal giving off silicon chip detect, and meanwhile silicon wafer conveying mechanism 1 drives silicon wafer horizontal to move Completing the scanning to whole sample, obtain the fluoroscopic image of whole sample, fluorescence imaging module 3 sends view data to image Collection-processing module 4, the image acquisition-processing module 4 fluoroscopic image to collecting carries out computational analysis and draws testing result, Judge sample defects type and grade, then send sorting order and to automatization's separation system, sample is sorted, wherein Fluorescence imaging module 3 can use multiple, and be directed at laser fine rule produced by generating device of laser, each fluorescence imaging simultaneously The fluorescence of different-waveband is acquired by module 3, can make this detection equipment simultaneously to the silicon materials fluorescence signal in sample and Impurities of materials fluorescence signal carries out imaging detection respectively.
Described generating device of laser includes laser rays lighting module 2 and fiber coupled laser diode 6, and laser rays illuminates Module 2 is connected by fiber output head 7 with fiber coupled laser diode 6, and laser rays lighting module 2 can be defeated by optical fiber The laser shaping of 7 outputs of lifting one's head is uniform laser line ultra-fine, high, use fiber coupled laser diode 6 as input light source, The diverging light exported laser fiber through laser rays lighting module 2 collimates, filters, homogenization and shaping, finally assembles A fine rule output for brightness uniformity.
Described laser rays lighting module 2 includes sphere collimation lens set 11, the dichroic mirror being arranged in order along radiation direction 12, cylindrical lens array 13, the negative positive cylindrical mirror of cylindrical mirror 14, first 15, second positive cylindrical mirror 16, cylindrical mirror group 17, wherein bear post The type direction, face of face mirror 14, cylindrical mirror group 17 cylindrical mirror positive with cylindrical lens array 13, first 15, second positive cylindrical mirror 16 is vertical, The laser alignment that fiber output head 7 is exported by sphere collimation lens set 11, dichroic mirror 12 carries out low-pass filtering to laser beam Thus eliminating veiling glare spectral content in laser, cylindrical lens array 13 carries out single direction and dissipates and uniformly incoming parallel beam Changing, the first positive cylindrical mirror 15 and the second positive cylindrical mirror 16 are to dissipating and laser beam after homogenization collimates thus forms one Uniform laser tape, negative cylindrical mirror 14 carries out another vertical direction to light beam and dissipates, and last laser tape is through cylindrical mirror group 17 Convergence is a uniform laser fine rule on silicon chip.
Described laser rays lighting module 2 and fluorescence imaging module 3 are placed in not having in the darkroom 8 of light, this side, darkroom 8 Wall is provided with and drives silicon chip 5 to pass in and out the slit 9 in darkroom 8 for silicon wafer conveying mechanism 1, and extraneous veiling glare can effectively be blocked to glimmering in darkroom 8 The interference of optical signal and effectively shielding high power laser light are to the leakage outside darkroom 8, and then improve detection degree of accuracy.
Described laser rays lighting module 2 and fluorescence imaging module 3 are positioned at silicon wafer conveying mechanism 1 homonymy or heteropleural, are positioned at During homonymy, equipment volume can be made small and exquisite;When being positioned at heteropleural, the laser that sample can be avoided to reflect enters fluorescence imaging module 3.
Described fluorescence imaging module 3 includes line scanning InGaAs camera 18, imaging lens 19 and the filter being arranged in order setting Mating plate 20, this line scanning InGaAs camera 18 sensitivity curve covers luminescence from silicon spectral region, and has higher responsiveness, becomes As camera lens 19 is for being imaged onto silicon chip in line scanning InGaAs camera 18 through laser excitation fluorescence signal out, optical filter 20 Fluorescence signal is had higher transmitance and laser is had stronger absorption.
Line scanning InGaAs image detector 21 pixels tall that described line scanning InGaAs camera 18 is configured is more than picture Element width, its advantage is easy for the laser fine rule alignment that fluorescence imaging module 3 produces with laser rays illumination mould.
Described fluorescence imaging module 3 is additionally provided with the switching device of optical fiber 22 for switching different optical filter 20, this filter Mating plate switching device 22 is provided with pass filter 20 long wave pass filter different with several cutoff wavelengths 20, these optical filters 20 are possible not only to completely cut off the laser that sample is reflected, and InGaAs image detector can be made only to connect by switching different optical filters 20 Receive the silicon materials fluorescence signal near 1150nm wavelength, InGaAs image detector can be made only to receive the material more than 1200nm wavelength Material impurity fluorescence signal, it is possible to make InGaAs image detector simultaneously receive silicon materials fluorescence signal and impurities of materials fluorescence letter Number.Described switching device of optical fiber 22 act as switching over different optical filters 20, but is not limited to its implementation.Should Switching device of optical fiber 22 can be rotary-disk type structure, arranges the optical filter 20 of some different sizes on rotating disk, by rotating Rotating disk makes different optical filters 20 align with imaging lens 19, also or by arranging optical filter 20 19 times at imaging lens Accommodating device, realizes the installation and removal of different optical filter 20 by fast quick-detach mode, also or board-like, by taking out by sliding Draw the different optical filter 20 of realization corresponding with imaging lens 19, etc..
Being additionally provided with silicon chip minority carrier life measurement module 23, this silicon chip minority carrier life measurement module can be to fluorescent image Calibrate.

Claims (7)

1. a solar silicon wafers high-speed line scanning photoluminescence imaging detection device, is characterized in that: include frame, silicon chip transmission Mechanism (1), generating device of laser, fluorescence imaging module (3) and image acquisition-processing module (4), described generating device of laser, At least one fluorescence imaging module (3) and image acquisition-processing module (4) are fixedly arranged in frame respectively, silicon wafer conveying mechanism (1) Can carry silicon chip to be detected and arrive detection position, generating device of laser can launch the laser rays being perpendicular to the silicon chip direction of motion And the silicon chip to be detected of irradiating and detecting position, the fluorescence signal that the silicon chip of detection position can be sent by fluorescence imaging module (3) Carrying out detecting and be messaging in image acquisition-processing module (4) be analyzed and process, described generating device of laser includes laser rays Lighting module (2) and fiber coupled laser diode (6), laser rays lighting module (2) and fiber coupled laser diode (6) it is connected by fiber output head (7), the laser shaping that fiber output head (7) can be exported by laser rays lighting module (2) For uniform laser line ultra-fine, high, described laser rays lighting module (2) includes the sphere collimating lens being arranged in order along radiation direction Group (11), dichroic mirror (12), cylindrical lens array (13), negative cylindrical mirror (14), the first positive cylindrical mirror (15), the second positive cylindrical mirror (16), cylindrical mirror group (17), wherein bear cylindrical mirror (14), cylindrical mirror group (17) and cylindrical lens array (13), the first positive cylindrical mirror (15), the type direction, face of the second positive cylindrical mirror (16) is vertical.
2. solar silicon wafers high-speed line scanning photoluminescence imaging detection device as claimed in claim 1, is characterized in that: described Laser rays lighting module (2) and fluorescence imaging module (3) are placed in not having in the darkroom (8) of light, on this darkroom (8) sidewall It is provided with the slit (9) driving silicon chip (5) turnover darkroom (8) for silicon wafer conveying mechanism (1).
3. solar silicon wafers high-speed line scanning photoluminescence imaging detection device as claimed in claim 1, is characterized in that: described Laser rays lighting module (2) and fluorescence imaging module (3) are positioned at silicon wafer conveying mechanism (1) homonymy or heteropleural.
4. solar silicon wafers high-speed line scanning photoluminescence imaging detection device as claimed in claim 1, is characterized in that: described Fluorescence imaging module (3) includes line scanning InGaAs camera (18), imaging lens (19) and the optical filter being arranged in order setting (20)。
5. solar silicon wafers high-speed line scanning photoluminescence imaging detection device as claimed in claim 4, is characterized in that: described Line scanning InGaAs image detector (21) pixels tall that line scanning InGaAs camera (18) is configured is more than pixel wide.
6. solar silicon wafers high-speed line scanning photoluminescence imaging detection device as claimed in claim 4, is characterized in that: described Fluorescence imaging module (3) is additionally provided with the switching device of optical fiber (22) for switching different optical filter (20).
7. solar silicon wafers high-speed line scanning photoluminescence imaging detection device as claimed in claim 1, is characterized in that: also set Having silicon chip minority carrier life measurement module (23), fluorescent image can be calibrated by this silicon chip minority carrier life measurement module.
CN201310155633.5A 2013-04-28 2013-04-28 Solar silicon wafers high-speed line scanning photoluminescence imaging detection device Active CN104122266B (en)

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WO2016162398A1 (en) * 2015-04-07 2016-10-13 Albert-Ludwigs-Universität Freiburg Apparatus for detecting electronic faults on silicon-based semiconductor wafers
TWI646323B (en) * 2016-12-01 2019-01-01 友達晶材股份有限公司 Silicon crystal material detection method and detection device
CN110646433A (en) * 2018-06-27 2020-01-03 东泰高科装备科技(北京)有限公司 Online detection method and device for internal defects of battery and solar battery production line
CN111024723A (en) * 2019-12-26 2020-04-17 苏州市建设工程质量检测中心有限公司 Vision application device based on fluorescent coating and processing method

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Effective date of registration: 20220715

Address after: 526238 No. 20, Beijiang Avenue, high tech Zone, Zhaoqing City, Guangdong Province

Patentee after: ZHONGDAO OPTOELECTRONIC EQUIPMENT CO.,LTD.

Address before: 215311 Rui'an Road, Lingang Industrial Park, Bacheng Town, Kunshan City, Suzhou City, Jiangsu Province

Patentee before: Suzhou Zhongdao Photoelectric Equipment Co.,Ltd.

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