CN104118883B - A kind of can the modified alta-mud of insect-pest and its preparation method - Google Patents

Abstract

The present invention disclose a kind of can the modified alta-mud of insect-pest, it is characterized in that, it is made up of the raw material of following weight part: wilkinite 90-95, pulverizing leaf of Yellow cinnamon 3-4, pulverizing Ginkgo Leaf 2-3, cationic starch 2.5-3.5, Terpineol 350 0.6-1, peach gum 2-3, silicon sol 5-7, natural rubber 4-6, vermiculite power 3-4, monobutyl itaconate 4-6, modification infusorial earth 3-4; The present invention adds the crude substance such as leaf of Yellow cinnamon, Ginkgo Leaf, peach gum, there is certain insect-pest, anti-effect of damaging by worms, safety non-toxic, add high molecular polymer and modification infusorial earth, wilkinite is made to have good dispersion and consistency, as having very strong bonding force in coating, using in a large number, physicals and the energy that also can not reduce product are anti-insect.

Description

A kind of can the modified alta-mud of insect-pest and its preparation method

Technical field

The present invention relates to industrial filler field, particularly a kind of can the modified alta-mud of insect-pest and its preparation method.

Background technology

The bentonite ore resource of China is very abundant, and reserves occupy first place in the world, and account for the 60% of world's total amount, prognostic resources more than 7,000,000,000 tons, and taking distribute wide, bury digging shallow, easy and great variety of goods as feature. Wilkinite and remodeling product of purifying thereof have some superior characteristics all to some extent, these characteristics mainly contain swelling property, wetting ability (or lipophilicity, such as organobentonite), adsorptivity, cationic exchange, catalytic activity, dispersion, suspension, cementability, thixotropy, stability, nontoxicity. Along with the development of science and technology, the understanding of wilkinite crystallization property and physicochemical property is deepened by people gradually, and the use of wilkinite in industrial and agricultural production and scientific research is increasingly extensive. There is application prospect very widely in the fields such as it is herded in metallurgy, machine casting, probing, petrochemical complex, light industry, agricultural as binding agent, suspension agent, thickening material, thixotropic agent, flocculation agent, stablizer, purification and decoloration agent, filling agent, catalyzer and support of the catalyst, construction work, environmental protection.

Summary of the invention

It is an object of the invention to provide a kind of can the modified alta-mud of insect-pest and its preparation method.

In order to realize the object of the present invention, the present invention is by following scheme implementation:

Can the modified alta-mud of insect-pest, be made up of the raw material of following weight part: wilkinite 90-95, pulverize leaf of Yellow cinnamon 3-4, pulverize Ginkgo Leaf 2-3, cationic starch 2.5-3.5, Terpineol 350 0.6-1, peach gum 2-3, silicon sol 5-7, natural rubber 4-6, vermiculite power 3-4, monobutyl itaconate 4-6, modification infusorial earth 3-4;

Described modification infusorial earth is made up of the raw material of following weight part: diatomite 50-60, charcoal 4-7, sodium lignosulfonate 3-5, stearic acid 2-4, MALEIC ANHYDRIDE 4-6, lauryl methacrylate(LMA) 4-7, terpolycyantoamino-formaldehyde resin 5-7, tripoly phosphate sodium STPP 4-5, water 50-60; First preparation method adds diatomite, charcoal, lauryl methacrylate(LMA), water stirring evenly, form suspension, add MALEIC ANHYDRIDE, terpolycyantoamino-formaldehyde resin, tripoly phosphate sodium STPP mix and blend 25-35 minute, then all the other remaining components are added, stir under 1200-1500 rev/min of condition, dry at 50-60 DEG C, pulverize into 200-400 order powder and get final product.

Of the present invention a kind of can the modified alta-mud of insect-pest, be made up of following concrete steps:

(1) wilkinite, pulverizing leaf of Yellow cinnamon, pulverizing Ginkgo Leaf, cationic starch, vermiculite power are mixed and add in shredder, grind 15-20 minute with the speed of 1500-2000 rev/min, take out and dry, pulverize and grind carefully, cross 100-200 order sieve, obtain mixed powder stand-by;

(2) Terpineol 350, peach gum, silicon sol, natural rubber are put into mixing tank, it is warming up between 80-90 DEG C, mix and blend half an hour, continue to add monobutyl itaconate, continue to be warming up to 130-160 DEG C, mix and pour out after 15-20 minute, obtain material modified;

(3) mixed powder is mixed with material modified, add suitable quantity of water, stir and grind 2-3 hour, form suspension stand-by;

(4) suspension is mixed with modification infusorial earth, stir 10-15 minute under 800-1000 rev/min, dry, pulverize into 200-400 order powder and get final product.

The invention has the beneficial effects as follows: the present invention adds the crude substance such as leaf of Yellow cinnamon, Ginkgo Leaf, peach gum, there is certain insect-pest, anti-effect of damaging by worms, safety non-toxic, add high molecular polymer and modification infusorial earth, wilkinite is made to have good dispersion and consistency, as having very strong bonding force in coating, using in a large number, physicals and the energy that also can not reduce product are anti-insect.

Specific embodiments

Below by specific examples, the present invention is described in detail.

Can the modified alta-mud of insect-pest, be made up of the raw material of following weight part (kilogram): wilkinite 90, pulverize leaf of Yellow cinnamon 3, pulverize Ginkgo Leaf 2, cationic starch 2.5, Terpineol 350 0.6, peach gum 2, silicon sol 5, natural rubber 4, vermiculite power 3, monobutyl itaconate 4, modification infusorial earth 3;

Described modification infusorial earth is made up of the raw material of following weight part (kilogram): diatomite 50, charcoal 4, sodium lignosulfonate 3, stearic acid 2, MALEIC ANHYDRIDE 4, lauryl methacrylate(LMA) 4, terpolycyantoamino-formaldehyde resin 5, tripoly phosphate sodium STPP 4, water 50; First preparation method adds diatomite, charcoal, lauryl methacrylate(LMA), water stirring evenly, form suspension, add MALEIC ANHYDRIDE, terpolycyantoamino-formaldehyde resin, tripoly phosphate sodium STPP mix and blend 25-35 minute, then all the other remaining components are added, stir under 1200-1500 rev/min of condition, dry at 50-60 DEG C, pulverize into 200-400 order powder and get final product.

Of the present invention a kind of can the modified alta-mud of insect-pest, be made up of following concrete steps:

(1) wilkinite, pulverizing leaf of Yellow cinnamon, pulverizing Ginkgo Leaf, cationic starch, vermiculite power are mixed and add in shredder, grind 15-20 minute with the speed of 1500-2000 rev/min, take out and dry, pulverize and grind carefully, cross 100-200 order sieve, obtain mixed powder stand-by;

(2) Terpineol 350, peach gum, silicon sol, natural rubber are put into mixing tank, it is warming up between 80-90 DEG C, mix and blend half an hour, continue to add monobutyl itaconate, continue to be warming up to 130-160 DEG C, mix and pour out after 15-20 minute, obtain material modified;

(3) mixed powder is mixed with material modified, add suitable quantity of water, stir and grind 2-3 hour, form suspension stand-by;

(4) suspension is mixed with modification infusorial earth, stir 10-15 minute under 800-1000 rev/min, dry, pulverize into 200-400 order powder and get final product.

The modified alta-mud of the present invention and the Performance Detection of common wilkinite are compared as follows:

First measuring the tap density of the forward and backward wilkinite of modification, then join in rubber item by wilkinite good for modification and unmodified wilkinite calcium, make sample, test both mechanical properties respectively, comparing result sees the following form:

As can be seen from the above table, the loose bulk density of modified wilkinite diminishes, and illustrates that wilkinite split fully disperses, still further it can be seen that every mechanical property of modified wilkinite is all improved.

Claims (2)

1. one kind can the modified alta-mud of insect-pest, it is characterized in that, it is prepared from by the raw material of following weight part: wilkinite 90-95, pulverizing leaf of Yellow cinnamon 3-4, pulverizing Ginkgo Leaf 2-3, cationic starch 2.5-3.5, Terpineol 350 0.6-1, peach gum 2-3, silicon sol 5-7, natural rubber 4-6, vermiculite power 3-4, monobutyl itaconate 4-6, modification infusorial earth 3-4;

Described modification infusorial earth is made up of the raw material of following weight part: diatomite 50-60, charcoal 4-7, sodium lignosulfonate 3-5, stearic acid 2-4, MALEIC ANHYDRIDE 4-6, lauryl methacrylate(LMA) 4-7, terpolycyantoamino-formaldehyde resin 5-7, tripoly phosphate sodium STPP 4-5, water 50-60; First preparation method adds diatomite, charcoal, lauryl methacrylate(LMA), water stirring evenly, form suspension, add MALEIC ANHYDRIDE, terpolycyantoamino-formaldehyde resin, tripoly phosphate sodium STPP mix and blend 25-35 minute, then all the other remaining components are added, stir under 1200-1500 rev/min of condition, dry at 50-60 DEG C, pulverize into 200-400 order powder and get final product.

2. a kind of according to claim 1 can the modified alta-mud of insect-pest, it is characterised in that, be made up of following concrete steps:

(1) wilkinite, pulverizing leaf of Yellow cinnamon, pulverizing Ginkgo Leaf, cationic starch, vermiculite power are mixed and add in shredder, grind 15-20 minute with the speed of 1500-2000 rev/min, take out and dry, pulverize and grind carefully, cross 100-200 order sieve, obtain mixed powder stand-by;

(2) Terpineol 350, peach gum, silicon sol, natural rubber are put into mixing tank, it is warming up between 80-90 DEG C, mix and blend half an hour, continue to add monobutyl itaconate, continue to be warming up to 130-160 DEG C, mix and pour out after 15-20 minute, obtain material modified;

(3) mixed powder is mixed with material modified, add suitable quantity of water, stir and grind 2-3 hour, form suspension stand-by;

(4) suspension is mixed with modification infusorial earth, stir 10-15 minute under 800-1000 rev/min, dry, pulverize into 200-400 order powder and get final product.