CN104112866A - Combustion reforming premixing integrated apparatus for fuel cell system - Google Patents
Combustion reforming premixing integrated apparatus for fuel cell system Download PDFInfo
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- CN104112866A CN104112866A CN201310138809.6A CN201310138809A CN104112866A CN 104112866 A CN104112866 A CN 104112866A CN 201310138809 A CN201310138809 A CN 201310138809A CN 104112866 A CN104112866 A CN 104112866A
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- chamber
- reformation
- premix
- tubulation
- gas outlet
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04223—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids during start-up or shut-down; Depolarisation or activation, e.g. purging; Means for short-circuiting defective fuel cells
- H01M8/04268—Heating of fuel cells during the start-up of the fuel cells
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
- H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
- H01M8/0612—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
- H01M8/0618—Reforming processes, e.g. autothermal, partial oxidation or steam reforming
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Fuel Cell (AREA)
Abstract
The invention discloses a combustion reforming premixing integrated apparatus for a fuel cell system. Concretely, the apparatus comprises a combustion chamber, a reforming chamber and a vaporization premixing chamber which are connected from top to bottom, the outer wall of a flue-gas expansion chamber of the combustion chamber forms the outer wall of the reforming chamber and the vaporization premixing chamber. The high-quality heat of the combustion chamber is firstly used to supply heat for the reforming reaction, and the residual heat is further used to preheat methane and vaporize water, so that gradient utilization of the energy is realized, and the system efficiency is maximized.
Description
Technical field
The present invention relates to a kind of burning reformation premix integrated apparatus, especially a kind of burning reformation premix integrated apparatus for fuel cell system.
Background technology
Fuel cell can be efficiently, environmental friendliness ground is leniently converted into electric energy by being stored in chemical energy in fuel etc.; hydrogen is the optimum fuel of fuel cell; if only adopt hydrogen as fuel, can the industrialization of fuel cell system, large-scale development, how the fuel such as natural gas are converted into hydrogen and seem most important.
At industrial steam reformation hydrogen production technology (CH
4+ H
2o → CO+3H
2) quite ripe, but this extensive hydrogen producing technology can not meet the requirement of fuel cell system compactness, miniaturization.
Because fuel cell system hydrogen demand is few, so cannot dwindle merely the design parameter of ripe large-scale process for making hydrogen, therefore, this area in the urgent need to develop be applicable to fuel cell system and steam reformation integrated small device.
Summary of the invention
The invention provides a kind of reformer that integrates burning, reformation, vaporization, preheating and mixed function for fuel cell system.
A first aspect of the present invention, provides burning reformation premix integrated apparatus for a kind of fuel cell system, and described device is connected with burner, reformation chamber and vaporization premix chamber from bottom to up.
In another preference, described burner also comprises flue gas expansion chamber, and described flue gas expansion chamber is located at burner top, extends upward and surround described reformation chamber and vaporization premix chamber.
In another preference, the shell of described flue gas expansion chamber forms the closure in described reformation chamber and vaporization premix chamber.
In another preference, the exhanst gas outlet of described flue gas expansion chamber is positioned at top or the top of flue gas expansion chamber.
In another preference, described flue gas expansion chamber (or its shell) is stainless steel or alloy material.
In another preference, the size of described flue gas expansion chamber is 90-320, preferably, and 100-305mm, more preferably, 133-245mm.
In another preference, described burner also comprises fuel inlet, air intlet and fuel-air hybrid chamber, and fuel inlet, air intlet and fuel-air hybrid chamber and described flue gas expansion chamber are interconnected.
In another preference, described burner also comprises spark plug, flame plate and/or exhanst gas outlet.
In another preference, described burner also comprises flame-proof switch, gas flowmeter.
In another preference, the pipe diameter of described fuel inlet is 5-20mm, is more preferably 10-15mm.
In another preference, the pipe diameter of described air intlet is 5-40mm, is more preferably 10-30mm.
In another preference, described fuel-air hybrid chamber comprises He Zhonghun chamber, just mixed chamber, and the burner end of described fuel inlet stretches in just mixed chamber.
In another preference, the shape in described He Zhonghun chamber, first mixed chamber comprises taper shape or cylindrical.
In another preference, the burner end tube wall of described fuel inlet is provided with cellular opening.
In another preference, the arrangement mode of described cellular opening is arranged along even circumferential.
In another preference, between described Yu Zhonghun chamber, first mixed chamber, be provided with dismountable jockey.
In another preference, described dismountable jockey comprises that flange connects.
In another preference, described vaporization premix chamber comprises material inlet, reducing premix coil pipe, mixes surge tank and mixed gas outlet, and wherein, described material inlet, reducing premix coil pipe, mixing surge tank and mixed gas outlet communicate mutually according to the order of sequence.
In another preference, described vaporization premix chamber comprises material inlet, reducing premix coil pipe, mixes surge tank and mixed gas outlet, and wherein, described material inlet, reducing premix coil pipe, mixing surge tank and mixed gas outlet interconnect according to the order of sequence.
In another preference, described reducing premix coil pipe coiling is located at and is mixed surge tank outside.
In another preference, in described mixing surge tank, be provided with Heat Conduction Material.
In another preference, described Heat Conduction Material comprises honeycomb metal, net metal, porous media material or its combination.
In another preference, described material inlet comprises water inlet and methane import.
In another preference, the diameter of described reducing premix coil pipe is increased thick by import-Way out; And/or
Described reducing premix coil pipe at least comprises two kinds of diameters.
In another preference, described reducing premix coil pipe comprises slim pipe diameter coil pipe and extra heavy pipe footpath coil pipe.
In another preference, it is peripheral that described slim pipe diameter coil pipe is paperwrapped in extra heavy pipe footpath coil pipe.
In another preference, described reformation chamber comprises mixed gas outlet, reformation tubulation and reformate gas outlet, and described mixed gas outlet, reformation tubulation and reformate gas outlet are interconnected according to the order of sequence.
In another preference, between described mixed gas outlet and reformation tubulation, be provided with gas distribution dish, wherein, described gas distribution dish mixes for collecting the mist flowing out in surge tank certainly, and described mist is entered to reformation tubulation; And/or
Between described reformation tubulation and reformate gas outlet, be provided with gas current collecting plates, wherein, described gas current collecting plates is used for collecting the reformed gas of reformation tubulation, and described reformed gas is entered to reformate gas outlet.
In another preference, described reformation tubulation is evenly arranged around the center line of shunting disk and current collecting plates.
In another preference, described reformation tubulation quantity is n, wherein the positive integer of n=2-16; And/or
In another preference, the tube wall of described reformation tubulation is provided with external thread structure.
In another preference, on described gas distribution dish or gas current collecting plates, respectively establish n through hole, the positive integer that n is 2-16, and gas distribution dish is connected by described reformation tubulation with the through hole of gas current collecting plates.
In another preference, described reformation chamber is also provided with temperature controller.
Second aspect present invention, a kind of fuel cell system is provided, described fuel cell system comprises burning reformation premix integrated apparatus as described in first aspect present invention and fuel cell, air compressor machine, water knockout drum and water tank, measuring pump, all kinds of valve control and attemperating unit.
In should be understood that within the scope of the present invention, above-mentioned each technical characterictic of the present invention and can combining mutually between specifically described each technical characterictic in below (eg embodiment), thus form new or preferred technical scheme.As space is limited, at this, tire out and state no longer one by one.
Accompanying drawing explanation
Fig. 1 is the structural representation for the burning reformation vaporization preheating integrated apparatus of fuel cell system;
Fig. 2 is the internal structure schematic diagram of burning reformation vaporization preheating integrated apparatus;
Fig. 3 is the reformer tubes structural pipe wall schematic diagram of external thread structure.
Wherein, 1-burner, 2-reformer, 3-vaporization preheating mixing arrangement, 4-fuel inlet, 5-air intlet, 6-is mixed chamber just, 7-flange, the eventually mixed chamber of 8-, 9-flame plate, 10-spark plug, 11-bolt, 12-reformate gas outlet, 13-gas current collecting plates, 14-flue gas expansion chamber, 15-external thread structure reformation tubulation, 16-gas distribution dish, 17-has filled poroid metal material mixing surge tank, 18-slim pipe diameter coil pipe, 19-extra heavy pipe footpath coil pipe, the outlet of 20-combustion product gases, 21-water inlet, 22-Imported gas, 23-mixed gas outlet, 24, 25-thermocouple, the anti-riot switch interface of 26-.
Embodiment
The inventor is through extensive and deep research, first by the burner in fuel cell system, reformation chamber and vaporization premix chamber connect combination from bottom to up, make reformation and vaporization premix chamber be positioned at the flue gas expansion chamber inside of burner, thereby take full advantage of the heat in burner, it is temperature required to be that flue gas reformer that combustion fuel produces reaches reaction, the flue gas after-heat that reforming reaction has been utilized is required for feed-water flashing and natural gas preheating, in vaporization preheating mixing arrangement, make water is vaporized into into steam, natural gas pre-heating temperature elevation and mix with steam after resupply reformer.Apparatus of the present invention make the utilization of waste heat ladder, are conducive to improve level of integrated system and entire system efficiency.
Burner
In the present invention, burner is for anode exhaust gas or other fuel gas of combustion fuel battery.After anode exhaust gas or fuel gas, its heat is used in the premix of reforming reaction and reforming reaction raw material for ladder.Conventionally, described fuel gas comprises natural gas.
Burner of the present invention comprises flue gas fuel inlet, air intlet and fuel-air hybrid chamber, and described fuel inlet, air intlet are connected with fuel-air hybrid chamber, and described fuel inlet pipeline used stretches in fuel-air hybrid chamber.
Wherein, described fuel-air hybrid chamber also can further comprise He Zhonghun chamber, just mixed chamber.For fuel can fully be mixed with air, the burner end of described fuel inlet is positioned at just mixed chamber, and its tube wall is provided with cellular opening, and the arrangement mode of described cellular opening is arranged along even circumferential.When passing into air and fuel, cavernous opening can make fuel mix with air with certain pressure, thereby burns fully.
The pipe diameter that can be used for fuel inlet of the present invention or air intlet is not particularly limited, and can carry out different designs according to the amount of the size of burning reformation premix integrated apparatus and described fuel and air needs.Conventionally, the pipe diameter of described fuel inlet is 5-20mm, preferably 10-15mm; The pipe diameter of described air intlet is 5-40mm, preferably 10-30mm.
In the present invention, described burner is provided with a flue gas expansion chamber, and described flue gas expansion chamber is located at burner top, extends upward and surround described reformation chamber and vaporization premix chamber.The top of flue gas expansion chamber is also provided with one for discharging the exhanst gas outlet of residue flue gas.
The material that can be used for flue gas expansion chamber of the present invention (or its shell) is not particularly limited, and can be the material of any withstand high temperatures.Conventionally, described flue gas expansion chamber (or its shell) is stainless steel or alloy material.
The diameter of flue gas expansion chamber of the present invention is not particularly limited, as long as can cover or surround reformer and vaporization preheating cavity, or designs or manufactures according to the size of burning reformation premix integrated apparatus.Conventionally, the size of described flue gas expansion chamber (external diameter) is 90-320, preferably, and 100-305mm, more preferably, 133-245mm.
In another preference, described fuel and air enter just mixed chamber and enter after preliminary mixing, entering eventually mixed chamber mixes again, by electricity, striking sparks, at flame plate place, burning produces flue gas to spark plug, flue gas injection goes out to enter flue gas expansion chamber, when the shell of described flue gas expansion chamber forms the closure in described reformation chamber and vaporization premix chamber, flue gas diffusion reduction of speed in the peripheral encapsulation of the vaporization preheating cavity cavity on the reformation chamber near above burner and top, is positioned at the reformation chamber on burner top and the premix chamber of vaporizing thereby heat.
In addition, burner of the present invention also comprises spark plug, flame plate, exhanst gas outlet, flame-proof switch and/or gas flowmeter.Burner charging, just between mixed cavity segment and combustion flame dish, eventually mixed cavity segment separate, and adopts flange connection, flexible for installation, dismounting and change is conveniently.In order to prevent that burner from becoming the dangerous situations such as high-pressure bottle and occurring, be provided with flame-proof switch, guarantee safe and reliable operation.By flowmeter, control fuel flow rate 1-35l/min carrys out control combustion power, regulates natural gas and AIR Proportional 10-20 to come control combustion flame location and height simultaneously.
Vaporization premix chamber
In the present invention, vaporization premix chamber comprises material inlet, reducing premix coil pipe, mixes surge tank and mixed gas outlet, and described material inlet, reducing premix coil pipe, mixing surge tank and mixed gas outlet interconnect according to the order of sequence.
Wherein, described material inlet comprises water inlet and methane import; Described reducing premix coil pipe coiling is located at and is mixed surge tank outside, and reducing premix coil pipe at least comprises two kinds of diameters, and its diameter is increased thick by import-Way out.Conventionally, described reducing premix coil pipe comprises slim pipe diameter coil pipe and extra heavy pipe footpath coil pipe.
The flow that can be used for reducing premix coil pipe caliber of the present invention and fuel is not particularly limited, and can design or manufacture according to the size of burning reformation premix integrated apparatus.Conventionally, slim pipe diameter coil pipe is paperwrapped in the periphery of extra heavy pipe footpath coil pipe, and the diameter of slim pipe diameter coil pipe is 2-10mm, more preferably, is 4-6mm, and discharge is 1-160g/min; The diameter of extra heavy pipe footpath coil pipe is 6-20mm, more preferably, is 8-16mm, when methane and aqueous water enter after slim pipe diameter coil pipe by material inlet, the heat heating providing via burner, aqueous water is gradually through being vaporized into water vapour, and after volumetric expansion, enters the more coil pipe in extra heavy pipe footpath.Certainly, the diameter of reducing premix coil pipe can also be gradual change type or multistage, all can be for the heating of aqueous water.
In the present invention, mix the far-end that surge tank is connected in reducing premix coil pipe, its inside can be filled Heat Conduction Material with buffering mist and further be made its heating.The Heat Conduction Material and the size that can be used for the present invention's mixing surge tank are all not particularly limited, wherein, Heat Conduction Material can for any heat conduction fast and can form the material of air-flow buffer effect, such as, metal or other heat-conducting mediums, preferably, described metal or heat-conducting medium material are cellular, netted or cellular; The size of mixing surge tank can design or manufacture according to the size of burning reformation premix integrated apparatus, as 50-102mm.
Can be used for the vaporize unstrpped gas in premix chamber of the present invention and comprise methane or natural gas.Methane or natural gas can lead directly to surge tank, or jointly lead to reducing coil pipe with water inlet.In another preference, unstrpped gas can directly enter mixing surge tank, and after fully mixing with steam, enters reformer and carry out reforming reaction.
Total in the present invention, the ratio of unstrpped gas and steam can be through source of the gas or flowmeter according to different need to the adjusting of the steam/hydrocarbons ratio of reforming reactants (mol ratio of water vapour and natural gas is between 1 to 5).In another preference, vaporization pre-mixing apparatus is reformed in this burning can be for the hydrogen that in fuel cell system, gas renormalizing made for fuel cell power generation.
Reformation chamber
In the present invention, described reformation chamber comprises mixed gas outlet, reformation tubulation and reformate gas outlet, and described mixed gas outlet, reformation tubulation and reformate gas outlet are interconnected according to the order of sequence.
Wherein, between described mixed gas outlet and reformation tubulation, be provided with gas distribution dish, wherein, described gas distribution dish mixes for collecting the mist flowing out in surge tank certainly, and described mist is entered to reformation tubulation; And/or
Between described reformation tubulation and reformate gas outlet, be provided with gas current collecting plates, described gas current collecting plates is used for collecting the reformed gas of reformation tubulation, and described reformed gas is entered to reformate gas outlet.
In the present invention, on described gas distribution dish or gas current collecting plates, respectively establish n through hole, the positive integer that n is 2-16, and gas distribution dish is connected by described reformation tubulation with the through hole of gas current collecting plates.And the quantity of reformation tubulation can be according to the via design of shunting disk or current collecting plates; In a preference, described through hole is uniformly distributed on gas distribution dish or current collecting plates, and described reformation tubulation is evenly arranged around the center line of shunting disk and current collecting plates.Wherein, described reformation tubulation quantity is n, wherein the positive integer of n=2-16.Reformer tubes number can 2-26 root, and in a preference, described reformation tubulation number is 6-16 root
For heat exchange and the reforming reaction of the reformed gas of the tubulation inside that can make to reform are more abundant, preferably the tube wall at described reformation tubulation is provided with external thread structure, thereby strengthens the heat exchange area of reformed gas.
The size that can be used for reformation tubulation of the present invention is not particularly limited, and can comprise the various sizes that are suitable for apparatus of the present invention, and conventionally, its size is 10-50mm*250mm-700mm, and more preferably, described reformation tubulation is 18-28*330-465mm.
In the present invention, premix chamber is led on top, reformation chamber, and the mixed gas inlet with steam and natural gas is connected through shunting disk therebetween, and burner is led in bottom, connects therebetween with current collecting plates.Mist in gas distribution dish enters by through hole the tubulation of respectively reforming and carries out reforming reaction, and the reformate gas that in each tubulation of reforming, reaction produces is collected by current collecting plates, and discharges by gas outlet.
In addition described reformation chamber is also provided with temperature controller, by temperature controller, can feed back reformer tubes interior reaction temperature, carrys out the burning import fuel of control combustion device.Gaseous mixture after reforming reaction is conveyed in the anode of fuel cell pack and reacts use.
Fuel cell system
Fuel cell system of the present invention comprises the present invention burn reformation premix integrated apparatus and fuel cell, air compressor machine, water knockout drum and water tank, measuring pump, all kinds of valve control and attemperating unit.
Application
The present invention's reformation premix integrated apparatus that burns can be used on a small scale hydrogen manufacturing, also can be used for the outer reformation of fuel cell system, thereby there is not storage hydrogen and transportation problem, as long as connect natural gas to the reformation premix integrated apparatus of fuel cell system, just can continuously export electric energy.This system can be used as a kind of safety, environmental protection, reliability is good and the portable or distributed fuel cell power generating system of compact conformation, reasonable Arrangement.Fuel cell distributed co-generation unit can, for the webserver, telecommunication apparatus, residential quarters, hospital, bank etc. provide stabilized power supply, provide cheap thermal source in regionality in can network simultaneously.Its market scale is large and user's ability to bear is moderate, has good market application foreground and commercial value.
Beneficial effect of the present invention
The invention provides the reforming reaction device of burning capacity cascade utilization for a kind of fuel cell.This device is by being located at the flue gas expansion chamber of burner the periphery in reformation chamber and vaporization premix chamber, make the heat energy that combustion chamber produces through reformation chamber, He Shui-methane premix chamber, carry out repeatedly step heat exchange successively, by multi-functional being integrated in one such as burning, vaporization, preheating, mixing, reformations, and simple in structure, can meet the requirement of miniaturization, save steam generator, improved the integrated level of device.First the high-quality heat of combustion chamber is used to as peripheral reforming reaction heat supply, and remaining heat is further used in preheating methane vaporize water, has realized the cascade utilization of energy, has realized system effectiveness maximization.
All documents of mentioning in the present invention are all quoted as a reference in this application, just as each piece of document, are quoted as a reference separately.In addition should be understood that those skilled in the art can make various changes or modifications the present invention after having read above-mentioned instruction content of the present invention, these equivalent form of values fall within the application's appended claims limited range equally.
Claims (12)
1. a burning reformation premix integrated apparatus for fuel cell system, is characterized in that, described device is connected with burner, reformation chamber and vaporization premix chamber from bottom to up.
2. device as claimed in claim 1, is characterized in that, described burner also comprises flue gas expansion chamber, and described flue gas expansion chamber is located at burner top, extends upward and surround described reformation chamber and vaporization premix chamber.
3. device as claimed in claim 2, is characterized in that, described burner also comprises fuel inlet, air intlet and fuel-air hybrid chamber, and fuel inlet, air intlet and fuel-air hybrid chamber and described flue gas expansion chamber are interconnected.
4. device as claimed in claim 3, is characterized in that, described fuel-air hybrid chamber comprises He Zhonghun chamber, just mixed chamber, and the burner end of described fuel inlet stretches in just mixed chamber.
5. the device as described in as arbitrary in claim 2-4, it is characterized in that, described vaporization premix chamber comprises material inlet, reducing premix coil pipe, mixes surge tank and mixed gas outlet, wherein, described material inlet, reducing premix coil pipe, mixing surge tank and mixed gas outlet communicate mutually according to the order of sequence.
6. device as claimed in claim 1, it is characterized in that, described vaporization premix chamber comprises material inlet, reducing premix coil pipe, mixes surge tank and mixed gas outlet, and wherein, described material inlet, reducing premix coil pipe, mixing surge tank and mixed gas outlet interconnect according to the order of sequence.
7. device as claimed in claim 6, is characterized in that, the diameter of described reducing premix coil pipe is increased thick by import-Way out; And/or
Described reducing premix coil pipe at least comprises two kinds of diameters.
8. device as claimed in claim 1, is characterized in that, described reformation chamber comprises mixed gas outlet, reformation tubulation and reformate gas outlet, and described mixed gas outlet, reformation tubulation and reformate gas outlet are interconnected according to the order of sequence.
9. device as claimed in claim 8, it is characterized in that, between described mixed gas outlet and reformation tubulation, be provided with gas distribution dish, wherein, described gas distribution dish mixes for collecting the mist flowing out in surge tank certainly, and described mist is entered to reformation tubulation; And/or
Between described reformation tubulation and reformate gas outlet, be provided with gas current collecting plates, wherein, described gas current collecting plates is used for collecting the reformed gas of reformation tubulation, and described reformed gas is entered to reformate gas outlet.
10. device as claimed in claim 9, is characterized in that, described reformation tubulation is evenly arranged around the center line of shunting disk and current collecting plates.
11. devices as claimed in claim 9, is characterized in that, respectively establish n through hole on described gas distribution dish or gas current collecting plates, the positive integer that n is 2-16, and gas distribution dish is connected by described reformation tubulation with the through hole of gas current collecting plates.
12. 1 kinds of fuel cell systems, is characterized in that, described fuel cell system comprises burning reformation premix integrated apparatus as claimed in claim 1 and fuel cell, air compressor machine, water knockout drum and water tank, measuring pump, all kinds of valve control and attemperating unit.
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CN201310138809.6A CN104112866B (en) | 2013-04-19 | 2013-04-19 | The burning of a kind of fuel cell system is reformed and is premixed integrated apparatus |
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CN201310138809.6A CN104112866B (en) | 2013-04-19 | 2013-04-19 | The burning of a kind of fuel cell system is reformed and is premixed integrated apparatus |
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Cited By (3)
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CN107910570A (en) * | 2017-12-14 | 2018-04-13 | 上海新源动力有限公司 | A kind of hydrogen air body dual disposal structure of fuel cell system |
CN112072146A (en) * | 2020-10-14 | 2020-12-11 | 浙江浙能技术研究院有限公司 | Heat exchange, combustion and reformer assembly and method for high-temperature fuel cell power generation system |
CN112151831A (en) * | 2019-06-27 | 2020-12-29 | 国家能源投资集团有限责任公司 | Reformer and fuel cell power generation system thereof |
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CN102826507A (en) * | 2012-08-24 | 2012-12-19 | 华南理工大学 | Method and device of hydrogen production by natural gas and steam reforming for micro fuel cells |
CN202737041U (en) * | 2012-08-24 | 2013-02-13 | 华南理工大学 | Natural gas steam reforming hydrogen production device for micro fuel cells |
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CN1568286A (en) * | 2002-06-03 | 2005-01-19 | 日产自动车株式会社 | Combustor, fuel reforming device, fuel cell system and method for starting up the fuel reforming system |
US20040194384A1 (en) * | 2003-04-04 | 2004-10-07 | Texaco Inc. | Method and apparatus for rapid heating of fuel reforming reactants |
CN102826507A (en) * | 2012-08-24 | 2012-12-19 | 华南理工大学 | Method and device of hydrogen production by natural gas and steam reforming for micro fuel cells |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN107910570A (en) * | 2017-12-14 | 2018-04-13 | 上海新源动力有限公司 | A kind of hydrogen air body dual disposal structure of fuel cell system |
CN112151831A (en) * | 2019-06-27 | 2020-12-29 | 国家能源投资集团有限责任公司 | Reformer and fuel cell power generation system thereof |
CN112151831B (en) * | 2019-06-27 | 2022-11-22 | 国家能源投资集团有限责任公司 | Reformer and fuel cell power generation system thereof |
CN112072146A (en) * | 2020-10-14 | 2020-12-11 | 浙江浙能技术研究院有限公司 | Heat exchange, combustion and reformer assembly and method for high-temperature fuel cell power generation system |
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