CN107366165A - A kind of carbon fibre material and its high pressure rolling manufacture craft - Google Patents
A kind of carbon fibre material and its high pressure rolling manufacture craft Download PDFInfo
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- CN107366165A CN107366165A CN201710607937.9A CN201710607937A CN107366165A CN 107366165 A CN107366165 A CN 107366165A CN 201710607937 A CN201710607937 A CN 201710607937A CN 107366165 A CN107366165 A CN 107366165A
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- carbon fibre
- high pressure
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06N3/042—Acrylic polymers
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0015—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Carbon And Carbon Compounds (AREA)
- Inorganic Fibers (AREA)
- Moulding By Coating Moulds (AREA)
- Reinforced Plastic Materials (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
Abstract
A kind of carbon fibre material and its high pressure rolling manufacture craft, including carbon fiber layer, polyacrylamide amine layer, the parylene layer set gradually from inside to outside.Carbon fiber surface surface roughness can be brought up to Ra2.4~Ra0.2 μm by the present invention from original Ra6.3, and 0.1 μm of Ra0.05 mirror surface accuracy can be even realized by control condition;And surface is obtained extruding hardening, wearability, fatigue strength improve;Surface stress plastic deformation is eliminated, dimensional accuracy relatively long-term can keep stable;After rolling, carbon fiber material hardness can improve 15~30%, and fatigue resistance improves more than 15%;Due to rolled fiber material surface deformation, make textura epidermoidea's cold hardening and crystal grains fine, form fine and close threadiness, and form residual stress layer, hardness and intensity improve, so as to improve the wearability on essence material surface, corrosion resistance and conformability, the interlaminar shear strength for making final products using this technique brings up to 95 99MPa by 55-70MPa.
Description
Technical field:
The present invention relates to a kind of carbon fibre material and its high pressure rolling manufacture craft.
Background technology:
Nowadays in the market is a kind of referred to as T-shaped commonly using the two kinds of carbon fibre material for making high-end fishing rod,
One kind is referred to as M types.The phosphorus content of T-shaped carbon fibre material is general all 75% or so, resin content 25% or so, has fine
Stretching and tough sexual function, its defect cause its hardness to decline, weight is laid particular stress on precisely due to content resin is too high.M type carbon fibers
Cloth phosphorus content 85% or so, resin 15% or so, there is good hardness, and weight is also light, but because resin content is inclined
Low, its toughness and drawing effect substantially reduces.In addition, carbon fiber surface is smooth, inertia is big, has chemically active functional group
It is few, cause the interface binding intensity between carbon fiber and matrix resin low, interface has more defect, often as composite
Weak link.Prior art does not have the plan of solution to this.
The content of the invention:
The present invention is in order to make up the deficiencies in the prior art, there is provided a kind of carbon fibre material and its high pressure rolling make work
Skill, its rational technology, surface roughness substantially reduce, and interlaminar shear strength greatly improves, and solves present in prior art
Problem.
The present invention is that technical scheme is used by solving above-mentioned technical problem:
A kind of carbon fibre material, including carbon fiber layer, polyacrylamide amine layer, the Parylene set gradually from inside to outside
Layer.
A kind of high pressure rolling manufacture craft of carbon fibre material, comprises the following steps:
S1, utilize carbon cloth making carbon fiber layer;
S2, coating polyacrylamide:Polyacrylamide is coated on carbon fiber layer surface, obtains polyacrylamide amine layer;
S3, overlay film application of vacuum:Polymerization technique is cracked by ring disome to polymerize to form poly- pair in the obtained material surfaces of S2
Diformazan benzene layer;
S4, high pressure rolling fusion treatment:Using high pressure roll unit, the material obtained with roller rolling press S3, densification is obtained
Carbon fibre material;
S5, hot setting processing:By the fine and close carbon fibre material that S4 is obtained by heating, material temperature is heated to 135-
150 DEG C, forming and hardening, final products are made.
Preferably, in S1, the mass fraction of carbon fiber is 89-92 parts in the carbon cloth, the mass fraction of resin
For 8-11 parts.
Preferably, in S2, the thickness of the polyacrylamide amine layer is 0.85-1.0mm.
Preferably, in S3, the ring disome cracking polymerization technique comprises the following steps:
S31, in vacuum film formation equipment, solid-state ring disome is gaseous state ring disome in 150-170 DEG C of distillation;
S32, gaseous state ring disome are cracked into stable unimolecule at 680-700 DEG C;
S33, unimolecule enter in vacuum moulding machine room, adsorb on the surface of S2 resulting materials, and polymerize and to form linear poly- pair
Dimethylbenzene film.
Preferably, in S4, the surface roughness of the fine and close carbon fibre material is R0.2-R2.4 μm.
Preferably, in S5, the surface roughness of the fine and close carbon fibre material is R0.05-R0.1 μm.
Preferably, in S5, mode of heating is Electromagnetic Heating.
Preferably, in S4, for temperature control at 90-110 DEG C, rolling drafts is 0.08-0.12mm.
The present invention uses such scheme, and the technology of the present invention can improve carbon fiber surface surface roughness from original Ra6.3
To Ra2.4~Ra0.2 μm, Ra0.05-0.1 μm of mirror surface accuracy can be even realized by control condition;And obtain surface
Extruding hardening, wearability, fatigue strength improve;Surface stress plastic deformation is eliminated, dimensional accuracy relatively long-term can keep steady
It is fixed;After rolling, carbon fiber material hardness can improve 15~30%, and fatigue resistance improves more than 15%;Due to rolled
Fiber material surface deformation, make textura epidermoidea's cold hardening and crystal grains fine, form the threadiness of densification, and form residual stress
Layer, hardness and intensity improve, and so as to improve the wearability on essence material surface, corrosion resistance and conformability, are made most using this technique
The interlaminar shear strength of finished product brings up to 95-99MPa by 55-70MPa.
Brief description of the drawings:
Fig. 1 is the structural representation of the present invention.
In figure:1st, carbon fiber layer, 2, polyacrylamide amine layer, 3, parylene layer.
Embodiment:
For the technical characterstic for illustrating this programme can be understood, below by embodiment, and its accompanying drawing is combined, to this hair
It is bright to be described in detail.
As shown in figure 1, a kind of carbon fibre material, including set gradually from inside to outside carbon fiber layer 1, polyacrylamide amine layer
2nd, parylene layer 3.
A kind of high pressure rolling manufacture craft of carbon fibre material, comprises the following steps:
S1, utilize carbon cloth making carbon fiber layer 1;
S2, coating polyacrylamide:Polyacrylamide is coated on the surface of carbon fiber layer 1, obtains polyacrylamide amine layer 2;
S3, overlay film application of vacuum:Polymerization technique is cracked by ring disome to polymerize to form poly- pair in the obtained material surfaces of S2
Diformazan benzene layer 3;Parylene layer 3 is attached to outside, can prevent or alleviate extraneous dirty erosion and the generation of broken ring factor, from
And play a protective role, extend product service life.
S4, high pressure rolling fusion treatment:Using high pressure roll unit, the material obtained with roller rolling press S3, densification is obtained
Carbon fibre material;With the surface of the above-mentioned carbon fibre material of roller rolling press, make its fine and close, by carbon fiber surface surface roughness from Ra6.3
Ra0.2-Ra2.4 μm is brought up to, realizes Ra0.05-Ra0.1 μm of mirror surface accuracy;And surface is obtained extruding and harden, wearability,
Fatigue strength improves;Surface stress plastic deformation is eliminated, dimensional accuracy relatively long-term can keep stable.After rolling, make
Carbon fiber material hardness can improve 15~30%, and fatigue resistance improves 15%.Due to rolled fiber material surface deformation,
Making textura epidermoidea's cold hardening and crystal grains fine, form the threadiness of densification, and form residual stress layer, hardness and intensity improve,
So as to improve the wearability on essence material surface, corrosion resistance and conformability.
S5, hot setting processing:By the fine and close carbon fibre material that S4 is obtained by heating, material temperature is heated to 135-
150 DEG C, forming and hardening, final products are made.
In S1, the mass fraction of carbon fiber is 89-92 parts in the carbon cloth, and the mass fraction of resin is 8-11
Part.The content of raising carbon itself can improve the hardness of material and mitigate weight.
In S2, the thickness of the polyacrylamide amine layer 2 is 0.85-1.0mm.As the transition zone outside carbon fiber layer 1,
Because itself has caking property, so can be good inside and outside fusion two layers, and can make up the carbon content of carbon fiber layer 1 it is high and
Caused by toughness weaken the shortcomings that, improve the toughness of its own.
In S3, the ring disome cracking polymerization technique comprises the following steps:
S31, in vacuum film formation equipment, solid-state ring disome is gaseous state ring disome in 150-170 DEG C of distillation;
S32, gaseous state ring disome are cracked into stable unimolecule at 680-700 DEG C;
S33, unimolecule enter in vacuum moulding machine room, adsorb on the surface of S2 resulting materials, and polymerize and to form linear poly- pair
Dimethylbenzene film.
In S4, the surface roughness of the fine and close carbon fibre material is R0.2-R2.4 μm.
In S5, the surface roughness of the fine and close carbon fibre material is R0.05-R0.1 μm.Because high pressure rolling is handled
Carbon fibre material is routine techniques, by controlling high pressure roll unit to control its surface roughness, due to polyacrylamide
The addition of layer 2, thus surface roughness can be reduced further, so as to improve the feel of user.
In S5, mode of heating is Electromagnetic Heating.Electromagnetic Heating is interior mode of heating, suitable for fine and close carbon fibre material
Hot setting processing.
In S4, for temperature control at 90-110 DEG C, rolling drafts is 0.08-0.12mm.
Embodiment 1:
S1, utilize carbon cloth making carbon fiber layer 1;The mass fraction of carbon fiber is 89 parts in the carbon cloth, tree
The mass fraction of fat is 11 parts.
S2, coating polyacrylamide:On the surface of carbon fiber layer 1, polyacrylamide thick coating 0.85mm, obtains polypropylene
Amide layer 2;
S3, overlay film application of vacuum:Polymerization technique is cracked by ring disome to polymerize to form poly- pair in the obtained material surfaces of S2
Diformazan benzene layer 3, step is as follows:
S31, in vacuum film formation equipment, solid-state ring disome is gaseous state ring disome in 150 DEG C of distillations;
S32, gaseous state ring disome are cracked into stable unimolecule at 680 DEG C;
S33, unimolecule enter in vacuum moulding machine room, adsorb on the surface of S2 resulting materials, and polymerize and to form linear poly- pair
Dimethylbenzene film.
S4, high pressure rolling fusion treatment:Using high pressure roll unit, the material obtained with roller rolling press S3, densification is obtained
Carbon fibre material, for temperature control at 90 DEG C, rolling drafts is 0.08mm;
S5, hot setting processing:Material temperature is heated to by the fine and close carbon fibre material that S4 is obtained by Electromagnetic Heating
135 DEG C, forming and hardening, No. 1 product is made.
Embodiment 2:
S1, utilize carbon cloth making carbon fiber layer 1;The mass fraction of carbon fiber is 92 parts in the carbon cloth, tree
The mass fraction of fat is 8 parts.
S2, coating polyacrylamide:On the surface of carbon fiber layer 1, polyacrylamide thick coating 1.0mm, obtains polyacrylamide
Amine layer 2;
S3, overlay film application of vacuum:Polymerization technique is cracked by ring disome to polymerize to form poly- pair in the obtained material surfaces of S2
Diformazan benzene layer 3, step is as follows:
S31, in vacuum film formation equipment, solid-state ring disome is gaseous state ring disome in 170 DEG C of distillations;
S32, gaseous state ring disome are cracked into stable unimolecule at 700 DEG C;
S33, unimolecule enter in vacuum moulding machine room, adsorb on the surface of S2 resulting materials, and polymerize and to form linear poly- pair
Dimethylbenzene film.
S4, high pressure rolling fusion treatment:Using high pressure roll unit, the material obtained with roller rolling press S3, densification is obtained
Carbon fibre material, for temperature control at 110 DEG C, rolling drafts is 0.12mm;
S5, hot setting processing:Material temperature is heated to by the fine and close carbon fibre material that S4 is obtained by Electromagnetic Heating
150 DEG C, forming and hardening, No. 2 products are made.
Embodiment 3:
S1, utilize carbon cloth making carbon fiber layer 1;The mass fraction of carbon fiber is 90.5 parts in the carbon cloth,
The mass fraction of resin is 9.5 parts.
S2, coating polyacrylamide:On the surface of carbon fiber layer 1, polyacrylamide thick coating 0.93mm, obtains polypropylene
Amide layer 2;
S3, overlay film application of vacuum:Polymerization technique is cracked by ring disome to polymerize to form poly- pair in the obtained material surfaces of S2
Diformazan benzene layer 3, step is as follows:
S31, in vacuum film formation equipment, solid-state ring disome is gaseous state ring disome in 160 DEG C of distillations;
S32, gaseous state ring disome are cracked into stable unimolecule at 690 DEG C;
S33, unimolecule enter in vacuum moulding machine room, adsorb on the surface of S2 resulting materials, and polymerize and to form linear poly- pair
Dimethylbenzene film.
S4, high pressure rolling fusion treatment:Using high pressure roll unit, the material obtained with roller rolling press S3, densification is obtained
Carbon fibre material, for temperature control at 100 DEG C, rolling drafts is 0.1mm;
S5, hot setting processing:Material temperature is heated to by the fine and close carbon fibre material that S4 is obtained by Electromagnetic Heating
143 DEG C, forming and hardening, No. 3 products are made.
Embodiment 4:
S1, utilize carbon cloth making carbon fiber layer 1;The mass fraction of carbon fiber is 89 parts in the carbon cloth, tree
The mass fraction of fat is 11 parts.
S2, polyacrylamide is not coated by, directly carries out S3;
S3, overlay film application of vacuum:Polymerization technique is cracked by ring disome to polymerize to form poly- pair in the obtained material surfaces of S2
Diformazan benzene layer 3, step is as follows:
S31, in vacuum film formation equipment, solid-state ring disome is gaseous state ring disome in 150 DEG C of distillations;
S32, gaseous state ring disome are cracked into stable unimolecule at 680 DEG C;
S33, unimolecule enter in vacuum moulding machine room, adsorb on the surface of S2 resulting materials, and polymerize and to form linear poly- pair
Dimethylbenzene film.
S4, high pressure rolling fusion treatment:Using high pressure roll unit, the material obtained with roller rolling press S3, densification is obtained
Carbon fibre material, for temperature control at 90 DEG C, rolling drafts is 0.08mm;
S5, hot setting processing:Material temperature is heated to by the fine and close carbon fibre material that S4 is obtained by Electromagnetic Heating
135 DEG C, forming and hardening, No. 4 products are made.
Embodiment 5:
S1, utilize carbon cloth making carbon fiber layer 1;The mass fraction of carbon fiber is 92 parts in the carbon cloth, tree
The mass fraction of fat is 8 parts.
S2, polyacrylamide is not coated by, directly carries out S3;
S3, overlay film application of vacuum:Polymerization technique is cracked by ring disome to polymerize to form poly- pair in the obtained material surfaces of S2
Diformazan benzene layer 3, step is as follows:
S31, in vacuum film formation equipment, solid-state ring disome is gaseous state ring disome in 170 DEG C of distillations;
S32, gaseous state ring disome are cracked into stable unimolecule at 700 DEG C;
S33, unimolecule enter in vacuum moulding machine room, adsorb on the surface of S2 resulting materials, and polymerize and to form linear poly- pair
Dimethylbenzene film.
S4, high pressure rolling fusion treatment:Using high pressure roll unit, the material obtained with roller rolling press S3, densification is obtained
Carbon fibre material, for temperature control at 110 DEG C, rolling drafts is 0.12mm;
S5, hot setting processing:Material temperature is heated to by the fine and close carbon fibre material that S4 is obtained by Electromagnetic Heating
150 DEG C, forming and hardening, No. 5 products are made.
Embodiment 6:
S1, utilize carbon cloth making carbon fiber layer 1;The mass fraction of carbon fiber is 90.5 parts in the carbon cloth,
The mass fraction of resin is 9.5 parts.
S2, polyacrylamide is not coated by, directly carries out S3;
S3, overlay film application of vacuum:Polymerization technique is cracked by ring disome to polymerize to form poly- pair in the obtained material surfaces of S2
Diformazan benzene layer 3, step is as follows:
S31, in vacuum film formation equipment, solid-state ring disome is gaseous state ring disome in 160 DEG C of distillations;
S32, gaseous state ring disome are cracked into stable unimolecule at 690 DEG C;
S33, unimolecule enter in vacuum moulding machine room, adsorb on the surface of S2 resulting materials, and polymerize and to form linear poly- pair
Dimethylbenzene film.
S4, high pressure rolling fusion treatment:Using high pressure roll unit, the material obtained with roller rolling press S3, densification is obtained
Carbon fibre material, for temperature control at 100 DEG C, rolling drafts is 0.1mm;
S5, hot setting processing:Material temperature is heated to by the fine and close carbon fibre material that S4 is obtained by Electromagnetic Heating
143 DEG C, forming and hardening, No. 6 products are made.
Embodiment 7:
S1, utilize carbon cloth making carbon fiber layer 1;The mass fraction of carbon fiber is 89 parts in the carbon cloth, tree
The mass fraction of fat is 11 parts.
S2, coating polyacrylamide:On the surface of carbon fiber layer 1, polyacrylamide thick coating 0.85mm, obtains polypropylene
Amide layer 2;
S3, overlay film application of vacuum:Polymerization technique is cracked by ring disome to polymerize to form poly- pair in the obtained material surfaces of S2
Diformazan benzene layer 3, step is as follows:
S31, in vacuum film formation equipment, solid-state ring disome is gaseous state ring disome in 150 DEG C of distillations;
S32, gaseous state ring disome are cracked into stable unimolecule at 680 DEG C;
S33, unimolecule enter in vacuum moulding machine room, adsorb on the surface of S2 resulting materials, and polymerize and to form linear poly- pair
Dimethylbenzene film.
S4, without high pressure roll fusion treatment, be directly entered S5;
S5, hot setting processing:Material temperature is heated to by the fine and close carbon fibre material that S4 is obtained by Electromagnetic Heating
135 DEG C, forming and hardening, No. 7 products are made.
Embodiment 8:
S1, utilize carbon cloth making carbon fiber layer 1;The mass fraction of carbon fiber is 92 parts in the carbon cloth, tree
The mass fraction of fat is 8 parts.
S2, coating polyacrylamide:On the surface of carbon fiber layer 1, polyacrylamide thick coating 1.0mm, obtains polyacrylamide
Amine layer 2;
S3, overlay film application of vacuum:Polymerization technique is cracked by ring disome to polymerize to form poly- pair in the obtained material surfaces of S2
Diformazan benzene layer 3, step is as follows:
S31, in vacuum film formation equipment, solid-state ring disome is gaseous state ring disome in 170 DEG C of distillations;
S32, gaseous state ring disome are cracked into stable unimolecule at 700 DEG C;
S33, unimolecule enter in vacuum moulding machine room, adsorb on the surface of S2 resulting materials, and polymerize and to form linear poly- pair
Dimethylbenzene film.
S4, without high pressure roll fusion treatment, be directly entered S5;
S5, hot setting processing:Material temperature is heated to by the fine and close carbon fibre material that S4 is obtained by Electromagnetic Heating
150 DEG C, forming and hardening, No. 8 products are made.
Embodiment 9:
S1, utilize carbon cloth making carbon fiber layer 1;The mass fraction of carbon fiber is 90.5 parts in the carbon cloth,
The mass fraction of resin is 9.5 parts.
S2, coating polyacrylamide:On the surface of carbon fiber layer 1, polyacrylamide thick coating 0.93mm, obtains polypropylene
Amide layer 2;
S3, overlay film application of vacuum:Polymerization technique is cracked by ring disome to polymerize to form poly- pair in the obtained material surfaces of S2
Diformazan benzene layer 3, step is as follows:
S31, in vacuum film formation equipment, solid-state ring disome is gaseous state ring disome in 160 DEG C of distillations;
S32, gaseous state ring disome are cracked into stable unimolecule at 690 DEG C;
S33, unimolecule enter in vacuum moulding machine room, adsorb on the surface of S2 resulting materials, and polymerize and to form linear poly- pair
Dimethylbenzene film.
S4, without high pressure roll fusion treatment, be directly entered S5;
S5, hot setting processing:Material temperature is heated to by the fine and close carbon fibre material that S4 is obtained by Electromagnetic Heating
143 DEG C, forming and hardening, No. 9 products are made.
The surface roughness and interlaminar shear strength of 1-9 products are measured, obtains following table
It is can be seen that from above-mentioned test result by adding polyacrylamide amine layer 2, it will be apparent that it is strong to improve interlayer shear
Degree, reduce the roughness after rolling;And high pressure rolling processing is utilized, significantly improving the same of interlaminar shear strength
When, roughness also greatly reduces.
Above-mentioned embodiment cannot function as limiting the scope of the invention, for the technology people of the art
For member, any alternate modification or conversion made to embodiment of the present invention are all fallen within protection scope of the present invention.
Part is not described in detail by the present invention, is the known technology of those skilled in the art of the present technique.
Claims (9)
- A kind of 1. carbon fibre material, it is characterised in that:Including set gradually from inside to outside carbon fiber layer, polyacrylamide amine layer, Parylene layer.
- A kind of 2. high pressure rolling manufacture craft for making a kind of carbon fibre material as claimed in claim 1, it is characterised in that:Bag Include following steps:S1, utilize carbon cloth making carbon fiber layer;S2, coating polyacrylamide:Polyacrylamide is coated on carbon fiber layer surface, obtains polyacrylamide amine layer;S3, overlay film application of vacuum:It polymerize to be formed in the obtained material surfaces of S2 by ring disome cracking polymerization technique and gathers to diformazan Benzene layer;S4, high pressure rolling fusion treatment:Using high pressure roll unit, the material obtained with roller rolling press S3, dense carbon fibre is obtained Tie up material;S5, hot setting processing:By the fine and close carbon fibre material that S4 is obtained by heating, material temperature is heated to 135-150 DEG C, forming and hardening, final products are made.
- A kind of 3. high pressure rolling manufacture craft of carbon fibre material according to claim 2, it is characterised in that:In S1, The mass fraction of carbon fiber is 89-92 parts in the carbon cloth, and the mass fraction of resin is 8-12 parts.
- A kind of 4. high pressure rolling manufacture craft of carbon fibre material according to claim 2, it is characterised in that:In S2, The thickness of the polyacrylamide amine layer is 0.85-1.0mm.
- A kind of 5. high pressure rolling manufacture craft of carbon fibre material according to claim 1, it is characterised in that:In S3, The ring disome cracking polymerization technique comprises the following steps:S31, in vacuum film formation equipment, solid-state ring disome is gaseous state ring disome in 150-170 DEG C of distillation;S32, gaseous state ring disome are cracked into stable unimolecule at 680-700 DEG C;S33, unimolecule enter in vacuum moulding machine room, adsorb on the surface of S2 resulting materials, and polymerize and to form linear gather to diformazan Benzene film.
- A kind of 6. high pressure rolling manufacture craft of carbon fibre material according to claim 2, it is characterised in that:In S4, The surface roughness of the fine and close carbon fibre material is R0.2-R2.4 μm.
- A kind of 7. high pressure rolling manufacture craft of carbon fibre material according to claim 2, it is characterised in that:In S5, The surface roughness of the fine and close carbon fibre material is R0.05-R0.1 μm.
- A kind of 8. high pressure rolling manufacture craft of carbon fibre material according to claim 2, it is characterised in that:In S5, Mode of heating is Electromagnetic Heating.
- A kind of 9. high pressure rolling manufacture craft of carbon fibre material according to claim 2, it is characterised in that:In S4, For temperature control at 90-110 DEG C, rolling drafts is 0.08-0.12mm.
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Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN103276486A (en) * | 2004-11-09 | 2013-09-04 | 得克萨斯大学体系董事会 | Fabrication and application of nanofiber ribbons and sheets and twisted and non-twisted nanofiber yarns |
CN104094440A (en) * | 2011-11-24 | 2014-10-08 | 罗伯特·博世有限公司 | Housing for a galvanic element consisting of carbon fibre-reinforced polymer with a moisture-impermeable layer, galvanic cell, rechargeable battery and motor vehicle |
EP2970612A1 (en) * | 2013-03-14 | 2016-01-20 | University Of Surrey | A carbon fibre reinforced plastic |
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2017
- 2017-07-24 CN CN201710607937.9A patent/CN107366165B/en active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103276486A (en) * | 2004-11-09 | 2013-09-04 | 得克萨斯大学体系董事会 | Fabrication and application of nanofiber ribbons and sheets and twisted and non-twisted nanofiber yarns |
CN104094440A (en) * | 2011-11-24 | 2014-10-08 | 罗伯特·博世有限公司 | Housing for a galvanic element consisting of carbon fibre-reinforced polymer with a moisture-impermeable layer, galvanic cell, rechargeable battery and motor vehicle |
EP2970612A1 (en) * | 2013-03-14 | 2016-01-20 | University Of Surrey | A carbon fibre reinforced plastic |
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