CN107366165A - A kind of carbon fibre material and its high pressure rolling manufacture craft - Google Patents

A kind of carbon fibre material and its high pressure rolling manufacture craft Download PDF

Info

Publication number
CN107366165A
CN107366165A CN201710607937.9A CN201710607937A CN107366165A CN 107366165 A CN107366165 A CN 107366165A CN 201710607937 A CN201710607937 A CN 201710607937A CN 107366165 A CN107366165 A CN 107366165A
Authority
CN
China
Prior art keywords
carbon fibre
high pressure
fibre material
layer
carbon
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201710607937.9A
Other languages
Chinese (zh)
Other versions
CN107366165B (en
Inventor
王威
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shandong Yingda Fishing Tackle Co. Ltd.
Original Assignee
王威
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 王威 filed Critical 王威
Priority to CN201710607937.9A priority Critical patent/CN107366165B/en
Publication of CN107366165A publication Critical patent/CN107366165A/en
Application granted granted Critical
Publication of CN107366165B publication Critical patent/CN107366165B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/042Acrylic polymers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0015Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Inorganic Fibers (AREA)
  • Moulding By Coating Moulds (AREA)
  • Reinforced Plastic Materials (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Casting Or Compression Moulding Of Plastics Or The Like (AREA)

Abstract

A kind of carbon fibre material and its high pressure rolling manufacture craft, including carbon fiber layer, polyacrylamide amine layer, the parylene layer set gradually from inside to outside.Carbon fiber surface surface roughness can be brought up to Ra2.4~Ra0.2 μm by the present invention from original Ra6.3, and 0.1 μm of Ra0.05 mirror surface accuracy can be even realized by control condition;And surface is obtained extruding hardening, wearability, fatigue strength improve;Surface stress plastic deformation is eliminated, dimensional accuracy relatively long-term can keep stable;After rolling, carbon fiber material hardness can improve 15~30%, and fatigue resistance improves more than 15%;Due to rolled fiber material surface deformation, make textura epidermoidea's cold hardening and crystal grains fine, form fine and close threadiness, and form residual stress layer, hardness and intensity improve, so as to improve the wearability on essence material surface, corrosion resistance and conformability, the interlaminar shear strength for making final products using this technique brings up to 95 99MPa by 55-70MPa.

Description

A kind of carbon fibre material and its high pressure rolling manufacture craft
Technical field:
The present invention relates to a kind of carbon fibre material and its high pressure rolling manufacture craft.
Background technology:
Nowadays in the market is a kind of referred to as T-shaped commonly using the two kinds of carbon fibre material for making high-end fishing rod, One kind is referred to as M types.The phosphorus content of T-shaped carbon fibre material is general all 75% or so, resin content 25% or so, has fine Stretching and tough sexual function, its defect cause its hardness to decline, weight is laid particular stress on precisely due to content resin is too high.M type carbon fibers Cloth phosphorus content 85% or so, resin 15% or so, there is good hardness, and weight is also light, but because resin content is inclined Low, its toughness and drawing effect substantially reduces.In addition, carbon fiber surface is smooth, inertia is big, has chemically active functional group It is few, cause the interface binding intensity between carbon fiber and matrix resin low, interface has more defect, often as composite Weak link.Prior art does not have the plan of solution to this.
The content of the invention:
The present invention is in order to make up the deficiencies in the prior art, there is provided a kind of carbon fibre material and its high pressure rolling make work Skill, its rational technology, surface roughness substantially reduce, and interlaminar shear strength greatly improves, and solves present in prior art Problem.
The present invention is that technical scheme is used by solving above-mentioned technical problem:
A kind of carbon fibre material, including carbon fiber layer, polyacrylamide amine layer, the Parylene set gradually from inside to outside Layer.
A kind of high pressure rolling manufacture craft of carbon fibre material, comprises the following steps:
S1, utilize carbon cloth making carbon fiber layer;
S2, coating polyacrylamide:Polyacrylamide is coated on carbon fiber layer surface, obtains polyacrylamide amine layer;
S3, overlay film application of vacuum:Polymerization technique is cracked by ring disome to polymerize to form poly- pair in the obtained material surfaces of S2 Diformazan benzene layer;
S4, high pressure rolling fusion treatment:Using high pressure roll unit, the material obtained with roller rolling press S3, densification is obtained Carbon fibre material;
S5, hot setting processing:By the fine and close carbon fibre material that S4 is obtained by heating, material temperature is heated to 135- 150 DEG C, forming and hardening, final products are made.
Preferably, in S1, the mass fraction of carbon fiber is 89-92 parts in the carbon cloth, the mass fraction of resin For 8-11 parts.
Preferably, in S2, the thickness of the polyacrylamide amine layer is 0.85-1.0mm.
Preferably, in S3, the ring disome cracking polymerization technique comprises the following steps:
S31, in vacuum film formation equipment, solid-state ring disome is gaseous state ring disome in 150-170 DEG C of distillation;
S32, gaseous state ring disome are cracked into stable unimolecule at 680-700 DEG C;
S33, unimolecule enter in vacuum moulding machine room, adsorb on the surface of S2 resulting materials, and polymerize and to form linear poly- pair Dimethylbenzene film.
Preferably, in S4, the surface roughness of the fine and close carbon fibre material is R0.2-R2.4 μm.
Preferably, in S5, the surface roughness of the fine and close carbon fibre material is R0.05-R0.1 μm.
Preferably, in S5, mode of heating is Electromagnetic Heating.
Preferably, in S4, for temperature control at 90-110 DEG C, rolling drafts is 0.08-0.12mm.
The present invention uses such scheme, and the technology of the present invention can improve carbon fiber surface surface roughness from original Ra6.3 To Ra2.4~Ra0.2 μm, Ra0.05-0.1 μm of mirror surface accuracy can be even realized by control condition;And obtain surface Extruding hardening, wearability, fatigue strength improve;Surface stress plastic deformation is eliminated, dimensional accuracy relatively long-term can keep steady It is fixed;After rolling, carbon fiber material hardness can improve 15~30%, and fatigue resistance improves more than 15%;Due to rolled Fiber material surface deformation, make textura epidermoidea's cold hardening and crystal grains fine, form the threadiness of densification, and form residual stress Layer, hardness and intensity improve, and so as to improve the wearability on essence material surface, corrosion resistance and conformability, are made most using this technique The interlaminar shear strength of finished product brings up to 95-99MPa by 55-70MPa.
Brief description of the drawings:
Fig. 1 is the structural representation of the present invention.
In figure:1st, carbon fiber layer, 2, polyacrylamide amine layer, 3, parylene layer.
Embodiment:
For the technical characterstic for illustrating this programme can be understood, below by embodiment, and its accompanying drawing is combined, to this hair It is bright to be described in detail.
As shown in figure 1, a kind of carbon fibre material, including set gradually from inside to outside carbon fiber layer 1, polyacrylamide amine layer 2nd, parylene layer 3.
A kind of high pressure rolling manufacture craft of carbon fibre material, comprises the following steps:
S1, utilize carbon cloth making carbon fiber layer 1;
S2, coating polyacrylamide:Polyacrylamide is coated on the surface of carbon fiber layer 1, obtains polyacrylamide amine layer 2;
S3, overlay film application of vacuum:Polymerization technique is cracked by ring disome to polymerize to form poly- pair in the obtained material surfaces of S2 Diformazan benzene layer 3;Parylene layer 3 is attached to outside, can prevent or alleviate extraneous dirty erosion and the generation of broken ring factor, from And play a protective role, extend product service life.
S4, high pressure rolling fusion treatment:Using high pressure roll unit, the material obtained with roller rolling press S3, densification is obtained Carbon fibre material;With the surface of the above-mentioned carbon fibre material of roller rolling press, make its fine and close, by carbon fiber surface surface roughness from Ra6.3 Ra0.2-Ra2.4 μm is brought up to, realizes Ra0.05-Ra0.1 μm of mirror surface accuracy;And surface is obtained extruding and harden, wearability, Fatigue strength improves;Surface stress plastic deformation is eliminated, dimensional accuracy relatively long-term can keep stable.After rolling, make Carbon fiber material hardness can improve 15~30%, and fatigue resistance improves 15%.Due to rolled fiber material surface deformation, Making textura epidermoidea's cold hardening and crystal grains fine, form the threadiness of densification, and form residual stress layer, hardness and intensity improve, So as to improve the wearability on essence material surface, corrosion resistance and conformability.
S5, hot setting processing:By the fine and close carbon fibre material that S4 is obtained by heating, material temperature is heated to 135- 150 DEG C, forming and hardening, final products are made.
In S1, the mass fraction of carbon fiber is 89-92 parts in the carbon cloth, and the mass fraction of resin is 8-11 Part.The content of raising carbon itself can improve the hardness of material and mitigate weight.
In S2, the thickness of the polyacrylamide amine layer 2 is 0.85-1.0mm.As the transition zone outside carbon fiber layer 1, Because itself has caking property, so can be good inside and outside fusion two layers, and can make up the carbon content of carbon fiber layer 1 it is high and Caused by toughness weaken the shortcomings that, improve the toughness of its own.
In S3, the ring disome cracking polymerization technique comprises the following steps:
S31, in vacuum film formation equipment, solid-state ring disome is gaseous state ring disome in 150-170 DEG C of distillation;
S32, gaseous state ring disome are cracked into stable unimolecule at 680-700 DEG C;
S33, unimolecule enter in vacuum moulding machine room, adsorb on the surface of S2 resulting materials, and polymerize and to form linear poly- pair Dimethylbenzene film.
In S4, the surface roughness of the fine and close carbon fibre material is R0.2-R2.4 μm.
In S5, the surface roughness of the fine and close carbon fibre material is R0.05-R0.1 μm.Because high pressure rolling is handled Carbon fibre material is routine techniques, by controlling high pressure roll unit to control its surface roughness, due to polyacrylamide The addition of layer 2, thus surface roughness can be reduced further, so as to improve the feel of user.
In S5, mode of heating is Electromagnetic Heating.Electromagnetic Heating is interior mode of heating, suitable for fine and close carbon fibre material Hot setting processing.
In S4, for temperature control at 90-110 DEG C, rolling drafts is 0.08-0.12mm.
Embodiment 1:
S1, utilize carbon cloth making carbon fiber layer 1;The mass fraction of carbon fiber is 89 parts in the carbon cloth, tree The mass fraction of fat is 11 parts.
S2, coating polyacrylamide:On the surface of carbon fiber layer 1, polyacrylamide thick coating 0.85mm, obtains polypropylene Amide layer 2;
S3, overlay film application of vacuum:Polymerization technique is cracked by ring disome to polymerize to form poly- pair in the obtained material surfaces of S2 Diformazan benzene layer 3, step is as follows:
S31, in vacuum film formation equipment, solid-state ring disome is gaseous state ring disome in 150 DEG C of distillations;
S32, gaseous state ring disome are cracked into stable unimolecule at 680 DEG C;
S33, unimolecule enter in vacuum moulding machine room, adsorb on the surface of S2 resulting materials, and polymerize and to form linear poly- pair Dimethylbenzene film.
S4, high pressure rolling fusion treatment:Using high pressure roll unit, the material obtained with roller rolling press S3, densification is obtained Carbon fibre material, for temperature control at 90 DEG C, rolling drafts is 0.08mm;
S5, hot setting processing:Material temperature is heated to by the fine and close carbon fibre material that S4 is obtained by Electromagnetic Heating 135 DEG C, forming and hardening, No. 1 product is made.
Embodiment 2:
S1, utilize carbon cloth making carbon fiber layer 1;The mass fraction of carbon fiber is 92 parts in the carbon cloth, tree The mass fraction of fat is 8 parts.
S2, coating polyacrylamide:On the surface of carbon fiber layer 1, polyacrylamide thick coating 1.0mm, obtains polyacrylamide Amine layer 2;
S3, overlay film application of vacuum:Polymerization technique is cracked by ring disome to polymerize to form poly- pair in the obtained material surfaces of S2 Diformazan benzene layer 3, step is as follows:
S31, in vacuum film formation equipment, solid-state ring disome is gaseous state ring disome in 170 DEG C of distillations;
S32, gaseous state ring disome are cracked into stable unimolecule at 700 DEG C;
S33, unimolecule enter in vacuum moulding machine room, adsorb on the surface of S2 resulting materials, and polymerize and to form linear poly- pair Dimethylbenzene film.
S4, high pressure rolling fusion treatment:Using high pressure roll unit, the material obtained with roller rolling press S3, densification is obtained Carbon fibre material, for temperature control at 110 DEG C, rolling drafts is 0.12mm;
S5, hot setting processing:Material temperature is heated to by the fine and close carbon fibre material that S4 is obtained by Electromagnetic Heating 150 DEG C, forming and hardening, No. 2 products are made.
Embodiment 3:
S1, utilize carbon cloth making carbon fiber layer 1;The mass fraction of carbon fiber is 90.5 parts in the carbon cloth, The mass fraction of resin is 9.5 parts.
S2, coating polyacrylamide:On the surface of carbon fiber layer 1, polyacrylamide thick coating 0.93mm, obtains polypropylene Amide layer 2;
S3, overlay film application of vacuum:Polymerization technique is cracked by ring disome to polymerize to form poly- pair in the obtained material surfaces of S2 Diformazan benzene layer 3, step is as follows:
S31, in vacuum film formation equipment, solid-state ring disome is gaseous state ring disome in 160 DEG C of distillations;
S32, gaseous state ring disome are cracked into stable unimolecule at 690 DEG C;
S33, unimolecule enter in vacuum moulding machine room, adsorb on the surface of S2 resulting materials, and polymerize and to form linear poly- pair Dimethylbenzene film.
S4, high pressure rolling fusion treatment:Using high pressure roll unit, the material obtained with roller rolling press S3, densification is obtained Carbon fibre material, for temperature control at 100 DEG C, rolling drafts is 0.1mm;
S5, hot setting processing:Material temperature is heated to by the fine and close carbon fibre material that S4 is obtained by Electromagnetic Heating 143 DEG C, forming and hardening, No. 3 products are made.
Embodiment 4:
S1, utilize carbon cloth making carbon fiber layer 1;The mass fraction of carbon fiber is 89 parts in the carbon cloth, tree The mass fraction of fat is 11 parts.
S2, polyacrylamide is not coated by, directly carries out S3;
S3, overlay film application of vacuum:Polymerization technique is cracked by ring disome to polymerize to form poly- pair in the obtained material surfaces of S2 Diformazan benzene layer 3, step is as follows:
S31, in vacuum film formation equipment, solid-state ring disome is gaseous state ring disome in 150 DEG C of distillations;
S32, gaseous state ring disome are cracked into stable unimolecule at 680 DEG C;
S33, unimolecule enter in vacuum moulding machine room, adsorb on the surface of S2 resulting materials, and polymerize and to form linear poly- pair Dimethylbenzene film.
S4, high pressure rolling fusion treatment:Using high pressure roll unit, the material obtained with roller rolling press S3, densification is obtained Carbon fibre material, for temperature control at 90 DEG C, rolling drafts is 0.08mm;
S5, hot setting processing:Material temperature is heated to by the fine and close carbon fibre material that S4 is obtained by Electromagnetic Heating 135 DEG C, forming and hardening, No. 4 products are made.
Embodiment 5:
S1, utilize carbon cloth making carbon fiber layer 1;The mass fraction of carbon fiber is 92 parts in the carbon cloth, tree The mass fraction of fat is 8 parts.
S2, polyacrylamide is not coated by, directly carries out S3;
S3, overlay film application of vacuum:Polymerization technique is cracked by ring disome to polymerize to form poly- pair in the obtained material surfaces of S2 Diformazan benzene layer 3, step is as follows:
S31, in vacuum film formation equipment, solid-state ring disome is gaseous state ring disome in 170 DEG C of distillations;
S32, gaseous state ring disome are cracked into stable unimolecule at 700 DEG C;
S33, unimolecule enter in vacuum moulding machine room, adsorb on the surface of S2 resulting materials, and polymerize and to form linear poly- pair Dimethylbenzene film.
S4, high pressure rolling fusion treatment:Using high pressure roll unit, the material obtained with roller rolling press S3, densification is obtained Carbon fibre material, for temperature control at 110 DEG C, rolling drafts is 0.12mm;
S5, hot setting processing:Material temperature is heated to by the fine and close carbon fibre material that S4 is obtained by Electromagnetic Heating 150 DEG C, forming and hardening, No. 5 products are made.
Embodiment 6:
S1, utilize carbon cloth making carbon fiber layer 1;The mass fraction of carbon fiber is 90.5 parts in the carbon cloth, The mass fraction of resin is 9.5 parts.
S2, polyacrylamide is not coated by, directly carries out S3;
S3, overlay film application of vacuum:Polymerization technique is cracked by ring disome to polymerize to form poly- pair in the obtained material surfaces of S2 Diformazan benzene layer 3, step is as follows:
S31, in vacuum film formation equipment, solid-state ring disome is gaseous state ring disome in 160 DEG C of distillations;
S32, gaseous state ring disome are cracked into stable unimolecule at 690 DEG C;
S33, unimolecule enter in vacuum moulding machine room, adsorb on the surface of S2 resulting materials, and polymerize and to form linear poly- pair Dimethylbenzene film.
S4, high pressure rolling fusion treatment:Using high pressure roll unit, the material obtained with roller rolling press S3, densification is obtained Carbon fibre material, for temperature control at 100 DEG C, rolling drafts is 0.1mm;
S5, hot setting processing:Material temperature is heated to by the fine and close carbon fibre material that S4 is obtained by Electromagnetic Heating 143 DEG C, forming and hardening, No. 6 products are made.
Embodiment 7:
S1, utilize carbon cloth making carbon fiber layer 1;The mass fraction of carbon fiber is 89 parts in the carbon cloth, tree The mass fraction of fat is 11 parts.
S2, coating polyacrylamide:On the surface of carbon fiber layer 1, polyacrylamide thick coating 0.85mm, obtains polypropylene Amide layer 2;
S3, overlay film application of vacuum:Polymerization technique is cracked by ring disome to polymerize to form poly- pair in the obtained material surfaces of S2 Diformazan benzene layer 3, step is as follows:
S31, in vacuum film formation equipment, solid-state ring disome is gaseous state ring disome in 150 DEG C of distillations;
S32, gaseous state ring disome are cracked into stable unimolecule at 680 DEG C;
S33, unimolecule enter in vacuum moulding machine room, adsorb on the surface of S2 resulting materials, and polymerize and to form linear poly- pair Dimethylbenzene film.
S4, without high pressure roll fusion treatment, be directly entered S5;
S5, hot setting processing:Material temperature is heated to by the fine and close carbon fibre material that S4 is obtained by Electromagnetic Heating 135 DEG C, forming and hardening, No. 7 products are made.
Embodiment 8:
S1, utilize carbon cloth making carbon fiber layer 1;The mass fraction of carbon fiber is 92 parts in the carbon cloth, tree The mass fraction of fat is 8 parts.
S2, coating polyacrylamide:On the surface of carbon fiber layer 1, polyacrylamide thick coating 1.0mm, obtains polyacrylamide Amine layer 2;
S3, overlay film application of vacuum:Polymerization technique is cracked by ring disome to polymerize to form poly- pair in the obtained material surfaces of S2 Diformazan benzene layer 3, step is as follows:
S31, in vacuum film formation equipment, solid-state ring disome is gaseous state ring disome in 170 DEG C of distillations;
S32, gaseous state ring disome are cracked into stable unimolecule at 700 DEG C;
S33, unimolecule enter in vacuum moulding machine room, adsorb on the surface of S2 resulting materials, and polymerize and to form linear poly- pair Dimethylbenzene film.
S4, without high pressure roll fusion treatment, be directly entered S5;
S5, hot setting processing:Material temperature is heated to by the fine and close carbon fibre material that S4 is obtained by Electromagnetic Heating 150 DEG C, forming and hardening, No. 8 products are made.
Embodiment 9:
S1, utilize carbon cloth making carbon fiber layer 1;The mass fraction of carbon fiber is 90.5 parts in the carbon cloth, The mass fraction of resin is 9.5 parts.
S2, coating polyacrylamide:On the surface of carbon fiber layer 1, polyacrylamide thick coating 0.93mm, obtains polypropylene Amide layer 2;
S3, overlay film application of vacuum:Polymerization technique is cracked by ring disome to polymerize to form poly- pair in the obtained material surfaces of S2 Diformazan benzene layer 3, step is as follows:
S31, in vacuum film formation equipment, solid-state ring disome is gaseous state ring disome in 160 DEG C of distillations;
S32, gaseous state ring disome are cracked into stable unimolecule at 690 DEG C;
S33, unimolecule enter in vacuum moulding machine room, adsorb on the surface of S2 resulting materials, and polymerize and to form linear poly- pair Dimethylbenzene film.
S4, without high pressure roll fusion treatment, be directly entered S5;
S5, hot setting processing:Material temperature is heated to by the fine and close carbon fibre material that S4 is obtained by Electromagnetic Heating 143 DEG C, forming and hardening, No. 9 products are made.
The surface roughness and interlaminar shear strength of 1-9 products are measured, obtains following table
It is can be seen that from above-mentioned test result by adding polyacrylamide amine layer 2, it will be apparent that it is strong to improve interlayer shear Degree, reduce the roughness after rolling;And high pressure rolling processing is utilized, significantly improving the same of interlaminar shear strength When, roughness also greatly reduces.
Above-mentioned embodiment cannot function as limiting the scope of the invention, for the technology people of the art For member, any alternate modification or conversion made to embodiment of the present invention are all fallen within protection scope of the present invention.
Part is not described in detail by the present invention, is the known technology of those skilled in the art of the present technique.

Claims (9)

  1. A kind of 1. carbon fibre material, it is characterised in that:Including set gradually from inside to outside carbon fiber layer, polyacrylamide amine layer, Parylene layer.
  2. A kind of 2. high pressure rolling manufacture craft for making a kind of carbon fibre material as claimed in claim 1, it is characterised in that:Bag Include following steps:
    S1, utilize carbon cloth making carbon fiber layer;
    S2, coating polyacrylamide:Polyacrylamide is coated on carbon fiber layer surface, obtains polyacrylamide amine layer;
    S3, overlay film application of vacuum:It polymerize to be formed in the obtained material surfaces of S2 by ring disome cracking polymerization technique and gathers to diformazan Benzene layer;
    S4, high pressure rolling fusion treatment:Using high pressure roll unit, the material obtained with roller rolling press S3, dense carbon fibre is obtained Tie up material;
    S5, hot setting processing:By the fine and close carbon fibre material that S4 is obtained by heating, material temperature is heated to 135-150 DEG C, forming and hardening, final products are made.
  3. A kind of 3. high pressure rolling manufacture craft of carbon fibre material according to claim 2, it is characterised in that:In S1, The mass fraction of carbon fiber is 89-92 parts in the carbon cloth, and the mass fraction of resin is 8-12 parts.
  4. A kind of 4. high pressure rolling manufacture craft of carbon fibre material according to claim 2, it is characterised in that:In S2, The thickness of the polyacrylamide amine layer is 0.85-1.0mm.
  5. A kind of 5. high pressure rolling manufacture craft of carbon fibre material according to claim 1, it is characterised in that:In S3, The ring disome cracking polymerization technique comprises the following steps:
    S31, in vacuum film formation equipment, solid-state ring disome is gaseous state ring disome in 150-170 DEG C of distillation;
    S32, gaseous state ring disome are cracked into stable unimolecule at 680-700 DEG C;
    S33, unimolecule enter in vacuum moulding machine room, adsorb on the surface of S2 resulting materials, and polymerize and to form linear gather to diformazan Benzene film.
  6. A kind of 6. high pressure rolling manufacture craft of carbon fibre material according to claim 2, it is characterised in that:In S4, The surface roughness of the fine and close carbon fibre material is R0.2-R2.4 μm.
  7. A kind of 7. high pressure rolling manufacture craft of carbon fibre material according to claim 2, it is characterised in that:In S5, The surface roughness of the fine and close carbon fibre material is R0.05-R0.1 μm.
  8. A kind of 8. high pressure rolling manufacture craft of carbon fibre material according to claim 2, it is characterised in that:In S5, Mode of heating is Electromagnetic Heating.
  9. A kind of 9. high pressure rolling manufacture craft of carbon fibre material according to claim 2, it is characterised in that:In S4, For temperature control at 90-110 DEG C, rolling drafts is 0.08-0.12mm.
CN201710607937.9A 2017-07-24 2017-07-24 A kind of carbon fibre material and its high pressure roll manufacture craft Active CN107366165B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710607937.9A CN107366165B (en) 2017-07-24 2017-07-24 A kind of carbon fibre material and its high pressure roll manufacture craft

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710607937.9A CN107366165B (en) 2017-07-24 2017-07-24 A kind of carbon fibre material and its high pressure roll manufacture craft

Publications (2)

Publication Number Publication Date
CN107366165A true CN107366165A (en) 2017-11-21
CN107366165B CN107366165B (en) 2019-10-11

Family

ID=60308401

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710607937.9A Active CN107366165B (en) 2017-07-24 2017-07-24 A kind of carbon fibre material and its high pressure roll manufacture craft

Country Status (1)

Country Link
CN (1) CN107366165B (en)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103276486A (en) * 2004-11-09 2013-09-04 得克萨斯大学体系董事会 Fabrication and application of nanofiber ribbons and sheets and twisted and non-twisted nanofiber yarns
CN104094440A (en) * 2011-11-24 2014-10-08 罗伯特·博世有限公司 Housing for a galvanic element consisting of carbon fibre-reinforced polymer with a moisture-impermeable layer, galvanic cell, rechargeable battery and motor vehicle
EP2970612A1 (en) * 2013-03-14 2016-01-20 University Of Surrey A carbon fibre reinforced plastic

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103276486A (en) * 2004-11-09 2013-09-04 得克萨斯大学体系董事会 Fabrication and application of nanofiber ribbons and sheets and twisted and non-twisted nanofiber yarns
CN104094440A (en) * 2011-11-24 2014-10-08 罗伯特·博世有限公司 Housing for a galvanic element consisting of carbon fibre-reinforced polymer with a moisture-impermeable layer, galvanic cell, rechargeable battery and motor vehicle
EP2970612A1 (en) * 2013-03-14 2016-01-20 University Of Surrey A carbon fibre reinforced plastic

Also Published As

Publication number Publication date
CN107366165B (en) 2019-10-11

Similar Documents

Publication Publication Date Title
CN107354760B (en) Low-temperature-deflection-resistant perforated breathable polyvinyl chloride artificial leather and preparation method thereof
WO2008064985A3 (en) Lightweight moulded piece and corresponding production method
WO2009016552A3 (en) A method of manufacturing a curved element made of composite material
CN105269833A (en) Two-time compression molding technology for thermoplastic composite material
CN102851997A (en) Method for manufacturing artificial leather with magnetic induction
CN107366165B (en) A kind of carbon fibre material and its high pressure roll manufacture craft
DE102016123562B4 (en) Process for treating a composite wrist pin and surface treated composite wrist pins
CN109612348B (en) Composite material missile wing and forming method thereof
CN101973153A (en) Composite molding technology
CN102493216A (en) TPU leather and preparation method thereof
CN206144924U (en) Fastener
JP2016153216A5 (en)
CN104924731B (en) A kind of combined producing tech of the flexible unleaded gamma shielding material of rolling
CN107379579B (en) A kind of flat coiled form method for winding of carbon fiber and carbon fiber bar processing technology based on this method
CN105644024A (en) High strength carbon fiber composite cloth for earthquake resistant and hazard reducing buildings and processing technology thereof
CN107214990A (en) A kind of daggers and swords formula method for winding of carbon fiber and the carbon fiber bar processing technology based on this method
CN106715995A (en) Heat insulation material and method for producing same
DE102010049457A1 (en) Roller or roller element with reinforced roll shell
CN107399094A (en) A kind of gene formula method for winding of carbon fiber and the carbon fiber bar processing technology based on this method
TWI616324B (en) Soft carbon fiber composite with three-dimensional surface textures and method for manufacturing the same
CN108789918B (en) Preparation method of preformed body and fiber fabric intermediate
CN103660304B (en) Thermoplastic gasket in individual protection helmet and manufacturing method of thermoplastic gasket
CN108437487A (en) A kind of polyphenyl thioether composite material and preparation method thereof of high content of glass fiber
CN205443741U (en) Dark line organic silicon synthetic leather
CN209869447U (en) Carbon fiber felt composite glass fiber knitted felt prepreg

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
TA01 Transfer of patent application right

Effective date of registration: 20181031

Address after: 250000 Shandong, Shandong, Ji'nan, Cape of Good Hope, No. 800, Minghu West Road, Cape of Good Hope, A 1601

Applicant after: Shandong Yingda Fishing Tackle Co. Ltd.

Address before: 250000 Ginza, Cape of Good Hope, A, 1601, Ming Hu West Road, Tianqiao District, Ji'nan, Shandong 1601

Applicant before: Wang Wei

TA01 Transfer of patent application right
GR01 Patent grant
GR01 Patent grant