CN105524368A - Special polyvinyl chloride sheath material for robot wires and cables and preparation method thereof - Google Patents
Special polyvinyl chloride sheath material for robot wires and cables and preparation method thereof Download PDFInfo
- Publication number
- CN105524368A CN105524368A CN201410520936.7A CN201410520936A CN105524368A CN 105524368 A CN105524368 A CN 105524368A CN 201410520936 A CN201410520936 A CN 201410520936A CN 105524368 A CN105524368 A CN 105524368A
- Authority
- CN
- China
- Prior art keywords
- sheath material
- parts
- cable special
- polychloroethylene
- speed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Insulated Conductors (AREA)
- Organic Insulating Materials (AREA)
Abstract
The invention discloses a special polyvinyl chloride sheath material for robot wires and cables. The material comprises the following components in parts by weight: 100 parts of polyvinyl chloride resin, 60-90 parts of polyester plasticizer, 5-10 parts of epoxy soybean oil, 10-40 parts of filler, 2-5 parts of compound stabilizer, 10-25 parts of compound flame retardant, 0.5-2 parts of lubricant, 1-5 parts of processing aid and 2-4 parts of pigment. The invention also discloses a preparation method. The material has the advantages of excellent flexibility, excellent oil resistance and excellent heat resistance, and can be widely used in the field of robot cables with requirements for oil resistance, flame retardancy and unceasing movement.
Description
Technical field
The present invention relates to and be a kind ofly exclusively used in PVC sheath material of robot cable and preparation method thereof, belong to field of high polymer material processing.
Background technology
In cable sheath material field, environment protection PVC power cable sheath material not only has excellent mechanical property, cheap, and environmental protection, become trend of the times already.The processing characteristics of existing environment protection PVC power cable sheath material is poor, and particularly when plasticizer consumption is larger, compound is not easily processed; And weather resistance is bad, when having oil and need not stop to move around, work-ing life is short.The softening agent that traditional PVC sheath material adopts is Phthalic acids softening agent, and anti-volatility, resistance to migration and anti-extractable are poor.The stablizer that traditional PVC sheath material adopts has lead salt stabilizer, not environmentally poisonous; Calcium-zinc composite stabilizing agent, stabilization efficiency is low, can only improve the stability of material by increasing addition.
Summary of the invention
The processing characteristics that the present invention is directed to environment protection PVC power cable sheath material in prior art is poor, stabilizing agent dosage is large, flame retarding efficiency is poor, be produced into goods after the defect of poor durability, propose a kind of robot cable special-purpose polychloroethylene sheath material and preparation method thereof.
For achieving the above object, the present invention adopts following technical proposals to be achieved:
A kind of robot cable special-purpose polychloroethylene sheath material, comprise the component of following weight part: polyvinyl chloride (PVC) RESINS 100 parts, polyester plasticizer 60-90 part, epoxy soybean oil 5-10 part, weighting agent 10-40 part, compound stabilizer 2-5 part, compound flame retardant 10-25 part, lubricant 0.5-2 part, processing aid 1-5 part, pigment 2-4 part.
Preferred compound stabilizer comprises Hinered phenols antioxidant, beta-diketon class synergistic stablizer, calcium stearate, Zinic stearas and hydrotalcite, and mass ratio is 1-2:2-3:2-5:8-12:20-25.
Preferred compound flame retardant comprises antimonous oxide, aluminium hydroxide and 3.5 hydrate zinc borates.
Preferred compound flame retardant hybrid technique for add antimonous oxide in high-speed kneading machine; add static inhibitor high-speed cruising 2-5min simultaneously; rotating speed is 1000-1500r/min; then turn low cruise, rotating speed is 100-300r/min, adds hyper-dispersant; 3.5 hydrate zinc borates and aluminium hydroxide is added after 2min; shut down after high-speed cruising 5min, rotating speed is 1000-1500r/min, and material being put into cold mixer, to be cooled to room temperature stand-by.
The mass ratio of preferred antimonous oxide, 3.5 hydrate zinc borates, aluminium hydroxide, static inhibitor, hyper-dispersant is 200:100:200:1-3:1-3.
Preferred static inhibitor is alkyl sodium sulfonate class tensio-active agent; Described hyper-dispersant is polyacrylate dispersant.
Preferred polyester plasticizer is the low-molecular-weight polyester of aliphatic dibasic acid and dibasic alcohol polycondensation; Described aliphatic dibasic acid is hexanodioic acid or sebacic acid, and described dibasic alcohol is ethylene glycol, propylene glycol or butyleneglycol.
Preferred polyvinyl chloride (PVC) RESINS to be mean polymerisation degree be more than 2000 the homogeneous powder of polychloroethylene with high polymerization degree; Described weighting agent is one or more in calcium carbonate, talcum powder, kaolin; Described lubricant is one or more of stearic acid, polyethylene wax or oxidized polyethlene wax; Described processing aid is acrylic acid esters co-polymer.
The preparation method of a kind of robot of the present invention cable special-purpose polychloroethylene sheath material, comprises following steps:
A) mix: according to weight proportion, polyvinyl chloride (PVC) RESINS, compound stabilizer, lubricant, pigment are added in high-speed kneading machine, low speed mixing is even, rotating speed is 100-300r/min, then adds epoxy soybean oil and transfers high-speed mixing to, and rotating speed is 500--800r/min; Then, treat that material temperature reaches 70-80 DEG C and adds polyester plasticizer, described epoxy soybean oil and polyester plasticizer are preheating to 80 ± 10 DEG C, treat that material temperature reaches 100 ± 5 DEG C of polyester plasticizers and absorbs completely, add weighting agent and compound flame retardant mixes, material temperature reaches 125 ± 5 DEG C and adds processing aid mixing 3min, mixes rear stopping mixing, is discharged into by compound in cold mixer to material temperature less than 70 DEG C;
B) extrusion moulding: the cooling material mixed is discharged in twin screw extruder and extrudes, then by Single screw extrusion granulation; Twin screw extruder temperature is 120-140 DEG C, and single screw extrusion machine temperature is 130-140 DEG C, and temperature of getting to know is 140 DEG C.
Compared with prior art, advantage of the present invention and positively effect are: the present invention take polychloroethylene with high polymerization degree as major ingredient, adopt polyester plasticizer, compound stabilizer and compositional flame-retardant technology, form through twin screw extruder plasticizing granulation.This material has excellent over-all properties: excellent flexibility, and the cable sheath resist bending made with this material test can reach more than 5,000 ten thousand times; Excellent oil-proofness, by 80 DEG C of * 1440H immersion oil tests; Excellent thermotolerance, heat resisting temperature 105 DEG C; Excellent mechanical property, excellent flame retardant resistance; Can be widely used in there is oil resistant flame-retardancy requirements and need not stop the robot cable field of movement.
Embodiment
In order to make object of the present invention, technical scheme and advantage clearly understand, below embodiment is described in further detail the present invention.
The invention provides a kind of high flexibility resist bending, oil resistant, fire-retardant robot cable special-purpose polychloroethylene sheath material, comprise the component of following weight part: polyvinyl chloride (PVC) RESINS 100 parts, polyester plasticizer 60-90 part, epoxy soybean oil 5-10 part, weighting agent 10-40 part, compound stabilizer 2-5 part, compound flame retardant 10-25 part, lubricant 0.5-2 part, processing aid 1-5 part, pigment 2-4 part.
Preferred compound stabilizer comprises Hinered phenols antioxidant, beta-diketon class synergistic stablizer, calcium stearate, Zinic stearas and hydrotalcite, and mass ratio is 1-2:2-3:2-5:8-12:20-25.Contriver find, adopts the quality proportioning of compound stabilizer of the present invention obtain material has better stabilising effect, cost is lower.
Preferred compound flame retardant comprises antimonous oxide, aluminium hydroxide and 3.5 hydrate zinc borates.Hybrid technique for add antimonous oxide in high-speed kneading machine; add static inhibitor high-speed cruising 2-5min simultaneously; rotating speed is 1000-1500r/min; then turn low cruise, rotating speed is 100-300r/min, adds hyper-dispersant; 3.5 hydrate zinc borates and aluminium hydroxide is added after 2min; shut down after high-speed cruising 5min, rotating speed is 1000-1500r/min, and material being put into cold mixer, to be cooled to room temperature stand-by.Wherein the mass ratio of antimonous oxide, 3.5 hydrate zinc borates, aluminium hydroxide, static inhibitor, hyper-dispersant is 200:100:200:1-3:1-3.Wherein said static inhibitor is alkyl sodium sulfonate class tensio-active agent; Described hyper-dispersant is polyacrylate dispersant.Contriver finds, the compound flame retardant prepared through this technique reduces the reunion of fire-retardant powder in the course of processing, to make it in polyvinyl chloride dispersion evenly, flame retarding efficiency is improved, and low-temperature performance also promotes thereupon.
Preferred polyester plasticizer is the low-molecular-weight polyester of aliphatic dibasic acid and dibasic alcohol polycondensation; Described aliphatic dibasic acid is hexanodioic acid or sebacic acid, and described dibasic alcohol is ethylene glycol, propylene glycol or butyleneglycol.Polyester plasticizer volatility in the course of processing that the present invention adopts is low, not easily extracted out by water, oil and other solvent, and transport property is little in finished product, high temperature resistant; So strong with the obtained sheath material resist bending of polyester plasticizer, oil resistance, there is excellent weather resistance.
Described polyvinyl chloride (PVC) RESINS to be mean polymerisation degree be more than 2000 the homogeneous powder of polychloroethylene with high polymerization degree; Described weighting agent is one or more in calcium carbonate, talcum powder, kaolin; Described lubricant is one or more of stearic acid, polyethylene wax or oxidized polyethlene wax; Described processing aid is acrylic acid esters co-polymer.
The preparation method of a kind of robot of the present invention cable special-purpose polychloroethylene sheath material, comprises following steps:
1) weigh: often kind of raw material is weighed by above-mentioned magnitude relation.
2) mix: according to weight proportion, polyvinyl chloride (PVC) RESINS, compound stabilizer, lubricant, pigment are added in high-speed kneading machine, low speed mixing is even, rotating speed is 100-300r/min, then adds epoxy soybean oil and transfers high-speed mixing to, and rotating speed is 500-800r/min; Then, treat that material temperature reaches 70-80 DEG C and adds polyester plasticizer, described epoxy soybean oil and polyester plasticizer are preheating to 80 ± 10 DEG C, treat that material temperature reaches 100 ± 5 DEG C of polyester plasticizers and absorbs completely, add weighting agent and compound flame retardant mixes, material temperature reaches 125 ± 5 DEG C and adds processing aid mixing 3min, mixes rear stopping mixing, is discharged into by compound in cold mixer to material temperature less than 70 DEG C;
3) extrusion moulding: the cooling material mixed is discharged in twin screw extruder and extrudes, then by Single screw extrusion granulation; Twin screw extruder temperature is 120-140 DEG C, and single screw extrusion machine temperature is 130-140 DEG C, and temperature of getting to know is 140 DEG C.
4) pack: warehouse-in packaging.
Embodiment 1
A kind of robot of the present invention cable special-purpose polychloroethylene sheath material, its raw material ratio in table 1, wherein: polyester plasticizer is adipic acid polyester plasticizer, viscosity 3000mPa ﹒ about s; Epoxy soybean oil oxirane value >=6, iodine value≤3.0; Weighting agent is calcium carbonate; Compound stabilizer is antioxidant 1010, beta-diketon class synergistic stablizer, calcium stearate, Zinic stearas and hydrotalcite, and mass ratio is 1:2:5:12:20; Compound flame retardant is antimonous oxide, 3.5 hydrate zinc borates, aluminium hydroxide, static inhibitor, hyper-dispersant, and mass ratio is 200:100:200:3:3; Lubricant is stearic acid and oxidized polyethlene wax, and mass ratio is 1:1; Processing aid is acrylic acid esters co-polymer, and pigment is carbon black.
Wherein the hybrid technique of compound flame retardant is as follows: first join in high-speed kneading machine by the antimonous oxide of 100 parts; and together add the static inhibitor high-speed cruising 3min of 1.5 parts; rotating speed is 1200r/min, then turns low cruise, and rotating speed is 100r/min; and add the hyper-dispersant of 1.5 parts; add 3.5 hydrate zinc borates of 50 parts and the aluminium hydroxide of 100 parts after 2min, high-speed cruising, rotating speed is 1200r/min; shut down after 5min, and material being put into cold mixer, to be cooled to room temperature stand-by.
The preparation method of robot of the present invention cable special-purpose polychloroethylene sheath material comprises the following steps:
1) weigh: often kind of raw material is weighed by above-mentioned magnitude relation.
2) mix: first add in high-speed kneading machine by load weighted polyvinyl chloride (PVC) RESINS, compound stabilizer, lubricant, pigment, low speed mixing is even, and rotating speed is 200r/min, then adds epoxy soybean oil and transfers high-speed mixing to, and rotating speed is 600r/min; Then, treat that material temperature reaches 80 DEG C and adds polyester plasticizer, wherein epoxy soybean oil and polyester plasticizer should be heated to 80 DEG C in advance, reach after 100 DEG C of softening agent absorb completely until material temperature and add weighting agent and compound flame retardant, even material temperature to be mixed reaches 125 DEG C and adds processing aid, mix after 3min and stop mixing, material is discharged in cold mixer and is mixed to material temperature less than 70 DEG C.
3) extruding pelletization: the material that cooling mixing is good is discharged in twin screw extruder and extrudes, then by Single screw extrusion granulation; Twin screw extruder temperature is 120-140 DEG C, and single screw extrusion machine temperature is 130-140 DEG C, and temperature of getting to know is 140 DEG C.
4) pack: warehouse-in packaging.
Embodiment 2
A kind of high flexibility resist bending described in this example, oil resistant, fire-retardant robot cable special-purpose polychloroethylene sheath material, its raw material ratio in table 1, wherein: polyester plasticizer is adipic acid polyester plasticizer, viscosity 3000mPa ﹒ about s; Epoxy soybean oil oxirane value >=6, iodine value≤3.0; Weighting agent is calcium carbonate; Compound stabilizer is Hinered phenols antioxidant, beta-diketon class synergistic stablizer, calcium stearate, Zinic stearas and hydrotalcite, and mass ratio is 2:3:2:8:25; Compound flame retardant is antimonous oxide, 3.5 hydrate zinc borates, aluminium hydroxide, static inhibitor, hyper-dispersant, and mass ratio is 200:100:200:2:2; Lubricant is oxidized polyethlene wax, and processing aid is acrylic acid esters co-polymer, and pigment is carbon black.
Wherein the hybrid technique of compound flame retardant is as follows: first join in high-speed kneading machine by the antimonous oxide of 100 parts; and together add the static inhibitor high-speed cruising 3min of 1 part; rotating speed is 1300r/min, then turns low cruise, and rotating speed is 200r/min; and add the hyper-dispersant of 1 part; add 3.5 hydrate zinc borates of 50 parts and the aluminium hydroxide of 100 parts after 2min, high-speed cruising, rotating speed is 1300r/min; shut down after 5min, and material being put into cold mixer, to be cooled to room temperature stand-by.
The preparation method of high flexibility resist bending, oil resistant, fire-retardant robot cable special-purpose polychloroethylene sheath material comprises the following steps:
1) weigh: often kind of raw material is weighed by above-mentioned magnitude relation.
2) mix: first add in high-speed kneading machine by load weighted polyvinyl chloride (PVC) RESINS, compound stabilizer, lubricant, pigment, low speed mixing is even, and rotating speed is 200r/min, then adds epoxy soybean oil and transfers high-speed mixing to, and rotating speed is 700r/min; Then, treat that material temperature reaches 70 DEG C and adds polyester plasticizer, wherein epoxy soybean oil and polyester plasticizer should be heated to 70 DEG C in advance, reach after 95 DEG C of softening agent absorb completely until material temperature and add weighting agent and compound flame retardant, even material temperature to be mixed reaches 120 DEG C and adds processing aid, mix after 3min and stop mixing, material is discharged in cold mixer and is mixed to material temperature less than 70 DEG C.
3) extruding pelletization: the material that cooling mixing is good is discharged in twin screw extruder and extrudes, then by Single screw extrusion granulation; Twin screw extruder temperature is 120-140 DEG C, and single screw extrusion machine temperature is 130-140 DEG C, and temperature of getting to know is 140 DEG C.
4) pack: warehouse-in packaging.
Comparative example 1:
A kind of robot cable special-purpose polychloroethylene sheath material described in this example, its raw material ratio is in table 1, and wherein except stablizer, all the other raw material ratios, with embodiment 1, are traditional calcium-zinc composite stabilizing agent unlike the stablizer described in this sheath material.
Compound flame retardant is prepared according to method as described in Example 1.
Polyvinyl chloride cable material is prepared according to method as described in Example 1.
Comparative example 2:
A kind of robot cable special-purpose polychloroethylene sheath material described in this example, its raw material ratio is in table 1, wherein raw material ratio is with embodiment 1, do not adopt the hybrid technique of the compound flame retardant described in embodiment 1 to carry out pre-mixing unlike the fire retardant described in this sheath material, but directly join when batch mixing.
Polyvinyl chloride cable material is prepared according to method as described in Example 1.
Comparative example 3:
A kind of robot cable special-purpose polychloroethylene sheath material described in this example, its raw material ratio is in table 1, wherein except fire retardant all the other raw material ratios with embodiment 2, be antimonous oxide unlike the fire retardant described in this sheath material, and not with embodiment 2 pre-mixing like that, but directly join during batch mixing.
Polyvinyl chloride cable material is prepared according to method as described in Example 2.
Table 1. robot cable special-purpose polychloroethylene sheath material raw material ratio
Test by the polyvinyl chloride cable material obtained by embodiment of the present invention 1-2 and comparative example 1-3 and with the cable obtained by this CABLE MATERIALS, concrete detected result is as shown in table 2:
Table 2 result shows that each performance perameter of polyvinyl chloride cable material prepared by the present invention is excellent:
1, as can be seen from embodiment 1 and comparative example 1: it is more far better than the heat-proof aging experiment effect adding traditional calcium-zinc composite stabilizing agent to add compound stabilizer of the present invention, add the tensile strength of compound stabilizer of the present invention and elongation at break conservation rate all about 100%, and the stretching strength retentivity adding traditional calcium-zinc composite stabilizing agent is less than 75%, elongation at break conservation rate is less than 65%, and 105 DEG C of thermal ageing tests are defective; The cable heat resisting temperature causing final production to go out only has 80 DEG C.Illustrate in compound stabilizer of the present invention to possess synergistic complementary action between each component, thus more efficient.
2, as can be seen from comparative example 2 and embodiment 1: brought up to 31% to adding 25 parts of oxygen indexs through the compound flame retardant of pre-mixing from 28% from adding 25 parts of compound flame retardants without pre-mixing, brittle temperature-28 DEG C has been reduced to-32 DEG C.Those skilled in the art are known: the flame retardant properties that improve material, and conventional method improves the addition of fire retardant, but the low-temperature performance of material will reduce thereupon.And the present invention adopts compound flame retardant technology, and by specific hybrid technique, reduce the reunion of fire-retardant powder in the course of processing, make it dispersion in polyvinyl chloride evenly, thus flame retardant properties is improved, and low-temperature performance also gets a promotion simultaneously.
3, as can be seen from comparative example 3 and embodiment 2: brought up to 31% to adding 25 parts of oxygen indexs through the compound flame retardant of pre-mixing from 28% from adding 25 parts of antimonous oxides without pre-mixing, illustrate that each component in the present invention in compound flame retardant has synergistic effect to material is fire-retardant, have flame retarding efficiency and promote greatly;-33 DEG C have been reduced to adding 25 parts of brittle temperatures-28 DEG C through the compound flame retardant of pre-mixing from adding 25 parts of antimonous oxides without pre-mixing, also illustrate that in the present invention, the hybrid technique of compound flame retardant reduces the reunion of fire-retardant powder in the course of processing, the low-temperature performance of material is greatly improved simultaneously.
Above embodiment only in order to technical scheme of the present invention to be described, but not is limited; Although with reference to previous embodiment to invention has been detailed description, for the person of ordinary skill of the art, still can modify to the technical scheme described in previous embodiment, or equivalent replacement is carried out to wherein portion of techniques feature; And these amendments or replacement, do not make the essence of appropriate technical solution depart from the spirit and scope of the present invention's technical scheme required for protection.
Claims (10)
1. a robot cable special-purpose polychloroethylene sheath material, it is characterized in that: the component comprising following weight part: polyvinyl chloride (PVC) RESINS 100 parts, polyester plasticizer 60-90 part, epoxy soybean oil 5-10 part, weighting agent 10-40 part, compound stabilizer 2-5 part, compound flame retardant 10-25 part, lubricant 0.5-2 part, processing aid 1-5 part, pigment 2-4 part.
2. a kind of robot according to claim 1 cable special-purpose polychloroethylene sheath material, it is characterized in that, described compound stabilizer comprises Hinered phenols antioxidant, beta-diketon class synergistic stablizer, calcium stearate, Zinic stearas and hydrotalcite, and mass ratio is 1-2:2-3:2-5:8-12:20-25.
3. a kind of robot according to claim 1 and 2 cable special-purpose polychloroethylene sheath material, it is characterized in that, described compound flame retardant comprises antimonous oxide, aluminium hydroxide and 3.5 hydrate zinc borates.
4. a kind of robot according to claim 3 cable special-purpose polychloroethylene sheath material; it is characterized in that; described compound flame retardant hybrid technique for add antimonous oxide in high-speed kneading machine; add static inhibitor high-speed cruising 2-5min simultaneously; rotating speed is 1000-1500r/min; then low cruise is turned; rotating speed is 100-300r/min; add hyper-dispersant; 3.5 hydrate zinc borates and aluminium hydroxide is added after 2min; shut down after high-speed cruising 5min, rotating speed is 1000-1500r/min, and material being put into cold mixer, to be cooled to room temperature stand-by.
5. a kind of robot according to claim 4 cable special-purpose polychloroethylene sheath material, it is characterized in that, the mass ratio of described antimonous oxide, 3.5 hydrate zinc borates, aluminium hydroxide, static inhibitor, hyper-dispersant is 200:100:200:1-3:1-3.
6. a kind of robot cable special-purpose polychloroethylene sheath material according to claim 4 or 5, it is characterized in that, described static inhibitor is alkyl sodium sulfonate class tensio-active agent; Described hyper-dispersant is polyacrylate dispersant.
7. a kind of robot according to claim 1 cable special-purpose polychloroethylene sheath material, it is characterized in that, described polyester plasticizer is the low-molecular-weight polyester of aliphatic dibasic acid and dibasic alcohol polycondensation; Described aliphatic dibasic acid is hexanodioic acid or sebacic acid, and described dibasic alcohol is ethylene glycol, propylene glycol or butyleneglycol.
8. a kind of robot according to claim 1 cable special-purpose polychloroethylene sheath material, is characterized in that, described polyvinyl chloride (PVC) RESINS to be mean polymerisation degree be more than 2000 the homogeneous powder of polychloroethylene with high polymerization degree; Described weighting agent is one or more in calcium carbonate, talcum powder, kaolin.
9. a kind of robot according to claim 1 cable special-purpose polychloroethylene sheath material, is characterized in that, described lubricant is one or more of stearic acid, polyethylene wax or oxidized polyethlene wax; Described processing aid is acrylic acid esters co-polymer.
10. the preparation method of a kind of robot according to claim 1 cable special-purpose polychloroethylene sheath material, is characterized in that, comprise following steps:
A) mix: according to weight proportion, polyvinyl chloride (PVC) RESINS, compound stabilizer, lubricant, pigment are added in high-speed kneading machine, low speed mixing is even, rotating speed is 100-300r/min, then adds epoxy soybean oil and transfers high-speed mixing to, and rotating speed is 500-800r/min; Then, treat that material temperature reaches 70-80 DEG C and adds polyester plasticizer, described epoxy soybean oil and polyester plasticizer are preheating to 80 ± 10 DEG C, treat that material temperature reaches 100 ± 5 DEG C of polyester plasticizers and absorbs completely, add weighting agent and compound flame retardant mixes, material temperature reaches 125 ± 5 DEG C and adds processing aid mixing 3min, mixes rear stopping mixing, is discharged into by compound in cold mixer to material temperature less than 70 DEG C;
B) extrusion moulding: the cooling material mixed is discharged in twin screw extruder and extrudes, then by Single screw extrusion granulation; Twin screw extruder temperature is 120-140 DEG C, and single screw extrusion machine temperature is 130-140 DEG C, and temperature of getting to know is 140 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410520936.7A CN105524368B (en) | 2014-09-30 | 2014-09-30 | A kind of robot cable special-purpose polychloroethylene sheath material and preparation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410520936.7A CN105524368B (en) | 2014-09-30 | 2014-09-30 | A kind of robot cable special-purpose polychloroethylene sheath material and preparation method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105524368A true CN105524368A (en) | 2016-04-27 |
| CN105524368B CN105524368B (en) | 2018-07-10 |
Family
ID=55766912
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410520936.7A Active CN105524368B (en) | 2014-09-30 | 2014-09-30 | A kind of robot cable special-purpose polychloroethylene sheath material and preparation method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105524368B (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109192379A (en) * | 2018-09-28 | 2019-01-11 | 佛山市懿燊科技服务有限公司 | A kind of heat proof cable |
| CN109467839A (en) * | 2018-10-08 | 2019-03-15 | 百通赫思曼工业（苏州）有限公司 | A kind of PVC automotive line CABLE MATERIALS of low temperature resistant heat-resisting long term life |
| CN109735021A (en) * | 2018-12-27 | 2019-05-10 | 中广核三角洲（江苏）塑化有限公司 | Welding robot high temperature resistant oil resistant flame retarding PVC composition for cable and preparation method thereof |
| CN110551346A (en) * | 2018-06-04 | 2019-12-10 | 江苏瑞文新材料科技有限公司 | high-temperature-resistant high-flame-retardant thermoplastic polyvinyl chloride insulating sheath material and preparation method thereof |
| CN111849088A (en) * | 2020-07-28 | 2020-10-30 | 浙江万马高分子材料集团有限公司 | Polyvinyl chloride sheath material and application thereof |
| CN112724661A (en) * | 2020-12-29 | 2021-04-30 | 河北亿正线缆有限公司 | High flame-retardant insulation type wire and cable |
| IT202100012449A1 (en) | 2021-05-14 | 2022-11-14 | Prysmian Spa | Flame retardant cable |
| CN116836489A (en) * | 2023-07-08 | 2023-10-03 | 东莞宝特电业股份有限公司 | A high elasticity PVC cable for robot |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102952352A (en) * | 2011-08-30 | 2013-03-06 | 苏州亨利通信材料有限公司 | Special 105 DEG C environment-friendly flame retardant PVC (polyvinyl chloride) cable sheath material for indoor flexible optical cable |
| CN102993537A (en) * | 2011-09-09 | 2013-03-27 | 滁州格美特科技有限公司 | Weather-proof flame retardation antistatic crosslinking polyethylene tubing, preparation method and application |
| CN103059471A (en) * | 2012-12-26 | 2013-04-24 | 深圳市帝源新材料科技有限公司 | Environment-friendly nontoxic high-insulation low temperature-resistant polyvinyl chloride cable material and preparation process thereof |
| CN103073819A (en) * | 2013-01-04 | 2013-05-01 | 深圳市帝源新材料科技有限公司 | Ultra-thin walled semi-rigid polyvinyl chloride cable material and preparing technology thereof |
| CN103897300A (en) * | 2014-04-11 | 2014-07-02 | 东莞市烨青电业有限公司 | Transparent PVC (polyvinyl chloride) heat stabilizer |
-
2014
- 2014-09-30 CN CN201410520936.7A patent/CN105524368B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102952352A (en) * | 2011-08-30 | 2013-03-06 | 苏州亨利通信材料有限公司 | Special 105 DEG C environment-friendly flame retardant PVC (polyvinyl chloride) cable sheath material for indoor flexible optical cable |
| CN102993537A (en) * | 2011-09-09 | 2013-03-27 | 滁州格美特科技有限公司 | Weather-proof flame retardation antistatic crosslinking polyethylene tubing, preparation method and application |
| CN103059471A (en) * | 2012-12-26 | 2013-04-24 | 深圳市帝源新材料科技有限公司 | Environment-friendly nontoxic high-insulation low temperature-resistant polyvinyl chloride cable material and preparation process thereof |
| CN103073819A (en) * | 2013-01-04 | 2013-05-01 | 深圳市帝源新材料科技有限公司 | Ultra-thin walled semi-rigid polyvinyl chloride cable material and preparing technology thereof |
| CN103897300A (en) * | 2014-04-11 | 2014-07-02 | 东莞市烨青电业有限公司 | Transparent PVC (polyvinyl chloride) heat stabilizer |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110551346A (en) * | 2018-06-04 | 2019-12-10 | 江苏瑞文新材料科技有限公司 | high-temperature-resistant high-flame-retardant thermoplastic polyvinyl chloride insulating sheath material and preparation method thereof |
| CN109192379A (en) * | 2018-09-28 | 2019-01-11 | 佛山市懿燊科技服务有限公司 | A kind of heat proof cable |
| CN109467839A (en) * | 2018-10-08 | 2019-03-15 | 百通赫思曼工业（苏州）有限公司 | A kind of PVC automotive line CABLE MATERIALS of low temperature resistant heat-resisting long term life |
| CN109735021A (en) * | 2018-12-27 | 2019-05-10 | 中广核三角洲（江苏）塑化有限公司 | Welding robot high temperature resistant oil resistant flame retarding PVC composition for cable and preparation method thereof |
| CN111849088A (en) * | 2020-07-28 | 2020-10-30 | 浙江万马高分子材料集团有限公司 | Polyvinyl chloride sheath material and application thereof |
| CN112724661A (en) * | 2020-12-29 | 2021-04-30 | 河北亿正线缆有限公司 | High flame-retardant insulation type wire and cable |
| IT202100012449A1 (en) | 2021-05-14 | 2022-11-14 | Prysmian Spa | Flame retardant cable |
| EP4089693A1 (en) | 2021-05-14 | 2022-11-16 | Prysmian S.p.A. | Flame-retardant cable |
| CN116836489A (en) * | 2023-07-08 | 2023-10-03 | 东莞宝特电业股份有限公司 | A high elasticity PVC cable for robot |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105524368B (en) | 2018-07-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105524368A (en) | Special polyvinyl chloride sheath material for robot wires and cables and preparation method thereof | |
| CN102964724B (en) | Thin-wall insulated wire material for automobile and preparation method thereof | |
| CN102585396B (en) | Water-resistant polyvinyl chloride (PVC) cable insulating material | |
| CN103450598A (en) | Modified polyvinyl chloride cable material | |
| CN103788528A (en) | Oil-proof and anti-corrosion PVC cable material and preparation method thereof | |
| CN101348590A (en) | Special material for mining flame-retardant conveyer belt coating rubber and manufacturing method thereof | |
| CN101157785A (en) | Radiation crosslinking polyethylene-insulated cable material for electric wire and cable and method for making same | |
| CN102675776A (en) | High-fluidity high-fire resistance polyvinyl chloride composite material and method for preparing same | |
| CN104004296A (en) | Antimony-free flame-retardant polyvinyl chloride cable material and preparation method thereof | |
| CN103589086A (en) | Flexible polyvinyl chloride cable material and preparation method thereof | |
| CN108003509A (en) | Prefabricated branch cable oil resistant flame-proof PVC injection molding material and preparation method | |
| CN107189324A (en) | A kind of electronic engineering cable elastomer sheathing material and preparation method thereof | |
| CN105949662A (en) | Flame-retardant jacket material for low-medium voltage cable | |
| CN105885169A (en) | Wear-proof high-intensity composite power cable material and preparation method thereof | |
| CN104140614A (en) | Method for preparing oil-proof high-low-temperature-resistant elastomer for express elevator cable | |
| CN105111622A (en) | Sheath material for CMR-level high-flame-retardant environment-friendly data cable and preparation method thereof | |
| CN102924796A (en) | Modified polyethylene resin and preparation method thereof | |
| CN103756174A (en) | Low-temperature-resistant flame-retardant flexible polyvinyl chloride environmental-protection cable material and preparation method thereof | |
| CN105949569A (en) | Environment-friendly and aging-resistant power cable insulating material and preparation method thereof | |
| CN103059441A (en) | Modified polyvinyl chloride wire and cable material | |
| CN112175318A (en) | Formula of environment-friendly hydrophobic and fireproof cable material for cable sheath | |
| CN102295797B (en) | Zero-halogen flame-retardant polyolefin material and preparation method as well as application thereof | |
| CN110760139B (en) | High-resistivity flame-retardant polyvinyl chloride cable material composition | |
| CN106366686A (en) | Plastic wood material for manufacturing flame retardant door plank and preparation method of plastic wood | |
| CN105175852A (en) | Composite flame-retardant cable material with excellent insulation performance and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB02 | Change of applicant information | ||
| CB02 | Change of applicant information |
Address after: 266300 Haier International Industrial Park, Jiaozhou economic and Technological Development Zone, Qingdao, Shandong Applicant after: Qingdao Haier New Material Research & development Co., Ltd. Address before: 266101 Haier Industrial Park, 1 Haier Road, Laoshan District, Qingdao, Shandong. Applicant before: Qingdao Haier New Material Research & development Co., Ltd. |
|
| GR01 | Patent grant | ||
| GR01 | Patent grant |