CN104120441A - A double-membrane gas balancing device for hydrogen production by hydrolyzation - Google Patents

A double-membrane gas balancing device for hydrogen production by hydrolyzation Download PDF

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Publication number
CN104120441A
CN104120441A CN201410329056.1A CN201410329056A CN104120441A CN 104120441 A CN104120441 A CN 104120441A CN 201410329056 A CN201410329056 A CN 201410329056A CN 104120441 A CN104120441 A CN 104120441A
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intermediate ring
hydrogen
gas
oxygen
film
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CN201410329056.1A
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包秀敏
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/36Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

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  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

Abstract

The invention relates to a double-membrane gas balancing device for hydrogen production by hydrolyzation. The double-membrane gas balancing device is characterized in that: the device comprises a pair of U-shaped housings; a middle ring (7) is disposed between the U-shaped housings; the middle ring (7) is separated from each of the U-shaped housings at two sides with a thin membrane sheet (6); the U-shaped housings and the corresponding thin membrane sheets (6) form two gas chambers, namely a hydrogen chamber with a hydrogen inlet (1) and a hydrogen outlet (4) and an oxygen chamber with an oxygen inlet (12) and an oxygen outlet; a movable membrane sheet (8) is disposed in the space between the two thin membrane sheets (6); and the side surface of the middle ring (7) is provided with at least one gas outlet. Once the thin membrane sheet in one chamber at a side is damaged and gas leaks, the leaked gas is discharged from the gas outlet in the middle ring and is not mixed with the gas in the other chamber, thus avoiding potential safety hazards.

Description

The two film gaseous equilibrium devices of hydrolytic hydrogen production
Technical field
The present invention relates to the two film gaseous equilibrium devices of a kind of hydrolytic hydrogen production, belong to hydrolytic hydrogen production technical field.
Background technology
In water electrolysis hydrogen producing process, as larger in the pressure change of electrolyzer, can cause interpenetrating of hydrogen, oxygen, directly affect the purity of hydrogen manufacturing.So hydrogen-oxygen wall pressure in adjustment tank at any time in hydrogen production process.The electrolyzer of normal pressure operation is generally by gas holder, and steam separator, washer are adjusted pressure.But in the time that pressure moves, a pair of pressure regulator must be set in system, and (one is hydrogen pressure regulator, another is oxygen pressure regulator), gas in gas holder is carried out to pressure adjustment, to ensure producing at any time the gaseous tension changing with the variation of consumption in equilibrium state because of gas holder.The above-mentioned pressure regulator adopting in existing installation mainly contains two kinds: a kind of is float regulator valve, and another kind is diaphragm valve.Above-mentioned two kinds of pressure regulators are generally and occur in pairs supporting the use, and its internal structure is more complicated, thereby make existing hydrogen producer internal hydrogen carrier of oxygen equilibrium system very loaded down with trivial details, have reduced the reliability using, and have also increased device fabrication cost.
Therefore, Granted publication number is that the Chinese patent literature of CN102212839B discloses a kind of gaseous equilibrium device for water electrolysis hydrogen producing, and gas pressure balancing equipment has been simplified in the application of this gaseous equilibrium device, has accelerated the balance of gaseous tension.Once damaged but diaphragm occurs, oxyhydrogen is known from experience generation and mixed, and has potential safety hazard, reliability standard is lower.
Summary of the invention
The technical issues that need to address of the present invention are: the gaseous equilibrium device of water electrolysis hydrogen producing of the prior art, once breakage occurs diaphragm, oxyhydrogen is known from experience generation and mixed, and causes potential safety hazard.
The present invention is by the following technical solutions:
The two film gaseous equilibrium devices of a kind of water electrolysis hydrogen producing, this device comprises pair of U-shaped case, between described pair of U-shaped case, is provided with intermediate ring 7, described intermediate ring 7 respectively separates by a slice diaphragm 6 with the U-shaped case of both sides; Described pair of U-shaped case and each self-corresponding diaphragm 6 form two air cavitys, are respectively the hydrogen chamber with hydrogen inlet 1 and hydrogen outlet 4 and the oxygen chamber with oxygen intake 12 and oxygen outlet; In space between two diaphragms 6, be provided with moving film 8; The side of described intermediate ring 7 is provided with at least one production well.
The feature of the technical program is: in the basis of prior art " for the gaseous equilibrium device of water electrolysis hydrogen producing ", the improvement that the structure of single diaphragm is carried out.Be provided with intermediate ring, on intermediate ring, set out pore, the both sides of intermediate ring respectively arrange a diaphragm, between two diaphragms, there is certain space, once there is damaged gas leakage in the diaphragm of a side cavity, the gas spilling can be discharged by the production well from intermediate ring, and can not mix with the gas in opposite side cavity, has avoided potential safety hazard.Moving film has two effects, and 2. 1. transmitting thrust is guaranteed to have certain interval between two diaphragms, ensures that production well gives vent to anger unimpeded.
Further, the thickness of described moving film 8 is greater than the aperture of described production well, is less than intermediate ring 7 thickness; Directly through being less than intermediate ring 7 internal diameters.
Further, the side of described intermediate ring 7 is provided with two production wells, two production well conllinear.
Further, described diaphragm 6 is rounded.
Further, described moving film 8 is rounded.
Further, described oxygen chamber has boss, and described oxygen outlet 9 runs through described boss.
Beneficial effect of the present invention is:
1) once breakage occurs diaphragm, hydrogen or oxygen gas also can not mix, and has avoided potential safety hazard.
2) moving film has effectively been brought into play transmitting thrust and has been guaranteed the effect that production well is unimpeded, designs ingenious.
3) simple in structure, reliability is strong, and device manufacturing cost is lower.
4) after device power-up, pressure equilibrium speed is accelerated, corresponding hydrogen output time shorten.
Brief description of the drawings
Fig. 1 is the sectional view of the two film gaseous equilibrium devices of water electrolysis hydrogen producing of the present invention.
Fig. 2 be in Fig. 1 A-A to cross-sectional schematic.
In figure, 1. hydrogen inlet, 2. bolt hole, 3. left outside shell, 4. hydrogen outlet, 5. hydrogen chamber, 6. diaphragm, 7. intermediate ring, 8. moving film, 9. oxygen outlet, 10. right air cavity, 11. right casings.
Embodiment
Below in conjunction with specific embodiments and the drawings, the present invention is further described.
Referring to Fig. 1-2, the two film gaseous equilibrium devices of a kind of water electrolysis hydrogen producing, this device comprises pair of U-shaped case, is respectively left outside shell 3 and right casing 11, be provided with intermediate ring 7 therebetween, described intermediate ring 7 respectively separates by a slice diaphragm 6 with left outside shell 3, the right casing 11 of both sides; Left outside shell 3, right casing 11 form two air cavitys with each self-corresponding diaphragm 6, are respectively the hydrogen chamber with hydrogen inlet 1 and hydrogen outlet 4 and the oxygen chamber with oxygen intake 12 and oxygen outlet; In space between two diaphragms 6, be provided with moving film 8; The side of described intermediate ring 7 is provided with at least one production well.
Referring to Fig. 1, the thickness of described moving film 8 is greater than the aperture of described production well, is less than intermediate ring 7 thickness, directly through being less than intermediate ring 7 internal diameters.So more can guarantee the patency that production well is given vent to anger.
Referring to Fig. 1, the side of described intermediate ring 7 is provided with two production wells, two production well conllinear.
Referring to Fig. 1, described diaphragm 6 is rounded.
Referring to Fig. 1-2, described moving film 8 is rounded.
Referring to Fig. 1, described oxygen chamber has boss, and described oxygen outlet 9 runs through described boss, can suitably reduce the volume in oxygen chamber, adapts to self pressure ratio of hydrogen and oxygen.
When concrete use, the hydrogen, carrier of oxygen that equipment is produced passes in gaseous equilibrium device after steam separator, cooling, washing condensation, when uneven hydrogen or oxygen gas enters after air cavity at gas input port separately respectively, due to draught head, the built-in film 6 of equilibrator produces corresponding expansion, the diaphragm of the larger side of pressure outwards expands, promote the diaphragm of the less side of moving film 8 squeeze pressures, adjust spatial volume and pressure size in the air cavity of both sides thereupon, until both sides air chamber pressure and film are equilibrium state, thereby reach the object of balanced gas.
The two film gaseous equilibrium device profiles of water electrolysis hydrogen producing of the present invention adopt cylindrical structural.
The present invention is in the basis of prior art " for the gaseous equilibrium device of water electrolysis hydrogen producing ", the improvement that the structure of single diaphragm is carried out.Be provided with intermediate ring, on intermediate ring, set out pore, the both sides of intermediate ring respectively arrange a diaphragm, between two diaphragms, there is certain space, once there is damaged gas leakage in the diaphragm of a side cavity, the gas spilling can be discharged by the production well from intermediate ring, and can not mix with the gas in opposite side cavity, has avoided potential safety hazard.Moving film has two effects, and 2. 1. transmitting thrust is guaranteed to have certain interval between two diaphragms, ensures that production well gives vent to anger unimpeded.

Claims (6)

1. the two film gaseous equilibrium devices of water electrolysis hydrogen producing, is characterized in that:
This device comprises pair of U-shaped case, is provided with intermediate ring (7) between described pair of U-shaped case, and described intermediate ring (7) respectively separates by a slice diaphragm (6) with the U-shaped case of both sides;
Described pair of U-shaped case and each self-corresponding diaphragm (6) form two air cavitys, are respectively the hydrogen chamber of have hydrogen inlet (1) and hydrogen outlet (4) and have the oxygen chamber of oxygen intake (12) and oxygen outlet;
In space between two diaphragms (6), be provided with moving film (8); The side of described intermediate ring (7) is provided with at least one production well.
2. the two film gaseous equilibrium devices of water electrolysis hydrogen producing as claimed in claim 1, it is characterized in that: the thickness of described moving film (8) is greater than the aperture of described production well, be less than intermediate ring (7) thickness, it is directly through being less than intermediate ring (7) internal diameter.
3. the two film gaseous equilibrium devices of water electrolysis hydrogen producing as claimed in claim 1, is characterized in that: the side of described intermediate ring (7) is provided with two production wells two production well conllinear.
4. the two film gaseous equilibrium devices of water electrolysis hydrogen producing as claimed in claim 1, is characterized in that: described diaphragm (6) is rounded.
5. the two film gaseous equilibrium devices of water electrolysis hydrogen producing as claimed in claim 1, is characterized in that: described moving film (8) is rounded.
6. the two film gaseous equilibrium devices of water electrolysis hydrogen producing as claimed in claim 1, is characterized in that: described oxygen chamber has boss, and described oxygen outlet (9) runs through described boss.
CN201410329056.1A 2014-07-11 2014-07-11 A double-membrane gas balancing device for hydrogen production by hydrolyzation Pending CN104120441A (en)

Priority Applications (1)

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CN201410329056.1A CN104120441A (en) 2014-07-11 2014-07-11 A double-membrane gas balancing device for hydrogen production by hydrolyzation

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Application Number Priority Date Filing Date Title
CN201410329056.1A CN104120441A (en) 2014-07-11 2014-07-11 A double-membrane gas balancing device for hydrogen production by hydrolyzation

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111389247A (en) * 2020-04-22 2020-07-10 张家港汇致机电设备有限公司 Gas balance valve for gas proportioning cabinet
WO2023045435A1 (en) * 2021-09-23 2023-03-30 中国华能集团清洁能源技术研究院有限公司 Differential pressure adjusting device for electrolytic hydrogen production system, and electrolytic hydrogen production system

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US3324872A (en) * 1964-04-27 1967-06-13 Honeywell Inc Shower control valve
US3688790A (en) * 1970-07-13 1972-09-05 Harold Esten Pressure balance valve
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CN102317505A (en) * 2008-10-27 2012-01-11 卡萨尔化学股份有限公司 High pressure electrolyser
JP2012052208A (en) * 2010-09-03 2012-03-15 Honda Motor Co Ltd Method of operating water electrolysis system
CN102560524A (en) * 2012-03-06 2012-07-11 中国船舶重工集团公司第七一八研究所 Gas-liquid separator without leakage
CN203212570U (en) * 2013-04-09 2013-09-25 山东明硕新能源科技有限公司 Positive-negative pressure protector
CN204058602U (en) * 2014-07-11 2014-12-31 包秀敏 The two film gaseous equilibrium device of hydrolytic hydrogen production

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* Cited by examiner, † Cited by third party
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US2695874A (en) * 1950-02-22 1954-11-30 Ewald A Zdansky Pressure regulating device for electrolytic gas generating diaphragm cells
US3324872A (en) * 1964-04-27 1967-06-13 Honeywell Inc Shower control valve
US3688790A (en) * 1970-07-13 1972-09-05 Harold Esten Pressure balance valve
US4254790A (en) * 1977-08-30 1981-03-10 Innoventa Aps Pressure control unit for the control of the pressure of at least one gas depending on the pressure of another gas
US5261452A (en) * 1991-03-01 1993-11-16 American Air Liquide Critical orifice dilution system and method
CN1144544A (en) * 1994-03-08 1997-03-05 水气新西兰有限公司 Electrolytic apparatus
US5507309A (en) * 1995-07-05 1996-04-16 United Technologies Corporation Pressure differential regulator
US5914199A (en) * 1997-08-04 1999-06-22 Lockheed Martin Tactical Defense Systems, Inc. Pressure equalized fuel cell stack
JP2001011675A (en) * 1999-06-29 2001-01-16 Mitsubishi Heavy Ind Ltd Solid polymer membrane water electrolyzing device
CN1444666A (en) * 2000-07-26 2003-09-24 神钢汎技术股份有限公司 Hydrogen/oxygen supply system
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US20040072040A1 (en) * 2002-04-23 2004-04-15 University Of Massachusetts Lowell Electrolyzer pressure equalization system
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111389247A (en) * 2020-04-22 2020-07-10 张家港汇致机电设备有限公司 Gas balance valve for gas proportioning cabinet
CN111389247B (en) * 2020-04-22 2022-02-25 赤峰广钢气体有限公司 Gas balance valve for gas proportioning cabinet
WO2023045435A1 (en) * 2021-09-23 2023-03-30 中国华能集团清洁能源技术研究院有限公司 Differential pressure adjusting device for electrolytic hydrogen production system, and electrolytic hydrogen production system

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Application publication date: 20141029