CN104112866B - The burning of a kind of fuel cell system is reformed and is premixed integrated apparatus - Google Patents

The burning of a kind of fuel cell system is reformed and is premixed integrated apparatus Download PDF

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Publication number
CN104112866B
CN104112866B CN201310138809.6A CN201310138809A CN104112866B CN 104112866 B CN104112866 B CN 104112866B CN 201310138809 A CN201310138809 A CN 201310138809A CN 104112866 B CN104112866 B CN 104112866B
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chamber
reformation
gas
premix
tubulation
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CN104112866A (en
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黄媛
叶爽
王蔚国
关有明
彭军
姜松林
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Ningbo Institute of Material Technology and Engineering of CAS
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Ningbo Institute of Material Technology and Engineering of CAS
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04223Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids during start-up or shut-down; Depolarisation or activation, e.g. purging; Means for short-circuiting defective fuel cells
    • H01M8/04268Heating of fuel cells during the start-up of the fuel cells
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/06Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0606Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
    • H01M8/0612Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
    • H01M8/0618Reforming processes, e.g. autothermal, partial oxidation or steam reforming
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Fuel Cell (AREA)

Abstract

The invention discloses a kind of fuel cell system burning reformation premix integrated apparatus.Specifically, described device is connected with burner, reformation chamber and vaporization premix chamber from bottom to up, and the outer wall of the flue gas expansion chamber of burner simultaneously constitutes reformation chamber and the outer wall of vaporization premix chamber.The high-quality heat of combustor of the present invention is primarily used for reforming reaction heat supply, and remaining heat is then further used in preheating methane and vaporizes water, it is achieved that the cascade utilization of energy, it is achieved that system effectiveness maximizes.

Description

The burning of a kind of fuel cell system is reformed and is premixed integrated apparatus
Technical field
The present invention relates to a kind of burning reformation premix integrated apparatus, a kind of burning for fuel cell system Reform and premix integrated apparatus.
Background technology
Fuel cell efficiently, environmentally friendly by the chemical energy etc. being stored in fuel can leniently be converted into electric energy, Hydrogen is the optimum fuel of fuel cell, if only with hydrogen as fuel, and can fuel cell system industry, rule Modelling develops, and how the fuel such as natural gas is converted into hydrogen and seems most important.
Steam reformation hydrogen production technology (CH industrially4+H2O→CO+3H2) the most ripe, but this extensive hydrogen manufacturing Technology can not meet the requirement of fuel cell system compact, miniaturization.
Owing to fuel cell system hydrogen demand is few, so the design ginseng of the large-scale process for making hydrogen of maturation cannot be reduced merely Number, therefore, this area in the urgent need to develop be applicable to fuel cell system and steam reformation integrated small device.
Summary of the invention
The invention provides a kind of collecting burning, reform, vaporize, preheat and mixed function is in one for fuel cell system The reformer of body.
A first aspect of the present invention, it is provided that a kind of fuel cell system is reformed with burning and premixed integrated apparatus, described Device be connected with from bottom to up burner, reformation chamber and vaporization premix chamber.
In another preference, described burner also includes flue gas expansion chamber, and described flue gas expansion chamber is located at burning Device top, upwardly extends and surrounds described reformation chamber and vaporization premix chamber.
In another preference, the shell of described flue gas expansion chamber forms described reformation chamber and the closing of vaporization premix chamber Shell.
In another preference, the exhanst gas outlet of described flue gas expansion chamber is positioned at top or the top of flue gas expansion chamber.
In another preference, described flue gas expansion chamber (or its shell) is stainless steel or alloy material.
In another preference, the size of described flue gas expansion chamber is 90-320, it is preferred that 100-305mm, more preferably Ground, 133-245mm.
In another preference, described burner also includes fuel inlet, air intlet and Fuel-air hybrid chamber, And fuel inlet, air intlet and Fuel-air hybrid chamber are interconnected with described flue gas expansion chamber.
In another preference, described burner also includes spark plug, flame plate and/or exhanst gas outlet.
In another preference, described burner also includes flame-proof switch, gas flowmeter.
In another preference, the pipe diameter of described fuel inlet is 5-20mm, is more preferably 10-15mm.
In another preference, the pipe diameter of described air intlet is 5-40mm, is more preferably 10-30mm.
In another preference, described Fuel-air hybrid chamber includes the most mixed chamber and the most mixed chamber, and described fuel enters The combustor end of mouth stretches in the most mixed chamber.
In another preference, the shape in described first mixed chamber and the most mixed chamber includes cone or cylinder.
In another preference, the combustor end tube wall of described fuel inlet is provided with cellular opening.
In another preference, the arrangement mode of described cellular opening is the most evenly distributed.
In another preference, between described first mixed chamber and the most mixed chamber, it is provided with dismountable attachment means.
In another preference, described dismountable attachment means includes Flange joint.
In another preference, described vaporization premix chamber include material inlet, reducing premix coil pipe, mixing surge tank with And mixed gas outlet, wherein, described material inlet, reducing premix coil pipe, mixing surge tank and mixed gas outlet are sequentially Communicate mutually.
In another preference, described vaporization premix chamber include material inlet, reducing premix coil pipe, mixing surge tank with And mixed gas outlet, wherein, described material inlet, reducing premix coil pipe, mixing surge tank and mixed gas outlet are sequentially Interconnect.
In another preference, described reducing premix coil pipe coiling is located at outside mixing surge tank.
In another preference, described mixing surge tank is provided with Heat Conduction Material.
In another preference, described Heat Conduction Material include honeycomb metal, net metal, porous media material or A combination thereof.
In another preference, described material inlet includes water inlet and methane import.
In another preference, the diameter of described reducing premix coil pipe is increased thick by inlet-outlet direction;And/or
Described reducing premix coil pipe at least includes two kinds of diameters.
In another preference, described reducing premix coil pipe includes slim pipe diameter coil pipe and extra heavy pipe footpath coil pipe.
In another preference, it is peripheral that described slim pipe diameter coil pipe is paperwrapped in extra heavy pipe footpath coil pipe.
In another preference, described reformation chamber includes that mixed gas outlet, reformation tubulation and reformate are given vent to anger Mouthful, and described mixed gas outlet, reformation tubulation and reformate gas outlet be sequentially interconnected.
In another preference, between described mixed gas outlet and reformation tubulation, it is provided with gas distribution dish, wherein, described The mixed gas that gas distribution dish flows out in being collected from mixing surge tank, and described mixed gas is entered reformation row Pipe;And/or
Gas current collecting plates, wherein, described gas current collecting plates it is provided with between described reformation tubulation and reformate gas outlet For collecting the reformed gas in reformation tubulation, and described reformed gas is entered reformate gas outlet.
In another preference, described reformation tubulation is evenly arranged around the centrage of shunting disk and current collecting plates.
In another preference, described reformation tubulation quantity is n, the wherein positive integer of n=2-16;And/or
In another preference, the tube wall of described reformation tubulation is provided with external thread structure.
In another preference, described gas distribution dish or gas current collecting plates respectively set n through hole, n be 2-16 just Integer, and gas distribution dish is connected by described reformation tubulation with the through hole of gas current collecting plates.
In another preference, described reformation chamber is additionally provided with temperature controller.
Second aspect present invention, it is provided that a kind of fuel cell system, described fuel cell system includes such as the present invention the Burning described in Yi Fangmian is reformed premix integrated apparatus and fuel cell, air compressor machine, water knockout drum and water tank, dosing pump, each Class valve control and attemperating unit.
In should be understood that within the scope of the present invention, above-mentioned each technical characteristic of the present invention and having in below (eg embodiment) Can be combined with each other between each technical characteristic that body describes, thus constitute new or preferred technical scheme.As space is limited, exist This tires out the most one by one states.
Accompanying drawing explanation
Fig. 1 is the structural representation of the burning reformation vaporization preheating integrated apparatus for fuel cell system;
Fig. 2 is the internal structure schematic diagram of burning reformation vaporization preheating integrated apparatus;
Fig. 3 is the reformer tubes structural pipe wall schematic diagram of external thread structure.
Wherein, 1-burner, 2-reformer, 3-vaporization preheats at the beginning of mixing arrangement, 4-fuel inlet, 5-air intlet, 6- Mixed chamber, 7-flange, the most mixed chamber of 8-, 9-flame plate, 10-spark plug, 11-bolt, 12-reformate gas outlet, 13-gas afflux Dish, 14-flue gas expansion chamber, 15-external thread structure reformation tubulation, 16-gas distribution dish, 17-is filled with perforated metal material and mixes Closing surge tank, 18-slim pipe diameter coil pipe, 19-extra heavy pipe footpath coil pipe, 20-combustion product gases exports, 21-water inlet, 22-Imported gas, 23-mixed gas outlet, 24,25-thermocouple, the anti-riot switch interface of 26-.
Detailed description of the invention
The present inventor through extensively in-depth study, first by the burner in fuel cell system, reformation chamber and Vaporization premix chamber connects combination from bottom to up, makes reformation and vaporization premix chamber be positioned at inside the flue gas expansion chamber of burner, from And taking full advantage of the heat in burner, the flue gas reformer that i.e. burning fuel produces reaches to react temperature required, weight The flue gas after-heat that whole reaction has utilized is required for feed-water flashing and natural gas preheating, makes water in vaporization preheating mixing arrangement Vaporization resupplies reformer after becoming steam, natural gas pre-heating temperature elevation and mixing with steam.Apparatus of the present invention make waste heat Ladder utilizes, and is conducive to improving level of integrated system and system whole efficiency.
Burner
In the present invention, burner is for the anode exhaust gas of fuel cell or other fuel gas of burning.Anode exhaust gas or After fuel gas, its heat is used in reforming reaction and the premix of reforming reaction raw material for ladder.Generally, described Fuel gas includes natural gas.
The burner of the present invention includes flue gas fuel inlet, air intlet and Fuel-air hybrid chamber, described fuel Import, air intlet are connected with Fuel-air hybrid chamber, and the described pipeline used by fuel inlet stretches into Fuel-air and mixes Close intracavity.
Wherein, described Fuel-air hybrid chamber also can farther include the most mixed chamber and the most mixed chamber.In order to make fuel with empty Gas can be sufficiently mixed, and the combustor end of described fuel inlet is positioned at the most mixed intracavity, and its tube wall is provided with cellular opening, and institute The arrangement mode of the cellular opening stated is the most evenly distributed.When being passed through air and fuel, cavernous opening energy Make fuel mix with air with certain pressure, thus sufficiently burn.
The pipe diameter that can be used for fuel inlet of the present invention or air intlet is not particularly limited, and can reform according to burning The amount that the size of premix integrated apparatus and described fuel and air need carries out different designs.Generally, described combustion The pipe diameter of material import is 5-20mm, preferably 10-15mm;The pipe diameter of described air intlet is 5-40mm, excellent Choosing for 10-30mm.
In the present invention, described burner is provided with a flue gas expansion chamber, and described flue gas expansion chamber is located at burner top, Upwardly extend and surround described reformation chamber and vaporization premix chamber.The top of flue gas expansion chamber is additionally provided with one for discharging residue cigarette The exhanst gas outlet of gas.
The material that can be used for flue gas expansion chamber of the present invention (or its shell) is not particularly limited, and can be any tolerance high temperature Material.Generally, described flue gas expansion chamber (or its shell) is rustless steel or alloy material.
The diameter of flue gas expansion chamber of the present invention is not particularly limited, as long as reformer and vaporization preheating can be covered or surround Chamber, or be designed according to the size of burning reformation premix integrated apparatus or manufacture.Generally, described flue gas expansion chamber Size (external diameter) is 90-320, it is preferred that 100-305mm, more preferably, 133-245mm.
In another preference, after described fuel and air enter the preliminary mixing of the most mixed chamber entrance, enter back into the most mixed chamber Mix homogeneously, is burnt at flame plate by electricity sparking spark plug and produces flue gas, and flue gas injection goes out to enter flue gas expansion chamber, works as institute The shell stating flue gas expansion chamber forms described reformation chamber and the closure of vaporization premix chamber, then flue gas is on burner Diffusion reduction of speed in the reformation chamber of side and the vaporization preheating cavity surrounding package cavity on top, thus heating is positioned at burner top Reformation chamber and vaporization premix chamber.
Additionally, the burner of the present invention also includes spark plug, flame plate, exhanst gas outlet, flame-proof switch and/or gas flow Meter.Burner charging, just mixed between cavity segment with combustion flame dish, the most mixed cavity segment separate, and use Flange joint, install clever Work, dismounting and change are conveniently.Occur to prevent burner from becoming the dangerous situations such as high-pressure bottle, be provided with flame-proof switch, it is ensured that Safe and reliable operation.Control fuel flow rate 1-35l/min by effusion meter simultaneously and control combustion power, regulation natural gas and sky Gas ratio 10-20 controls combustion flame position and height.
Vaporization premix chamber
In the present invention, vaporization premix chamber includes material inlet, reducing premix coil pipe, mixing surge tank and mixed gas Outlet, described material inlet, reducing premix coil pipe, mixing surge tank and mixed gas outlet sequentially interconnect.
Wherein, described material inlet includes water inlet and methane import;Described reducing premix coil pipe coiling is located at mixed Closing outside surge tank, reducing premix coil pipe at least includes two kinds of diameters, and its diameter is increased thick by inlet-outlet direction.Generally, described Reducing premix coil pipe include slim pipe diameter coil pipe and extra heavy pipe footpath coil pipe.
The flow of the reducing premix coil pipe caliber and fuel that can be used for the present invention is not particularly limited, and can reform according to burning The size of premix integrated apparatus is designed or manufactures.Generally, slim pipe diameter coil pipe is paperwrapped in the periphery of extra heavy pipe footpath coil pipe, and carefully A diameter of 2-10mm of caliber coil pipe, more preferably, for 4-6mm, discharge is 1-160g/min;A diameter of 6-of extra heavy pipe footpath coil pipe 20mm, more preferably, for 8-16mm, after methane and aqueous water enter slim pipe diameter coil pipe by material inlet, carries via burner The heat of confession, aqueous water is gradually through being vaporized into water vapour, and enters the coil pipe in more extra heavy pipe footpath after volumetric expansion.Certainly, The diameter of reducing premix coil pipe can also be gradual change type or multi-stag, may be incorporated for the heating of aqueous water.
In the present invention, mixing surge tank is connected to the far-end of reducing premix coil pipe, can fill Heat Conduction Material with slow inside it Rush mixed gas and make it heat further.Can be used for the present invention and mix the Heat Conduction Material of surge tank and size does not all have special limit System, wherein, Heat Conduction Material can be that any heat conduction is quick and can form the material of air-flow buffer effect, such as, metal or other Heat-conducting medium, it is preferred that described metal or heat-conducting medium material are cellular, netted or cellular;The size of mixing surge tank Can be designed or manufacture according to the size of burning reformation premix integrated apparatus, such as 50-102mm.
Can be used for the present invention to vaporize the unstrpped gas of premix chamber and include methane or natural gas.Methane or natural gas can lead directly to slow Rush tank, or jointly lead to reducing coil pipe with water inlet.In another preference, unstrpped gas can be directly entered mixing surge tank, And after being sufficiently mixed with steam, enter reformer and carry out reforming reaction.
Total in the present invention, the ratio of unstrpped gas and steam can be through source of the gas or effusion meter according to the water of reforming reactants The different needs of carbon ratio (water vapour is between 1 to 5 from the mol ratio of natural gas) are adjusted.In another preference, this combustion The hydrogen that burning reformation vaporization pre-mixing apparatus may be used for being prepared by gas renormalizing in fuel cell system is for fuel cell power generation.
Reformation chamber
In the present invention, described reformation chamber includes mixed gas outlet, reformation tubulation and reformate gas outlet, and Described mixed gas outlet, reformation tubulation and reformate gas outlet are sequentially interconnected.
Wherein, gas distribution dish, wherein, described gas distribution dish it are provided with between described mixed gas outlet and reformation tubulation The mixed gas flowed out in being collected from mixing surge tank, and described mixed gas is entered reformation tubulation;And/or
Being provided with gas current collecting plates between described reformation tubulation and reformate gas outlet, described gas current collecting plates is used for receiving Reformed gas in collection reformation tubulation, and described reformed gas is entered reformate gas outlet.
In the present invention, described gas distribution dish or gas current collecting plates respectively setting n through hole, n is the positive integer of 2-16, And gas distribution dish is connected by described reformation tubulation with the through hole of gas current collecting plates.And the quantity of tubulation of reforming can be according to dividing Flow table or the via design of current collecting plates;In a preference, described through hole is uniformly distributed on gas distribution dish or current collecting plates, And described reformation tubulation is evenly arranged around the centrage of shunting disk and current collecting plates.Wherein, described reformation tubulation quantity is n Individual, the wherein positive integer of n=2-16.Reformer tubes number can 2-26 root, in a preference, described reformation tubulation number is 6-16 root
In order to be able to make the heat exchange of the reformed gas within reformation tubulation and reforming reaction more abundant, preferably in described reformation The tube wall of tubulation is provided with external thread structure, thus strengthens the heat exchange area of reformed gas.
The size of the reformation tubulation that can be used for the present invention is not particularly limited, and can include various being suitable for apparatus of the present invention Size, generally, its size is 10-50mm*250mm-700mm, and more preferably, described reformation tubulation is 18-28*330- 465mm。
In the present invention, premix chamber is led on top, reformation chamber, therebetween with the mixed gas inlet warp of steam and natural gas Shunting disk connects, and burner is led in bottom, connects with current collecting plates therebetween.Mixed gas in gas distribution dish is entered by through hole Each reformation tubulation carries out reforming reaction, and the reformate gas reacting generation in each reformation tubulation is collected by current collecting plates, and led to Cross gas outlet to discharge.
In addition described reformation chamber is additionally provided with temperature controller, can feed back reformer tubes interior reaction temperature by temperature controller, control The burning inlet fuel of burner.Gaseous mixture after reforming reaction is conveyed in the anode of fuel cell pack and carries out reaction and make With.
Fuel cell system
Fuel cell system of the present invention includes that the present invention burns to reform and premixes integrated apparatus and fuel cell, pneumatics Machine, water knockout drum and water tank, dosing pump, all kinds of valve control and attemperating unit.
Application
The present invention reformation premix integrated apparatus that burns can be used on a small scale hydrogen manufacturing it can also be used to outside fuel cell system Reform, thus there is not hydrogen storage and transportation problem, as long as connecting natural to the reformation premix integrated apparatus of fuel cell system Gas, just can continuously export electric energy.This system can be as a kind of safe and environment-friendly, of good reliability and compact conformation, reasonable cloth Portable or the distributed fuel cell TRT put.Fuel cell distributed co-generation unit can network in regionality In can be that the webserver, telecommunication apparatus, residential quarters, hospital, bank etc. provide stabilized power source, cheap heat is provided simultaneously Source.Its market scale, compared with big and user's ability to bear is moderate, has good market application foreground and commercial value.
Beneficial effects of the present invention
The invention provides the reforming reaction device of a kind of fuel cell burning capacity cascade utilization.This device passes through will The flue gas expansion chamber of burner is located at reformation chamber and the periphery of vaporization premix chamber, and the heat energy making combustor produce sequentially passes through reformation Chamber, He Shui-methane premix chamber carry out repeatedly step heat exchange, by burning, vaporize, preheat, mix, the multifunctional unit such as reformation in Integrally, and simple in construction, it is possible to meet the requirement of miniaturization, eliminate steam generator, improve the integrated level of device.Combustor High-quality heat be primarily used for as peripheral reforming reaction heat supply, remaining heat is then further used in preheating methane also Vaporization water, it is achieved that the cascade utilization of energy, it is achieved that system effectiveness maximizes.
The all documents mentioned in the present invention are incorporated as reference the most in this application, just as each document by individually It is incorporated as with reference to like that.In addition, it is to be understood that after the above-mentioned teachings having read the present invention, those skilled in the art can To make various changes or modifications the present invention, these equivalent form of values fall within the model that the application appended claims is limited equally Enclose.

Claims (9)

1. a fuel cell system is reformed with burning and is premixed integrated apparatus, it is characterised in that described device is from bottom to top Be connected with burner, reformation chamber and vaporization premix chamber;Wherein
Described reformation chamber includes mixed gas outlet, reformation tubulation and reformate gas outlet, and described mixed gas Outlet, reformation tubulation and reformate gas outlet are sequentially interconnected;And
Being provided with gas distribution dish between described mixed gas outlet and reformation tubulation, described gas distribution dish is used for being collected from mixing The mixed gas flowed out in surge tank, and described mixed gas is entered reformation tubulation;And/or
Being provided with gas current collecting plates between described reformation tubulation and reformate gas outlet, wherein, described gas current collecting plates is used for Collect the reformed gas in reformation tubulation, and described reformed gas is entered reformate gas outlet.
2. device as claimed in claim 1, it is characterised in that described burner also includes flue gas expansion chamber, and described cigarette Gas expansion chamber is located at burner top, upwardly extends and surround described reformation chamber and vaporization premix chamber.
3. device as claimed in claim 2, it is characterised in that described burner also include fuel inlet, air intlet and Fuel-air hybrid chamber, and fuel inlet, air intlet and Fuel-air hybrid chamber interconnect mutually with described flue gas expansion chamber Logical.
4. device as claimed in claim 3, it is characterised in that described Fuel-air hybrid chamber includes that the most mixed chamber is with the most mixed Chamber, and the combustor end of described fuel inlet stretches into just in mixed chamber.
5. the device as described in claim 1-4 is arbitrary, it is characterised in that described vaporization premix chamber includes material inlet, change Footpath premix coil pipe, mixing surge tank and mixed gas outlet, wherein, described material inlet, reducing premix coil pipe, mixing buffering Tank and mixed gas outlet communicate the most mutually.
6. device as claimed in claim 5, it is characterised in that the diameter of described reducing premix coil pipe is by inlet-outlet side Thick to increasing;And/or
Described reducing premix coil pipe at least includes two kinds of diameters.
7. device as claimed in claim 1, it is characterised in that described reformation tubulation is around shunting disk and the center of current collecting plates Line is evenly arranged.
8. device as claimed in claim 1, it is characterised in that respectively set n on described gas distribution dish or gas current collecting plates Through hole, n is the positive integer of 2-16, and gas distribution dish is connected by described reformation tubulation with the through hole of gas current collecting plates.
9. a fuel cell system, it is characterised in that described fuel cell system includes the weight that burns as claimed in claim 1 Whole premix integrated apparatus and fuel cell, air compressor machine, water knockout drum and water tank, dosing pump, all kinds of valve control and attemperating unit.
CN201310138809.6A 2013-04-19 2013-04-19 The burning of a kind of fuel cell system is reformed and is premixed integrated apparatus Active CN104112866B (en)

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CN107910570A (en) * 2017-12-14 2018-04-13 上海新源动力有限公司 A kind of hydrogen air body dual disposal structure of fuel cell system
CN112151831B (en) * 2019-06-27 2022-11-22 国家能源投资集团有限责任公司 Reformer and fuel cell power generation system thereof
CN112072146A (en) * 2020-10-14 2020-12-11 浙江浙能技术研究院有限公司 Heat exchange, combustion and reformer assembly and method for high-temperature fuel cell power generation system

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CN202737041U (en) * 2012-08-24 2013-02-13 华南理工大学 Natural gas steam reforming hydrogen production device for micro fuel cells

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CN102826507A (en) * 2012-08-24 2012-12-19 华南理工大学 Method and device of hydrogen production by natural gas and steam reforming for micro fuel cells
CN202737041U (en) * 2012-08-24 2013-02-13 华南理工大学 Natural gas steam reforming hydrogen production device for micro fuel cells

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