CN104109973B - Fabric finishing liquor and the finishing technique thereof of the art of composition is struck in a kind of employing - Google Patents
Fabric finishing liquor and the finishing technique thereof of the art of composition is struck in a kind of employing Download PDFInfo
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- CN104109973B CN104109973B CN201410305712.4A CN201410305712A CN104109973B CN 104109973 B CN104109973 B CN 104109973B CN 201410305712 A CN201410305712 A CN 201410305712A CN 104109973 B CN104109973 B CN 104109973B
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 34
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Landscapes
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a kind of employing and strike fabric finishing liquor and the finishing technique thereof of the art of composition, including the component of following mass percent: functional finishing agent 0.001 8%；Cross-linking agent 0.05 15%；Thickening agent 0.5 2%；Water 40 50%；Methylsiloxane sticks with paste surplus.The present invention has that method is simple, easily operated, raw material availability is high, with low cost, and energy-saving and emission-reduction, the finishing effect similar to existing technique can be obtained.
Description
Technical field
The present invention relates to a kind of employing and strike fabric finishing liquor and the finishing technique thereof of the art of composition, belong to and knit
Thing printing technology, particularly relates to the function finishing technique of weaving face fabric.
Background technology
Along with the sustainable development of China's economic and improving constantly of human civilization degree, healthy,
Comfortable high-quality life has increasingly becomed pursuit and the yearning of modern, traditional textile
Hide body, insulation, the effect such as attractive in appearance are difficult to the most far away meet people to textile wearability more
High request, increases the added value of textile, and development functionality textile is increasingly by people's
Common concern.The finishing functions field of textile is wide, including antibacterial and deodouring, acaricide, disease-resistant
Poison, anti-ultraviolet, anti-electromagnetic radiation, skin-protection and health-care and spice finish etc..
It is described as the textile of mankind's " Second Skin " to become modern's life already and depend on the most
One of product relied, summary is got up, and the finishing functions of fabric is mainly had following several means,
Various functional materials simply and are directly applied to fabric table by the easiest method exactly
Face, as a example by spice finish, makes fabric have armaticity by methods such as directly sprinkling, incenses,
Although this method is simple, but volatile oil is the material that a kind of volatility is stronger, and the short time is i.e.
Totally, not only aroma-keeping time is short, and does not more tolerate washing, other functional materials in volatilization
There is Similar Problems too.The second means are that the preparation from functional fiber is set about, and use
The methods such as blended, composite spinning prepare function fabric, to give fabric specific function, this type of
The loss of methodological function material is more serious, and production cost is high.Strengthen the merit of functional materials
Can be ageing, extending its residence time on the textile is an important direction,
Conventional method mainly has microcapsule method, cyclodextrin method and porous material absorption method, its principle
Be to be coated with the functional materials special material of inefficacy volatile, easy, and use absorption,
The forms such as crosslinking, adhesion put on fabric, have both obtained preferable washability, the most functional thing
Matter can slowly discharge again, the permanence being provided with in timeliness.At present, traditional finishing technique has
Pad, impregnate, coating etc., though can reach the effect of permanent lasting, but energy consumption during arranging
Relatively big, individual process is the most loaded down with trivial details and has waste water to produce, with the development trend phase of energy-saving and emission-reduction
Run counter to；Meanwhile, the fabric feel after current finishing technique processes is the most soft, sometimes
There is additionally required increase this additional process of soft finish.And even to this day, above-mentioned relevant whole
Reason technical study the most very system and deeply, and obtained in actual production preferable achievement and
Being widely applied, the space continued deeper into is the most extremely limited.
The present invention is based on the principle striking chapter, utilizes seal device by formulated functional material
Material be transferred on fabric, after through drying and training baking process so that the component of binding agent can be handed over
Connection forms network structure thus functional material is anchored in fiber surface and interfibrous gap
In, while improving given function durability, fabric is also provided with more soft feel.
Existing process introduction
1, padding method
Padding method is with padding machine as main process apparatus, by micro encapsulation, cyclodextrin or by
The functional materials of porous material absorption is configured to dressing liquid, fabric in dressing liquid through of short duration
After dipping, using roll roll compacting immediately, dressing liquid is squeezed into yarn fabric under the pressure effect of roll
Tissue void in, the most removable unnecessary dressing liquid, finally under the effect of binding agent will
Microcapsule is bonded in fabric.
Its basic finishing formulation is:
Functional finish Xg/L
Low-temperature adhesive Yg/L
The process for preparation of dressing liquid: add the 70 80% of the regulation water yield, by functional treatment
Agent stirs into uniform thin pulp with a small amount of water, then adds low-temperature adhesive, stirring in stirring
The water of surplus is added to specifying scale after uniformly.
It arranges flow process:
Fabric → pad → dry → train baking → finished product
As a example by the functional material of micro encapsulation, for padding method, it mainly relies on
Microcapsule is processed on fabric by the pressure in roll, in the rolling process of roll, to micro-glue
The wall material of capsule creates certain External Force Acting, due to the limited strength of wall material itself, microcapsule
It is easily broken and destroys the integrity of its wall material, result in part cladding or absorption in inside
Functional material contacts with external environment again, and it mostly is volatile material, thus makes
Become the volatilization of part of functions material, the action time of effective ingredient has shortened.Another
Aspect, the preparation of dressing liquid needs more water, and during padding, remaining arrangement
Liquid is consumed to padding groove in vain by the direct roll compacting of roll, is a kind of waste to water resource,
The pollution to environment can be caused again.
2, infusion process
Infusion process refers to fabric is immersed the impregnation liquid containing functional materials, relies on capillary pressure
The effect of power makes impregnation liquid diffuse in fiber surface and interfibrous space, utilize microcapsule,
Physical absorption and the chemical adhesion of binding agent between cyclodextrin or porous material and fiber surface are made
With being bonded on fabric, in the way of dehydration, remove unnecessary impregnation liquid after impregnating.
Its basic finishing formulation is:
Functional finish X% (o.w.f)
Low-temperature adhesive Y% (o.w.f)
It arranges flow process:
Fabric → dipping → dehydration → drying → training is dried → is become
Product
For infusion process, first during dipping and dehydration, a part of is functional
Material can be removed along with impregnation liquid, makes fabric face residual volume reduce, and the leaching removed
Water body may can be caused certain pollution by stain liquid, disagrees with the general orientation of current energy-saving and emission-reduction
The back of the body；Secondly, the functional materials uniformity being organized on fabric is uncontrollable, easily causes micro-
It is uneven that functional materials is distributed, thus causes the uneven of action effect.
3, coating
Coating is by micro encapsulation, cyclodextrin or by the functional thing of porous material absorption
Plasmogamy is set to coating slurry, uses scraper to scratch one layer of top finish slurry equably at fabric face,
During follow-up drying and baking, owing to dressing liquid is connect with textile fiber part
Mutual polymerization between branch polymerization or finishing agent, adheres to fabric by functional material, reaches long
The purpose of effect for a long time.
Its basic finishing formulation is:
It arranges flow process:
Fabric → coating → dry → bake → finished product
Compare the method arranged with other, and the coating slurry preparation of coating and coating process are more
Loaded down with trivial details, meanwhile, coating defines one or more layers macromolecule material film at fabric face,
The breathability of fabric is created certain impact.
Summary of the invention
Object of the present invention is to provide a kind of employing and strike the fabric finishing liquor of the art of composition and whole
Science and engineering skill, the present invention has that method is simple, easily operated, raw material availability is high, with low cost,
And energy-saving and emission-reduction, the finishing effect similar to existing technique can be obtained.
For reaching above-mentioned purpose, the technical scheme is that
The fabric finishing liquor of the art of composition is struck in a kind of employing, including the component of following mass percent:
The mass percent of described component is preferably:
Described fragrant microcapsule uses fragrance slow-release microcapsule (to be purchased from the limited public affairs of Shanghai Qi Huadun
Department), aromatic micro-capsule finishing agent (be purchased from open up receive chemistry), clean language Flos Rosae Multiflorae microcapsule (be purchased from sky
Span essence and flavoring agent Technew SA of Jinshi City) in one.
The cross-linking agent that described cross-linking agent uses model to be AF6100 (is purchased from He Te global group
Company limited)；The thickening agent that described thickening agent uses model to be LYOPRINTPT-RV (is purchased
Company limited is stepped) in Hensel.
Described cross-linking agent AF6100 is mainly composed of the polymer blocks with active epoxy group
Copolymer, during drying and baking, heat energy act as epoxide group and provides and can open
The chemical environment of ring, fabric face contains hydroxyl, carboxyl, amino isoreactivity group simultaneously,
Under the attack of these groups, the C-O bond fission of active epoxy group, there occurs ring-opening reaction,
Thus bind microcapsule at fabric face, thus obtain the cloth specimen finished product of finishing functions.Simultaneously
Strike the error brought of chapter operation need to accomplish following 2 points for reducing: when (1) holds chapter will just, directly,
Can not excessively rock and move seal；(2) want light, slow during lower print of affixing one's seal, firmly need as far as possible
Uniformly.
Described methylsiloxane is stuck with paste and is mixed with water for raw material with methylsiloxane, mixed weight ratio
For methylsiloxane: water=3:1；Then in mixed solution, add nonionic surfactant,
And high speed emulsifying obtains methylsiloxane paste under high-speed emulsifying machine, described non-ionic surface is lived
Property agent is fatty alcohol-polyoxyethylene ether, and its addition is the gross weight of methylsiloxane and water
1-2%.
Described methylsiloxane is a kind of liquid ring without oiliness colourless, tasteless, volatile
Siloxanes, it is with siliconoxygen bond as major key, and silicon atom is directly connected to organic group, methyl silica
Alkane has good volatility, the methylsiloxane of 90% all can in use or use after loss
Entering air, the life-span is the shortest in atmosphere, can quickly resolve into inorganic silicon salt, water, titanium dioxide
The material of the environmental sounds such as carbon, therefore methylsiloxane is as a kind of safety and environmental protection, ecological friend
Good chemicals and be widely used in health & beauty product.In the present invention, methyl silicon
Oxygen alkane sticks with paste the effect of thickener of primarily serving, and has three below aspect specifically: 1) as whole
The thickening agent of reason liquid, makes slurry have certain viscosity, can knit during impressing by partial offset
The capillary effect of thing and the imbibition that causes；2) as functional finishing agent, crosslinking in dressing liquid
Agent, the disperse medium of thickening agent and diluent, make these components dispersed；3) as merit
The delivery agent of the components such as energy finishing agent, cross-linking agent, thickening agent, plays the effect of carrier, is impressing
During these components be delivered to whereby on fabric.
The fabric finishing process of the art of composition is struck in a kind of employing, comprises the steps: 1) will be by right
The dressing liquid that the proportioning of requirement 1 is formulated uniformly puts into container, and covers above dressing liquid
Cover one layer of thin sponge, static placement 10min, penetrate into the purpose of sponge realizing dressing liquid,
Static placement process can suitably extrude sponge can be organized liquid and permeate completely；
2) then cloth specimen needed for clip, smooth is positioned on platen, and below cloth specimen on pad
Rigid block rubber is a piece of；
3) then dip dressing liquid with seal device, with all over and even be optimal, then affix one's seal down
The desired location being printed on cloth specimen；
4) finally carry out drying and baking process, complete fabric finishing process.
When described drying and the parameter baked are respectively as follows: drying temperature 60 80 DEG C, drying
Between 300 500s, baking temperature 100 120 DEG C, bake time 90 150s.
The present invention uses following two method test fabric aroma retaining effect:
Organoleptic method test fabric aroma retaining effect
Select 5 adults of osmatic 20 30 years old the fabric after Aroma finishing is entered
The independent sensory testing of row, and record sensory testing's result that every member is deep or light to fabric odor,
Finally the record result to 5 members carries out arranging statistics, and represents fragrance with the following methods
Strong and weak: +++ ++ represent that fragrance is extremely strong；++++represent, fragrance was stronger；+++ represent that fragrance is medium；
++ represent that fragrance is more weak；+ represent that fragrance is the most weak
Ultraviolet spectrophotometry test fabric aroma retaining effect
Use Lambda35 ultraviolet spectrophotometer.Knitting after arranging through aromatic micro-capsule
After thing shreds, accurately weigh 1g and put into the round-bottomed flask equipped with absolute methanol solution,
About 75 DEG C backflow 1h, and be continuously agitated with Magnetitum, it is therefore an objective to make essence be fully immersed into nothing
In water methanol solution, filter, by filtrate absolute methanol solution constant volume to 10mL, measure
Its absorbance.The perfume (or spice) corresponding to this absorbance is calculated from essence-absorbance standard absorption curve
Essence concentration, thus obtain the content of essence in fabric.
The invention have the benefit that the present invention and existing finishing functions liquid and finishing technique phase
Relatively, the key improvements point of the present invention mainly has following two aspect: first, and the present invention uses for reference
Striking the principle of chapter, and be allowed to be used among the finishing functions of fabric, the present invention uses
Micro encapsulation, cyclodextrin or by the functional materials of porous material absorption, be there is pressure resistant type and delay
The property released, uses the mode striking chapter to be arranged to fabric, and it easily embeds the knot of tissue of fabric
In structure, and to skin avirulence, non-stimulated, without anaphylaxis.In use, if
Material is rubbed or extrudes, and functional materials just can discharge from inside, when standing without releasing
Put, impart the action effect that fabric is lasting；Secondly, methylsiloxane is applied to by the present invention
Flexible nature good to give fabric in the formula of dressing liquid, it is as a kind of safety and environmental protection
Chemicals, be also provided with good volatility, air can be escaped into during baking,
Quickly resolve into a series of innocuous substance such as water, carbon dioxide, therefore soft finish can be shaped
Unite two into one with function treatment, while ensureing that fabric has soft feel, also improve
Production efficiency.
In sum 1) present invention will strike chapter mode and apply in yarn fabric finishing functions, and it is raw
Raw material availability during product is high, does not increases consuming excessively of the energy, and without any sewage
Discharge, have efficiently, feasibility is strong, energy-conserving and environment-protective, advantage that production cost is low.
2) during methylsiloxane has been applied to the preparation of dressing liquid by the present invention, methylsiloxane
For the raw material of a kind of environment-friendly type, and it is readily decomposed to as harmless products in heating process, because of
In this whole Aroma finishing flow process, Aroma finishing and soft finish, operating speed can be completed simultaneously
It is greatly increased, also improves production efficiency simultaneously.
3) finished product that the present invention prepares is soft, and function is durable, and can be according to different people
Different demands to difference in functionality, can select different arrangement concentration and different types of merit neatly
Energy material (such as antibacterial and deodouring, acaricide, antiviral, anti-ultraviolet, skin-protection and health-care etc.), no
Only can improve living environment quality, additionally aid alleviation stress, have calming soporific,
The effect such as allaying tiredness, facilitating digestion, can be adjusted on human physiology and psychology, even
Play the effect of auxiliary treatment, highly beneficial to health.
Detailed description of the invention
Embodiment 1
Present embodiments provide a kind of utilization and strike the method that chapter mode carries out fabric Aroma finishing, bag
Include following steps: 1) preparation of dressing liquid, the dressing liquid preparing following proportioning (is quality
Percentage ratio): clean language Flos Rosae Multiflorae microcapsule (is purchased from the Tianjin span limited public affairs of essence and flavoring agent new technique
Department) 0.005%, cross-linking agent AF6100 (being purchased from company limited of He Te global group) 0.1%,
LYOPRINTPT-RV thickening agent (Hensel steps company limited) 1%, water 49%, methylsiloxane
Stick with paste (methylsiloxane and water are blended) 49.895% in 3:1 ratio；Wherein methyl silica
The preparation method that alkane is stuck with paste is to mix with water with methylsiloxane for raw material, then in mixed solution
Add nonionic surfactant, and high speed emulsifying obtains methylsiloxane under high-speed emulsifying machine
Sticking with paste, described nonionic surfactant is fatty alcohol-polyoxyethylene ether, and its addition is methyl
The 1% of the gross weight of D5 and water.
2) by step 1) formulated dressing liquid puts into container, the thin sea of surface cover last layer
Silk floss, static placement 10min；To realize the purpose of dressing liquid infiltration sponge, placed static
Cheng Zhongke suitably extrudes sponge and can be organized liquid and permeate completely；
3) then cloth specimen needed for clip, smooth is positioned on platen, and below cloth specimen on pad
Rigid block rubber is a piece of；Then dip dressing liquid with seal device, with all over and even be optimal, so
After affix one's seal down the desired location being printed on cloth specimen, dressing liquid is impressed to fabric face；
4) under the temperature conditions of 60 DEG C dry 300s, after at 100 DEG C, bake 90s,
Obtain finished product.Fibre described in the present embodiment uses bafta, obtained by the present embodiment
Aroma finishing fabric use organoleptic method and ultraviolet spectrophotometry test its containing perfume amount number:
Organoleptic method test fabric aroma retaining effect
Select 5 adults of osmatic 20 30 years old the fabric after Aroma finishing is entered
The independent sensory testing of row, and record sensory testing's result that every member is deep or light to fabric odor,
Finally the record result to 5 members carries out arranging statistics, and represents fragrance with the following methods
Strong and weak: +++ ++ represent that fragrance is extremely strong；++++represent, fragrance was stronger；+++ represent that fragrance is medium；
++ represent that fragrance is more weak；+ represent that fragrance is the most weak
Ultraviolet spectrophotometry test fabric aroma retaining effect
Use Lambda35 ultraviolet spectrophotometer.Knitting after arranging through aromatic micro-capsule
After thing shreds, accurately weigh 1g and put into the round-bottomed flask equipped with absolute methanol solution,
About 75 DEG C backflow 1h, and be continuously agitated with Magnetitum, it is therefore an objective to make essence be fully immersed into nothing
In water methanol solution, filter, by filtrate absolute methanol solution constant volume to 10mL, measure
Its absorbance.The perfume (or spice) corresponding to this absorbance is calculated from essence-absorbance standard absorption curve
Essence concentration, thus obtain the content of essence in fabric.
Acquired results is shown in Table 1, and table 1 is the fibre correlative measurement after different Collator Mode arranges
Test result table.As seen from Table 1, strike the fabric after chapter arranges and can smell the lightest fragrance,
Essence content is at about 62.17ppm/g, it is achieved that the purpose of the present invention.
A kind of employing that the present embodiment provides is struck chapter mode and is carried out fabric Aroma finishing method, not only
Decrease the discharge of the pollutant such as waste water to greatest extent, and ensure that the complete of microcapsule structure
Whole, thus it is effectively improved the aroma retaining effect of fabric.The method of the present embodiment has operation letter
List, energy-conserving and environment-protective, it is applicable to the feature of large-scale application.
Embodiment 2
Present embodiments provide a kind of utilization and strike the method that chapter mode carries out fabric Aroma finishing, bag
Include following steps: 1) preparation of dressing liquid, the dressing liquid preparing following proportioning (is quality
Percentage ratio): clean language Flos Rosae Multiflorae microcapsule (is purchased from the Tianjin span limited public affairs of essence and flavoring agent new technique
Department) 0.01%, cross-linking agent AF6100 (being purchased from company limited of He Te global group) 0.2%,
LYOPRINTPT-RV thickening agent (Hensel steps company limited) 1%, water 49%, methylsiloxane
Stick with paste (methylsiloxane and water are blended) 49.79% in 3:1 ratio；Wherein methylsiloxane
The preparation method stuck with paste is to mix with water with methylsiloxane for raw material, then adds in mixed solution
Enter nonionic surfactant, and high speed emulsifying obtains methylsiloxane under high-speed emulsifying machine
Sticking with paste, described nonionic surfactant is fatty alcohol-polyoxyethylene ether, and its addition is methyl
The 1.5% of the gross weight of D5 and water.
2) by step 1) formulated dressing liquid puts into container, the thin sponge of surface cover last layer,
Static placement 10min；To realize the purpose of dressing liquid infiltration sponge, in static placement process
Can suitably extrude sponge can be organized liquid and permeate completely；
3) then cloth specimen needed for clip, smooth is positioned on platen, and below cloth specimen on pad
Rigid block rubber is a piece of；Then dip dressing liquid with seal device, with all over and even be optimal, so
After affix one's seal down the desired location being printed on cloth specimen, dressing liquid is impressed to fabric face；
4) under the temperature conditions of 70 DEG C dry 400s, after at 110 DEG C, bake 120s,
Obtain finished product.Fibre described in the present embodiment uses bafta, obtained by the present embodiment
Aroma finishing fabric use organoleptic method and ultraviolet spectrophotometry test its containing perfume amount number；
Organoleptic method test fabric aroma retaining effect
Select 5 adults of osmatic 20 30 years old the fabric after Aroma finishing is entered
The independent sensory testing of row, and record sensory testing's result that every member is deep or light to fabric odor,
Finally the record result to 5 members carries out arranging statistics, and represents fragrance with the following methods
Strong and weak: +++ ++ represent that fragrance is extremely strong；++++represent, fragrance was stronger；+++ represent that fragrance is medium；
++ represent that fragrance is more weak；+ represent that fragrance is the most weak
Ultraviolet spectrophotometry test fabric aroma retaining effect
Use Lambda35 ultraviolet spectrophotometer.Knitting after arranging through aromatic micro-capsule
After thing shreds, accurately weigh 1g and put into the round-bottomed flask equipped with absolute methanol solution,
About 75 DEG C backflow 1h, and be continuously agitated with Magnetitum, it is therefore an objective to make essence be fully immersed into nothing
In water methanol solution, filter, by filtrate absolute methanol solution constant volume to 10mL, measure
Its absorbance.The perfume (or spice) corresponding to this absorbance is calculated from essence-absorbance standard absorption curve
Essence concentration, thus obtain the content of essence in fabric.
Acquired results is shown in Table 1, and table 1 is the fibre correlative measurement after different Collator Mode arranges
Test result table.As seen from Table 1, strike the fabric after chapter arranges and can smell the fragrance of clean language Flos Rosae Multiflorae,
Essence content is at about 126.32ppm/g, it is achieved that the purpose of the present invention.
A kind of employing that the present embodiment provides is struck chapter mode and is carried out fabric Aroma finishing method, not only
Decrease the discharge of the pollutant such as waste water to greatest extent, and ensure that the complete of microcapsule structure
Whole, thus it is effectively improved the aroma retaining effect of fabric.The method of the present embodiment has operation letter
List, energy-conserving and environment-protective, it is applicable to the feature of large-scale application.
Embodiment 3
Present embodiments provide a kind of utilization and strike the method that chapter mode carries out fabric Aroma finishing, bag
Include following steps: 1) preparation of dressing liquid, the dressing liquid preparing following proportioning (is quality
Percentage ratio): aromatic micro-capsule finishing agent (be purchased from open up receive chemistry) 1%, cross-linking agent AF6100 (purchase
In company limited of He Te global group) 2%, LYOPRINTPT-RV thickening agent (Hensel step have
Limit company) 0.5%, water 40%, methylsiloxane stick with paste (methylsiloxane and water are in 3:1 ratio
It is blended) 56.5%；The preparation method that wherein methylsiloxane is stuck with paste is for methylsiloxane to be
Raw material mixes with water, then adds nonionic surfactant in mixed solution, and at a high speed
Under mulser, high speed emulsifying obtains methylsiloxane paste, and described nonionic surfactant is fat
Fat polyoxyethylenated alcohol, its addition is the 2% of the gross weight of methyl D5 and water.
By step 1) formulated dressing liquid puts into container, the thin sponge of surface cover last layer,
Static placement 10min；To realize the purpose of dressing liquid infiltration sponge, in static placement process
Can suitably extrude sponge can be organized liquid and permeate completely；
3) then cloth specimen needed for clip, smooth is positioned on platen, and below cloth specimen on pad
Rigid block rubber is a piece of；Then dip dressing liquid with seal device, with all over and even be optimal, so
After affix one's seal down the desired location being printed on cloth specimen, dressing liquid is impressed to fabric face；
4) under the temperature conditions of 80 DEG C dry 500s, after at 120 DEG C, bake 150s,
Obtain finished product.Fibre described in the present embodiment uses bafta, obtained by the present embodiment
Aroma finishing fabric use organoleptic method and ultraviolet spectrophotometry test its containing perfume amount number；
Organoleptic method test fabric aroma retaining effect
Select 5 adults of osmatic 20 30 years old the fabric after Aroma finishing is entered
The independent sensory testing of row, and record sensory testing's result that every member is deep or light to fabric odor,
Finally the record result to 5 members carries out arranging statistics, and represents fragrance with the following methods
Strong and weak: +++ ++ represent that fragrance is extremely strong；++++represent, fragrance was stronger；+++ represent that fragrance is medium；
++ represent that fragrance is more weak；+ represent that fragrance is the most weak
Ultraviolet spectrophotometry test fabric aroma retaining effect
Use Lambda35 ultraviolet spectrophotometer.Knitting after arranging through aromatic micro-capsule
After thing shreds, accurately weigh 1g and put into the round-bottomed flask equipped with absolute methanol solution,
About 75 DEG C backflow 1h, and be continuously agitated with Magnetitum, it is therefore an objective to make essence be fully immersed into nothing
In water methanol solution, filter, by filtrate absolute methanol solution constant volume to 10mL, measure
Its absorbance.The perfume (or spice) corresponding to this absorbance is calculated from essence-absorbance standard absorption curve
Essence concentration, thus obtain the content of essence in fabric.
Acquired results is shown in Table 1, and table 1 is the fibre correlative measurement after different Collator Mode arranges
Test result table.As seen from Table 1, strike the fabric after chapter arranges and can smell the strongest lavandula angustifolia
Fragrance, ultraviolet spectrophotometry essence content is at about 384.35ppm/g, it is achieved that this
Bright purpose.
A kind of employing that the present embodiment provides is struck chapter mode and is carried out fabric Aroma finishing method, not only
Decrease the discharge of the pollutant such as waste water to greatest extent, and ensure that the complete of microcapsule structure
Whole, thus it is effectively improved the aroma retaining effect of fabric.The method of the present embodiment has operation letter
List, energy-conserving and environment-protective, it is applicable to the feature of large-scale application.
Embodiment 4
Present embodiments provide a kind of utilization and strike the method that chapter mode carries out fabric Aroma finishing, bag
Include following steps: 1) preparation of dressing liquid, the dressing liquid preparing following proportioning (is quality
Percentage ratio): fragrance slow-release microcapsule (being purchased from Shanghai Givaudan Co., Ltd) 8%, cross-linking agent
AF6100 (being purchased from company limited of He Te global group) 15%, LYOPRINTPT-RV thickening agent
(Hensel steps company limited) 2%, water 50%, methylsiloxane stick with paste (methylsiloxane and water are pressed
3:1 ratio is blended) 25%；The preparation method that wherein methylsiloxane is stuck with paste is with methyl silicon
Oxygen alkane is that raw material mixes with water, then adds nonionic surfactant in mixed solution, and
Under high-speed emulsifying machine, high speed emulsifying obtains methylsiloxane paste, described non-ionic surface active
Agent is fatty alcohol-polyoxyethylene ether, and its addition is the gross weight of methyl D5 and water
1.7%.
By step 1) formulated dressing liquid puts into container, the thin sponge of surface cover last layer,
Static placement 10min；To realize the purpose of dressing liquid infiltration sponge, in static placement process
Can suitably extrude sponge can be organized liquid and permeate completely；
3) then cloth specimen needed for clip, smooth is positioned on platen, and below cloth specimen on pad
Rigid block rubber is a piece of；Then dip dressing liquid with seal device, with all over and even be optimal, so
After affix one's seal down the desired location being printed on cloth specimen, dressing liquid is impressed to fabric face；
4) under the temperature conditions of 75 DEG C dry 450s, after at 105 DEG C, bake 110s,
Obtain finished product.Fibre described in the present embodiment uses bafta, obtained by the present embodiment
Aroma finishing fabric use organoleptic method and ultraviolet spectrophotometry test its containing perfume amount number；
Organoleptic method test fabric aroma retaining effect
Select 5 adults of osmatic 20 30 years old the fabric after Aroma finishing is entered
The independent sensory testing of row, and record sensory testing's result that every member is deep or light to fabric odor,
Finally the record result to 5 members carries out arranging statistics, and represents fragrance with the following methods
Strong and weak: +++ ++ represent that fragrance is extremely strong；++++represent, fragrance was stronger；+++ represent that fragrance is medium；
++ represent that fragrance is more weak；+ represent that fragrance is the most weak
Ultraviolet spectrophotometry test fabric aroma retaining effect
Use Lambda35 ultraviolet spectrophotometer.Knitting after arranging through aromatic micro-capsule
After thing shreds, accurately weigh 1g and put into the round-bottomed flask equipped with absolute methanol solution,
About 75 DEG C backflow 1h, and be continuously agitated with Magnetitum, it is therefore an objective to make essence be fully immersed into nothing
In water methanol solution, filter, by filtrate absolute methanol solution constant volume to 10mL, measure
Its absorbance.The perfume (or spice) corresponding to this absorbance is calculated from essence-absorbance standard absorption curve
Essence concentration, thus obtain the content of essence in fabric.
Acquired results is shown in Table 1, and table 1 is the fibre correlative measurement after different Collator Mode arranges
Test result table.As known from Table 1, can smell the strongest fragrance with organoleptic method, the perfume (or spice) of gained
Essence test volume is 631.68ppm/g, it is achieved that the purpose of the present invention.
A kind of employing that the present embodiment provides is struck chapter mode and is carried out fabric Aroma finishing method, not only
Decrease the discharge of the pollutant such as waste water to greatest extent, and ensure that the complete of microcapsule structure
Whole, thus it is effectively improved the aroma retaining effect of fabric.The method of the present embodiment has operation letter
List, energy-conserving and environment-protective, it is applicable to the feature of large-scale application.
Comparative example 1
This comparative example comprises the steps: 1) preparation of padding liquid, prepare the leaching of following proportioning
Mangle: clean language Flos Rosae Multiflorae microcapsule (being purchased from Tianjin Double Horse Flavor and Fragrance New Technology Co., Ltd.)
0.01g/L, cross-linking agent AF6100 (being purchased from company limited of He Te global group) 0.01g/L；2)
Fabric is immersed in step 1) in formulated padding liquid；3) carry out two leachings two with padding machine to roll
Processing, wherein pick-up rate is about 75%；4) under the temperature conditions of 80 DEG C, 150s is dried, after
At 120 DEG C, bake 120s, i.e. can get finished product.Fibre described in the present embodiment uses
Pure cotton fabric, uses organoleptic method to test it containing perfume to the Aroma finishing fabric obtained by this comparative example
Effect.
Acquired results is shown in Table 1, and table 1 is the fibre correlative measurement after different Collator Mode arranges
Test result table.As known from Table 1, with the microcapsule concentration of 0.01g/L, the method padded is taked
After finish fabric, can smell the lightest fragrance with organoleptic method, the essence test volume of gained is
72.56ppm/g, compared with embodiment, the present invention uses the method striking chapter to can reach tradition leaching
The finishing functions effect that method of rolling is similar.For padding method, during arranging, a side
The preparation of face dressing liquid needs more water, and next pads place and comprehends and make remaining dressing liquid be rolled
The direct roll compacting of roller consumes in vain to padding groove, is a kind of waste to water resource, can make again
The pollution of environment, also exists the limitation of self in pairs.
Comparative example 2
This comparative example comprises the steps: 1) preparation of impregnation liquid, prepare the leaching of following proportioning
Stain liquid: clean language Flos Rosae Multiflorae microcapsule (being purchased from Tianjin Double Horse Flavor and Fragrance New Technology Co., Ltd.)
0.01g/L, cross-linking agent AF6100 (being purchased from company limited of He Te global group) 0.01g/L；2)
Fabric is immersed in step 1) formulated impregnation liquid interior immersion 30min；3) at 80 DEG C
Under temperature conditions dry, after at 120 DEG C, bake 120s, i.e. can get finished product.The present embodiment
Described fibre uses pure cotton fabric, adopts the Aroma finishing fabric obtained by this comparative example
It is tested containing fragrant effect with organoleptic method.
Acquired results is shown in Table 1, and table 1 is the fibre correlative measurement after different Collator Mode arranges
Test result table.As known from Table 1, with the microcapsule concentration of 0.01g/L, the method taking dipping
After finish fabric, can smell the lightest fragrance with organoleptic method, the essence test volume of gained is
54.21ppm/g, compares with embodiment, strikes the art of composition and can reach and infusion process finishing functions
The most excellent finishing effect.For infusion process, first during dipping and dehydration,
The aromatic micro-capsule of a part can be removed along with impregnation liquid, makes fabric face residual volume subtract
Lack, and water body may can be caused certain pollution by the impregnation liquid removed.
Table 1
Claims (6)
1. the fabric finishing liquor of the art of composition is struck in an employing, it is characterised in that include following quality
The component of percentage ratio:
Described methylsiloxane is stuck with paste and is mixed with water for raw material with methylsiloxane, mixed weight ratio
For methylsiloxane: water=3:1；Then in mixed solution, add nonionic surfactant,
And high speed emulsifying obtains methylsiloxane paste under high-speed emulsifying machine, described non-ionic surface is lived
Property agent is fatty alcohol-polyoxyethylene ether, and its addition is the gross weight of methylsiloxane and water
1-2%.
The fabric finishing liquor of the art of composition is struck in a kind of employing the most as claimed in claim 1, its feature
Being, described functional finishing agent is fragrant microcapsule, and the mass percent of each component is:
The fabric finishing liquor of the art of composition is struck in a kind of employing the most as claimed in claim 2, its feature
Be: described fragrant microcapsule use fragrance slow-release microcapsule, aromatic micro-capsule finishing agent,
One in clean language Flos Rosae Multiflorae microcapsule.
The fabric finishing liquor of the art of composition is struck in a kind of employing the most as claimed in claim 1 or 2, its
It is characterised by: described cross-linking agent uses model to be the cross-linking agent of AF6100；Described thickening
The thickening agent that agent uses model to be LYOPRINT PT-RV.
5. the fabric finishing process of the art of composition is struck in an employing, it is characterised in that include walking as follows
Rapid: 1) dressing liquid formulated by the proportioning in claim 1 is uniformly put into container,
And above dressing liquid, cover one layer of thin sponge, static placement 10min；
2) then cloth specimen needed for clip, smooth is positioned on platen, and below cloth specimen on pad
Rigid block rubber is a piece of；
3) then dip dressing liquid with seal device, with all over and even be optimal, then affix one's seal down
The desired location being printed on cloth specimen；
4) finally carry out drying and baking process, complete fabric finishing process.
The fabric finishing process of the art of composition is struck in a kind of employing the most as claimed in claim 5, and it is special
Levy and be: described drying and the parameter baked are respectively as follows: drying temperature 60-80 DEG C, dry
Time 300-500s, baking temperature 100-120 DEG C, bake time 90-150s.
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| CN201410305712.4A CN104109973B (en) | 2014-06-30 | 2014-06-30 | Fabric finishing liquor and the finishing technique thereof of the art of composition is struck in a kind of employing |
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| CN201410305712.4A CN104109973B (en) | 2014-06-30 | 2014-06-30 | Fabric finishing liquor and the finishing technique thereof of the art of composition is struck in a kind of employing |
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| CN107227571B (en) * | 2017-05-15 | 2019-11-29 | 日信纺织有限公司 | A kind of dazzling charming visual effect coating hydrophilic fabric |
| CN107513864A (en) * | 2017-08-10 | 2017-12-26 | 宁波广源纺织品有限公司 | A kind of lavender oil microcapsules dressing liquid and its application |
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| CN1101387A (en) * | 1993-10-06 | 1995-04-12 | 山东工业大学 | Preparing process and application of micro capsule fragrant finishing agent |
| CN101407582A (en) * | 2007-10-10 | 2009-04-15 | 戈尔德施米特有限公司 | Linear poly(dialkyl) organosiloxane having poly(oxyalkylene), amino functional group and end alkoxy |
| KR20100134855A (en) * | 2009-06-16 | 2010-12-24 | 이용인 | Microcapsules using a phase change material and printing-processing composition and processes for producing the same |
| CN102978906A (en) * | 2011-12-14 | 2013-03-20 | 郑建光 | Clothing softener |
| CN103451939B (en) * | 2013-09-11 | 2015-09-30 | 上海应用技术学院 | A kind of double-layer aromatic phase-change microcapsule fabric finishing liquor and preparation method and application |
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