CN104098854A - High-temperature-resistant PVC pipe for water supply engineering and preparation method for high-temperature-resistant PVC pipe - Google Patents
High-temperature-resistant PVC pipe for water supply engineering and preparation method for high-temperature-resistant PVC pipe Download PDFInfo
- Publication number
- CN104098854A CN104098854A CN201410272031.2A CN201410272031A CN104098854A CN 104098854 A CN104098854 A CN 104098854A CN 201410272031 A CN201410272031 A CN 201410272031A CN 104098854 A CN104098854 A CN 104098854A
- Authority
- CN
- China
- Prior art keywords
- parts
- temperature
- pvc pipe
- resistant pvc
- bis
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 13
- 238000002360 preparation method Methods 0.000 title claims description 11
- 238000012407 engineering method Methods 0.000 title 1
- -1 1-2 parts of 5 Chemical compound 0.000 claims abstract description 28
- PXDJXZJSCPSGGI-UHFFFAOYSA-N palmityl palmitate Chemical compound CCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCC PXDJXZJSCPSGGI-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000002253 acid Substances 0.000 claims abstract description 13
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 claims abstract description 8
- UKWUOTZGXIZAJC-UHFFFAOYSA-N 4-nitrosalicylic acid Chemical compound OC(=O)C1=CC=C([N+]([O-])=O)C=C1O UKWUOTZGXIZAJC-UHFFFAOYSA-N 0.000 claims abstract description 7
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000004593 Epoxy Substances 0.000 claims abstract description 7
- 239000004594 Masterbatch (MB) Substances 0.000 claims abstract description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000004200 microcrystalline wax Substances 0.000 claims abstract description 7
- 235000019808 microcrystalline wax Nutrition 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 7
- 229920005989 resin Polymers 0.000 claims abstract description 7
- 239000011347 resin Substances 0.000 claims abstract description 7
- WSFQLUVWDKCYSW-UHFFFAOYSA-M sodium;2-hydroxy-3-morpholin-4-ylpropane-1-sulfonate Chemical compound [Na+].[O-]S(=O)(=O)CC(O)CN1CCOCC1 WSFQLUVWDKCYSW-UHFFFAOYSA-M 0.000 claims abstract description 7
- TXQVDVNAKHFQPP-UHFFFAOYSA-N [3-hydroxy-2,2-bis(hydroxymethyl)propyl] octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(CO)(CO)CO TXQVDVNAKHFQPP-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000004519 grease Substances 0.000 claims abstract description 4
- 230000001050 lubricating effect Effects 0.000 claims abstract description 4
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 20
- 239000004800 polyvinyl chloride Substances 0.000 claims description 20
- 239000000463 material Substances 0.000 claims description 15
- 229920001903 high density polyethylene Polymers 0.000 claims description 12
- 239000004700 high-density polyethylene Substances 0.000 claims description 12
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 claims description 9
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 claims description 9
- 239000000945 filler Substances 0.000 claims description 9
- 239000008187 granular material Substances 0.000 claims description 9
- 238000005469 granulation Methods 0.000 claims description 9
- 230000003179 granulation Effects 0.000 claims description 9
- 238000005453 pelletization Methods 0.000 claims description 9
- CIRMGZKUSBCWRL-LHLOQNFPSA-N (e)-10-[2-(7-carboxyheptyl)-5,6-dihexylcyclohex-3-en-1-yl]dec-9-enoic acid Chemical compound CCCCCCC1C=CC(CCCCCCCC(O)=O)C(\C=C\CCCCCCCC(O)=O)C1CCCCCC CIRMGZKUSBCWRL-LHLOQNFPSA-N 0.000 claims description 6
- LEACJMVNYZDSKR-UHFFFAOYSA-N 2-octyldodecan-1-ol Chemical compound CCCCCCCCCCC(CO)CCCCCCCC LEACJMVNYZDSKR-UHFFFAOYSA-N 0.000 claims description 6
- GBRSPKXOFRTAHS-UHFFFAOYSA-N 5-(4-nitrophenyl)-1,2-oxazole-3-carboxylic acid Chemical compound O1N=C(C(=O)O)C=C1C1=CC=C([N+]([O-])=O)C=C1 GBRSPKXOFRTAHS-UHFFFAOYSA-N 0.000 claims description 6
- 229910002012 Aerosil® Inorganic materials 0.000 claims description 6
- 229910052582 BN Inorganic materials 0.000 claims description 6
- 229940126062 Compound A Drugs 0.000 claims description 6
- NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 claims description 6
- 235000021355 Stearic acid Nutrition 0.000 claims description 6
- 125000004423 acyloxy group Chemical group 0.000 claims description 6
- BTFJIXJJCSYFAL-UHFFFAOYSA-N arachidyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCO BTFJIXJJCSYFAL-UHFFFAOYSA-N 0.000 claims description 6
- 235000013871 bee wax Nutrition 0.000 claims description 6
- 239000012166 beeswax Substances 0.000 claims description 6
- 238000001354 calcination Methods 0.000 claims description 6
- 239000003245 coal Substances 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 6
- 238000007599 discharging Methods 0.000 claims description 6
- 150000002148 esters Chemical class 0.000 claims description 6
- 239000005038 ethylene vinyl acetate Substances 0.000 claims description 6
- 229910052900 illite Inorganic materials 0.000 claims description 6
- 239000003595 mist Substances 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- VGIBGUSAECPPNB-UHFFFAOYSA-L nonaaluminum;magnesium;tripotassium;1,3-dioxido-2,4,5-trioxa-1,3-disilabicyclo[1.1.1]pentane;iron(2+);oxygen(2-);fluoride;hydroxide Chemical compound [OH-].[O-2].[O-2].[O-2].[O-2].[O-2].[F-].[Mg+2].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[K+].[K+].[K+].[Fe+2].O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2 VGIBGUSAECPPNB-UHFFFAOYSA-L 0.000 claims description 6
- 239000005332 obsidian Substances 0.000 claims description 6
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 6
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 6
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims description 6
- 229910052851 sillimanite Inorganic materials 0.000 claims description 6
- 239000008117 stearic acid Substances 0.000 claims description 6
- JNXDCMUUZNIWPQ-UHFFFAOYSA-N trioctyl benzene-1,2,4-tricarboxylate Chemical compound CCCCCCCCOC(=O)C1=CC=C(C(=O)OCCCCCCCC)C(C(=O)OCCCCCCCC)=C1 JNXDCMUUZNIWPQ-UHFFFAOYSA-N 0.000 claims description 6
- 239000001993 wax Substances 0.000 claims description 6
- HHRAWPICZKGGFQ-UHFFFAOYSA-N 2-methyl-4,6-bis(octylsulfanylmethylidene)cyclohex-2-en-1-ol Chemical compound C(CCCCCCC)SC=C1C(C(=CC(C1)=CSCCCCCCCC)C)O HHRAWPICZKGGFQ-UHFFFAOYSA-N 0.000 claims description 3
- MXRIRQGCELJRSN-UHFFFAOYSA-N O.O.O.[Al] Chemical compound O.O.O.[Al] MXRIRQGCELJRSN-UHFFFAOYSA-N 0.000 claims description 3
- 235000010290 biphenyl Nutrition 0.000 claims description 3
- 239000004305 biphenyl Substances 0.000 claims description 3
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 3
- 238000001125 extrusion Methods 0.000 claims description 3
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims description 3
- 229920003210 poly(4-hydroxy benzoic acid) Polymers 0.000 claims description 3
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 3
- 229920001652 poly(etherketoneketone) Polymers 0.000 claims description 3
- 230000032683 aging Effects 0.000 abstract description 3
- 238000000034 method Methods 0.000 abstract description 2
- GAODDBNJCKQQDY-UHFFFAOYSA-N 2-methyl-4,6-bis(octylsulfanylmethyl)phenol Chemical compound CCCCCCCCSCC1=CC(C)=C(O)C(CSCCCCCCCC)=C1 GAODDBNJCKQQDY-UHFFFAOYSA-N 0.000 abstract 1
- KLLLJCACIRKBDT-UHFFFAOYSA-N 2-phenyl-1H-indole Chemical compound N1C2=CC=CC=C2C=C1C1=CC=CC=C1 KLLLJCACIRKBDT-UHFFFAOYSA-N 0.000 abstract 1
- BQPNUOYXSVUVMY-UHFFFAOYSA-N [4-[2-(4-diphenoxyphosphoryloxyphenyl)propan-2-yl]phenyl] diphenyl phosphate Chemical compound C=1C=C(OP(=O)(OC=2C=CC=CC=2)OC=2C=CC=CC=2)C=CC=1C(C)(C)C(C=C1)=CC=C1OP(=O)(OC=1C=CC=CC=1)OC1=CC=CC=C1 BQPNUOYXSVUVMY-UHFFFAOYSA-N 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- NQOFUSUDAMVORD-UHFFFAOYSA-N bis(6-methylheptyl) phenyl phosphate Chemical compound CC(C)CCCCCOP(=O)(OCCCCCC(C)C)OC1=CC=CC=C1 NQOFUSUDAMVORD-UHFFFAOYSA-N 0.000 abstract 1
- 238000005260 corrosion Methods 0.000 abstract 1
- 230000007797 corrosion Effects 0.000 abstract 1
- IRFPIPNMASANJY-UHFFFAOYSA-L dimethyltin(2+);2-(6-methylheptoxy)-2-oxoethanethiolate Chemical compound CC(C)CCCCCOC(=O)CS[Sn](C)(C)SCC(=O)OCCCCCC(C)C IRFPIPNMASANJY-UHFFFAOYSA-L 0.000 abstract 1
- 229910021485 fumed silica Inorganic materials 0.000 abstract 1
- 235000021388 linseed oil Nutrition 0.000 abstract 1
- 239000000944 linseed oil Substances 0.000 abstract 1
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 abstract 1
- 238000003672 processing method Methods 0.000 abstract 1
- 238000005516 engineering process Methods 0.000 description 2
- 230000003628 erosive effect Effects 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Lubricants (AREA)
Abstract
The invention discloses a high-temperature-resistant PVC pipe for water supply engineering, which is prepared from the following raw materials in parts by weight: 56-78 parts of SG-2 type PVC resin, 22-34 parts of poly(ether-ketone-ketone), 16-28 parts of polyparahydroxybenzoic acid, 15-20 parts of fumed silica, 12-18 parts of cubic boron nitride micro powder, 3-5 parts of hexadecyl palmitate, 2-4 parts of pentaerythritol stearate, 1.5-2.5 parts of dimethyltin bis(isooctylmercaptoacetate), 1-2 parts of barium laurate, 0.5-1.5 parts of zinc naphthenate, 1-2 parts of 5,2-phenylindole, 4-8 parts of epoxy linseed oil, 10-15 parts of bisphenol-A bis(diphenyl phosphate), 5-10 parts of antimonous oxide, 4-8 parts of hydrated alumina, 4-6 parts of microcrystalline wax, 2.5-4.5 parts of molykote lubricating grease, 15-20 parts of filling master batch, 1-2 parts of 2,4-bis(n-octylthiomethyl)-6-methylphenol and 2-3 parts of diisooctyl phenyl phosphate. The PVC pipe disclosed by the invention is excellent in high temperature resistance, can normally wok at the high temperature of 105-125 DEG C, meanwhile, is good in flame retardance, mechanical property, ageing resistance and corrosion resistance, the processing method of the pipe is simple and easy to operate, the cost is low, and the method is suitable for popularization and application.
Description
Technical field
The present invention relates to a kind of pvc pipe material and preparation method thereof, be specifically related to high temperature resistant PVC tubing and preparation method thereof for a kind of water supply engineering.
Background technology
Pvc pipe material is good because having mechanical property, good insulation preformance, and erosion resistance is strong, and long service life is lightweight, be easy to the plurality of advantages such as transportation, installation, is widely used in various water supply engineerings.In recent years, along with the fast development of scientific and technological level and improving constantly of living standards of the people, more and more high to the performance requriements of PVC water-feeding pipes, PVC water-feeding pipes resistance to elevated temperatures is in the market poor, easily softening under hot conditions, cannot long term operation, greatly reduce the work-ing life of PVC pipe, limited its range of application.Therefore, be badly in need of a kind of water supply engineering of exploitation high temperature resistant PVC tubing, to meet market demands.
Summary of the invention
The deficiency existing for prior art, technical problem to be solved by this invention is to provide a kind of cost low
High temperature resistant PVC tubing and preparation method thereof for the water supply engineering honest and clean, resistance to elevated temperatures is excellent, to meet market demands.
For solving the problems of the technologies described above, the technical solution used in the present invention is:
A kind of water supply engineering high temperature resistant PVC tubing, raw material by following weight part is made: SG-2 type polyvinyl chloride resin 56-78, PEKK 22-34, ekonol 16-28, aerosil 15-20, cubic boron nitride micro mist 12-18, hexadecyl palmitate 3-5, pentaerythritol stearate 2-4, dimethyl dimercapto 2-ethyl hexyl ethanoate tin 1.5-2.5, barium laurate 1-2, zinc naphthenate 0.5-1.5, 2-phenylindone 1-2, epoxy Toenol 1140 4-8, dihydroxyphenyl propane-bis-(diphenyl phosphoester) 10-15, antimonous oxide 5-10, hydrated aluminum oxide 4-8, microcrystalline wax 4-6, rub and make every effort to overcome lubricating grease 2.5-4.5, filler parent granule 15-20, 2, 4-bis-(n-octylthiomethylene)-6-methylphenol 1-2, diisooctyl phenyl phosphite 2-3,
The preparation method of described filler parent granule is as follows: a, take the raw material of following weight part: sillimanite 30-40, obsidian 20-30, coal gangue 15-20, illite 10-15, sec.-propyl three (dioctylphyrophosphoric acid acyloxy) titanic acid ester 2-3, oxyethyl group aminopropyl polydimethylsiloxane 1.5-2.5, stearic acid 3-5, trioctyl trimellitate 8-12, dioctyl phthalate (DOP) 5-10, linoleic acid dimer multipolymer 2-3, octyl dodecanol beeswax acid esters 2-3, OP wax 4-6, EPSAN 25-35, ethylene-vinyl acetate copolymer 20-30, high density polyethylene(HDPE) 40-50, b, get sillimanite, illite mixes, pulverized 150-200 mesh sieve, 820-880 ℃ of calcining 1-2h, after being cooled to room temperature, add sec.-propyl three (dioctylphyrophosphoric acid acyloxy) titanic acid ester, trioctyl trimellitate, octyl dodecanol beeswax acid esters, after high-speed mixing 4-6min, together input in double-screw extruding pelletizing machine with EPSAN, melt extrude granulation and obtain master batch A, c, get obsidian, coal gangue mixes, pulverized 150-200 mesh sieve, 900-950 ℃ of calcining 1-2h, after being cooled to room temperature, add oxyethyl group aminopropyl polydimethylsiloxane, dioctyl phthalate (DOP), linoleic acid dimer multipolymer, after high-speed mixing 3-5min, together input in double-screw extruding pelletizing machine with ethylene-vinyl acetate copolymer, melt extrude granulation and obtain mother particle B, d, the above-mentioned master batch A making, mother particle B are mixed in rear input double-screw extruding pelletizing machine with high density polyethylene(HDPE), OP wax, stearic acid, melt extrude granulation and obtain required filler parent granule.
The preparation method of high temperature resistant PVC tubing for water supply engineering of the present invention, comprises the following steps:
(1) get in SG-2 type polyvinyl chloride resin, aerosil, cubic boron nitride micro mist, hexadecyl palmitate, barium laurate, zinc naphthenate, 2-phenylindone, epoxy Toenol 1140, microcrystalline wax, diisooctyl phenyl phosphite input kneader and mediate, treat that material frictional heat is to 90-100 ℃, material is entered in cold mixer and lowered the temperature, discharging when temperature drops to below 50 ℃, obtains compound A;
(2) get in surplus stock input kneader and mediate, treat that material frictional heat, to 80-90 ℃, enters material in cold mixer and lowers the temperature, discharging when temperature drops to below 45 ℃, obtains compound B;
(3) deliver to extrusion moulding in twin screw extruder after the compound A of above-mentioned gained and compound B are mixed and make tubing.
Beneficial effect of the present invention:
Pvc pipe material resistance to elevated temperatures of the present invention is excellent, can normally work for a long time under 105-125 ℃ of hot conditions, there is good flame retardant resistance, mechanical property, ageing resistance and erosion resistance, and working method of the present invention is simple to operation simultaneously, with low cost, be applicable to applying.
Embodiment
A kind of water supply engineering high temperature resistant PVC tubing, raw material by following weight part is made: SG-2 type polyvinyl chloride resin 68, PEKK 32, ekonol 24, aerosil 18, cubic boron nitride micro mist 16, hexadecyl palmitate 4, pentaerythritol stearate 3, dimethyl dimercapto 2-ethyl hexyl ethanoate tin 2, barium laurate 1.5, zinc naphthenate 1, 2-phenylindone 1.5, epoxy Toenol 1140 6, dihydroxyphenyl propane-bis-(diphenyl phosphoester) 12, antimonous oxide 8, hydrated aluminum oxide 6, microcrystalline wax 5, rub and make every effort to overcome lubricating grease 3.5, filler parent granule 18, 2, 4-bis-(n-octylthiomethylene)-6-methylphenol 1.5, diisooctyl phenyl phosphite 2.5,
The preparation method of described filler parent granule is as follows: a, take the raw material of following weight part: sillimanite 30, obsidian 30, coal gangue 15, illite 15, sec.-propyl three (dioctylphyrophosphoric acid acyloxy) titanic acid ester 2, oxyethyl group aminopropyl polydimethylsiloxane 2, stearic acid 4, trioctyl trimellitate 8, dioctyl phthalate (DOP) 7, linoleic acid dimer multipolymer 2, octyl dodecanol beeswax acid esters 2, OP wax 5, EPSAN 25, ethylene-vinyl acetate copolymer 25, high density polyethylene(HDPE) 45, b, get sillimanite, illite mixes, pulverized 200 mesh sieves, 850 ℃ of calcining 2h, after being cooled to room temperature, add sec.-propyl three (dioctylphyrophosphoric acid acyloxy) titanic acid ester, trioctyl trimellitate, octyl dodecanol beeswax acid esters, after high-speed mixing 4min, together input in double-screw extruding pelletizing machine with EPSAN, melt extrude granulation and obtain master batch A, c, get obsidian, coal gangue mixes, pulverized 200 mesh sieves, 920 ℃ of calcining 2h, after being cooled to room temperature, add oxyethyl group aminopropyl polydimethylsiloxane, dioctyl phthalate (DOP), linoleic acid dimer multipolymer, after high-speed mixing 3min, input in double-screw extruding pelletizing machine with ethylene-vinyl acetate copolymer, melt extrude granulation and obtain mother particle B, d, the above-mentioned master batch A making, mother particle B are mixed in rear input double-screw extruding pelletizing machine with high density polyethylene(HDPE), OP wax, stearic acid, melt extrude granulation and obtain required filler parent granule.
The preparation method of high temperature resistant PVC tubing for water supply engineering, comprises the following steps:
(1) get in SG-2 type polyvinyl chloride resin, aerosil, cubic boron nitride micro mist, hexadecyl palmitate, barium laurate, zinc naphthenate, 2-phenylindone, epoxy Toenol 1140, microcrystalline wax, diisooctyl phenyl phosphite input kneader and mediate, treat material frictional heat to 95 ℃, material is entered in cold mixer and lowered the temperature, discharging when temperature drops to below 50 ℃, obtains compound A;
(2) get in surplus stock input kneader and mediate, treat material frictional heat to 85 ℃, material is entered in cold mixer and lowered the temperature, discharging when temperature drops to below 45 ℃, obtains compound B;
(3) deliver to extrusion moulding in twin screw extruder after the compound A of above-mentioned gained and compound B are mixed and make tubing.
The above-mentioned PVC water-feeding pipes Performance Detection making is as shown in the table:
| Test item | Detected result |
| Tensile strength (MPa) | 51 |
| Yield strength (MPa) | 56 |
| Ultimate compression strength (MPa) | 112 |
| Modulus in tension (MPa) | 4200 |
| Bending elastic modulus (GPa) | 3.8 |
| Horizontal relaxation shrinkage (%) | 2.5 |
| Aging coefficient (70 ℃, 144h) | 0.80 |
| Vicat softening temperature (℃) | 118 |
Claims (2)
1. a water supply engineering high temperature resistant PVC tubing, it is characterized in that, raw material by following weight part is made: SG-2 type polyvinyl chloride resin 56-78, PEKK 22-34, ekonol 16-28, aerosil 15-20, cubic boron nitride micro mist 12-18, hexadecyl palmitate 3-5, pentaerythritol stearate 2-4, dimethyl dimercapto 2-ethyl hexyl ethanoate tin 1.5-2.5, barium laurate 1-2, zinc naphthenate 0.5-1.5, 2-phenylindone 1-2, epoxy Toenol 1140 4-8, dihydroxyphenyl propane-bis-(diphenyl phosphoester) 10-15, antimonous oxide 5-10, hydrated aluminum oxide 4-8, microcrystalline wax 4-6, rub and make every effort to overcome lubricating grease 2.5-4.5, filler parent granule 15-20, 2, 4-bis-(n-octylthiomethylene)-6-methylphenol 1-2, diisooctyl phenyl phosphite 2-3,
The preparation method of described filler parent granule is as follows: a, take the raw material of following weight part: sillimanite 30-40, obsidian 20-30, coal gangue 15-20, illite 10-15, sec.-propyl three (dioctylphyrophosphoric acid acyloxy) titanic acid ester 2-3, oxyethyl group aminopropyl polydimethylsiloxane 1.5-2.5, stearic acid 3-5, trioctyl trimellitate 8-12, dioctyl phthalate (DOP) 5-10, linoleic acid dimer multipolymer 2-3, octyl dodecanol beeswax acid esters 2-3, OP wax 4-6, EPSAN 25-35, ethylene-vinyl acetate copolymer 20-30, high density polyethylene(HDPE) 40-50, b, get sillimanite, illite mixes, pulverized 150-200 mesh sieve, 820-880 ℃ of calcining 1-2h, after being cooled to room temperature, add sec.-propyl three (dioctylphyrophosphoric acid acyloxy) titanic acid ester, trioctyl trimellitate, octyl dodecanol beeswax acid esters, after high-speed mixing 4-6min, together input in double-screw extruding pelletizing machine with EPSAN, melt extrude granulation and obtain master batch A, c, get obsidian, coal gangue mixes, pulverized 150-200 mesh sieve, 900-950 ℃ of calcining 1-2h, after being cooled to room temperature, add oxyethyl group aminopropyl polydimethylsiloxane, dioctyl phthalate (DOP), linoleic acid dimer multipolymer, after high-speed mixing 3-5min, together input in double-screw extruding pelletizing machine with ethylene-vinyl acetate copolymer, melt extrude granulation and obtain mother particle B, d, the above-mentioned master batch A making, mother particle B are mixed in rear input double-screw extruding pelletizing machine with high density polyethylene(HDPE), OP wax, stearic acid, melt extrude granulation and obtain required filler parent granule.
2. the preparation method of high temperature resistant PVC tubing for water supply engineering according to claim 1, is characterized in that comprising the following steps:
(1) get in SG-2 type polyvinyl chloride resin, aerosil, cubic boron nitride micro mist, hexadecyl palmitate, barium laurate, zinc naphthenate, 2-phenylindone, epoxy Toenol 1140, microcrystalline wax, diisooctyl phenyl phosphite input kneader and mediate, treat that material frictional heat is to 90-100 ℃, material is entered in cold mixer and lowered the temperature, discharging when temperature drops to below 50 ℃, obtains compound A;
(2) get in surplus stock input kneader and mediate, treat that material frictional heat, to 80-90 ℃, enters material in cold mixer and lowers the temperature, discharging when temperature drops to below 45 ℃, obtains compound B;
(3) deliver to extrusion moulding in twin screw extruder after the compound A of above-mentioned gained and compound B are mixed and make tubing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410272031.2A CN104098854B (en) | 2014-06-18 | 2014-06-18 | A kind of water engineering high temperature resistant PVC tubing and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410272031.2A CN104098854B (en) | 2014-06-18 | 2014-06-18 | A kind of water engineering high temperature resistant PVC tubing and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104098854A true CN104098854A (en) | 2014-10-15 |
| CN104098854B CN104098854B (en) | 2016-08-24 |
Family
ID=51667423
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410272031.2A Active CN104098854B (en) | 2014-06-18 | 2014-06-18 | A kind of water engineering high temperature resistant PVC tubing and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104098854B (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1974631A (en) * | 2006-11-21 | 2007-06-06 | 吉林大学 | Prepn process of poly (ether-ketone-ketone) as high performance polymer |
| CN103467808A (en) * | 2013-08-16 | 2013-12-25 | 安徽省振云塑胶有限公司 | Heat-resistant stable PE water supply pipe |
| CN103554773A (en) * | 2013-10-30 | 2014-02-05 | 安徽国通高新管业股份有限公司 | Corrugated pipe containing sillimanite |
-
2014
- 2014-06-18 CN CN201410272031.2A patent/CN104098854B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1974631A (en) * | 2006-11-21 | 2007-06-06 | 吉林大学 | Prepn process of poly (ether-ketone-ketone) as high performance polymer |
| CN103467808A (en) * | 2013-08-16 | 2013-12-25 | 安徽省振云塑胶有限公司 | Heat-resistant stable PE water supply pipe |
| CN103554773A (en) * | 2013-10-30 | 2014-02-05 | 安徽国通高新管业股份有限公司 | Corrugated pipe containing sillimanite |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104098854B (en) | 2016-08-24 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107857955B (en) | Cold-resistant (-40 ℃) high-flame-retardant (OI is more than or equal to 38) PVC cable material and preparation method thereof | |
| CN102585396B (en) | Water-resistant polyvinyl chloride (PVC) cable insulating material | |
| CN101250307B (en) | Low-temperature resistant soft environment-protective plastic casing material and preparation method thereof | |
| CN103842428A (en) | Process for mixing polyvinyl chloride with a bio-based plasticizer | |
| CN102690476B (en) | Heat-resisting material and preparing method thereof as well as base station antenna outer cover | |
| CN102558808B (en) | Environment-friendly flame-retardant scratch-resistant polycarbonate resin and preparation method thereof | |
| CN101845206B (en) | Heat and flame resistant thin-film polybutylece terephthalate/polyethylene terephthalate (PBT/PET) alloy | |
| CN103923411A (en) | Hollow glass bead/polyvinyl chloride component type wire and cable compound and preparation method thereof | |
| CN105524368A (en) | Special polyvinyl chloride sheath material for robot wires and cables and preparation method thereof | |
| CN103509263B (en) | A kind of environmental protection addition type polyethylene anti-flaming master batch and preparation method thereof | |
| CN102241857A (en) | Polypropylene flame-retardant masterbatch material and preparation method thereof | |
| CN103396631B (en) | Flame-proof PVC electric adhesive tape base material | |
| CN103351547A (en) | Environment-friendly and cold-resistant polyvinyl chloride cable material and preparation method thereof | |
| CN104098850A (en) | Anti-impact PVC water supply pipe and preparation method thereof | |
| CN102051007A (en) | Soft polrvinyl chloride composition and preparation method thereof | |
| CN104098852A (en) | Low temperature resistant PVC water supply pipe used in severe cold region and preparation method thereof | |
| CN103554668A (en) | Novel polypropylene double-wall corrugated pipe | |
| CN104098822A (en) | Insect-and-ant prevention polyethylene water supply tubular product and preparation method thereof | |
| CN104098854A (en) | High-temperature-resistant PVC pipe for water supply engineering and preparation method for high-temperature-resistant PVC pipe | |
| CN104419166A (en) | PC flame retardant master batch | |
| CN103102609A (en) | Mining high-impact flame-retardant special material for polyvinyl chloride (PVC)/6000-mesh superfine coarse whiting ore | |
| CN104098853A (en) | Wear-resistant PVC water supply pipe material and preparation method thereof | |
| CN103059407A (en) | Polypropylene composite material and preparation method thereof and application | |
| CN104098821A (en) | Outdoor feedwater anti-ageing PE tubular product and preparation method thereof | |
| CN102477181B (en) | High-gloss scraping-resistant filling PP resin and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20170223 Address after: 454150 Jiaozuo high tech Zone, Henan, No. 6 the Yellow River Road Patentee after: HENAN JIN RUN PLASTIC TECHNOLOGY CO.,LTD. Address before: 233200 Dingyuan Industrial Park, Chuzhou, Anhui Patentee before: ZHENYUN PLASTICS CO.,LTD. ANHUI |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20170330 Address after: 233200 Dingyuan Industrial Park, Anhui, Chuzhou Patentee after: ZHENYUN PLASTICS CO.,LTD. ANHUI Address before: 454150 Jiaozuo high tech Zone, Henan, No. 6 the Yellow River Road Patentee before: HENAN JIN RUN PLASTIC TECHNOLOGY CO.,LTD. |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20191225 Address after: Plot 2, east of Baogong road and south of Luqiao Road, Dingyuan Economic Development Zone, Chuzhou City, Anhui Province Patentee after: Anhui ruiti Pipeline Co.,Ltd. Address before: 233200 Dingyuan Industrial Park, Anhui, Chuzhou Patentee before: ZHENYUN PLASTICS CO.,LTD. ANHUI |
|
| CP01 | Change in the name or title of a patent holder | ||
| CP01 | Change in the name or title of a patent holder |
Address after: 233200 plot 2, east of Bao road and south of Luqiao Road, Dingyuan Economic Development Zone, Chuzhou City, Anhui Province Patentee after: Anhui Ruiyuan Pipeline Co.,Ltd. Address before: 233200 plot 2, east of Bao road and south of Luqiao Road, Dingyuan Economic Development Zone, Chuzhou City, Anhui Province Patentee before: Anhui ruiti Pipeline Co.,Ltd. |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: The invention relates to a high temperature resistant PVC pipe for water supply engineering and a preparation method thereof Effective date of registration: 20210929 Granted publication date: 20160824 Pledgee: Dingyuan County Credit Guarantee Co.,Ltd. Pledgor: Anhui Ruiyuan Pipeline Co.,Ltd. Registration number: Y2021980010080 |
|
| PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20220929 Granted publication date: 20160824 Pledgee: Dingyuan County Credit Guarantee Co.,Ltd. Pledgor: Anhui Ruiyuan Pipeline Co.,Ltd. Registration number: Y2021980010080 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A high temperature resistant PVC pipe for water supply engineering and its preparation method Effective date of registration: 20220930 Granted publication date: 20160824 Pledgee: Dingyuan County Credit Guarantee Co.,Ltd. Pledgor: Anhui Ruiyuan Pipeline Co.,Ltd. Registration number: Y2022980017319 |