CN104094440A - Housing for a galvanic element consisting of carbon fibre-reinforced polymer with a moisture-impermeable layer, galvanic cell, rechargeable battery and motor vehicle - Google Patents
Housing for a galvanic element consisting of carbon fibre-reinforced polymer with a moisture-impermeable layer, galvanic cell, rechargeable battery and motor vehicle Download PDFInfo
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- CN104094440A CN104094440A CN201280057601.5A CN201280057601A CN104094440A CN 104094440 A CN104094440 A CN 104094440A CN 201280057601 A CN201280057601 A CN 201280057601A CN 104094440 A CN104094440 A CN 104094440A
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- Prior art keywords
- housing
- primary cell
- battery
- carbon fibre
- motor vehicle
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 18
- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 16
- 229920002430 Fibre-reinforced plastic Polymers 0.000 title claims abstract description 12
- 239000011151 fibre-reinforced plastic Substances 0.000 title claims abstract description 12
- 229910001416 lithium ion Inorganic materials 0.000 claims abstract description 19
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 claims description 17
- 238000003860 storage Methods 0.000 claims description 16
- 229910052751 metal Inorganic materials 0.000 claims description 15
- 239000002184 metal Substances 0.000 claims description 15
- 239000000463 material Substances 0.000 claims description 10
- 229920003023 plastic Polymers 0.000 claims description 9
- 239000004033 plastic Substances 0.000 claims description 9
- 229910052744 lithium Inorganic materials 0.000 claims description 8
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- -1 polypropylene Polymers 0.000 claims description 6
- 238000004804 winding Methods 0.000 claims description 6
- 239000004743 Polypropylene Substances 0.000 claims description 5
- 229920001155 polypropylene Polymers 0.000 claims description 5
- 229920000098 polyolefin Polymers 0.000 claims description 4
- 239000004734 Polyphenylene sulfide Substances 0.000 claims description 3
- 229920001577 copolymer Polymers 0.000 claims description 3
- 150000003961 organosilicon compounds Chemical class 0.000 claims description 3
- 229920000069 polyphenylene sulfide Polymers 0.000 claims description 3
- 235000012239 silicon dioxide Nutrition 0.000 claims description 3
- 239000000377 silicon dioxide Substances 0.000 claims description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 2
- 229920000052 poly(p-xylylene) Polymers 0.000 claims description 2
- 229920001169 thermoplastic Polymers 0.000 claims description 2
- 210000004027 cell Anatomy 0.000 description 12
- 238000000034 method Methods 0.000 description 7
- 239000004411 aluminium Substances 0.000 description 5
- 229910052782 aluminium Inorganic materials 0.000 description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
- 238000005240 physical vapour deposition Methods 0.000 description 5
- 229920000049 Carbon (fiber) Polymers 0.000 description 4
- 239000004917 carbon fiber Substances 0.000 description 4
- 238000005229 chemical vapour deposition Methods 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 229910001290 LiPF6 Inorganic materials 0.000 description 3
- 238000009831 deintercalation Methods 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- QGHDLJAZIIFENW-UHFFFAOYSA-N 4-[1,1,1,3,3,3-hexafluoro-2-(4-hydroxy-3-prop-2-enylphenyl)propan-2-yl]-2-prop-2-enylphenol Chemical group C1=C(CC=C)C(O)=CC=C1C(C(F)(F)F)(C(F)(F)F)C1=CC=C(O)C(CC=C)=C1 QGHDLJAZIIFENW-UHFFFAOYSA-N 0.000 description 2
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 239000011149 active material Substances 0.000 description 2
- 238000010504 bond cleavage reaction Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 230000003301 hydrolyzing effect Effects 0.000 description 2
- 238000005457 optimization Methods 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 230000007017 scission Effects 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 238000009628 steelmaking Methods 0.000 description 2
- 240000004859 Gamochaeta purpurea Species 0.000 description 1
- 229910032387 LiCoO2 Inorganic materials 0.000 description 1
- 241000156302 Porcine hemagglutinating encephalomyelitis virus Species 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 210000002421 cell wall Anatomy 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000005253 cladding Methods 0.000 description 1
- DZUDZSQDKOESQQ-UHFFFAOYSA-N cobalt hydrogen peroxide Chemical compound [Co].OO DZUDZSQDKOESQQ-UHFFFAOYSA-N 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000013016 damping Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000005518 electrochemistry Effects 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 230000002687 intercalation Effects 0.000 description 1
- 238000009830 intercalation Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000007774 positive electrode material Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 229910000314 transition metal oxide Inorganic materials 0.000 description 1
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings, jackets or wrappings of a single cell or a single battery
- H01M50/102—Primary casings, jackets or wrappings of a single cell or a single battery characterised by their shape or physical structure
- H01M50/107—Primary casings, jackets or wrappings of a single cell or a single battery characterised by their shape or physical structure having curved cross-section, e.g. round or elliptic
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings, jackets or wrappings of a single cell or a single battery
- H01M50/14—Primary casings, jackets or wrappings of a single cell or a single battery for protecting against damage caused by external factors
- H01M50/141—Primary casings, jackets or wrappings of a single cell or a single battery for protecting against damage caused by external factors for protecting against humidity
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings, jackets or wrappings of a single cell or a single battery
- H01M50/116—Primary casings, jackets or wrappings of a single cell or a single battery characterised by the material
- H01M50/117—Inorganic material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings, jackets or wrappings of a single cell or a single battery
- H01M50/116—Primary casings, jackets or wrappings of a single cell or a single battery characterised by the material
- H01M50/117—Inorganic material
- H01M50/119—Metals
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings, jackets or wrappings of a single cell or a single battery
- H01M50/116—Primary casings, jackets or wrappings of a single cell or a single battery characterised by the material
- H01M50/121—Organic material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings, jackets or wrappings of a single cell or a single battery
- H01M50/116—Primary casings, jackets or wrappings of a single cell or a single battery characterised by the material
- H01M50/122—Composite material consisting of a mixture of organic and inorganic materials
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings, jackets or wrappings of a single cell or a single battery
- H01M50/116—Primary casings, jackets or wrappings of a single cell or a single battery characterised by the material
- H01M50/124—Primary casings, jackets or wrappings of a single cell or a single battery characterised by the material having a layered structure
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Abstract
The invention relates to a housing for a galvanic element, preferably a lithium-ion cell, wherein the housing consists of a carbon fibre-reinforced plastic (CFK) provided with a moisture-impermeable layer. In addition, a galvanic element, a rechargeable battery and a motor vehicle are disclosed.
Description
Technical field
The present invention relates to the housing for primary cell, primary cell, storage battery and motor vehicle.
Background technology
No matter be in fixation application, for example, in wind power plant, in motor vehicle, for example, at motor vehicle driven by mixed power and motor vehicle, or for example, in consumer field, in notebook computer and mobile phone, through the fail safe of being everlasting, reliability, performance and used life aspect proposes higher requirement to used battery system.
An important parameter in the useful life in storage battery-mono-pond is energy density or capacitance, also depends on capacitance in addition by the haul distance of electric motor driven vehicle.Capacitance also can represent by per kilogram watt hour (Wh/kg) in weight.
The capacitance in storage battery-mono-pond or specified-capacitance are to be determined by the so-called active material in storage battery-mono-pond.For example the in the situation that of lithium ion list pond, this is graphite or carbon in metal oxide and the negative pole of the lithiumation in positive pole.In addition, in single pond, so-called inertia-material is also essential as separator and electrode adhesive for the function of cell.For optimization energy density people are devoted to reduce single pond-material part of inertia, wherein also comprise the housing in single pond, to correspondingly improve energy density.
In particular, lithium ion technique is particularly suitable for application widely.In addition, the salient point of lithium ion technique is embodied in that energy density is high and self discharge is extremely low.Lithium ion list pond has at least one positive electrode and negative electrode (positive pole and negative electrode), can reversibly embed (Intercalation) or deintercalation again (Deintercalation) lithium ion (Li+).Attractive storage battery-the system of the second be can recharge lithium metal-system.Here negative pole by lithium-metal make with positive electrode active materials for example taking have the transition metal oxide of layer structure as the cobalt dioxide of lithium (LiCoO2) as basis.
In order to carry out the embedding of lithium ion or the deintercalation of lithium ion, must there is bath composition, so-called lithium-conducting salt.In fact for whole current lithium ion single batteries, no matter be that (mobile phone, MP3-player or powerful tool) still all used lithium hexafluoro phosphate (LiPF6) as lithium-conducting salt in automotive field (hybrid vehicle-HEV) plug-in hybrid automobile (PHEV) and electric automobile (EV) in consumer field.Described LiPF6 is active especially for humidity, becomes fluorine hydrogen (HF) through multistage hydrolytic scission.
In order to prevent because the moist lithium ion list pond that the hydrolytic scission of conducting salt produces is damaged, use the housing with the metal part that is generally metallic film or sheet metal form according to background technology, wherein metallic film or sheet metal represent the obstruct to there was dampness in the air substantially.Wherein can be divided into the so-called Soft Roll with blister-pack and hard, the single pond in metal shell (hard box), described single pond is usually designed to prismatic and cylindrical.Described hard metal shell can be for example to make by aluminium with by cold deep-drawing technique.In this field, also do not show and used plastics, this is because conventionally have certain penetrability with respect to moist plastics.
But, compared with plastics, hard box is for example heavier in the situation that volume is identical by the hard box of aluminium or high-quality steel making.But in the aspect of single pond, improve special energy density owing to pursuing, reduce as much as possible the share of inert material.
In addition the housing being made of metal according to the natural law, externally conducts electricity.Can for example easily cause the high pressure-storage battery-intrasystem electric insulation problem between the basis-mono-pond connecting.
The in the situation that of mechanism, especially being caused metal shell to damage in this accident process by cracked or similar incidents, metal shell may cause internal short-circuit at Dan Chizhong.This may cause heating tempestuously, and open in single pond, and smoldering of single pond assembly, forms flame or even blast.For example when single pond in be full of electric state time, especially to note observe.
As for the share that how to reduce the inert material in storage battery, the housing film of known a kind of housing for fixing single pond from DE 10 2,008 023571 A1, described film is made and is arranged in the above the damp-proof layer of being made up of organo-silicon compound by polyolefin or similar material.But correspondingly the housing of design is easy to be subject to the danger to damaging and causing thus equally.
Also can each single pond be connected into battery module and connect into batteries again by being connected in parallel or being connected in series.Wherein formed by least two single ponds that connected according to a storage battery of definition.Can not use as synonym using these concepts of pond and storage battery that place an order.But contrary, storage battery, battery system, battery module and batteries will continue synonymously to use.
Summary of the invention
To provide a kind of housing for primary cell according to the present invention, damp-proof layer is made and disposed to described housing by carbon fibre reinforced plastic (CFK).
Preferably, primary cell relates to a kind of lithium ion battery or lithium battery that can recharge, and described battery especially can be moistureproof based on normally used active material.But also can be for other battery types according to housing of the present invention.
Professional person is known applicable carbon fibre reinforced plastic from background technology.Wherein preferably use thermoplastics and especially polyolefin and optimization polypropylene (PP) especially, polyethylene (PE) or their copolymer.Another kind of particularly preferred plastics are polyphenylene sulfide (PPS).
The known applicable carbon fiber with corresponding moulding and length of professional person.
Described carbon fibre reinforced plastic has good thermal endurance, outstanding anti-chemistry and mechanical stability.
With for example aluminium film is contrary, the plastics that use are moist transparent.Therefore in outside and/or the inner side of housing, moist impervious layer is set according to the present invention, wherein preferably on outside, manufactures described layer, this is because more simple and economical like this.Described damp-proof layer aspect humidity resistance can with metal film or sheet metal, for example aluminum-film is comparable.
Damp-proof layer can be by for example conventional method as chemical vapour deposition (CVD) (CVD), physical vapour deposition (PVD) (PVD) roll extrusion covering or similarly method apply.Certainly determine to take any method according to the layer that will apply.
Preferably, apply by CVD layer be by Parylene, organo-silicon compound be material or taking silicon dioxide as basis.Verifiedly especially be suitable as damp-proof layer taking silicon dioxide as basic layer.
Described layer also can be by the metal applying by PVD, for example aluminium or high-quality steel making.In the situation that being metal, also can use roll extrusion cladding technique, the thin metal layer wherein preferably applying by PVD.
In thin watertight composition " the Entwicklung einerhermetischen G1as-Silizium Verpackung Verkapselung (exploitation of seal glass silicon package film) " having been known for professional person and for example shown described above, be described to the housing of integrated lithium-polymer storage battery in DE102008023571A1 or at K.Marquardt etc.; MikroSystem Technik KONGRESS (KONGRESS microsystems technology company), Berlin, 2009,12-14.10.2010.
Can unexpectedly the favourable property combination of CFK be become to housing and the damp-proof layer for primary cell.Surprisingly, damp-proof layer can link together with CFK-housing long-term and stably.By reaching particularly preferred result by combined the glass barriers of carbon fiber RPP and sealing.
What do not make us expecting completely is; carbon fiber the inside in single pond chemically with electrochemistry on for the composition in single pond; for example organic carbon hydrochlorate, for example ethylene carbonate (EC), lithium-conducting salt, lithium hexafluoro phosphate (LiPF6) or micro-the fluorine hydrogen (HF) existing are inertia on long time, although carbon or graphite can react conventionally in corresponding environment.
Allow freely molded housing according to material used in the present invention, especially with the such as length of dimension of housing, the wall thickness aspect of width and height correlation.
In addition, can make housing match with the shape of the battery-winding being placed into better.For example can form circle in the inside of housing, can not packing of the prismatic shape of described circle to battery-winding compensates.
Also can realize mechanical support battery-winding better in enclosure interior thus, and not use retainer (Retainer), described retainer is held in place battery-winding and it is separated with interior cell wall portion.
The Mechanical Contact of the improvement of the battery-winding in housing-rounded portions makes to have on the whole higher useful life according to primary cell of the present invention.
In housing, only have thus little empty space, only need little free electrolyte in the inside of battery thus.
Other the applicable modification that carbon fibre reinforced plastic is shaped to three-dimensional hard shell body, by professional person is familiar with, is not here just elaborating.
By can advantageously replace without any problems according to the housing of primary cell of the present invention according to background technology so far taking metal as basic single pond-housing, wherein simultaneously can avoid its shortcoming.
There is thus lower weight according to the housing of primary cell of the present invention, and in the aspect of single pond, there is higher special weight energy thus.Carbon fibre reinforced composite is only equivalent to 50% of about aluminium, and is just 20% of steel.In addition described material used according to the present invention aspect material cost and manufacturing cost, expend also very low.
In addition carbon fibre reinforced plastic also has for example fabulous collision performance of other advantage, lower fatigue tendency and extra high corrosion resistance.
Advantageously realize vibration damping according to housing of the present invention, can prevent thus fatigue phenomenon, and there is extremely low thermal expansion.
The heat of the improvement of carbon fibre reinforced plastic shifts and causes uniform Temperature Distribution, this Temperature Distribution to realize the useful life extending.
The danger that metalwork can occur enter the inside, single pond at the Shi Buzai that breaks down, the infringement described in there will not be thus while beginning.Even housing also has good security feature in the time of breaking out of fire, this is because carbon fibre reinforced plastic is nonflammable especially.
The primary cell of preferred arrangements in housing is lithium ion list pond.
Another theme of the present invention is a kind of have at least two lithium-ions battery and a kind of motor vehicles in described lithium ion list pond before, and it has for the electric drive motor of driving machine motor-car and lithium-ions battery that be connected with electric drive motor or attachable.
Provided in the dependent claims and set forth preferred improvement project of the present invention in specification.
Embodiment
By an example, the present invention will be described below.
In order tentatively to prove to carry out bump test according to the crash safety of accumulator housing of the present invention.
100 (having soft pouch minor-mono-pond housing) lithium ion polymer list ponds are electrically connected into a frame of reference, are placed in an aluminium-housing and are full of electricity, and described system just has the voltage of 420 volts thus.
Storage battery obtains a housing of being made up of carbon fibre reinforced plastic, and other parts do not change, and is wherein as plastics with polypropylene (PP).
Test is to carry out by frontal impact according to Euro-NCAP-bump test, and wherein test vehicle is that 64 kilometers and coverage rate clash into deformable obstacle be 40% in the situation that in speed per hour.Use typical car as instruction carriage.The housing of frame of reference deforms and occurs short circuit and heating.Strengthen according to the carbon fiber of accumulator of the present invention that housing is not out of shape and its storage battery-function is not damaged.
Claims (11)
1. for a housing for primary cell, it is characterized in that, damp-proof layer is made and disposed to described housing by carbon fibre reinforced plastic (CFK).
2. housing according to claim 1, wherein, plastics are thermoplasticss.
3. housing according to claim 2, wherein, plastics are polyolefin or the copolymer or the polyphenylene sulfide that are made up of different polyolefin.
4. housing according to claim 3, wherein, plastics are polypropylene and poly copolymer.
5. according to the housing described in any one in claim 1 to 4, wherein, described damp-proof layer is to be made up of the material based on silicon dioxide, Parylene, organo-silicon compound or metal.
6. according to the housing described in any one in claim 1 to 5, wherein, described damp-proof layer is positioned at outside and/or the inner side of described housing.
7. according to the housing described in any one in claim 1 to 6, wherein, the shape of the battery winding of the inner space of described housing and primary cell matches.
8. a primary cell, is characterized in that, described primary cell has according to the housing described in any one in claim 1 to 7.
9. primary cell according to claim 8, wherein, described primary cell is lithium ion list pond or lithium battery that can recharge.
10. one kind has the storage battery of at least two lithium ion list ponds according to claim 9 or lithium battery that can recharge.
11. 1 kinds of motor vehicles, it has electric drive motor and storage battery according to claim 10 that be connected with described electric drive motor or attachable for driving described motor vehicle.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102011087003.2 | 2011-11-24 | ||
DE102011087003A DE102011087003A1 (en) | 2011-11-24 | 2011-11-24 | Housing for a galvanic element of carbon fiber reinforced plastic with moisture-impermeable layer, galvanic cell, accumulator and motor vehicle |
PCT/EP2012/071028 WO2013075904A1 (en) | 2011-11-24 | 2012-10-24 | Housing for a galvanic element consisting of carbon fibre-reinforced polymer with a moisture-impermeable layer, galvanic cell, rechargeable battery and motor vehicle |
Publications (2)
Publication Number | Publication Date |
---|---|
CN104094440A true CN104094440A (en) | 2014-10-08 |
CN104094440B CN104094440B (en) | 2018-04-13 |
Family
ID=47076233
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201280057601.5A Active CN104094440B (en) | 2011-11-24 | 2012-10-24 | For the housing made of carbon fibre reinforced plastic with damp-proof layer of primary battery, primary battery, storage battery and motor vehicle |
Country Status (3)
Country | Link |
---|---|
CN (1) | CN104094440B (en) |
DE (1) | DE102011087003A1 (en) |
WO (1) | WO2013075904A1 (en) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105895837A (en) * | 2014-12-26 | 2016-08-24 | 查志浩 | Application of carbon fiber composite material in battery box body for electric vehicle |
CN106217903A (en) * | 2016-07-04 | 2016-12-14 | 浙江合众新能源汽车有限公司 | A kind of method making carbon fibre composite batteries of electric automobile bag |
CN107366165A (en) * | 2017-07-24 | 2017-11-21 | 王威 | A kind of carbon fibre material and its high pressure rolling manufacture craft |
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CN105895837A (en) * | 2014-12-26 | 2016-08-24 | 查志浩 | Application of carbon fiber composite material in battery box body for electric vehicle |
CN106217903A (en) * | 2016-07-04 | 2016-12-14 | 浙江合众新能源汽车有限公司 | A kind of method making carbon fibre composite batteries of electric automobile bag |
CN110832671A (en) * | 2017-07-04 | 2020-02-21 | 奥迪股份公司 | Battery for an electric drive of a motor vehicle |
CN110832663A (en) * | 2017-07-04 | 2020-02-21 | 奥迪股份公司 | Battery for an electric drive of a motor vehicle |
CN110870093A (en) * | 2017-07-04 | 2020-03-06 | 奥迪股份公司 | Battery for an electric drive of a motor vehicle |
CN107366165A (en) * | 2017-07-24 | 2017-11-21 | 王威 | A kind of carbon fibre material and its high pressure rolling manufacture craft |
CN107366165B (en) * | 2017-07-24 | 2019-10-11 | 山东英大钓具有限公司 | A kind of carbon fibre material and its high pressure roll manufacture craft |
CN109390516A (en) * | 2017-08-02 | 2019-02-26 | 大众汽车有限公司 | Battery components and method for manufacturing the battery components |
CN109390516B (en) * | 2017-08-02 | 2022-05-17 | 大众汽车有限公司 | Battery component and method for producing same |
Also Published As
Publication number | Publication date |
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DE102011087003A1 (en) | 2013-05-29 |
WO2013075904A1 (en) | 2013-05-30 |
CN104094440B (en) | 2018-04-13 |
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