CN104099617A - Oil and rust removing agent - Google Patents
Oil and rust removing agent Download PDFInfo
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- CN104099617A CN104099617A CN201410304256.1A CN201410304256A CN104099617A CN 104099617 A CN104099617 A CN 104099617A CN 201410304256 A CN201410304256 A CN 201410304256A CN 104099617 A CN104099617 A CN 104099617A
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Abstract
The invention relates to the field of workpiece cleaning, in particular to oil and rust removing agent and a preparation method thereof. The oil and rust removing agent comprises the following components in percentage by weight: 5.6-9.8% of hydrochloric acid, 5-10% of emulsifying agent, 1-5% of penetrating agent, 2-7% of hexamine, 1-5% of thiourea, 2-5% of lauryl sodium sulfate, 2-5% of sodium chloride, 0.01-0.03% of defoaming agent, 0.01-0.03% of flavoring agent, and the balance of water to 100%. The preparation method comprises the following steps: the sodium chloride, the flavoring agent and the defoaming agent are dissolved by using part water; the hydrochloric acid, the emulsifying agent and the penetrating agent are added in the rest water for evenly mixing; and then, the hexamine, the thiourea, the lauryl sodium sulfate and solution are added for evenly mixing. The oil and rust removing agent has the advantages of quick dirt removal, good dirt removing effect, no harm to skin and clothes and no environmental pollution, and can be widely applied to the oil and rust removal of such workpieces as paint-sprayed workpieces, plastic-sprayed workpieces, film workpieces, electroplated workpieces and zinc oxide workpieces.
Description
(1) technical field
The present invention relates to workpiece cleaning field, particularly a kind of oil-removing rust-removing agent.
(2) background technology
Degreaser is the complex mixture with the organic and inorganic chemical composition of water-based, to utilize emulsification or saponification and the industrial degreaser developed, all have been widely used at industrial circles such as metal processing, food, weaving, traffic, boats and ships, building, electrical equipment, chemical industry, although the surface matrix of cleaning is not quite similar, but it is consistent cleaning object, be all recover the cleanliness factor of stromal surface and keep stromal surface integrity.Degreaser ubiquity in the market scent of, skin, clothes is had to the defects such as certain corrosive nature, and after using, cannot reuse need discharge, caused certain environmental pollution, be unfavorable for environmental protection.
(3) summary of the invention
The present invention is in order to make up the defect of prior art, provide a kind of smell low, do not corrode clothes and skin, use need not discharge, the oil-removing rust-removing agent of meet the requirement of environmental protection.
The present invention is achieved through the following technical solutions:
A kind of oil-removing rust-removing agent, it is characterized in that, each weight percentages of components is: hydrochloric acid 5.6～9.8%, emulsifying agent 5～10%, permeate agent 1～5%, vulkacit H 2～7%, thiocarbamide 1～5%, sodium lauryl sulphate 2～5%, sodium-chlor 2～5%, defoamer 0.01～0.03%, flavouring agent 0.01～0.03%, surplus is that water adds to 100%, wherein hydrochloric acid is the pure hydrochloric acid after aqueous hydrochloric acid converts, emulsifying agent is peregal, peregal os-15, paregal O-20, OP-10, any in EL or OP (TX), permeate agent is JFC or Sodium dodecylbenzene sulfonate, defoamer is dimethylbenzene silicone oil, polyester modification silicone oil, any in tributyl phosphate or higher alcohols.
Further, described emulsifying agent is OP-10, and described permeate agent is JFC, and described defoamer is tributyl phosphate.
Further, each weight percentages of components is: hydrochloric acid 7%, and OP-10 8%, JFC 3%, vulkacit H 5%, thiocarbamide 3%, sodium lauryl sulphate 3.5%, sodium-chlor 3%, tributyl phosphate 0.02%, flavouring agent 0.02%, surplus is that water adds to 100%.
The preparation method of above-mentioned oil-removing rust-removing agent, it is characterized in that, sodium-chlor, flavouring agent and defoamer are dissolved into after solution for subsequent use with part water completely, the temperature of water is 30-50 DEG C, then after adding hydrochloric acid, emulsifying agent and permeate agent in remaining water, stir, add again the solution that vulkacit H, thiocarbamide, sodium lauryl sulphate and dissolving are good, stir.
The outward appearance of oil-removing rust-removing agent of the present invention is light yellow, brown or colourless liquid, needn't dilute with water when use, just can use in room temperature, workpiece is immersed in in this invention 1～15 minute just can be cleaned up the greasy dirt of workpiece surface, rusty stain, do not fire not quick-friedly, non-ferrous metal is corrosive.
The invention has the beneficial effects as follows:
The material such as greasy dirt, rusty stain oxide compound of energy fast eliminating of the present invention metallic surface, metallic matrix is not produced to excessive erosion and Hydrogen Brittleness Phenomena, have no irritating odor, harmless to people, corrosion-free to skin, clothing, after using without discharge, while re-using, can dose according to the area of cleaning products, weight, muddy can precipitate down pond, after cleaning, can continue use, can be widely used in spray paint, the workpiece of plastic-blasting, film, plating, zinc oxide etc. deoils and derusts.
(4) embodiment
That the mulser in following examples uses is OP-10, it can be by any equivalent replacement in peregal, peregal os-15, paregal O-20, EL or OP (TX), permeate agent is JFC, it can be replaced by Sodium dodecylbenzene sulfonate equivalent, defoamer is tributyl phosphate, it can be replaced by any equivalent in dimethylbenzene silicone oil, polyester modification silicone oil, tributyl phosphate or higher alcohols, and what hydrochloric acid soln used is the hydrochloric acid soln of weight fraction 28%; In the process of dissolving sodium-chlor, flavouring agent and defoamer, the amount of water can be determined according to the amount of sodium-chlor, as long as can be dissolved, in order to accelerate dissolution rate, can also limit heating edge dissolve.
Embodiment mono-: each weight percentages of components formula is as follows:
28% hydrochloric acid: 20kg
OP-10：5kg
JFC：1kg
Vulkacit H: 2kg
Thiocarbamide: 1kg
Sodium lauryl sulphate: 2kg
Sodium-chlor: 2kg
Tributyl phosphate: 0.01kg
Flavouring agent: 0.01kg
Water: 66.98kg
Preparation method: first by 2kg sodium-chlor, 0.01kg flavouring agent and 0.01kg for tributyl phosphate the water dissolution of 10kg30～50 DEG C be diluted to solution for standby, then after adding 20kg 28% hydrochloric acid, 5kg OP-10 and 1kg JFC to stir in remaining 56.98kg water, the solution that adds 2kg vulkacit H, 1kg thiocarbamide, 2kg sodium lauryl sulphate again and dissolved, stirs and obtains 100kg oil-removing rust-removing agent of the present invention;
Embodiment bis-: each weight percentages of components formula is as follows:
28% hydrochloric acid: 35kg
OP-10：10kg
JFC：5kg
Vulkacit H: 7kg
Thiocarbamide: 5kg
Sodium lauryl sulphate: 5kg
Sodium-chlor: 5kg
Tributyl phosphate: 0.03kg
Flavouring agent: 0.03kg
Water: 27.94kg
Preparation method: first by 5kg sodium-chlor, 0.03kg flavouring agent and 0.03kg for tributyl phosphate the water dissolution of 10kg30～50 DEG C be diluted to solution for standby, then after adding 35kg 28% hydrochloric acid, 10kg OP-10 and 5kg JFC to stir in remaining 17.94kg water, the solution that adds 7kg vulkacit H, 5kg thiocarbamide, 5kg sodium lauryl sulphate again and dissolved, stirs and obtains 100kg oil-removing rust-removing agent of the present invention.
Embodiment tri-: each weight percentages of components formula is as follows:
28% hydrochloric acid: 25kg
OP-10：8kg
JFC：3kg
Vulkacit H: 5kg
Thiocarbamide: 3kg
Sodium lauryl sulphate: 3.5kg
Sodium-chlor: 3kg
Tributyl phosphate: 0.02kg
Flavouring agent: 0.02kg
Water: 49.46kg
Preparation method: first by 3kg sodium-chlor, 0.02kg flavouring agent and 0.02kg for tributyl phosphate the water dissolution of 10kg30～50 DEG C be diluted to solution for standby, then after adding 25kg 28% hydrochloric acid, 8kg OP-10 and 3kg JFC to stir in remaining 39.46kg water, the solution that adds 5kg vulkacit H, 3kg thiocarbamide, 3.5kg sodium lauryl sulphate again and dissolved, stirs and obtains 100kg oil-removing rust-removing agent of the present invention.
Embodiment tetra-: each weight percentages of components formula is as follows:
28% hydrochloric acid: 30kg
OP-10：5kg
JFC：5kg
Vulkacit H: 4kg
Thiocarbamide: 2kg
Sodium lauryl sulphate: 3kg
Sodium-chlor: 4kg
Tributyl phosphate: 0.03kg
Flavouring agent: 0.03kg
Water: 46.94
First by 4kg sodium-chlor, 0.03kg flavouring agent and 0.03kg for tributyl phosphate the water dissolution of 10kg30～50 DEG C be diluted to solution for standby, then after adding 30kg 28% hydrochloric acid, 5kg OP-10 and 5kg JFC to stir in remaining 46.94kg water, the solution that adds 4kg vulkacit H, 2kg thiocarbamide, 3kg sodium lauryl sulphate again and dissolved, stirs and obtains 100kg oil-removing rust-removing agent of the present invention.
Except technical characterictic described in specification sheets, all the other technical characterictics are those skilled in the art's known technology.
Claims (4)
1. an oil-removing rust-removing agent, it is characterized in that, each weight percentages of components is: hydrochloric acid 5.6～9.8%, emulsifying agent 5～10%, permeate agent 1～5%, vulkacit H 2～7%, thiocarbamide 1～5%, sodium lauryl sulphate 2～5%, sodium-chlor 2～5%, defoamer 0.01～0.03%, flavouring agent 0.01～0.03%, surplus is that water adds to 100%, wherein hydrochloric acid is the pure hydrochloric acid after aqueous hydrochloric acid converts, emulsifying agent is peregal, peregal os-15, paregal O-20, OP-10, (it is accurate to express for EL or OP (TX)?) in any, permeate agent is JFC or Sodium dodecylbenzene sulfonate, defoamer is dimethylbenzene silicone oil, polyester modification silicone oil, any in tributyl phosphate or higher alcohols.
2. oil-removing rust-removing agent according to claim 1, is characterized in that, described emulsifying agent is OP-10, and described permeate agent is JFC, and described defoamer is tributyl phosphate.
3. oil-removing rust-removing agent according to claim 2, it is characterized in that, each weight percentages of components is: hydrochloric acid 7%, OP-10 8%, JFC 3%, vulkacit H 5%, thiocarbamide 3%, sodium lauryl sulphate 3.5%, sodium-chlor 3%, tributyl phosphate 0.02%, flavouring agent 0.02%, surplus is that water adds to 100%.
4. the preparation method of the oil-removing rust-removing agent described in claims 1 to 3 any one, it is characterized in that, sodium-chlor, flavouring agent and defoamer are dissolved into after solution for subsequent use with part water completely, the temperature of water is 30-50 DEG C, then after adding hydrochloric acid, emulsifying agent and permeate agent in remaining water, stir, add again the solution that vulkacit H, thiocarbamide, sodium lauryl sulphate and dissolving are good, stir.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410304256.1A CN104099617B (en) | 2014-06-30 | 2014-06-30 | A kind of oil-removing rust-removing agent |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410304256.1A CN104099617B (en) | 2014-06-30 | 2014-06-30 | A kind of oil-removing rust-removing agent |
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| CN104099617A true CN104099617A (en) | 2014-10-15 |
| CN104099617B CN104099617B (en) | 2016-04-13 |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104630798A (en) * | 2015-02-05 | 2015-05-20 | 陕西凯利清洗有限公司 | Acid-washing rust remover for carbon steel product and application method of acid-washing rust remover |
| CN106167905A (en) * | 2016-08-12 | 2016-11-30 | 湖南中汉高分子材料科技有限公司 | A kind of efficiently room temperature antirust rust cleaning coating |
| CN107043937A (en) * | 2017-05-10 | 2017-08-15 | 朱敏 | A kind of environment-protecting comprehensive inorganic agent |
| CN107059020A (en) * | 2017-05-10 | 2017-08-18 | 朱敏 | A kind of preparation technology of environment-protecting comprehensive inorganic agent |
| CN110467974A (en) * | 2019-08-12 | 2019-11-19 | 山东聚力焊接材料有限公司 | Solid welding wire surface degreasing derusting mixing cleaning agent, manufacturing method and application method |
| CN112226777A (en) * | 2020-10-19 | 2021-01-15 | 武汉科润表面新材料有限公司 | Normal-temperature efficient degreasing agent for coiled steel silicon steel |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1479591A (en) * | 1974-07-01 | 1977-07-13 | English A | Method of removing rust and a rust removing composition |
| CN1778995A (en) * | 2005-08-03 | 2006-05-31 | 夏光甫 | Multifunctional high-efficient metal anti-rusting liquid for removing oil |
| CN101144167A (en) * | 2007-10-24 | 2008-03-19 | 定襄银河镀锌法兰有限公司 | Brightening rust removing agent |
| CN103469223A (en) * | 2013-09-30 | 2013-12-25 | 昆山市巴城镇顺拓工程机械配件厂 | Brightening and derusting agent |
| US20140116708A1 (en) * | 2012-11-01 | 2014-05-01 | Halliburton Energy Services, Inc. | Synergistic corrosion inhibitor intensifiers for acidizing emulsions |
-
2014
- 2014-06-30 CN CN201410304256.1A patent/CN104099617B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1479591A (en) * | 1974-07-01 | 1977-07-13 | English A | Method of removing rust and a rust removing composition |
| CN1778995A (en) * | 2005-08-03 | 2006-05-31 | 夏光甫 | Multifunctional high-efficient metal anti-rusting liquid for removing oil |
| CN101144167A (en) * | 2007-10-24 | 2008-03-19 | 定襄银河镀锌法兰有限公司 | Brightening rust removing agent |
| US20140116708A1 (en) * | 2012-11-01 | 2014-05-01 | Halliburton Energy Services, Inc. | Synergistic corrosion inhibitor intensifiers for acidizing emulsions |
| CN103469223A (en) * | 2013-09-30 | 2013-12-25 | 昆山市巴城镇顺拓工程机械配件厂 | Brightening and derusting agent |
Non-Patent Citations (2)
| Title |
|---|
| 张俊智: "《粉末涂料与涂装工艺学》", 31 March 2003, 化学工业出版社 * |
| 徐永成: "钢铁盐酸除锈常用添加剂及应用", 《四川冶金》 * |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104630798A (en) * | 2015-02-05 | 2015-05-20 | 陕西凯利清洗有限公司 | Acid-washing rust remover for carbon steel product and application method of acid-washing rust remover |
| CN106167905A (en) * | 2016-08-12 | 2016-11-30 | 湖南中汉高分子材料科技有限公司 | A kind of efficiently room temperature antirust rust cleaning coating |
| CN107043937A (en) * | 2017-05-10 | 2017-08-15 | 朱敏 | A kind of environment-protecting comprehensive inorganic agent |
| CN107059020A (en) * | 2017-05-10 | 2017-08-18 | 朱敏 | A kind of preparation technology of environment-protecting comprehensive inorganic agent |
| CN110467974A (en) * | 2019-08-12 | 2019-11-19 | 山东聚力焊接材料有限公司 | Solid welding wire surface degreasing derusting mixing cleaning agent, manufacturing method and application method |
| CN112226777A (en) * | 2020-10-19 | 2021-01-15 | 武汉科润表面新材料有限公司 | Normal-temperature efficient degreasing agent for coiled steel silicon steel |
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| Publication number | Publication date |
|---|---|
| CN104099617B (en) | 2016-04-13 |
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