CN104109307A - Anti-fatigue cable material and preparation method thereof - Google Patents
Anti-fatigue cable material and preparation method thereof Download PDFInfo
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- CN104109307A CN104109307A CN201410284378.9A CN201410284378A CN104109307A CN 104109307 A CN104109307 A CN 104109307A CN 201410284378 A CN201410284378 A CN 201410284378A CN 104109307 A CN104109307 A CN 104109307A
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Abstract
The invention discloses an anti-fatigue cable material and a preparation method thereof. The material is prepared by the following raw materials by weight:80 to 90 of SG-5-type PVC, 15 to 25 of impact-resistance polystyrene, 10 to 15 of PEEK, 5 to 10 of epoxidized soybean oil, 10 to 15 of antimony trioxide, 8 to 12 of active aluminum hydroxide, 15 to 20 of nano bauxite , 4 to 8 of glass fiber, 5 to 10 of composite filler, 10 to 15 of TOTM, 5 to 10 of acetyl tributyl citrate, 4 to 8 of dioctyl phthalate, 2 to 3 of calcium zinc composite stabilizer, 1 to 2 of tributyltin chloride, 0.5 to 1 of isopropyl three (two octyl pyrophosphateacyloxy) titanate, 0.4 to 0.6 of erucamide, and 0.5 to 1 of oxidized polyethylene wax. The cable material is good in flexibility and has excellent mechanical performance of fatigue resistance, tearing resistance, oil resistance, heat resistance, flame retardancy and the like, and the cable material is safe, reliable, and durable in use.
Description
Technical field
The present invention relates to a kind of CABLE MATERIALS and preparation method thereof, be specifically related to a kind of weariness resistance cable material and preparation method thereof.
Background technology
The toughness of electric wire outer protective sleeve insulating material is in the market inadequate, fatigue resistance is poor, cause electric wire in process of deployment, often need bending, around time the phenomenon such as easily occur fractureing, break, during transmission of electricity, easily occur to get an electric shock and electric leakage accident, can cause great financial loss and social danger.
Summary of the invention
The object of the invention is to for the deficiencies in the prior art, provide that a kind of toughness is high, the weariness resistance cable material of good springiness and preparation method thereof.
The technical solution used in the present invention is as follows:
A kind of weariness resistance cable material, raw material by following weight part is made: SG-5 type polyvinyl chloride 80-90, impact resistant polystyrene 15-25, polyether-ether-ketone 10-15, epoxy soybean oil 5-10, antimonous oxide 10-15, active aluminium hydroxide 8-12, nano aluminum alumina 15-20, glass fibre 4-8, compounded mix 5-10, trioctyl trimellitate 10-15, tributyl acetylcitrate 5-10, dioctyl phthalate (DOP) 4-8, calcium-zinc composite stabilizing agent 2-3, tributyltin chloride 1-2, sec.-propyl three (dioctylphyrophosphoric acid acyloxy) titanic acid ester 0.5-1, erucicamide 0.4-0.6, oxidized polyethlene wax 0.5-1,
The preparation method of described compounded mix is as follows: a. takes off the raw material of row weight part: kaolinite 10-15, agalmatolite 5-10, zeolite powder 4-8, flyash 3-6, stearic acid 2-3, sec.-propyl distearyl acyl-oxygen base Aluminate 1-2, calcium lignin sulphonate 3-5, epoxy oleum lini 10-15, nano zircite 2-4, nanometer jade powder 4-8, isocaprylic acid cerium 1-2, isocaprylic acid neodymium 0.5-1, b, by kaolinite, agalmatolite is calcined 3-5h at 520-540 ℃, after being cooled to room temperature, put into the hydrochloric acid soln that concentration is 10-15%, 70-80 ℃ of heating in water bath 1-2h, taking-up is washed with distilled water to neutrality, dry, being crushed to granularity is 0.1-0.2mm, then add stearic acid, sec.-propyl distearyl acyl-oxygen base Aluminate, zeolite powder, flyash, calcium lignin sulphonate, 4000-5000rpm speed lapping 10-15min, dry, pulverize, cross 300-400 mesh sieve, c, powder after sieving is mixed with all the other raw materials, 1500-2000rpm high-speed stirring 5-10min.
The preparation method of weariness resistance cable material, comprises the following steps:
(1) SG-5 type polyvinyl chloride, epoxy soybean oil, antimonous oxide, nano aluminum alumina, glass fibre, trioctyl trimellitate, calcium-zinc composite stabilizing agent, sec.-propyl three (dioctylphyrophosphoric acid acyloxy) titanic acid ester, oxidized polyethlene wax are dropped in high-speed kneading machine to high-speed kneading 10-15min at 95-105 ℃;
(2) impact resistant polystyrene, polyether-ether-ketone, active aluminium hydroxide, compounded mix, tributyl acetylcitrate, dioctyl phthalate (DOP), tributyltin chloride, erucicamide are dropped in mill, control roller temperature 90-100 ℃, roll spacing 0.4-0.6mm, mixing 8-12min, and be cut into masterbatch particle by flat plate cutting grain machine;
(3) the kneaded PVC of step (1) is dropped in mill and plasticated, roller temperature control is at 160-180 ℃, after PVC plasticizing bag roller, by roller temperature drop to 110-120 ℃, the masterbatch particle that adds step (2) to make closes refining, adopt the method for high-shear, the 15-20min that plasticates, evenly rear extrusion granulating.
Beneficial effect of the present invention:
CABLE MATERIALS snappiness of the present invention is good, has the mechanical propertys such as excellent fatigue resistance, tear strength, and has good oil resistant, the performance such as wear-resisting, heat-resisting and fire-retardant, completely reliable, durable in use.
Embodiment
A weariness resistance cable material, is made by the raw material of following weight (kg): SG-5 type polyvinyl chloride 80, impact resistant polystyrene 20, polyether-ether-ketone 15, epoxy soybean oil 8, antimonous oxide 12, active aluminium hydroxide 1-, nano aluminum alumina 18, glass fibre 6, compounded mix 7, trioctyl trimellitate 12, tributyl acetylcitrate 8, dioctyl phthalate (DOP) 6, calcium-zinc composite stabilizing agent 2, tributyltin chloride 1.5, sec.-propyl three (dioctylphyrophosphoric acid acyloxy) titanic acid ester 0.8, erucicamide 0.5, oxidized polyethlene wax 0.8;
The preparation method of described compounded mix is as follows: a. takes off the raw material of column weight amount (kg): kaolinite 15, agalmatolite 5, zeolite powder 6, flyash 5, stearic acid 2, sec.-propyl distearyl acyl-oxygen base Aluminate 1, calcium lignin sulphonate 3, epoxy oleum lini 10, nano zircite 3, nanometer jade powder 5, isocaprylic acid cerium 1, isocaprylic acid neodymium 0.5; B, kaolinite, agalmatolite are calcined to 5h at 520 ℃, being cooled to and putting into concentration after room temperature is 10% hydrochloric acid soln, 80 ℃ of heating in water bath 1h, taking-up is washed with distilled water to neutrality, dry, being crushed to granularity is 0.2mm, then add stearic acid, sec.-propyl distearyl acyl-oxygen base Aluminate, zeolite powder, flyash, calcium lignin sulphonate, 5000rpm speed lapping 10min, dry, pulverize, cross 400 mesh sieves, c, the powder after sieving is mixed to 2000rpm high-speed stirring 5min with all the other raw materials.
The preparation method of weariness resistance cable material, comprises the following steps:
(1) SG-5 type polyvinyl chloride, epoxy soybean oil, antimonous oxide, nano aluminum alumina, glass fibre, trioctyl trimellitate, calcium-zinc composite stabilizing agent, sec.-propyl three (dioctylphyrophosphoric acid acyloxy) titanic acid ester, oxidized polyethlene wax are dropped in high-speed kneading machine to high-speed kneading 12min at 95 ℃;
(2) impact resistant polystyrene, polyether-ether-ketone, active aluminium hydroxide, compounded mix, tributyl acetylcitrate, dioctyl phthalate (DOP), tributyltin chloride, erucicamide are dropped in mill, 98 ℃ of control roller temperature, roll spacing 0.4mm, mixing 10min, and be cut into masterbatch particle by flat plate cutting grain machine;
(3) the kneaded PVC of step (1) is dropped in mill and plasticated, roller temperature is 175 ℃, after PVC plasticizing bag roller, by roller temperature drop to 115 ℃, the masterbatch particle that adds step (2) to make closes refining, adopts the method for high-shear, the 15min that plasticates, evenly after extrusion granulating.
The performance test results of the CABLE MATERIALS making is as follows:
Claims (2)
1. a weariness resistance cable material, it is characterized in that, raw material by following weight part is made: SG-5 type polyvinyl chloride 80-90, impact resistant polystyrene 15-25, polyether-ether-ketone 10-15, epoxy soybean oil 5-10, antimonous oxide 10-15, active aluminium hydroxide 8-12, nano aluminum alumina 15-20, glass fibre 4-8, compounded mix 5-10, trioctyl trimellitate 10-15, tributyl acetylcitrate 5-10, dioctyl phthalate (DOP) 4-8, calcium-zinc composite stabilizing agent 2-3, tributyltin chloride 1-2, sec.-propyl three (dioctylphyrophosphoric acid acyloxy) titanic acid ester 0.5-1, erucicamide 0.4-0.6, oxidized polyethlene wax 0.5-1,
The preparation method of described compounded mix is as follows: a. takes off the raw material of row weight part: kaolinite 10-15, agalmatolite 5-10, zeolite powder 4-8, flyash 3-6, stearic acid 2-3, sec.-propyl distearyl acyl-oxygen base Aluminate 1-2, calcium lignin sulphonate 3-5, epoxy oleum lini 10-15, nano zircite 2-4, nanometer jade powder 4-8, isocaprylic acid cerium 1-2, isocaprylic acid neodymium 0.5-1, b, by kaolinite, agalmatolite is calcined 3-5h at 520-540 ℃, after being cooled to room temperature, put into the hydrochloric acid soln that concentration is 10-15%, 70-80 ℃ of heating in water bath 1-2h, taking-up is washed with distilled water to neutrality, dry, being crushed to granularity is 0.1-0.2mm, then add stearic acid, sec.-propyl distearyl acyl-oxygen base Aluminate, zeolite powder, flyash, calcium lignin sulphonate, 4000-5000rpm speed lapping 10-15min, dry, pulverize, cross 300-400 mesh sieve, c, powder after sieving is mixed with all the other raw materials, 1500-2000rpm high-speed stirring 5-10min.
2. the preparation method of weariness resistance cable material as claimed in claim 1, is characterized in that comprising the following steps:
SG-5 type polyvinyl chloride, epoxy soybean oil, antimonous oxide, nano aluminum alumina, glass fibre, trioctyl trimellitate, calcium-zinc composite stabilizing agent, sec.-propyl three (dioctylphyrophosphoric acid acyloxy) titanic acid ester, oxidized polyethlene wax are dropped in high-speed kneading machine to high-speed kneading 10-15min at 95-105 ℃;
Impact resistant polystyrene, polyether-ether-ketone, active aluminium hydroxide, compounded mix, tributyl acetylcitrate, dioctyl phthalate (DOP), tributyltin chloride, erucicamide are dropped in mill, control roller temperature 90-100 ℃, roll spacing 0.4-0.6mm, mixing 8-12min, and be cut into masterbatch particle by flat plate cutting grain machine;
The kneaded PVC of step (1) is dropped in mill and plasticated, and roller temperature control is at 160-180 ℃, after PVC plasticizing bag roller, by roller temperature drop, to 110-120 ℃, the masterbatch particle that adds step (2) to make closes refining, adopts the method for high-shear, the 15-20min that plasticates, evenly after extrusion granulating.
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Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104592710A (en) * | 2014-12-30 | 2015-05-06 | 东莞市高能磁电技术有限公司 | Heat-resistant flame-retardant wave-absorbing insulating material and preparation method thereof |
| CN105255057A (en) * | 2015-11-10 | 2016-01-20 | 芜湖市艾德森自动化设备有限公司 | Anti-insect and anti-mold interior decoration PVC modified material and preparation method thereof |
| CN105255051A (en) * | 2015-11-10 | 2016-01-20 | 芜湖市艾德森自动化设备有限公司 | Sound absorbing and noise lowering interior decoration PVC modified material and preparation method thereof |
| CN105255053A (en) * | 2015-11-10 | 2016-01-20 | 芜湖市艾德森自动化设备有限公司 | Stain-resistant indoor decorative PVC modified material easy to clean and preparation method thereof |
| CN105255056A (en) * | 2015-11-10 | 2016-01-20 | 芜湖市艾德森自动化设备有限公司 | Light warm-keeping interior decoration PVC modified material and preparation method thereof |
| CN105255049A (en) * | 2015-11-10 | 2016-01-20 | 芜湖市艾德森自动化设备有限公司 | Antiskid and wear-resistant interior decoration PVC modified material and preparation method thereof |
| CN105255054A (en) * | 2015-11-10 | 2016-01-20 | 芜湖市艾德森自动化设备有限公司 | Shock-resistant PVC modified material for interior decoration and preparation method thereof |
| CN105348717A (en) * | 2015-10-30 | 2016-02-24 | 安徽天星光纤通信设备有限公司 | Acid and fatigue resistant cable material and preparation method thereof |
| CN105440464A (en) * | 2015-12-08 | 2016-03-30 | 宁国市开源橡塑汽车零部件有限公司 | Damping rubber material |
| CN105936706A (en) * | 2016-06-15 | 2016-09-14 | 马晓权 | High strength and flame retardant cable insulation sheath material and preparation method thereof |
| CN106700299A (en) * | 2016-12-20 | 2017-05-24 | 安徽华天电缆有限公司 | Polystyrene cable material good toughness and difficult to tear |
| CN107189267A (en) * | 2017-06-22 | 2017-09-22 | 安徽机电职业技术学院 | A kind of preparation method of the mechanical sheath material of hard shock resistance |
| CN109233139A (en) * | 2018-07-03 | 2019-01-18 | 安徽安远塑胶股份有限公司 | A kind of high-strength PVC CABLE MATERIALS |
| CN114429842A (en) * | 2022-03-02 | 2022-05-03 | 广东新亚光电缆股份有限公司 | Preparation method of compact cable with steel core |
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| CN102115558A (en) * | 2010-12-29 | 2011-07-06 | 四川大学 | High-conductivity polymer carbon nanotube composite material and micro-processing method thereof |
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Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104592710A (en) * | 2014-12-30 | 2015-05-06 | 东莞市高能磁电技术有限公司 | Heat-resistant flame-retardant wave-absorbing insulating material and preparation method thereof |
| CN105348717A (en) * | 2015-10-30 | 2016-02-24 | 安徽天星光纤通信设备有限公司 | Acid and fatigue resistant cable material and preparation method thereof |
| CN105255054A (en) * | 2015-11-10 | 2016-01-20 | 芜湖市艾德森自动化设备有限公司 | Shock-resistant PVC modified material for interior decoration and preparation method thereof |
| CN105255053A (en) * | 2015-11-10 | 2016-01-20 | 芜湖市艾德森自动化设备有限公司 | Stain-resistant indoor decorative PVC modified material easy to clean and preparation method thereof |
| CN105255056A (en) * | 2015-11-10 | 2016-01-20 | 芜湖市艾德森自动化设备有限公司 | Light warm-keeping interior decoration PVC modified material and preparation method thereof |
| CN105255049A (en) * | 2015-11-10 | 2016-01-20 | 芜湖市艾德森自动化设备有限公司 | Antiskid and wear-resistant interior decoration PVC modified material and preparation method thereof |
| CN105255051A (en) * | 2015-11-10 | 2016-01-20 | 芜湖市艾德森自动化设备有限公司 | Sound absorbing and noise lowering interior decoration PVC modified material and preparation method thereof |
| CN105255057A (en) * | 2015-11-10 | 2016-01-20 | 芜湖市艾德森自动化设备有限公司 | Anti-insect and anti-mold interior decoration PVC modified material and preparation method thereof |
| CN105440464A (en) * | 2015-12-08 | 2016-03-30 | 宁国市开源橡塑汽车零部件有限公司 | Damping rubber material |
| CN105936706A (en) * | 2016-06-15 | 2016-09-14 | 马晓权 | High strength and flame retardant cable insulation sheath material and preparation method thereof |
| CN106700299A (en) * | 2016-12-20 | 2017-05-24 | 安徽华天电缆有限公司 | Polystyrene cable material good toughness and difficult to tear |
| CN107189267A (en) * | 2017-06-22 | 2017-09-22 | 安徽机电职业技术学院 | A kind of preparation method of the mechanical sheath material of hard shock resistance |
| CN109233139A (en) * | 2018-07-03 | 2019-01-18 | 安徽安远塑胶股份有限公司 | A kind of high-strength PVC CABLE MATERIALS |
| CN114429842A (en) * | 2022-03-02 | 2022-05-03 | 广东新亚光电缆股份有限公司 | Preparation method of compact cable with steel core |
| CN114429842B (en) * | 2022-03-02 | 2023-12-26 | 广东新亚光电缆股份有限公司 | Preparation method of strip steel core tight compression type cable |
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