CN104111565B - Micro-nano optical switch based on surface plasmon Fano resonance and cascade optical switch using same - Google Patents

Micro-nano optical switch based on surface plasmon Fano resonance and cascade optical switch using same Download PDF

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CN104111565B
CN104111565B CN201410265615.7A CN201410265615A CN104111565B CN 104111565 B CN104111565 B CN 104111565B CN 201410265615 A CN201410265615 A CN 201410265615A CN 104111565 B CN104111565 B CN 104111565B
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李孝峰
詹耀辉
吴绍龙
翟雄飞
吴凯
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Suzhou Bingchen Intellectual Property Operation Co ltd
Suzhou Junyi Network Intelligent Technology Co ltd
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Abstract

本发明公开了一种基于表面等离激元法诺共振的微纳光开关,包括透明衬底,其特征在于透明衬底上依次叠置有金属薄膜层、向列相液晶取向转换层和起偏器,其中:起偏器给予透过光以初始的极化方向;向列相液晶取向转换层,用于接纳上述具有初始极化方向的透过光,并控制经由其透射出去的光的极化方向;金属薄膜层,其上蚀刻有单独的金属孔四聚体单元构型或由该单元经四方排列或六方排列而成的阵列拓扑构型,金属孔四聚体单元构型中的四孔呈D2h群对称,具有正交的短轴和长轴;当通过向列相液晶取向转换层透射下来的光的极化方向与短轴平行时,打开光路,反之则激发表面等离激元法诺共振,关闭光路。本发明不仅具有液晶光开关的所有优势,同时兼具传统液晶光开关不具备的波长选择功能。

The invention discloses a micro-nano optical switch based on surface plasmon Fano resonance, which includes a transparent substrate, and is characterized in that a metal thin film layer, a nematic liquid crystal orientation conversion layer and a photoelectric switching layer are sequentially stacked on the transparent substrate. A polarizer, wherein: the polarizer gives an initial polarization direction to the transmitted light; the nematic liquid crystal alignment conversion layer is used to receive the above-mentioned transmitted light with the initial polarization direction, and control the direction of the transmitted light through it. Polarization direction; the metal thin film layer is etched with a separate metal hole tetramer unit configuration or an array topology formed by the unit through a tetragonal arrangement or a hexagonal arrangement, and the metal hole tetramer unit configuration The four holes are D 2h group symmetric, with orthogonal short axis and long axis; when the polarization direction of the light transmitted through the nematic liquid crystal alignment conversion layer is parallel to the short axis, the optical path is opened, otherwise, the surface plasmon is excited The polariton Fano resonance closes the optical path. The invention not only has all the advantages of the liquid crystal light switch, but also has the wavelength selection function that the traditional liquid crystal light switch does not have.

Description

一种基于表面等离激元法诺共振的微纳光开关及使用它的级 联光开关A micro-nano optical switch based on surface plasmon Fano resonance and its level Optical switch

技术领域technical field

本发明涉及一种基于表面等离激元法诺共振的微纳光开关及使用它的级联光开关。The invention relates to a micro-nano optical switch based on surface plasmon Fano resonance and a cascaded optical switch using it.

背景技术Background technique

信息技术与人类生活和生产密切相关,它的发展经历了人工手段、电磁技术和电子技术阶段,现在正在朝着光子技术阶段发展。光子技术是以光子为载体实现信息的传输、处理和存储的现代技术。因为光子比电子学频率高1000多倍,支持空间上的多维信息处理,并且抗电磁干扰,所以在信息通信方面光子与电子相比具有无法比拟的优越性:信息携带容量更大,信息处理速度更快,信息传输的保密性更好。在日益发展的光通信网络中,光链路和光节点是主要组成部分;而光节点中的所有路由、交换和处理系统的基本单元都是光开关。因此光开关是光通信网络的核心技术和关键器件。从研究趋势看,光开关正面临性能最优化、规模可扩展、功能多样化等多方面的挑战,并成为建设下一代光网络的瓶颈。Information technology is closely related to human life and production. Its development has gone through the stages of artificial means, electromagnetic technology and electronic technology, and is now developing towards the stage of photon technology. Photon technology is a modern technology that realizes the transmission, processing and storage of information with photon as the carrier. Because the frequency of photons is more than 1000 times higher than that of electronics, it supports multi-dimensional information processing in space, and is resistant to electromagnetic interference, so photons have incomparable advantages compared with electrons in information communication: larger information carrying capacity and faster information processing Faster, better confidentiality of information transmission. In the growing optical communication network, optical links and optical nodes are the main components; and the basic units of all routing, switching and processing systems in optical nodes are optical switches. Therefore, the optical switch is the core technology and key device of the optical communication network. From the perspective of research trends, optical switches are facing challenges in performance optimization, scalable scale, and functional diversification, and have become a bottleneck in the construction of next-generation optical networks.

光开关严格定义为:在一定的驱动方式下,把光信号的某个参量(强度、波长、方向或偏振等)从一种状态快速地、可逆地、不连续地转变为另一种状态的过程。现有的光开关主要包括机械式光开关、磁光开关、声光开关、液晶开关、MEMS开关等。其中,液晶光开关与其他光开关相比,具有能耗低、隔离度高、使用寿命长、稳定性和可靠性好等优点,因此近几年来被大力发展。然而,传统的包括液晶光开关在内光开关是一种光强开关,不具有波长选择性,即对所有波长都是同时实现开关的切换。但是光通信的发展不但需要空间域和时间域的交换状态,而且需要频域的交换选择功能。另一方面,光通信网络正朝着集成光路方向发展,光通信的集成化是信息工业发展的必由之路,也是国家的重大战略需求。集成光路的发展必然要求光学元件(包括光开关)的尺寸逐渐微纳光化,因此研发新型微纳光光开关是集成光通信技术亟待实现的发展目标。An optical switch is strictly defined as: under a certain driving mode, a certain parameter (intensity, wavelength, direction or polarization, etc.) of an optical signal is rapidly, reversibly, and discontinuously changed from one state to another. process. Existing optical switches mainly include mechanical optical switches, magneto-optical switches, acousto-optic switches, liquid crystal switches, MEMS switches, and the like. Among them, compared with other optical switches, liquid crystal optical switches have the advantages of low energy consumption, high isolation, long service life, good stability and reliability, etc., so they have been vigorously developed in recent years. However, traditional optical switches including liquid crystal optical switches are a kind of light intensity switches, which do not have wavelength selectivity, that is, switches are simultaneously realized for all wavelengths. However, the development of optical communication requires not only the switching state of the space domain and the time domain, but also the switching selection function of the frequency domain. On the other hand, the optical communication network is developing towards the direction of integrated optical path. The integration of optical communication is the only way for the development of the information industry, and it is also a major strategic demand of the country. The development of integrated optical circuits inevitably requires that the size of optical components (including optical switches) be gradually reduced to micro-nano optical switches. Therefore, the development of new micro-nano optical switches is an urgent development goal of integrated optical communication technology.

法诺共振是连续背景场和离散共振场相互干涉作用而产生的一种特征共振现象,其在光谱上表现为非对称的共振线型。该现象是Ugo Fano在研究原子体系中电子的非弹性散射时发现的,起初被认为仅限于量子领域,之后拓展到众多科学工程领域。近年来人们发现金属颗粒能够模拟分子构型,并在光照驱动下产生不同模式的表面等离激元,这些不同模式之间相互干涉震荡,从而实现法诺共振。本发明涉及的法诺共振表现在散射光谱线型非对称、线宽极窄、散射低谷对应于表面等离激元相位相干抵消所产生的暗模式(Darkmode)。Fano resonance is a characteristic resonance phenomenon produced by the mutual interference between the continuous background field and the discrete resonance field, and it appears as an asymmetric resonance line shape in the spectrum. This phenomenon was discovered by Ugo Fano when he was studying the inelastic scattering of electrons in atomic systems. It was initially considered to be limited to the quantum field, and then expanded to many scientific and engineering fields. In recent years, it has been discovered that metal particles can simulate molecular configurations and generate surface plasmons in different modes under the drive of light. These different modes interfere with each other and oscillate, thereby realizing the Fano resonance. The Fano resonance involved in the present invention is manifested in the asymmetrical line shape of the scattering spectrum, the extremely narrow line width, and the scattering trough corresponding to the dark mode (Dark mode) produced by the surface plasmon phase coherence cancellation.

发明内容Contents of the invention

本发明目的是:提供一种基于表面等离激元法诺共振的微纳光开关,其器件工作原理完全不同于传统液晶光开关,利用了液晶的双折射特性,不仅具有液晶光开关的所有优势,同时兼具传统液晶光开关不具备的波长选择功能。The object of the present invention is: to provide a micro-nano optical switch based on surface plasmon Fano resonance, the working principle of the device is completely different from that of traditional liquid crystal optical switches, and utilizes the birefringence characteristics of liquid crystals, not only has all the advantages of liquid crystal optical switches Advantages, and at the same time, it has the wavelength selection function that traditional liquid crystal optical switches do not have.

本发明的技术方案是:一种基于表面等离激元法诺共振的微纳光开关,包括透明衬底,其特征在于所述透明衬底上依次叠置有金属薄膜层、向列相液晶取向转换层和起偏器,其中:The technical solution of the present invention is: a micro-nano optical switch based on surface plasmon Fano resonance, comprising a transparent substrate, characterized in that a metal thin film layer, a nematic liquid crystal layer, and a nematic liquid crystal are sequentially stacked on the transparent substrate. an orientation conversion layer and a polarizer, wherein:

起偏器,给予透过光以初始的极化方向;Polarizer, which gives the transmitted light an initial polarization direction;

向列相液晶取向转换层,用于接纳上述具有初始极化方向的透过光,并控制经由其透射出去的光的极化方向;The nematic liquid crystal alignment conversion layer is used to receive the above-mentioned transmitted light with the initial polarization direction, and control the polarization direction of the light transmitted through it;

金属薄膜层,其上蚀刻有单独的金属孔四聚体单元构型或由该单元经四方排列或六方排列而成的阵列拓扑构型,所述金属孔四聚体单元构型中的四孔呈D2h群对称,具有正交的短轴和长轴;当通过向列相液晶取向转换层透射下来的光的极化方向且与短轴平行时,打开光路;当通过向列相液晶取向转换层透射下来的光的极化方向相对于初始极化方向发生转变,且与长轴平行时,则激发表面等离激元法诺共振,关闭光路。The metal thin film layer is etched with a single metal hole tetramer unit configuration or an array topology configuration formed by the unit through a tetragonal arrangement or a hexagonal arrangement, and the four holes in the metal hole tetramer unit configuration It is D 2h group symmetric, with orthogonal short axis and long axis; when the polarization direction of the light transmitted through the nematic liquid crystal alignment conversion layer is parallel to the short axis, the optical path is opened; when the nematic liquid crystal is aligned When the polarization direction of the light transmitted by the conversion layer changes relative to the initial polarization direction and is parallel to the long axis, the surface plasmon Fano resonance is excited and the optical path is closed.

进一步的,本发明中所述金属薄膜层的厚度为20~100nm,金属孔四聚体单元构型中四孔的孔径Φ均为90~1000nm,孔间距s均为3~100nm。Further, the thickness of the metal thin film layer in the present invention is 20-100 nm, the pore diameters Φ of the four holes in the metal hole tetramer unit configuration are all 90-1000 nm, and the pore spacing s is 3-100 nm.

进一步的,本发明中所述向列相液晶取向转换层,包括依次叠置于金属薄膜层上的下液晶取向控制透明层、向列相液晶层、上液晶取向控制透明层;其中下液晶取向控制透明层的上表面设有平行间隔分布的若干沟槽,而上液晶取向控制透明层的下表面则设有交叉指型电极并引出电极线,所述交叉指型电极的叉指方向与下方沟槽平行或垂直,对应的,当交叉指型电极通电后,其产生的电场方向与下方沟槽垂直或者平行。Further, the nematic liquid crystal orientation conversion layer described in the present invention includes a lower liquid crystal orientation control transparent layer, a nematic liquid crystal layer, and an upper liquid crystal orientation control transparent layer stacked on the metal film layer in sequence; wherein the lower liquid crystal orientation The upper surface of the control transparent layer is provided with a number of grooves distributed in parallel at intervals, and the lower surface of the upper liquid crystal orientation control transparent layer is provided with interdigitated electrodes and lead out electrode lines. The grooves are parallel or vertical. Correspondingly, when the interdigitated electrodes are energized, the direction of the electric field generated by them is vertical or parallel to the grooves below.

更进一步的,本发明中所述下液晶取向控制透明层为聚酰亚胺薄膜层、ITO或FTO,而上液晶取向控制透明层为玻璃盖片层。Furthermore, the lower transparent layer for controlling liquid crystal orientation in the present invention is a polyimide film layer, ITO or FTO, and the upper transparent layer for controlling liquid crystal orientation is a cover glass layer.

进一步的,本发明中所述向列相液晶取向转换层,包括依次叠置于金属薄膜层上的下液晶取向控制透明层、向列相液晶层、上液晶取向控制透明层;其中下液晶取向控制透明层的上表面设有平行间隔分布的若干沟槽,而上液晶取向控制透明层的下表面也设有平行间隔分布的若干沟槽,这些沟槽与下液晶取向控制透明层上的沟槽垂直;还包括分别连接至上、下液晶取向控制透明层上的电极线,用于施加给向列相液晶层以垂直向电场。Further, the nematic liquid crystal orientation conversion layer described in the present invention includes a lower liquid crystal orientation control transparent layer, a nematic liquid crystal layer, and an upper liquid crystal orientation control transparent layer stacked on the metal film layer in sequence; wherein the lower liquid crystal orientation The upper surface of the control transparent layer is provided with several grooves distributed in parallel at intervals, and the lower surface of the upper liquid crystal orientation control transparent layer is also provided with several grooves distributed in parallel at intervals, and these grooves are connected with the grooves on the lower liquid crystal orientation control transparent layer. The groove is vertical; it also includes electrode lines respectively connected to the upper and lower liquid crystal orientation control transparent layers for applying a vertical electric field to the nematic liquid crystal layer.

更进一步的,本发明中所述下液晶取向控制透明层为聚酰亚胺薄膜层、ITO或FTO,而上液晶取向控制透明层为ITO导电膜层。Further, in the present invention, the lower transparent layer for controlling liquid crystal orientation is a polyimide film layer, ITO or FTO, and the upper transparent layer for controlling liquid crystal orientation is an ITO conductive film layer.

更进一步的,本发明中所述上液晶取向控制透明层的下表面旋涂一层直径为1~10微米的玻璃球作为垫衬,向列相液晶填充于所述玻璃球间隙内形成所述向列相液晶层。实际上,玻璃球衬底夹抵在上、下液晶取向控制透明层之间,玻璃球的直径尺寸与向列相液晶层的厚度相等。Furthermore, in the present invention, the lower surface of the upper liquid crystal orientation control transparent layer is spin-coated with a layer of glass balls with a diameter of 1-10 microns as a pad, and the nematic liquid crystal is filled in the gap of the glass balls to form the Nematic liquid crystal layer. In fact, the glass ball substrate is sandwiched between the upper and lower liquid crystal orientation control transparent layers, and the diameter of the glass ball is equal to the thickness of the nematic liquid crystal layer.

更进一步的,本发明中所述金属薄膜层的金属材料为Au、Ag或Al。Furthermore, the metal material of the metal thin film layer in the present invention is Au, Ag or Al.

本发明中所述向列相液晶为常规技术,例如选择正戊基联苯氰。The nematic liquid crystal described in the present invention is conventional technology, for example, n-pentyl biphenylcyanide is selected.

进一步的,本发明还包括设于所述透明衬底的下方的检偏器。Further, the present invention also includes an analyzer arranged under the transparent substrate.

本发明中的起偏器和检偏器均采用偏振片,同常规技术一样,起偏器可以把入射的复合偏振的自然光变成单一的线偏振光,而检偏器用途是检验和分析光的偏振状态。Both the polarizer and the analyzer in the present invention use polarizers. Like the conventional technology, the polarizer can change the incident compound polarized natural light into a single linearly polarized light, and the analyzer is used for inspection and analysis of light. the polarization state.

本发明中涉及的核心元件为模拟分子构型的金属孔四聚体单元构型:其由四孔组成且呈D2h群对称,当光波之电场极化方向与金属孔四聚体单元构型的短轴平行时,透射光谱只有一个散射峰;当光波之电场极化方向与金属孔四聚体单元构型的长轴平行时,透射峰出现一个狭窄的低谷,对应于表面等离激元暗模式。通过电压通断可以控制向列相液晶取向,进而调控经起偏器入射的光波极化方向,最终实现对光透射强度和波长有效控制。The core element involved in the present invention is the metal hole tetramer unit configuration that simulates the molecular configuration: it is composed of four holes and is D 2h group symmetric, when the electric field polarization direction of the light wave is consistent with the metal hole tetramer unit configuration When the short axis of the metal hole tetramer unit configuration is parallel, the transmission spectrum has only one scattering peak; when the electric field polarization direction of the light wave is parallel to the long axis of the metal hole tetramer unit configuration, a narrow trough appears in the transmission peak, corresponding to the surface plasmon dark mode. The orientation of the nematic liquid crystal can be controlled by switching the voltage on and off, and then the polarization direction of the light wave incident through the polarizer can be adjusted, and finally the effective control of the light transmission intensity and wavelength can be realized.

本发明体系中涉及的光与微纳结构(金属孔四聚体单元构型)的相互作用可以通过求解麦克斯韦方程精确描述,求解方法包括有限时域、有限元和边界元等数值方法。通过时域和频域的数值仿真,可以获得典型的光谱响应曲线。光谱响应的内在物理机制是表面等离激元模式的相干震荡:当各模式的相位一致时,表面等离激元波相干相长,出现散射峰;当暗模式(dark mode)出现,并与明模式(bright mode)交互作用时,由于其相位相反,表面等离激元波相干相消,出现散射谷。表面等离激元明模式往往属于偶极子模式(dipolemodes),由于辐射衰减速率大,散射谱线比较宽广;相反地,暗模式由于不能直接与入射光耦合,辐射衰减速率很小,散射谱线比较狭窄。正是这种狭窄的暗模式使得法诺共振的共振线宽只有几十纳米,因此该共振对波长非常敏感,可以应用于波长选择器件。The interaction between light and the micro-nano structure (metal hole tetramer unit configuration) involved in the system of the present invention can be accurately described by solving Maxwell's equations, and the solving methods include numerical methods such as finite time domain, finite element and boundary element. Typical spectral response curves can be obtained through numerical simulations in the time domain and frequency domain. The intrinsic physical mechanism of the spectral response is the coherent oscillation of the surface plasmon modes: when the phases of each mode are consistent, the surface plasmon waves are coherent and constructive, and a scattering peak appears; When the bright mode interacts, due to its opposite phase, the surface plasmon waves are coherent and destructive, and scattering valleys appear. The surface plasmon bright mode is often a dipole mode (dipolemodes), due to the large radiation attenuation rate, the scattering spectrum line is relatively broad; on the contrary, the dark mode cannot directly couple with the incident light, the radiation attenuation rate is very small, and the scattering spectrum The lines are narrower. It is this narrow dark mode that makes the Fano resonance have a resonance linewidth of only tens of nanometers, so the resonance is very sensitive to wavelength and can be applied to wavelength selective devices.

经过有限元数值求解体系中四聚体电磁学特性,得到典型几何参数对系统透射光谱的影响规律。金属孔四聚体单元构型的金属孔直径增大能够使得法诺共振峰红移,同时增加法诺共振数目;金属薄膜层厚度和孔间距增加可以使得共振波长蓝移。几何参量对波长的调控,使得法诺低谷红移或者蓝移,该特征反映了金属孔四聚体良好的共振波长选择能力。Through the finite element numerical solution of the tetramer electromagnetic properties in the system, the influence of typical geometric parameters on the transmission spectrum of the system is obtained. The increase of the metal pore diameter of the metal pore tetramer unit configuration can red-shift the Fano resonance peak and increase the number of Fano resonances; the increase of the thickness of the metal film layer and the hole spacing can make the resonance wavelength blue-shift. The adjustment of the wavelength by the geometric parameters makes the Fano trough red-shift or blue-shift, which reflects the good resonant wavelength selection ability of the metal hole tetramer.

本发明中作为核心的金属孔四聚体单元构型既可以是独立的四孔单元,也可以在此单元基础上演化成四方排列和六方排列的阵列拓扑结构。拓扑结构大小可以根据器件需要尺寸而定,对于四方排列而言,有两个垂直方向的周期a和b;对于六方排列而言,平移矢量之间存在非90度夹角。The metal pore tetramer unit configuration as the core in the present invention can be an independent four-pore unit, or can evolve into a tetragonal or hexagonal array topology based on the unit. The size of the topological structure can be determined according to the required size of the device. For the tetragonal arrangement, there are two periods a and b in the vertical direction; for the hexagonal arrangement, there is a non-90-degree angle between the translation vectors.

本发明另一目的是提供一种由至少两个基于表面等离激元法诺共振的微纳光开关串联而成的级联光开关。Another object of the present invention is to provide a cascaded optical switch formed by connecting at least two micro-nano optical switches based on surface plasmon Fano resonance in series.

即本发明提供的上述微纳光开关不仅可以单独工作,也可以串联起来,形成级联光开关,实现一系列波长的选择过滤。例如三个微纳光开关的工作波长对应于λ3,λ2和λ1,当它们同时入射到第一微纳光开关中,其中λ3落在第一微纳光开关的工作波长,即透射谷中无法通过,此时只有λ1,λ2透过;同理只有λ1通过第二微纳光开关,以此类推。That is, the micro-nano optical switch provided by the present invention can not only work alone, but also can be connected in series to form a cascaded optical switch to realize selective filtering of a series of wavelengths. For example, the operating wavelengths of the three micro-nano optical switches correspond to λ3, λ2 and λ1. When they are incident on the first micro-nano optical switch at the same time, λ3 falls on the operating wavelength of the first micro-nano optical switch, that is, the transmission valley cannot pass through , at this time, only λ1 and λ2 pass through; similarly, only λ1 passes through the second micro-nano optical switch, and so on.

本发明的优点是:The advantages of the present invention are:

1.本发明提供的这种基于表面等离激元法诺共振的微纳光开关,其器件工作原理完全不同于传统液晶光开关,利用了液晶的双折射特性,不仅具有液晶光开关的所有优势,同时兼具传统液晶光开关不具备的波长选择功能。1. The micro-nano optical switch based on the surface plasmon Fano resonance provided by the present invention is completely different from the traditional liquid crystal optical switch in its working principle. Advantages, and at the same time, it has the wavelength selection function that traditional liquid crystal optical switches do not have.

2.本发明涉及的金属孔四聚体单元构型,是首次提出的模拟分子构型的独特结构,无论是在结构上,还是在表面等离激元模式的激发和相干作用上都明显区别于最近国际上提出的同类金属颗粒结构。研究表明,本发明中的金属孔四聚体单元构型支持高次表面等离激元模式,例如四极子、六极子和八极子等,而相应的金属颗粒结构只支持偶极子模式;与金属颗粒相比,本发明中的金属孔四聚体单元构型制备更加简单,几何参数对谱线的调控更加敏感,法诺共振谱线更加狭窄。2. The metal hole tetramer unit configuration involved in the present invention is a unique structure for simulating molecular configuration proposed for the first time, which is obviously different in structure and in the excitation and coherence of surface plasmon modes The same kind of metal particle structure proposed in the world recently. Studies have shown that the metal hole tetramer unit configuration in the present invention supports high-order surface plasmon modes, such as quadrupoles, hexapoles, and octopoles, while the corresponding metal particle structure only supports dipoles Mode; compared with metal particles, the preparation of the metal hole tetramer unit configuration in the present invention is simpler, the geometric parameters are more sensitive to the regulation of spectral lines, and the Fano resonance spectral lines are narrower.

例如本发明一种具体实例中金属孔四聚体单元构型的孔径Φ(直径)为100nm,孔间距s(孔等距间隙)为6nm,金属材料选Au,金属薄膜层厚度为30nm。当满足上述条件时,对于平行长轴和短轴的极化方向而言,在700nm左右波段,明暗光响应相差远大于5倍,具有极佳的对比度。For example, in a specific example of the present invention, the pore diameter Φ (diameter) of the metal hole tetramer unit configuration is 100 nm, the hole spacing s (hole equidistant gap) is 6 nm, the metal material is Au, and the thickness of the metal film layer is 30 nm. When the above conditions are met, for the polarization directions parallel to the major axis and the minor axis, the light response difference between light and dark is much greater than 5 times in the band around 700nm, which has excellent contrast.

3.本发明涉及的金属孔四聚体单元构型及其衍生结构能够与光相互作用,激发表面等离激元;表面等离激元的暗模式(dark mode)和亮模式(bright mode)相干震荡形成法诺共振,该共振表现为强烈的极化敏感性和极其狭窄的散射峰谷,因此可以用来有效地调控模式的通断、同时精确地识别入射波段。3. The metal hole tetramer unit configuration and its derivative structure involved in the present invention can interact with light to excite surface plasmons; dark mode and bright mode of surface plasmons Coherent oscillations form the Fano resonance, which exhibits strong polarization sensitivity and extremely narrow scattering peaks and valleys, so it can be used to effectively control the on-off of the mode and accurately identify the incident band.

附图说明Description of drawings

下面结合附图及实施例对本发明作进一步描述:The present invention will be further described below in conjunction with accompanying drawing and embodiment:

图1是本发明基于表面等离激元法诺共振的微纳光开关器件结构之一;Fig. 1 is one of the micro-nano optical switch device structures based on the surface plasmon Fano resonance of the present invention;

图2是本发明基于表面等离激元法诺共振的微纳光开关器件结构之二;Fig. 2 is the second structure of the micro-nano optical switch device based on the surface plasmon Fano resonance of the present invention;

图3是独立的具有“D2h四聚物分子构型”的金属孔四聚体单元构型的示意图;Figure 3 is a schematic diagram of the configuration of an independent metal hole tetramer unit with "D 2h tetramer molecular configuration";

图4是金属孔四聚体单元构型在电压通断情况下的典型背散射光谱(或称透射光谱);Fig. 4 is a typical backscattering spectrum (or transmission spectrum) of the metal hole tetramer unit configuration under the voltage on-off situation;

图5是由金属孔四聚体单元构型衍生的呈四方排列的周期阵列拓扑结构;Figure 5 is a tetragonal periodic array topology derived from the metal hole tetramer unit configuration;

图6是由金属孔四聚体单元构型衍生的呈六方排列的周期阵列拓扑结构;Figure 6 is a hexagonal periodic array topology derived from the metal hole tetramer unit configuration;

图7是基于图1器件结构的工作原理图;Fig. 7 is a working principle diagram based on the device structure in Fig. 1;

图8是基于图2器件结构的工作原理图;Fig. 8 is a working principle diagram based on the device structure in Fig. 2;

图9是金属孔四聚体单元构型的三个几何参数对透射光谱的影响规律并列示意图;Figure 9 is a side-by-side schematic diagram of the influence of three geometric parameters of the metal hole tetramer unit configuration on the transmission spectrum;

图10是根据本发明金属孔四聚体单元构型的波长可调性提出的级联光开关示意图。Fig. 10 is a schematic diagram of a cascaded optical switch proposed according to the wavelength tunability of the metal hole tetramer unit configuration of the present invention.

其中:1、透明衬底;2、金属薄膜层;3、聚酰亚胺薄膜层;4、向列相液晶层;5、玻璃盖片层;6、电极线;7、起偏器;8、交叉指型电极;9、沟槽;10、ITO导电膜层;11、检偏器。Among them: 1. Transparent substrate; 2. Metal film layer; 3. Polyimide film layer; 4. Nematic liquid crystal layer; 5. Cover glass layer; 6. Electrode line; 7. Polarizer; 8 , Interdigitated electrodes; 9, grooves; 10, ITO conductive film layer; 11, analyzer.

具体实施方式detailed description

实施例1:如图1所示为本发明提供的一种基于表面等离激元法诺共振的微纳光开关具体实施例,其采用玻璃透明衬底,所述玻璃透明衬底1上依次叠置有金属薄膜层2、向列相液晶取向转换层和起偏器7,本发明中的向列相液晶取向转换层由依次叠置于金属薄膜层2上的聚酰亚胺薄膜层3、向列相液晶层4和玻璃盖片层5构成。聚酰亚胺薄膜层3的上表面设有平行间隔分布的若干沟槽9,而玻璃盖片层5的下表面则设有交叉指型电极8并引出电极线6,所述交叉指型电极8的叉指方向与下方沟槽9平行。本发明中在所述透明衬底的下方设有检偏器11。本实施例中的所述起偏器7和检偏器11均为偏振片。Embodiment 1: As shown in FIG. 1, it is a specific embodiment of a micro-nano optical switch based on surface plasmon Fano resonance provided by the present invention, which uses a glass transparent substrate, and the glass transparent substrate 1 is sequentially A metal thin film layer 2, a nematic liquid crystal orientation switching layer and a polarizer 7 are stacked, and the nematic liquid crystal orientation switching layer in the present invention consists of a polyimide film layer 3 stacked on the metal thin film layer 2 successively. , a nematic liquid crystal layer 4 and a cover glass layer 5. The upper surface of the polyimide film layer 3 is provided with several grooves 9 distributed in parallel at intervals, and the lower surface of the cover glass layer 5 is provided with interdigitated electrodes 8 and lead electrode lines 6, the interdigitated electrodes The interdigitation direction of 8 is parallel to the groove 9 below. In the present invention, an analyzer 11 is provided below the transparent substrate. Both the polarizer 7 and the analyzer 11 in this embodiment are polarizers.

结合图3所示,本发明中的金属薄膜层2,其上蚀刻有单独的金属孔四聚体单元构型,该单元构型中的四孔呈D2h群对称,具有正交的短轴和长轴。本实施例中金属孔的孔径Φ(直径)为100nm,孔间距s(等距间隙)为6nm,金属材料选用Au,金属薄膜层的厚度为30nm。As shown in Figure 3, the metal thin film layer 2 in the present invention is etched with a separate metal hole tetramer unit configuration, the four holes in the unit configuration are D 2h group symmetry, with orthogonal minor axes and long axis. In this embodiment, the aperture Φ (diameter) of the metal holes is 100 nm, the hole spacing s (equal distance gap) is 6 nm, the metal material is Au, and the thickness of the metal thin film layer is 30 nm.

结合图4所示,当光波之电场极化方向与金属孔四聚体单元构型的短轴平行时,透射光谱只有一个散射峰;当光波之电场极化方向与金属孔四聚体单元构型的长轴平行时,透射峰出现一个狭窄的低谷,对应于表面等离激元暗模式。通过电压通断可以控制向列相液晶取向,进而调控经起偏器入射的光波极化方向,最终实现对光透射强度和波长有效控制。As shown in Figure 4, when the electric field polarization direction of the light wave is parallel to the short axis of the metal hole tetramer unit configuration, the transmission spectrum has only one scattering peak; when the electric field polarization direction of the light wave is parallel to the metal hole tetramer unit configuration When the long axes of the two types are parallel, there is a narrow trough in the transmission peak, corresponding to the surface plasmon dark mode. The orientation of the nematic liquid crystal can be controlled by switching the voltage on and off, and then the polarization direction of the light wave incident through the polarizer can be adjusted, and finally the effective control of the light transmission intensity and wavelength can be realized.

本发明体系中涉及的光与微纳结构(金属孔四聚体单元构型)的相互作用可以通过求解麦克斯韦方程精确描述,求解方法包括有限时域、有限元和边界元等数值方法。通过时域和频域的数值仿真,可以获得典型的光谱响应曲线。光谱响应的内在物理机制是表面等离激元模式的相干震荡:当各模式的相位一致时,表面等离激元波相干相长,出现散射峰;当暗模式(dark mode)出现,并与明模式(bright mode)交互作用时,由于其相位相反,表面等离激元波相干相消,出现散射谷。表面等离激元明模式往往属于偶极子模式(dipolemodes),由于辐射衰减速率大,散射谱线比较宽广;相反地,暗模式由于不能直接与入射光耦合,辐射衰减速率很小,散射谱线比较狭窄。正是这种狭窄的暗模式使得法诺共振的共振线宽只有几十纳米,因此该共振对波长非常敏感,可以应用于波长选择器件。具体由图4分析可得出:对于平行长轴和短轴的极化方向而言,在700nm左右波段,明暗光响应相差远大于5倍,具有极佳的对比度。The interaction between light and the micro-nano structure (metal hole tetramer unit configuration) involved in the system of the present invention can be accurately described by solving Maxwell's equations, and the solving methods include numerical methods such as finite time domain, finite element and boundary element. Typical spectral response curves can be obtained through numerical simulations in the time domain and frequency domain. The intrinsic physical mechanism of the spectral response is the coherent oscillation of the surface plasmon modes: when the phases of each mode are consistent, the surface plasmon waves are coherent and constructive, and a scattering peak appears; When the bright mode interacts, due to its opposite phase, the surface plasmon waves are coherent and destructive, and scattering valleys appear. The surface plasmon bright mode is often a dipole mode (dipolemodes), due to the large radiation attenuation rate, the scattering spectrum line is relatively broad; on the contrary, the dark mode cannot directly couple with the incident light, the radiation attenuation rate is very small, and the scattering spectrum The lines are narrower. It is this narrow dark mode that makes the Fano resonance have a resonance linewidth of only tens of nanometers, so the resonance is very sensitive to wavelength and can be applied to wavelength selective devices. Specifically, it can be concluded from the analysis of Figure 4 that: for the polarization directions parallel to the major axis and the minor axis, the light response difference between light and dark is much greater than 5 times in the band around 700nm, which has excellent contrast.

本实施例的上述微纳光开关的具体制备方法如下:The specific preparation method of the above-mentioned micro-nano optical switch in this embodiment is as follows:

1)在玻璃透明衬底1上,制备Au薄膜,厚度30nm。1) On a glass transparent substrate 1 , prepare an Au thin film with a thickness of 30 nm.

2)在金属薄膜层2上利用电子束等蚀刻技术制备金属孔四聚体单元构型,其孔径Φ为100nm,孔间距s为6nm。2) On the metal thin film layer 2, the metal pore tetramer unit configuration is prepared by using electron beam etc. etching technology, the pore diameter Φ is 100nm, and the pore spacing s is 6nm.

3)利用旋涂仪旋涂聚酰亚胺薄膜层3,在200摄氏度恒温1小时,然后自然冷却完成退火热处理;沿着同一方向机械打磨聚酰亚胺薄膜层3,形成同向平行并列的微型沟槽9。3) Use a spin coater to spin-coat the polyimide film layer 3, keep the temperature at 200 degrees Celsius for 1 hour, and then cool naturally to complete the annealing heat treatment; mechanically polish the polyimide film layer 3 along the same direction to form parallel parallel micro-grooves in the same direction Slot 9.

4)在玻璃盖片层5上利用光刻法制备Au交叉指型电极,指型条宽度为50纳米,高度为70纳米,指型条之间的间距为8微米,利用焊锡链接并引出电极线6。4) Prepare Au interdigitated electrodes on the cover glass layer 5 by photolithography. The width of the fingers is 50 nanometers, the height is 70 nanometers, the distance between the fingers is 8 microns, and the electrodes are connected and drawn out by solder Line 6.

5)在玻璃盖片层5上设置交叉指型电极的一面旋涂一层尺寸在5微米的玻璃球,作为垫衬材料(图中未示意)。5) A layer of glass spheres with a size of 5 microns is spin-coated on the side of the cover glass layer 5 where the interdigitated electrodes are arranged, as a gasket material (not shown in the figure).

6)在光学显微镜下,将步骤5)制备的玻璃盖片层5放置到步骤3)制备的聚酰亚胺薄膜层3上,确保交叉指型电极8的叉指方向与聚酰亚胺薄膜层3上的打磨方向一致(即相互平行)。6) Under an optical microscope, the cover glass layer 5 prepared in step 5) is placed on the polyimide film layer 3 prepared in step 3), ensuring that the interdigitated electrode 8 is aligned with the direction of the polyimide film The sanding directions on layer 3 were consistent (ie, parallel to each other).

7)在玻璃球的间隙中填充向列相液晶正戊基联苯氰,使得液晶通过毛细力进入间隙中,同时加热液晶直到液晶成为均匀相,即形成向列相液晶层4,然后自然冷却至室温。7) Fill the gap between the glass balls with nematic liquid crystal n-pentyl biphenylcyanide, so that the liquid crystal enters the gap through capillary force, and heat the liquid crystal until the liquid crystal becomes a uniform phase, that is, the nematic liquid crystal layer 4 is formed, and then naturally cooled to room temperature.

8)在器件顶部贴上起偏器7(底部贴上检偏器11用于检测),利用环氧树脂胶布封装该装置。8) A polarizer 7 is pasted on the top of the device (a polarizer 11 is pasted on the bottom for detection), and the device is packaged with epoxy resin tape.

结合图3和图7所示,本实施例上述微纳光开关的具体作用原理简述如下:With reference to Fig. 3 and Fig. 7, the specific working principle of the above-mentioned micro-nano optical switch in this embodiment is briefly described as follows:

本实施例中起偏器7的初始电场极化方向如图1(偏振方向为P方向,其上的水平箭头代表水平方向)和图7所示,垂直于纸面且平行于金属孔四聚体单元构型之短轴。入射光为700nm自然光。The initial electric field polarization direction of the polarizer 7 in this embodiment is shown in Figure 1 (the polarization direction is the P direction, and the horizontal arrow on it represents the horizontal direction) and Figure 7, perpendicular to the paper and parallel to the metal hole tetramerization The minor axis of the body element configuration. The incident light is 700nm natural light.

1)电压断开的情况(即交叉指型电极8不通电)。由于液晶所接触的下表面沟槽和上表面交叉指型电极的取向一致,液晶取向在范德瓦尔斯力的作用下,呈一致向列相状态;因此被起偏器7过滤下来的极化光能够直接穿过液晶,并保持原有极化方向;结合图4及金属孔四聚体单元构型原理的描述可知,当该垂直于纸面的电场极化方向平行于金属孔四聚体单元构型之短轴时,不能发生法诺共振,表现为没有法诺透射谷且有透射峰,因此光路处于导通,检偏器11(偏振方向为A方向)得到高亮光信号。1) The case where the voltage is disconnected (that is, the interdigitated electrodes 8 are not energized). Since the orientation of the groove on the lower surface contacted by the liquid crystal is consistent with that of the interdigitated electrode on the upper surface, the orientation of the liquid crystal is in a consistent nematic state under the action of Van der Waals force; therefore, the polarization filtered by the polarizer 7 Light can directly pass through the liquid crystal and maintain the original polarization direction; combined with the description of Figure 4 and the configuration principle of the metal hole tetramer unit, it can be seen that when the electric field polarization direction perpendicular to the paper is parallel to the metal hole tetramer For the short axis of the unit configuration, Fano resonance cannot occur, and there are no Fano transmission valleys and transmission peaks, so the optical path is turned on, and the analyzer 11 (the polarization direction is the A direction) obtains a high-brightness light signal.

2)电压闭合(即交叉指型电极8通电)。3V电压加载在交叉指型电极上,指间形成垂直于叉指方向的电场,在电场力的作用下附近的液晶扭转为电场平行方向;同样由于范德瓦尔斯力的作用,液晶从下到上,逐渐由垂直取向朝着平行取向过渡,即扭曲向列相;在扭曲向列相的波导作用下,入射光经过液晶之后的极化方向发生反转,原来平行于金属孔四聚体单元构型之短轴的极化方向反转为平行于长轴,因此激发法诺共振,出现对应于暗模式的法诺透射谷,光路关闭。由上可知,电压通断导致液晶取向反转,继而导致法诺共振从无到有,最终实现光路开通与关闭。2) Voltage closure (ie interdigitated electrodes 8 energized). 3V voltage is loaded on the interdigitated electrodes, and an electric field perpendicular to the interdigitated direction is formed between the fingers. Under the action of the electric field force, the nearby liquid crystals are twisted to be parallel to the electric field; On the surface, it gradually transitions from vertical orientation to parallel orientation, that is, the twisted nematic phase; under the action of the waveguide of the twisted nematic phase, the polarization direction of the incident light after passing through the liquid crystal is reversed, and the original parallel to the metal hole tetramer unit The polarization direction of the short axis of the configuration is reversed to be parallel to the long axis, so the Fano resonance is excited, the Fano transmission valley corresponding to the dark mode appears, and the optical path is closed. It can be seen from the above that the switching of the voltage leads to the inversion of the liquid crystal orientation, which in turn leads to the Fano resonance from scratch, and finally realizes the opening and closing of the optical path.

上述原理简述中,由于电压断开时,光开关呈开通状态,因此称常白模式。而实际上通过改变起偏器取向、液晶初始取向和金属孔四聚体单元构型长短轴的取向等任一种取向,就能够使得光开关由常白模式进入常黑模式,即电压断开时光路呈关闭状态。In the brief description of the above principles, since the optical switch is in an on state when the voltage is disconnected, it is called a normally white mode. In fact, by changing the orientation of the polarizer, the initial orientation of the liquid crystal, and the orientation of the major and minor axes of the metal hole tetramer unit configuration, the optical switch can be turned from the normally white mode to the normally black mode, that is, the voltage is turned off. Timeway is closed.

实施例2:如图2所示为本发明提供的一种基于表面等离激元法诺共振的微纳光开关具体实施例,其采用玻璃透明衬底,所述玻璃透明衬底1上依次叠置有金属薄膜层2、向列相液晶取向转换层和起偏器7,本发明中的向列相液晶取向转换层由依次叠置于金属薄膜层2上的聚酰亚胺薄膜层3、向列相液晶层4和ITO导电膜层10构成。其中聚酰亚胺薄膜层3的上表面设有平行间隔分布的若干沟槽9,而ITO导电膜层10的下表面也设有平行间隔分布的若干沟槽9,这些沟槽9与聚酰亚胺薄膜层3上的沟槽9垂直;本实施例中在向列相液晶层4的上下端设置有电极线,用于施加垂直向电场。Embodiment 2: As shown in FIG. 2, it is a specific embodiment of a micro-nano optical switch based on surface plasmon Fano resonance provided by the present invention, which uses a glass transparent substrate, and the glass transparent substrate 1 is sequentially A metal thin film layer 2, a nematic liquid crystal orientation switching layer and a polarizer 7 are stacked, and the nematic liquid crystal orientation switching layer in the present invention consists of a polyimide film layer 3 stacked on the metal thin film layer 2 successively. , a nematic liquid crystal layer 4 and an ITO conductive film layer 10. Wherein the upper surface of polyimide thin film layer 3 is provided with some grooves 9 that are distributed in parallel at intervals, and the lower surface of ITO conductive film layer 10 is also provided with some grooves 9 that are distributed in parallel at intervals, these grooves 9 and polyimide The grooves 9 on the imide film layer 3 are vertical; in this embodiment, electrode lines are arranged on the upper and lower ends of the nematic liquid crystal layer 4 for applying a vertical electric field.

结合图5、图6所示,本发明中的金属薄膜层2,其上蚀刻由如图3所示的单独的金属孔四聚体单元构型经四方排列(图5),或者六方排列(图6)而成的阵列拓扑构型。单独的单元构型中的四孔呈D2h群对称,具有正交的短轴和长轴,金属孔的孔径Φ(直径)为90nm,孔间距s(等距间隙)为3nm,金属材料选用Au,金属薄膜层的厚度为50nm。阵列拓扑结构的大小可以根据整个微纳光开关的器件实际需要尺寸而定,对于四方排列而言,有两个垂直方向的周期a=500nm和b=500nm;对于六方排列而言,平移矢量之间存在非90度夹角,具体见图5和图6所示。Shown in conjunction with Fig. 5, Fig. 6, metal thin film layer 2 among the present invention, etch on it by the independent metal hole tetramer unit configuration as shown in Fig. 3 through tetragonal arrangement (Fig. 5), or hexagonal arrangement ( Figure 6) formed the array topology configuration. The four holes in the single unit configuration are D 2h group symmetric, with orthogonal short axis and long axis, the aperture Φ (diameter) of the metal hole is 90nm, the hole spacing s (equidistant gap) is 3nm, and the metal material is selected Au, the thickness of the metal thin film layer is 50nm. The size of the array topology can be determined according to the actual required size of the entire micro-nano optical switch device. For the tetragonal arrangement, there are two periods a=500nm and b=500nm in the vertical direction; for the hexagonal arrangement, the period between the translation vectors There is a non-90-degree angle between them, as shown in Figure 5 and Figure 6 for details.

本实施例的上述微纳光开关的具体制备方法如下:The specific preparation method of the above-mentioned micro-nano optical switch in this embodiment is as follows:

1)在玻璃透明衬底1上,制备Au薄膜,厚度30nm。1) On a glass transparent substrate 1 , prepare an Au thin film with a thickness of 30 nm.

2)在金属薄膜层2上利用电子束等蚀刻技术制备金属孔四聚体单元构型,其孔径Φ为100nm,孔间距s为6nm。2) On the metal thin film layer 2, the metal pore tetramer unit configuration is prepared by using electron beam etc. etching technology, the pore diameter Φ is 100nm, and the pore spacing s is 6nm.

3)利用旋涂仪旋涂聚酰亚胺薄膜层3,在200摄氏度恒温1小时,然后自然冷却完成退火热处理;沿着同一方向机械打磨聚酰亚胺薄膜层3,形成同向平行并列的微型沟槽9。3) Use a spin coater to spin-coat the polyimide film layer 3, keep the temperature at 200 degrees Celsius for 1 hour, and then cool naturally to complete the annealing heat treatment; mechanically polish the polyimide film layer 3 along the same direction to form parallel parallel micro-grooves in the same direction Slot 9.

4)在ITO导电膜层10上,利用机械法打磨处理使得出现平行并列且均匀一致的沟槽;再在沟槽的一面上旋涂一层尺寸在10微米的玻璃球,作为垫衬材料(图中未示意)。4) On the ITO conductive film layer 10, use mechanical method to polish and process so that there are parallel and uniform grooves; then spin-coat a layer of glass balls with a size of 10 microns on one side of the grooves as a pad material ( not shown in the figure).

5)在光学显微镜下,将步骤4)制备得到的ITO导电膜层10放置到步骤3)制备的聚酰亚胺薄膜层3上,确保ITO导电薄膜上的沟槽9方向与聚酰亚胺薄膜层3上的打磨方向垂直。5) under an optical microscope, the ITO conductive film layer 10 prepared in step 4) is placed on the polyimide film layer 3 prepared in step 3), ensuring that the direction of the groove 9 on the ITO conductive film is consistent with that of the polyimide film. The grinding direction on the film layer 3 is vertical.

6)在玻璃球的间隙中填充向列相液晶正戊基联苯氰,使得液晶通过毛细力进入间隙中,同时加热液晶直到液晶成为均匀相,即形成向列相液晶层4,然后自然冷却至室温。6) Fill the gap between the glass balls with nematic liquid crystal n-pentyl biphenylcyanide, so that the liquid crystal enters the gap through capillary force, and heat the liquid crystal at the same time until the liquid crystal becomes a uniform phase, that is, the nematic liquid crystal layer 4 is formed, and then naturally cooled to room temperature.

7)在器件顶部贴上偏振7(底部贴上检偏器11用于检测),利用环氧树脂胶布封装该装置。7) A polarizer 7 is pasted on the top of the device (a polarizer 11 is pasted on the bottom for detection), and the device is packaged with epoxy tape.

结合图3和图8所示,本实施例上述微纳光开关的具体作用原理简述如下:With reference to Figure 3 and Figure 8, the specific working principle of the above-mentioned micro-nano optical switch in this embodiment is briefly described as follows:

基于图2所示之实施例原理与图1所示之实施例1大致相同,为更加清晰起见,针对实施例器件的常黑模式进行具体简述。实施例2与实施例1相比,缺少交叉指型电极8,电压不是加在交叉指型电极之上,而是加载在向列相液晶的上下表面。因此该装置的液晶初始相一般为扭曲向列相,其主要通过使得液晶上下表面相互垂直的沟槽或者使用相反取向剂来实现。Based on the fact that the principle of the embodiment shown in FIG. 2 is substantially the same as that of Embodiment 1 shown in FIG. 1 , for the sake of clarity, the normally black mode of the device of the embodiment is briefly described. Compared with embodiment 1, embodiment 2 lacks the interdigitated electrodes 8, and the voltage is not applied on the interdigitated electrodes, but on the upper and lower surfaces of the nematic liquid crystal. Therefore, the initial phase of the liquid crystal of the device is generally a twisted nematic phase, which is mainly realized by making the upper and lower surfaces of the liquid crystal perpendicular to each other or using an opposite alignment agent.

本实施例中起偏器7的初始电场极化方向如图2(偏振方向为P方向,其上的水平箭头代表水平方向)和图8所示,与实施例1的情况一样,也是垂直于纸面且平行于金属孔四聚体单元构型之短轴。入射光为700nm自然光。The initial electric field polarization direction of polarizer 7 in the present embodiment is as shown in Fig. 2 (polarization direction is P direction, and the horizontal arrow on it represents horizontal direction) and Fig. 8, is the same as the situation of embodiment 1, also is perpendicular to On paper and parallel to the minor axis of the metal pore tetramer unit configuration. The incident light is 700nm natural light.

1)电压断开时(液晶上下不加电),自然光经过起偏器7过滤,只有垂直纸面的极化光进入液晶,经过扭曲向列相的引导,极化方向反转为平行四聚体的长轴方向,根据金属孔四聚体单元构型的特性,激发法诺共振,光路关闭;1) When the voltage is disconnected (the liquid crystal is not powered up and down), the natural light is filtered by the polarizer 7, and only the polarized light perpendicular to the paper surface enters the liquid crystal, guided by the twisted nematic phase, and the polarization direction is reversed to parallel tetramerization The long axis direction of the body, according to the characteristics of the tetramer unit configuration of the metal hole, excites the Fano resonance and closes the optical path;

2)电压加载时(液晶上下加电),液晶取向平行于电场方向,扭曲相转变为一致相,垂直于纸面的极化方向经过液晶之后保持不变,此时平行于金属孔四聚体单元构型的短轴方向,根据金属孔四聚体单元构型的特性,光路开通。此装置中,改变起偏器7取向或者90度旋转金属孔四聚体的轴向,即可把常黑模式调节为常白模式。2) When the voltage is applied (the liquid crystal is powered up and down), the orientation of the liquid crystal is parallel to the direction of the electric field, and the twisted phase transforms into a consistent phase. The polarization direction perpendicular to the paper remains unchanged after passing through the liquid crystal, and at this time it is parallel to the metal hole tetramer According to the characteristics of the metal hole tetramer unit configuration, the light path is opened in the minor axis direction of the unit configuration. In this device, the normally black mode can be adjusted to the normally white mode by changing the orientation of the polarizer 7 or rotating the axial direction of the metal hole tetramer by 90 degrees.

经过有限元数值求解体系中四聚体电磁学特性,得到典型几何参数对系统透射光谱的影响规律。如图9所示,金属孔直径增大能够使得法诺共振峰红移,同时增加法诺共振数目;金属薄膜厚度和孔间距增加可以使得共振波长蓝移。几何参量对波长的调控,使得法诺低谷红移或者蓝移,该特征反映了金属孔四聚体良好的共振波长选择能力。根据这一原理,可以针对不同的波长设计相应的金属孔四聚体单元构型,然后构成一系列微纳光开关。这些微纳光开关不仅可以单独工作,也可以串联起来,形成级联光开关,实现一系列波长的选择过滤。其结构和原理如图10所示。例如三个光开关1、2、3的工作波长对应于λ3,λ2和λ1,当它们同时入射到光开关1中,其中λ3落在开关1的工作波长,即透射谷中无法通过,此时只有λ1,λ2透过;同理只有λ1通过光开关2,以此类推。Through the finite element numerical solution of the tetramer electromagnetic properties in the system, the influence of typical geometric parameters on the transmission spectrum of the system is obtained. As shown in Figure 9, increasing the diameter of the metal hole can red-shift the Fano resonance peak and increase the number of Fano resonances; increasing the thickness of the metal film and the hole spacing can make the resonance wavelength blue-shift. The adjustment of the wavelength by the geometric parameters makes the Fano trough red-shift or blue-shift, which reflects the good resonant wavelength selection ability of the metal hole tetramer. According to this principle, the corresponding metal hole tetramer unit configuration can be designed for different wavelengths, and then a series of micro-nano optical switches can be formed. These micro-nano optical switches can not only work alone, but also can be connected in series to form a cascaded optical switch to achieve selective filtering of a series of wavelengths. Its structure and principle are shown in Figure 10. For example, the operating wavelengths of the three optical switches 1, 2, and 3 correspond to λ3, λ2, and λ1. When they are incident on the optical switch 1 at the same time, λ3 falls on the operating wavelength of the switch 1, that is, it cannot pass through the transmission valley. At this time, only λ1 and λ2 pass through; similarly, only λ1 passes through the optical switch 2, and so on.

上述实例只为说明本发明的技术构思及特点,其目的在于让熟悉此项技术的人是能够了解本发明的内容并据以实施,并不能以此限制本发明的保护范围。凡根据本发明精神实质所做的等效变换或修饰,都应涵盖在本发明的保护范围之内。The above examples are only to illustrate the technical conception and characteristics of the present invention, and its purpose is to allow people familiar with this technology to understand the content of the present invention and implement it accordingly, and cannot limit the protection scope of the present invention. All equivalent changes or modifications made according to the spirit of the present invention shall fall within the protection scope of the present invention.

Claims (10)

1.一种基于表面等离激元法诺共振的微纳光开关,包括透明衬底,其特征在于所述透明衬底(1)上依次叠置有金属薄膜层(2)、向列相液晶取向转换层和起偏器(7),其中:1. A micro-nano optical switch based on surface plasmon Fano resonance, comprising a transparent substrate, characterized in that the transparent substrate (1) is successively stacked with a metal thin film layer (2), a nematic phase Liquid crystal alignment conversion layer and polarizer (7), wherein: 起偏器(7),给予透过光以初始的极化方向;A polarizer (7), which gives the transmitted light an initial polarization direction; 向列相液晶取向转换层,用于接纳上述具有初始极化方向的透过光,并控制经由其透射出去的光的极化方向;The nematic liquid crystal alignment conversion layer is used to receive the above-mentioned transmitted light with the initial polarization direction, and control the polarization direction of the light transmitted through it; 金属薄膜层(2),其上蚀刻有单独的金属孔四聚体单元构型或由该单元经四方排列或六方排列而成的阵列拓扑构型,所述金属孔四聚体单元构型中的四孔呈D2h群对称,具有正交的短轴和长轴;当通过向列相液晶取向转换层透射下来的光的极化方向与短轴平行时,打开光路;当通过向列相液晶取向转换层透射下来的光的极化方向相对于初始极化方向发生转变,且与长轴平行时,则激发表面等离激元法诺共振,关闭光路。The metal thin film layer (2) is etched with a single metal hole tetramer unit configuration or an array topological configuration formed by the unit through a tetragonal arrangement or a hexagonal arrangement, and the metal hole tetramer unit configuration is The four holes are D 2h group symmetric, with orthogonal short axis and long axis; when the polarization direction of the light transmitted through the nematic liquid crystal alignment conversion layer is parallel to the short axis, the light path is opened; When the polarization direction of the light transmitted by the liquid crystal alignment conversion layer changes relative to the initial polarization direction and is parallel to the long axis, the surface plasmon Fano resonance is excited and the optical path is closed. 2.根据权利要求1所述的一种基于表面等离激元法诺共振的微纳光开关,其特征在于所述金属薄膜层(2)的厚度为20~100nm,金属孔四聚体单元构型中四孔的孔径Φ均为90~1000nm,孔间距s均为3~100nm。2. A micro-nano optical switch based on surface plasmon Fano resonance according to claim 1, characterized in that the thickness of the metal thin film layer (2) is 20-100 nm, and the metal hole tetramer unit The pore diameters of the four holes in the configuration are all 90-1000 nm, and the hole spacing s is all 3-100 nm. 3.根据权利要求1所述的一种基于表面等离激元法诺共振的微纳光开关,其特征在于所述向列相液晶取向转换层,包括依次叠置于金属薄膜层(2)上的下液晶取向控制透明层、向列相液晶层(4)、上液晶取向控制透明层;其中下液晶取向控制透明层的上表面设有平行间隔分布的若干沟槽(9),而上液晶取向控制透明层的下表面则设有交叉指型电极(8)并引出电极线(6),所述交叉指型电极(8)的叉指方向与下方沟槽(9)平行或垂直,对应的,当交叉指型电极(8)通电后,其产生的电场方向与下方沟槽(9)垂直或者平行。3. A kind of micro-nano optical switch based on surface plasmon Fano resonance according to claim 1, characterized in that said nematic liquid crystal orientation switching layer includes successively stacked metal thin film layers (2) The upper and lower liquid crystal orientation control transparent layer, the nematic liquid crystal layer (4), and the upper liquid crystal orientation control transparent layer; wherein the upper surface of the lower liquid crystal orientation control transparent layer is provided with a number of grooves (9) distributed in parallel intervals, and the upper The lower surface of the liquid crystal orientation control transparent layer is provided with interdigitated electrodes (8) and lead out electrode lines (6), and the interdigitated direction of the interdigitated electrodes (8) is parallel or perpendicular to the groove (9) below, Correspondingly, when the interdigitated electrodes (8) are energized, the direction of the electric field generated by them is vertical or parallel to the groove (9) below. 4.根据权利要求3所述的一种基于表面等离激元法诺共振的微纳光开关,其特征在于所述下液晶取向控制透明层为聚酰亚胺薄膜层(3)、ITO或FTO,而上液晶取向控制透明层为玻璃盖片层(5)。4. A kind of micro-nano optical switch based on surface plasmon Fano resonance according to claim 3, characterized in that the lower liquid crystal orientation control transparent layer is a polyimide film layer (3), ITO or FTO, and the upper liquid crystal orientation control transparent layer is the glass cover layer (5). 5.根据权利要求1所述的一种基于表面等离激元法诺共振的微纳光开关,其特征在于所述向列相液晶取向转换层,包括依次叠置于金属薄膜层上的下液晶取向控制透明层、向列相液晶层(4)、上液晶取向控制透明层;其中下液晶取向控制透明层的上表面设有平行间隔分布的若干沟槽(9),而上液晶取向控制透明层的下表面也设有平行间隔分布的若干沟槽(9),这些沟槽(9)与下液晶取向控制透明层上的沟槽(9)垂直;还包括分别连接至上、下液晶取向控制透明层上的电极线,用于施加给向列相液晶层(4)以垂直向电场。5. A micro-nano optical switch based on surface plasmon Fano resonance according to claim 1, characterized in that the nematic liquid crystal orientation conversion layer includes a lower layer stacked on the metal thin film layer in turn. A liquid crystal orientation control transparent layer, a nematic liquid crystal layer (4), and an upper liquid crystal orientation control transparent layer; wherein the upper surface of the lower liquid crystal orientation control transparent layer is provided with a plurality of grooves (9) distributed in parallel intervals, and the upper liquid crystal orientation control The lower surface of the transparent layer is also provided with several grooves (9) distributed in parallel at intervals, and these grooves (9) are perpendicular to the grooves (9) on the lower liquid crystal orientation control transparent layer; The electrode lines on the transparent layer are controlled to apply a vertical electric field to the nematic liquid crystal layer (4). 6.根据权利要求5所述的一种基于表面等离激元法诺共振的微纳光开关,其特征在于所述下液晶取向控制透明层为聚酰亚胺薄膜层(3)、ITO或FTO,而上液晶取向控制透明层为ITO导电膜层(10)。6. A kind of micro-nano optical switch based on surface plasmon Fano resonance according to claim 5, characterized in that the lower liquid crystal orientation control transparent layer is a polyimide film layer (3), ITO or FTO, and the upper liquid crystal orientation control transparent layer is an ITO conductive film layer (10). 7.根据权利要求3或5所述的一种基于表面等离激元法诺共振的微纳光开关,其特征在于所述上液晶取向控制透明层的下表面旋涂一层直径为1~10微米的玻璃球作为垫衬,向列相液晶填充于所述玻璃球间隙内形成所述向列相液晶层(4)。7. A micro-nano optical switch based on surface plasmon Fano resonance according to claim 3 or 5, characterized in that the lower surface of the upper liquid crystal orientation control transparent layer is spin-coated with a diameter of 1~ 10-micron glass balls are used as pads, and nematic liquid crystals are filled in the gaps of the glass balls to form the nematic liquid crystal layer (4). 8.根据权利要求1所述的一种基于表面等离激元法诺共振的微纳光开关,其特征在于所述金属薄膜层的金属材料为Au、Ag或Al。8. A micro-nano optical switch based on surface plasmon Fano resonance according to claim 1, characterized in that the metal material of the metal thin film layer is Au, Ag or Al. 9.根据权利要求1所述的一种基于表面等离激元法诺共振的微纳光开关,其特征在于所述透明衬底的下方设有检偏器(11)。9. A micro-nano optical switch based on surface plasmon Fano resonance according to claim 1, characterized in that an analyzer (11) is arranged below the transparent substrate. 10.一种由至少两个如权利要求1~9中任意一项所述微纳光开关串联而成的级联光开关。10. A cascaded optical switch formed by connecting at least two micro-nano optical switches according to any one of claims 1-9 in series.
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