CN104087189B - A kind of protective membrane of adhesive face softness and production technique thereof - Google Patents

A kind of protective membrane of adhesive face softness and production technique thereof Download PDF

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Publication number
CN104087189B
CN104087189B CN201410321942.XA CN201410321942A CN104087189B CN 104087189 B CN104087189 B CN 104087189B CN 201410321942 A CN201410321942 A CN 201410321942A CN 104087189 B CN104087189 B CN 104087189B
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China
Prior art keywords
solvent
adhesive face
protective membrane
type
linking agent
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Expired - Fee Related
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CN201410321942.XA
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Chinese (zh)
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CN104087189A (en
Inventor
薛卓臣
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FOSHAN KERN FINE MATERIALS Co Ltd
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FOSHAN KERN FINE MATERIALS Co Ltd
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Abstract

The invention discloses a kind of protective membrane and production technique thereof of adhesive face softness, comprise protective membrane body and be attached to the adhesive face of protective membrane body surface, adhesive face component by weight, comprising: solvent 550 parts; Linking agent 21 parts; 11 parts, solidifying agent; Resin 1000 parts; Solvent comprises the different solvent orange 2 A of boiling point and solvent B mixes, and solvent orange 2 A is solvent TOL; Solvent B is solvent MEK or solvent IPA; Linking agent comprises one or both mixing in 7387 type linking agents and 9250 type linking agents; Resin is 7650 type resins.The adhesive face thickness of protective membrane of the present invention is even, soft, and protective membrane and screen are fitted stable, have self-bleeding effect, can not produce bubble, adhesive face difficult drop-off, can secondary laminating.

Description

A kind of protective membrane of adhesive face softness and production technique thereof
Technical field
The present invention relates to a kind of protective membrane and production technique thereof, in particular a kind of protective membrane of adhesive face softness and production technique thereof.
Background technology
Touch screen electronic product on the market generally all posts the protective membrane of protection screen, and protective membrane on the market generally scribbles sizing agent, makes the contact surface of protective membrane and screen (i.e. adhesive face) have certain viscosity, and what make that protective membrane can be stable is attached on screen.But due to the less stable of sizing agent, the combination of adhesive face and protective membrane is very unstable, after protective membrane uses for some time; torn; screen there will be the residue of a large amount of adhesive face, need again to clean screen, trouble changed by protective membrane.In addition, the protective membrane after tearing cannot carry out secondary laminating, causes waste.Finally, the adhesive face pliability being mixed with sizing agent is poor, and the laminating weak effect with screen, easily produces bubble.
Therefore, prior art has yet to be improved and developed.
Summary of the invention
The object of the present invention is to provide a kind of protective membrane and production technique thereof of adhesive face softness, the adhesive face being intended to solve traditional protective membrane is unstable, easily comes off, and pliability is poor simultaneously, easily produces the technical problem of bubble.
Technical scheme of the present invention is as follows: a kind of protective membrane of adhesive face softness, comprises protective membrane body and is attached to the adhesive face of protective membrane body surface, wherein, and described adhesive face componentby weight, comprising:
Solvent 550 ± 5.5 parts;
Linking agent 21 ± 0.021 parts;
11 ± 0.011 parts, solidifying agent;
Resin 1000 ± 1 parts;
Described solvent comprises the different solvent orange 2 A of boiling point and solvent B mixes, and described solvent orange 2 A is solvent TOL; Described solvent B is solvent MEK or solvent IPA;
Described linking agent comprises one or both mixing in 7387 type linking agents and 9250 type linking agents;
Described resin is 7650 type resins.
The protective membrane of described adhesive face softness, wherein, described solvent B is solvent MEK, and the blending ratio of described solvent orange 2 A and solvent B is 10:1.
The protective membrane of described adhesive face softness, wherein, described solvent B is solvent IPA, and the blending ratio of described solvent orange 2 A and solvent B is 10:1.
The protective membrane of described adhesive face softness, wherein, described linking agent comprises 7387 type linking agents and the two kinds of linking agent mixing of 9250 type linking agents, and its blending ratio is 4:3.
The protective membrane of described adhesive face softness, wherein, described solidifying agent is 4000 type solidifying agent.
The production technique of the protective membrane of described adhesive face softness, wherein, comprises the following steps:
A: preparation adhesive face liquid;
B: utilize coating machine that adhesive face uniform liquid is coated in protective membrane body surface, dries, and forms adhesive face;
C: rolling, obtains finished product protection film volume.
The production technique of the protective membrane of described adhesive face softness, wherein, described step a comprises the following steps:
A1: the 85%-90% getting the amount of 7650 type resins, 7387 type linking agents, 9250 type linking agents, solvent B and solvent orange 2 A, adds in agitation vat, stirs 35 minutes; Wherein solvent B selects solvent IPA or solvent MEK, and solvent orange 2 A selects solvent TOL;
A2:; Solvent orange 2 A under remainder dilutes 4000 type solidifying agent, adds in agitation vat, stir 4000 type solidifying agent after dilution 15 minutes, obtained adhesive face liquid.
The production technique of the protective membrane of described adhesive face softness, wherein, in described step b, the speed that unreels of coating machine is 12-16M/min.
Beneficial effect of the present invention: the adhesive face thickness of protective membrane of the present invention is even, soft, protective membrane and screen are fitted stable, and soft adhesive face has self-bleeding effect, can not produce bubble.In addition, adhesive face of the present invention is a kind of netted molecular structure, and adhesive face is combined stable with protective membrane main body; difficult drop-off; protective membrane can not produce residue after screen is torn, and without the need to cleaning screen, protective membrane of the present invention can realize repeatedly fitting.
Accompanying drawing explanation
Fig. 1 is the structural representation of the protective membrane of adhesive face softness in the present invention.
Embodiment
For making object of the present invention, technical scheme and advantage clearly, clearly, developing simultaneously referring to accompanying drawing, the present invention is described in more detail for embodiment.
The invention discloses a kind of protective membrane of adhesive face softness, its structure as shown in Figure 1, comprises protective membrane body 100 and is attached to the adhesive face 200 of protective membrane body surface.Adhesive face due to traditional protective membrane all adopts sizing agent to make, and its adhesive face structural instability, easily comes off, and can not fit by secondary, adhesive face pliability is little simultaneously, and easily produce bubble after fitting with screen, result of use is poor.The present invention is by improving the composition of adhesive face; adhesive face is made to form a kind of cancellated molecular structure; the stability of adopting this molecular structure is high; can well fit with protective membrane body; difficult drop-off; the present invention simultaneously utilizes 7650 type resins as adhesive face, and its flexibility is strong, has automatic vent effect.Below, by embodiment, the present invention will be described in detail.
Embodiment 1
Present embodiment discloses a kind of protective membrane of adhesive face softness, the component of its adhesive face by weight, comprising:
Solvent 550 parts;
Linking agent 21 parts;
11 parts, solidifying agent;
Resin 1000 parts;
In the present embodiment, solvent comprises the different solvent orange 2 A of boiling point and solvent B mixes, and solvent orange 2 A is solvent TOL; Solvent B is solvent MEK, and the blending ratio of solvent orange 2 A and solvent B is 10:1.In practical application, solvent B also can select solvent IPA, and when selecting solvent IPA, the blending ratio of solvent orange 2 A and solvent B is 10:1.The solvent that the present embodiment have employed two kinds of volatilization temperatures different mixes; the adhesive face liquid in the present embodiment is made to present a kind of stepped volatilization effect; volatilize compared to a kind of moment of solvent; the character of the adhesive face liquid of the present embodiment is more stable, is conducive to adhesive face and the stable laminating of protective membrane body.
In the present embodiment, resin adopts 7650 type resins, concrete, can adopt 7650 resins of Dow Corning Corporation.Resin in the present embodiment is a kind of molecular structure of chain, is glial state (state of matter between liquid and solid), has good continuity and flexibility, be extremely suitable as the composition of adhesive face.
In the present embodiment, linking agent comprises 7387 type linking agents and the two kinds of linking agent mixing of 9250 type linking agents, and its blending ratio is 4:3.Wherein 7387 type linking agents can adopt 7387 linking agents of Dow Corning Corporation, and 9250 type linking agents can adopt 9250 linking agents of Dow Corning Corporation.Concrete, after 7387 type linking agents and resin reaction, make that the molecular resin shape of chain-like structure is a kind of is similar to netted molecular structure; this cancellated stability of molecule is high, and associativity is strong, stable the fitting with protective membrane body of energy; even if repeatedly tear laminating, adhesive face also can not come off.Simultaneously at the contact surface of adhesive face with screen, adhesive face present a kind of softness, be with sticking character, what adhesive face can be stable fit with screen, and the adhesive face of softness has certain automatic ventilating function, laminating bubble-free generation afterwards.
In the present embodiment, 4000 solidifying agent of Dow Corning Corporation selected by solidifying agent.
In the present embodiment, the concrete steps of producing protective membrane are as follows:
A1: the 85%-90% getting the amount of 7650 type resins, 7387 type linking agents, 9250 type linking agents, solvent B and solvent orange 2 A, adds in agitation vat, stirs 35 minutes; Wherein solvent B selects solvent IPA or solvent MEK, and solvent orange 2 A selects solvent TOL; Produce a kind of cancellated molecular structure after 7650 type resins and the reaction of 7387 type linking agents, this cancellated stability of molecule is high, and associativity is strong, and stable the fitting with protective membrane body of energy, even if repeatedly tear laminating, adhesive face also can not come off.Simultaneously at the contact surface of adhesive face with screen, adhesive face present a kind of softness, be with sticking character, what adhesive face can be stable fit with screen, and the adhesive face of softness has certain automatic ventilating function, laminating bubble-free generation afterwards.
A2:; Solvent orange 2 A under remainder dilutes 4000 type solidifying agent, adds in agitation vat, stir 4000 type solidifying agent after dilution 15 minutes, obtained adhesive face liquid.
In practical application, protective membrane body is PET film, and in order to improve the baking and curing effect of adhesive face, what make that it can be stable fits with PET film, in the present embodiment, in step b, coating machine unreel speed control between 12-16M/min.
In step b in the present embodiment and c, adopt traditional protective membrane production technique, but must note regulating the speed unreeled with rolling, to reach best effect.
The adhesive face pliability that the present embodiment produces the protective membrane obtained is high, fits stable with PET film, though repeatedly protective membrane and screen are torn be separated after fit again, adhesive face also can not come off and remain on screen.Simultaneously at the contact surface of adhesive face with screen, adhesive face present a kind of softness, be with sticking character, what adhesive face can be stable fit with screen, and the adhesive face of softness has certain automatic ventilating function, laminating bubble-free generation afterwards.
In the present invention; the address of the raw material of above-mentioned production protective membrane is that these chemicals are in tradition address on the market; such as 7387 type linking agents (this address is the code name of product), are commonly considered as the linking agent of the same with 7387 linking agent character of Dow Corning Corporation (or very similar).Therefore; though the present invention adopts the tradition address of chemical agent; but not limiting can only be with this kind of chemical agent; the chemical agent identical or quite similar with this chemical agent character all falls within the scope of protection of the present invention; such as 7387 linking agents adopting Dow Corning Corporation disclosed in the embodiment of the present invention; but not only limit 7387 linking agents that can only adopt Dow Corning Corporation; any chemical agent identical with 7387 linking agent character of Dow Corning Corporation all can substitute 7387 linking agents of Dow Corning Corporation, does not enumerate at this.
Should be understood that, application of the present invention is not limited to above-mentioned citing, for those of ordinary skills, can be improved according to the above description or convert, and all these improve and convert the protection domain that all should belong to claims of the present invention.

Claims (4)

1. a protective membrane for adhesive face softness, for the protection of screen, comprises protective membrane body and is attached to the adhesive face of protective membrane body surface, it is characterized in that, described adhesive face componentby weight, comprising:
Solvent 550 ± 5.5 parts;
Linking agent 21 ± 0.021 parts;
11 ± 0.011 parts, solidifying agent;
Resin 1000 ± 1 parts;
Described solvent comprises the different solvent orange 2 A of boiling point and solvent B mixes, and described solvent orange 2 A is solvent TOL; Described solvent B is solvent MEK or solvent IPA; The blending ratio of described solvent orange 2 A and solvent B is 10:1;
Described linking agent comprises one or both mixing in DOW CORNING 7387 type linking agent and DOW CORNING 9250 type linking agent;
Described resin is DOW CORNING 7650 type resin;
Described solidifying agent is DOW CORNING 4000 type solidifying agent.
2. the protective membrane of adhesive face softness according to claim 1, is characterized in that, described linking agent comprises DOW CORNING 7387 type linking agent and the two kinds of linking agent mixing of DOW CORNING 9250 type linking agent, and its blending ratio is 4:3.
3. produce a production technique for the protective membrane of the adhesive face softness as described in claim 1-2 any one, it is characterized in that, comprise the following steps:
A: preparation adhesive face liquid;
B: utilize coating machine that adhesive face uniform liquid is coated in protective membrane body surface, dries, and forms adhesive face;
C: rolling, obtains finished product protection film volume;
Described step a comprises the following steps:
A1: by way of the 85%-90% of the amount of healthy and free from worry 7650 type resins, DOW CORNING 7387 type linking agent, DOW CORNING 9250 type linking agent, solvent B and solvent orange 2 A, add in agitation vat, stir 35 minutes; Wherein solvent B selects solvent IPA or solvent MEK, and solvent orange 2 A selects solvent TOL;
A2:; Solvent orange 2 A dilution DOW CORNING 4000 type solidifying agent under remainder, adds in agitation vat by the DOW CORNING 4000 type solidifying agent after dilution, stirs 15 minutes, obtained adhesive face liquid.
4. the production technique of the protective membrane of adhesive face softness according to claim 3, is characterized in that, in described step b, the speed that unreels of coating machine is 12-16M/min.
CN201410321942.XA 2014-07-08 2014-07-08 A kind of protective membrane of adhesive face softness and production technique thereof Expired - Fee Related CN104087189B (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104945649B (en) * 2015-06-08 2018-03-30 佛山伟利信电子材料有限公司 A kind of smooth release mould release membrance of weight in silicone oil face and its production technology
CN104845528B (en) * 2015-06-08 2017-06-16 佛山伟利信电子材料有限公司 A kind of ventilative fire-resisting protection film and its production technology

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1724127A (en) * 2005-06-16 2006-01-25 南京工业大学 Organic and inorganic composite hydrophobic film and its preparing process
US20060148956A1 (en) * 2004-12-30 2006-07-06 Jung Ki S Anisotropic conductive film forming composition
CN102757692A (en) * 2011-06-10 2012-10-31 戴龙飞 Thermosetting system white ink composition of LED flexible strip plate

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060148956A1 (en) * 2004-12-30 2006-07-06 Jung Ki S Anisotropic conductive film forming composition
CN1724127A (en) * 2005-06-16 2006-01-25 南京工业大学 Organic and inorganic composite hydrophobic film and its preparing process
CN102757692A (en) * 2011-06-10 2012-10-31 戴龙飞 Thermosetting system white ink composition of LED flexible strip plate

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