CN104099622B - A kind of metal cleaner - Google Patents
A kind of metal cleaner Download PDFInfo
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- CN104099622B CN104099622B CN201310114759.8A CN201310114759A CN104099622B CN 104099622 B CN104099622 B CN 104099622B CN 201310114759 A CN201310114759 A CN 201310114759A CN 104099622 B CN104099622 B CN 104099622B
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- acid
- metal cleaner
- polyoxyethylene nonylphenol
- nonylphenol ether
- sodium bicarbonate
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Abstract
The present invention relates to clean-out system technical field, does is be specifically related to a kind of metal cleaner, it made up of the raw material of following weight percent: stearic acid 1-5%, citric acid 1-5%, lauric acid 1-5%, sodium bicarbonate? 0.5-3%, chromic anhydride 0.5-2%, water glass 0.5-2%, polyoxyethylene nonylphenol ether? 1-4%, surplus are water.The present invention adopts stearic acid, citric acid, lipid acid that lauric acid three kinds is different carries out composite, and eliminate rust effective, the chromic anhydride in raw material effectively can remove spot, and the sodium bicarbonate in raw material and water glass can deoil, again can protection against corrosion; Metal parts through the present invention cleaning after corrosion-free, noresidue; Environmental protection of the present invention, security are good, and nontoxic non-corrosiveness is free from environmental pollution, safety and stability.
Description
Technical field
The present invention relates to clean-out system technical field, be specifically related to a kind of metal cleaner.
Background technology
When the maintenance and repair of machining and mechanical means, automobile etc., mostly adopt diesel oil, coal Water Oil Or Gas carrys out cleaning components as scavenging solution.This not only wastes energy, and there is potential unsafe factor, careless slightly, then may lead to fire.In recent years, a kind of novel metal cleaner is widely used gradually, it ground diesel oil substitute, kerosene and gasoline can carry out cleaning components, and the Chinese invention patent application being 201110356104.2 as application number discloses in particular to a kind of metal cleaner being applicable to clean metal surface.The present invention is by tensio-active agent 30-55%; Cleaning additive 5%-8%; Rust-preventive agent 7%-12%; Defoamer 3%-5%; Additive 0.5%-3%, all the other compositions are that the compositions such as deionized water are formed.
But clean-out system of the prior art exists, and cleaning performance is undesirable, contaminate environment, harm user are healthy, corrode by clean metal, use uneasy congruent various defect.
Summary of the invention
The object of the invention is to for the deficiencies in the prior art, provide that a kind of cleaning performance is good, environmental protection, corrosion-free, use safety metal cleaner.
To achieve these goals, the present invention adopts following technical scheme:
A kind of metal cleaner, it is made up of the raw material of following weight percent:
Stearic acid 1-5%
Citric acid 1-5%
Lauric acid 1-5%
Sodium bicarbonate 0.5-3%
Chromic anhydride 0.5-2%
Water glass 0.5-2%
Polyoxyethylene nonylphenol ether 1-4%
Water surplus.
Preferably, it is made up of the raw material of following weight percent:
Stearic acid 2-5%
Citric acid 3-5%
Lauric acid 3-5%
Sodium bicarbonate 1-3%
Chromic anhydride 1-2%
Water glass 1-2%
Polyoxyethylene nonylphenol ether 1-3%
Water surplus.
More preferred, it is made up of the raw material of following weight percent:
Stearic acid 2%
Citric acid 4%
Lauric acid 4%
Sodium bicarbonate 3%
Chromic anhydride 2%
Water glass 2%
Polyoxyethylene nonylphenol ether 1%
Water surplus.
Preferably, it is made up of the raw material of following weight percent:
Stearic acid 1-4%
Citric acid 1-4%
Lauric acid 1-5%
Sodium bicarbonate 1-3%
Chromic anhydride 0.5-2%
Water glass 0.5-1.5%
Polyoxyethylene nonylphenol ether 1-3%
Water surplus.
More preferred, it is made up of the raw material of following weight percent:
Stearic acid 4%
Citric acid 4%
Lauric acid 5%
Sodium bicarbonate 3%
Chromic anhydride 1.5%
Water glass 1.3%
Polyoxyethylene nonylphenol ether 3%
Water surplus.
Wherein, the HLB value of described polyoxyethylene nonylphenol ether is 14-15, and the pH value of described polyoxyethylene nonylphenol ether is 6-7.
Or the polyoxyethylene nonylphenol ether of described polyoxyethylene nonylphenol ether to be model be TX-10, emulsifier effect is good.
The preparation method of above-mentioned metal cleaner, it comprises the following steps:
A, weighing: weigh each component according to formula ratio;
B, spice: the stearic acid weighed in step a, citric acid, lauric acid, sodium bicarbonate, chromic anhydride, water glass, polyoxyethylene nonylphenol ether and water are placed in container, stir, obtain described metal cleaner.
The present invention compared with prior art, beneficial effect is: the polyoxyethylene nonylphenol ether that 1) the present invention adopts can increase the consistency of each material, each material is well scattered in water, employing stearic acid, citric acid, the lipid acid that lauric acid three kinds is different carry out composite, eliminate rust effective, chromic anhydride in raw material effectively can remove spot, and the sodium bicarbonate in raw material and water glass can deoil, again can protection against corrosion; 2) metal parts is corrosion-free after the present invention's cleaning, noresidue; 3) environmental protection of the present invention, security are good, and nontoxic non-corrosiveness is free from environmental pollution, safety and stability.
Embodiment
Below in conjunction with embodiment, the present invention is further illustrated.
embodiment 1.
Take stearic acid 1 ㎏, citric acid 5 ㎏, lauric acid 1 ㎏, sodium bicarbonate 1 ㎏, chromic anhydride 0.5 ㎏, water glass 0.5 ㎏, HLB value be 14, pH value be 6 polyoxyethylene nonylphenol ether 4 ㎏, water 87 ㎏, be placed in container, stir, obtain metal cleaner.
The metal parts of the metal cleaner cleaning obtained with the present embodiment is corrosion-free, noresidue.Metal cleaner prepared by the present embodiment is not fluorine-containing, chlorine, bromine, iodine, cadmium, lead, mercury, sexavalent chrome, Polybrominated biphenyl, Poly Brominated Diphenyl Ethers, meet EN14582:2007 and ROHSDirective2011/65/EU examination criteria, environmental protection, security are good, nontoxic non-corrosiveness, free from environmental pollution, concrete detected result as shown in Table 1 and Table 2.
embodiment 2.
Take stearic acid 3 ㎏, citric acid 4 ㎏, lauric acid 2 ㎏, sodium bicarbonate 1 ㎏, chromic anhydride 1.5 ㎏, water glass 0.5 ㎏, HLB value be 15, pH value be 6 polyoxyethylene nonylphenol ether 3 ㎏, water 85 ㎏, be placed in container, stir, obtain metal cleaner.
The metal parts of the metal cleaner cleaning obtained with the present embodiment is corrosion-free, noresidue.Metal cleaner prepared by the present embodiment is not fluorine-containing, chlorine, bromine, iodine, cadmium, lead, mercury, sexavalent chrome, Polybrominated biphenyl, Poly Brominated Diphenyl Ethers, meet EN14582:2007 and ROHSDirective2011/65/EU examination criteria, environmental protection, security are good, nontoxic non-corrosiveness, free from environmental pollution, concrete detected result as shown in Table 1 and Table 2.
embodiment 3.
Take stearic acid 5 ㎏, citric acid 5 ㎏, lauric acid 5 ㎏, sodium bicarbonate 3 ㎏, chromic anhydride 2 ㎏, water glass 2 ㎏, HLB value be 15, pH value be 7 polyoxyethylene nonylphenol ether 4 ㎏, water 74 ㎏, be placed in container, stir, obtain metal cleaner.
The metal parts of the metal cleaner cleaning obtained with the present embodiment is corrosion-free, noresidue.Metal cleaner prepared by the present embodiment is not fluorine-containing, chlorine, bromine, iodine, cadmium, lead, mercury, sexavalent chrome, Polybrominated biphenyl, Poly Brominated Diphenyl Ethers, meet EN14582:2007 and ROHSDirective2011/65/EU examination criteria, environmental protection, security are good, nontoxic non-corrosiveness, free from environmental pollution, concrete detected result as shown in Table 1 and Table 2.
embodiment 4.
Take stearic acid 2 ㎏, citric acid 4 ㎏, polyoxyethylene nonylphenol ether 1 ㎏, water 82 ㎏ that lauric acid 4 ㎏, sodium bicarbonate 3 ㎏, chromic anhydride 2 ㎏, water glass 2 ㎏, model are TX-10, be placed in container, stir, obtain metal cleaner.
The metal parts of the metal cleaner cleaning obtained with the present embodiment is corrosion-free, noresidue.Metal cleaner prepared by the present embodiment is not fluorine-containing, chlorine, bromine, iodine, cadmium, lead, mercury, sexavalent chrome, Polybrominated biphenyl, Poly Brominated Diphenyl Ethers, meet EN14582:2007 and ROHSDirective2011/65/EU examination criteria, environmental protection, security are good, nontoxic non-corrosiveness, free from environmental pollution, concrete detected result as shown in Table 1 and Table 2.
embodiment 5.
Take stearic acid 4 ㎏, citric acid 4 ㎏, lauric acid 5 ㎏, sodium bicarbonate 3 ㎏, chromic anhydride 1.5 ㎏, water glass 1.3 ㎏, HLB value be 15, pH value be 6 polyoxyethylene nonylphenol ether 3 ㎏, water 78.2 ㎏, be placed in container, stir, obtain metal cleaner.
The metal parts of the metal cleaner cleaning obtained with the present embodiment is corrosion-free, noresidue.Metal cleaner prepared by the present embodiment is not fluorine-containing, chlorine, bromine, iodine, cadmium, lead, mercury, sexavalent chrome, Polybrominated biphenyl, Poly Brominated Diphenyl Ethers, meet EN14582:2007 and ROHSDirective2011/65/EU examination criteria, environmental protection, security are good, nontoxic non-corrosiveness, free from environmental pollution, concrete detected result as shown in Table 1 and Table 2.
embodiment 6.
Take stearic acid 4 ㎏, citric acid 4 ㎏, polyoxyethylene nonylphenol ether 1 ㎏, water 82 ㎏ that lauric acid 4 ㎏, sodium bicarbonate 1 ㎏, chromic anhydride 2 ㎏, water glass 2 ㎏, model are TX-10, be placed in container, stir, obtain metal cleaner.
The metal parts of the metal cleaner cleaning obtained with the present embodiment is corrosion-free, noresidue.Metal cleaner prepared by the present embodiment is not fluorine-containing, chlorine, bromine, iodine, cadmium, lead, mercury, sexavalent chrome, Polybrominated biphenyl, Poly Brominated Diphenyl Ethers, meet EN14582:2007 and ROHSDirective2011/65/EU examination criteria, environmental protection, security are good, nontoxic non-corrosiveness, free from environmental pollution, concrete detected result as shown in Table 1 and Table 2.
Table 1
。
Table 2
。
Note: (1) 1mg/Kg=1ppm=0.0001%
(2) MDL=method upper limit of detection
(3) ND=does not detect (< MDL)
(4) "--"=to content no requirement (NR).
Finally should be noted that; above embodiment is only in order to illustrate technical scheme of the present invention; but not limiting the scope of the invention; although done to explain to the present invention with reference to preferred embodiment; those of ordinary skill in the art is to be understood that; can modify to technical scheme of the present invention or equivalent replacement, and not depart from essence and the scope of technical solution of the present invention.
Claims (8)
1. a metal cleaner, is characterized in that: it is made up of the raw material of following weight percent:
Stearic acid 1-5%
Citric acid 1-5%
Lauric acid 1-5%
Sodium bicarbonate 0.5-3%
Chromic anhydride 0.5-2%
Water glass 0.5-2%
Polyoxyethylene nonylphenol ether 1-4%
Water surplus.
2. a kind of metal cleaner according to claim 1, is characterized in that: it is made up of the raw material of following weight percent:
Stearic acid 2-5%
Citric acid 3-5%
Lauric acid 3-5%
Sodium bicarbonate 1-3%
Chromic anhydride 1-2%
Water glass 1-2%
Polyoxyethylene nonylphenol ether 1-3%
Water surplus.
3. a kind of metal cleaner according to claim 2, is characterized in that: it is made up of the raw material of following weight percent:
Stearic acid 2%
Citric acid 4%
Lauric acid 4%
Sodium bicarbonate 3%
Chromic anhydride 2%
Water glass 2%
Polyoxyethylene nonylphenol ether 1%
Water surplus.
4. a kind of metal cleaner according to claim 1, is characterized in that: it is made up of the raw material of following weight percent:
Stearic acid 1-4%
Citric acid 1-4%
Lauric acid 1-5%
Sodium bicarbonate 1-3%
Chromic anhydride 0.5-2%
Water glass 0.5-1.5%
Polyoxyethylene nonylphenol ether 1-3%
Water surplus.
5. a kind of metal cleaner according to claim 4, is characterized in that: it is made up of the raw material of following weight percent:
Stearic acid 4%
Citric acid 4%
Lauric acid 5%
Sodium bicarbonate 3%
Chromic anhydride 1.5%
Water glass 1.3%
Polyoxyethylene nonylphenol ether 3%
Water surplus.
6. a kind of metal cleaner according to claim 1, is characterized in that: the HLB value of described polyoxyethylene nonylphenol ether is 14-15, and the pH value of described polyoxyethylene nonylphenol ether is 6-7.
7. a kind of metal cleaner according to claim 1, is characterized in that: the polyoxyethylene nonylphenol ether of described polyoxyethylene nonylphenol ether to be model be TX-10.
8. a kind of metal cleaner according to any one of claim 1-7, is characterized in that: its preparation method comprises the following steps:
A, weighing: weigh each component according to formula ratio;
B, spice: the stearic acid weighed in step a, citric acid, lauric acid, sodium bicarbonate, chromic anhydride, water glass, polyoxyethylene nonylphenol ether and water are placed in container, stir, obtain described metal cleaner.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310114759.8A CN104099622B (en) | 2013-04-03 | 2013-04-03 | A kind of metal cleaner |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310114759.8A CN104099622B (en) | 2013-04-03 | 2013-04-03 | A kind of metal cleaner |
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| Publication Number | Publication Date |
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| CN104099622A CN104099622A (en) | 2014-10-15 |
| CN104099622B true CN104099622B (en) | 2016-03-23 |
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| CN201310114759.8A Active CN104099622B (en) | 2013-04-03 | 2013-04-03 | A kind of metal cleaner |
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Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104328444A (en) * | 2014-10-23 | 2015-02-04 | 苏州莱特复合材料有限公司 | Rust remover for surface of powder metallurgy material and preparation method of rust remover |
| WO2016176793A1 (en) * | 2015-05-03 | 2016-11-10 | 南通启秀门窗有限公司 | Metal window cleaning agent |
| EP4208031A1 (en) * | 2020-09-03 | 2023-07-12 | DH Technologies Development Pte. Ltd. | Fast and effective conditioning solution for neutral capillary used in capillary isoelectric focusing |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3583923A (en) * | 1970-05-26 | 1971-06-08 | Grace W R & Co | Cleaning composition |
| CN1068601A (en) * | 1991-07-16 | 1993-02-03 | 孙天庆 | A kind of clean-out system and production technique thereof |
| CN101413129A (en) * | 2008-11-29 | 2009-04-22 | 江西省宜春市瑞思博化工有限公司 | Anti-rust metal detergent |
| CN101880885A (en) * | 2010-06-27 | 2010-11-10 | 金宏 | Cleaning agent special for galvanizing equipment and using method thereof |
| CN102994250A (en) * | 2012-12-06 | 2013-03-27 | 启东市海鹰阀门有限公司 | Oven cleaning agent |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60177191A (en) * | 1984-02-23 | 1985-09-11 | Kao Corp | Regenerating assistant for metal cleaning liquid |
| CA2453192A1 (en) * | 2003-06-26 | 2004-12-26 | John G. Lenhart | Cleaning formulations and methods for manufacturing the same |
| US20090120457A1 (en) * | 2007-11-09 | 2009-05-14 | Surface Chemistry Discoveries, Inc. | Compositions and method for removing coatings and preparation of surfaces for use in metal finishing, and manufacturing of electronic and microelectronic devices |
-
2013
- 2013-04-03 CN CN201310114759.8A patent/CN104099622B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3583923A (en) * | 1970-05-26 | 1971-06-08 | Grace W R & Co | Cleaning composition |
| CN1068601A (en) * | 1991-07-16 | 1993-02-03 | 孙天庆 | A kind of clean-out system and production technique thereof |
| CN101413129A (en) * | 2008-11-29 | 2009-04-22 | 江西省宜春市瑞思博化工有限公司 | Anti-rust metal detergent |
| CN101880885A (en) * | 2010-06-27 | 2010-11-10 | 金宏 | Cleaning agent special for galvanizing equipment and using method thereof |
| CN102994250A (en) * | 2012-12-06 | 2013-03-27 | 启东市海鹰阀门有限公司 | Oven cleaning agent |
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| CN104099622A (en) | 2014-10-15 |
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Address after: 523000 Pu heart village, two row Town, Shek Pai Town, Guangdong, Dongguan Patentee after: Guangdong Jian Xin Polytron Technologies Inc Address before: 523333, Guangdong City, Dongguan province stone Pai Town, Po two road Jintian restaurant, 100 meters on the left, Dongguan Xin Xin Electronic Materials Co., Ltd. Patentee before: Dongguan Jianxin Electronic Material Co., Ltd. |