CN106079738A - A kind of waterproof roll with electromagnetic shielding action - Google Patents

A kind of waterproof roll with electromagnetic shielding action Download PDF

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Publication number
CN106079738A
CN106079738A CN201610631130.4A CN201610631130A CN106079738A CN 106079738 A CN106079738 A CN 106079738A CN 201610631130 A CN201610631130 A CN 201610631130A CN 106079738 A CN106079738 A CN 106079738A
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CN
China
Prior art keywords
layer
waterproof
electromagnetic shielding
waterproof roll
shielding action
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201610631130.4A
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Chinese (zh)
Inventor
陈年宝
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Fuhua Novel Material Co Ltd Of Section In Hefei
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Fuhua Novel Material Co Ltd Of Section In Hefei
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fuhua Novel Material Co Ltd Of Section In Hefei filed Critical Fuhua Novel Material Co Ltd Of Section In Hefei
Priority to CN201610631130.4A priority Critical patent/CN106079738A/en
Publication of CN106079738A publication Critical patent/CN106079738A/en
Withdrawn legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B11/00Layered products comprising a layer of bituminous or tarry substances
    • B32B11/10Layered products comprising a layer of bituminous or tarry substances next to a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B11/00Layered products comprising a layer of bituminous or tarry substances
    • B32B11/04Layered products comprising a layer of bituminous or tarry substances comprising such bituminous or tarry substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B11/046Layered products comprising a layer of bituminous or tarry substances comprising such bituminous or tarry substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B25/00Layered products comprising a layer of natural or synthetic rubber
    • B32B25/04Layered products comprising a layer of natural or synthetic rubber comprising rubber as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B25/08Layered products comprising a layer of natural or synthetic rubber comprising rubber as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/04Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/20Properties of the layers or laminate having particular electrical or magnetic properties, e.g. piezoelectric
    • B32B2307/202Conductive
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/20Properties of the layers or laminate having particular electrical or magnetic properties, e.g. piezoelectric
    • B32B2307/212Electromagnetic interference shielding
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/554Wear resistance
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/582Tearability
    • B32B2307/5825Tear resistant
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/73Hydrophobic

Abstract

The invention provides a kind of waterproof roll with electromagnetic shielding action; including tire basic unit; the upper surface of described tire basic unit is provided with the first waterproof layer; the lower surface of tire basic unit is provided with the second waterproof layer; the upper surface of described first waterproof layer is provided with the first conductive rubber layer; the lower surface of described second waterproof layer is provided with the second conductive rubber layer, and another surface of described first conductive rubber layer and the second conductive rubber layer is provided with sealer.Described tire basic unit is nonwoven layer, and described first waterproof layer and the second waterproof layer are SBS modified asphalt layer, and described first conductive rubber layer and the second conductive rubber layer are Graphene/natural rubber nano composite material, and described sealer is PE film.Waterproof roll of the present invention, between each layer, cohesive is good, and preparation technology is simple, it is possible to be greatly improved the effectiveness of polymer modified asphalt waterproof roll, meets the demand in current building trade and market, has higher using value.

Description

A kind of waterproof roll with electromagnetic shielding action
Technical field
The present invention relates to architectural engineering waterproof material, be specifically related to a kind of waterproof roll with electromagnetic shielding action.
Background technology
Waterproof material is widely used in various industry and the roofing of civil buildings, the engineering waterproofing of basement, and subway, In the engineering waterproofing of the municipal administration such as tunnel, highway bridge and water conservancy projects, current waterproof roll collapse resistance power is poor, easily occurs puncturing Or tear phenomenon, need labor intensive, material resources to repair, shorten the service life of waterproof material, cause resource and fund Waste.
Waterproof roll is a kind of construction material conventional in construction, on road and bridge, roof or need waterproof building Build in the construction of thing, be required to the most paved waterproof roll.And waterproof roll conventional at present is high molecular polymer modification drip Green grass or young crops, according to the difference in the place of waterproof roll application, needs the property certain to waterproof roll, such as dirty in electromagnetic radiation Contaminate serious area, it is necessary to waterproof roll has certain electromagnetic shielding action, but waterproof roll does not have electromagnetic screen at present The effect covered, and developing and coming the soonest the application of more polyelectron appliance device rapidly along with present electromagnetic technique, various with The electromagnetic wave of the different frequency of energy brings interference greatly to health and the living environment of people, constitutes in life simultaneously " electromagnetic radiation pollution ", medical instrument, precision instrument are easily by Electromagnetic Interference, deal with improperly in military, economic field Greatly destruction can be caused, therefore the becoming more and more important of electromagnetic shielding problem.
Research and development have the polymer modified asphalt water-proof coiled material product of electromagnetic shielding action, can be greatly improved me Construction quality, create the social benefit that cannot estimate, external electromagnetic radiation pollution can not only be shielded, moreover it is possible to prevent military affairs, Economic information is stolen again by wireless signal, it is ensured that national, economic safety, has important social meaning and using value.
Summary of the invention
For defect of the prior art, it is an object of the invention to provide a kind of waterproof volume with electromagnetic shielding action Material, it is possible to effectively shield the electromagnetic radiation pollution of surrounding, and there is the water resistance of excellence.
The present invention solves technical problem and adopts the following technical scheme that
The present invention relates to a kind of waterproof roll with electromagnetic shielding action, including tire basic unit, the upper surface of described tire basic unit sets Having the first waterproof layer, the lower surface of tire basic unit to be provided with the second waterproof layer, the upper surface of described first waterproof layer is provided with the first conduction Rubber layer, the lower surface of described second waterproof layer is provided with the second conductive rubber layer, described first conductive rubber layer and the second conduction Another surface of rubber layer is provided with sealer.
Preferably, described tire basic unit is nonwoven layer.
Preferably, described first waterproof layer and the second waterproof layer are SBS modified asphalt layer.
Preferably, described SBS modified asphalt layer includes the chemical composition of following weight fraction: bitumen base 30 ~ 70 parts, SBS 10 ~ 20 parts, modifying agent 5 ~ 15 parts, inserts 15 ~ 30 parts, antioxidant 0.5 ~ 2 part, antistripping agent 0.1 ~ 1 part, softening agent 5 ~ 15 parts, toughener 0.5 ~ 2 part.
Preferably, the one during described modifying agent is butyl rubber, butadiene-styrene rubber.
Preferably, one or more during described inserts is Pulvis Talci, calcium carbonate, calcium phosphate.
Preferably, described first conductive rubber layer and the second conductive rubber layer are Graphene/natural rubber nano composite wood Material.
Preferably, described sealer is PE film.
Compared with prior art, the present invention has a following beneficial effect:
(1) a kind of waterproof roll with electromagnetic shielding action of the present invention, uses Graphene/natural rubber nano to be combined Material is as conductive layer, owing to Graphene has higher electrical conductivity, radius-thickness ratio and bigger surface area so that waterproof roll There is preferable electromagnetic shielding benefit.
(2) to carry out crosslinking compound for Graphene and natural rubber, is greatly improved the mechanical property of rubber, has the anti-tear of excellence Split and crocking resistance;
(3) described waterproof roll, between each layer, cohesive is good, and preparation technology is simple, it is possible to be greatly improved polymer modified asphalt The effectiveness of waterproof roll, meets the demand in current building trade and market, has higher using value.
Accompanying drawing explanation
By the detailed description non-limiting example made with reference to the following drawings of reading, the further feature of the present invention, Purpose and advantage will become more apparent upon:
Fig. 1 is the structural representation of the waterproof roll with electromagnetic shielding action of the present invention.
Detailed description of the invention
Below in conjunction with the accompanying drawings and specific embodiment, the present invention is expanded on further.These embodiments are merely to illustrate the present invention Rather than restriction the scope of the present invention.
Embodiment 1:
As it is shown in figure 1, the present invention relates to a kind of waterproof roll with electromagnetic shielding action, including tire basic unit 1, described tire basic unit The upper surface of 1 is provided with the first waterproof layer 2, and the lower surface of tire basic unit 1 is provided with the second waterproof layer 3, the upper table of described first waterproof layer 2 Face is provided with the first conductive rubber layer 4, and the lower surface of described second waterproof layer 3 is provided with the second conductive rubber layer 5, described first conduction Another surface of rubber layer 4 and the second conductive rubber layer 5 is provided with sealer 6.Wherein, described tire basic unit 1 is nonwoven layer, Described first waterproof layer 2 and the second waterproof layer 3 are SBS modified asphalt layer, described first conductive rubber layer 4 and the second conductive rubber Layer 5 is Graphene/natural rubber nano composite material, and described sealer 6 is PE film.
Wherein, described SBS modified asphalt layer includes the chemical composition of following weight fraction: bitumen base 50 parts, SBS 15 Part, modifying agent 10 parts, inserts 20 parts, antioxidant 1 part, antistripping agent 0.5 part, softening agent 10 parts, toughener 1 part.
Described modifying agent is butyl rubber, and described inserts is Pulvis Talci and calcium carbonate mixture.
The preparation of waterproof roll:
(1) preparation of SBS modified pitch: bitumen base is heated to 150 DEG C, adds softening agent reaction 0.5h, adds SBS group Point, it is sufficiently mixed, adds modifying agent, under the conditions of 180 DEG C, react 2h.Add according to proportioning in reactant mixture and fill Material, antioxidant, toughener, stirring reaction 40min, add antistripping agent, react 30min, reaction cools down after terminating, and i.e. makes Obtain modified pitch.
(2) preparation of Graphene/natural rubber nano composite material: by graphene dispersion in aqueous phase, then with rubber glue Breast mixing, obtains composite through flocculation, drying, mixing preparing.
(3) preparation of waterproof material: nonwoven layer tire basic unit is launched, respectively coats one layer of modification in tire basic unit upper and lower surface Bitumen layer, coating thickness is 1.5mm;At SBS modified asphalt layer surface-coated electricity rubber layer, i.e. Graphene/natural rubber nano Composite layer, coating thickness 0.5mm, PE film is covered on conductive rubber layer surface.
Embodiment 2:
The present invention relates to a kind of waterproof roll with electromagnetic shielding action, including tire basic unit, the upper surface of described tire basic unit sets Having the first waterproof layer, the lower surface of tire basic unit to be provided with the second waterproof layer, the upper surface of described first waterproof layer is provided with the first conduction Rubber layer, the lower surface of described second waterproof layer is provided with the second conductive rubber layer, described first conductive rubber layer and the second conduction Another surface of rubber layer is provided with sealer.Wherein, described tire basic unit is nonwoven layer, described first waterproof layer and second Waterproof layer is SBS modified asphalt layer, and described first conductive rubber layer and the second conductive rubber layer are Graphene/natural rubber nano Composite, described sealer is PE film.
Wherein, described SBS modified asphalt layer includes the chemical composition of following weight fraction: bitumen base 30 parts, SBS 10 Part, modifying agent 5 parts, inserts 15 parts, antioxidant 0.5 part, antistripping agent 0.1 part, softening agent 5 parts, toughener 0.5 part.
Described modifying agent is butadiene-styrene rubber, and described inserts is Pulvis Talci and calcium phosphate mixture.
The preparation of waterproof roll:
(1) preparation of SBS modified pitch: bitumen base is heated to 150 DEG C, adds softening agent reaction 0.5h, adds SBS group Point, it is sufficiently mixed, adds modifying agent, under the conditions of 180 DEG C, react 2h.Add according to proportioning in reactant mixture and fill Material, antioxidant, toughener, stirring reaction 40min, add antistripping agent, react 30min, reaction cools down after terminating, and i.e. makes Obtain modified pitch.
(2) preparation of Graphene/natural rubber nano composite material: by graphene dispersion in aqueous phase, then with rubber glue Breast mixing, obtains composite through flocculation, drying, mixing preparing.
(3) preparation of waterproof material: nonwoven layer tire basic unit is launched, respectively coats one layer of modification in tire basic unit upper and lower surface Bitumen layer, coating thickness is 1.5mm;At SBS modified asphalt layer surface-coated electricity rubber layer, i.e. Graphene/natural rubber nano Composite layer, coating thickness 0.5mm, PE film is covered on conductive rubber layer surface.
Embodiment 3:
The present invention relates to a kind of waterproof roll with electromagnetic shielding action, including tire basic unit, the upper surface of described tire basic unit sets Having the first waterproof layer, the lower surface of tire basic unit to be provided with the second waterproof layer, the upper surface of described first waterproof layer is provided with the first conduction Rubber layer, the lower surface of described second waterproof layer is provided with the second conductive rubber layer, described first conductive rubber layer and the second conduction Another surface of rubber layer is provided with sealer.Wherein, described tire basic unit is nonwoven layer, described first waterproof layer and second Waterproof layer is SBS modified asphalt layer, and described first conductive rubber layer and the second conductive rubber layer are Graphene/natural rubber nano Composite, described sealer is PE film.
Wherein, described SBS modified asphalt layer includes the chemical composition of following weight fraction: bitumen base 70 parts, SBS 20 Part, modifying agent 15 parts, inserts 30 parts, antioxidant 2 parts, antistripping agent 1 part, softening agent 15 parts, toughener 2 parts.
Described modifying agent is butadiene-styrene rubber, and described inserts is Pulvis Talci and calcium carbonate mixture.
The preparation of waterproof roll:
(1) preparation of SBS modified pitch: bitumen base is heated to 150 DEG C, adds softening agent reaction 0.5h, adds SBS group Point, it is sufficiently mixed, adds modifying agent, under the conditions of 180 DEG C, react 2h.Add according to proportioning in reactant mixture and fill Material, antioxidant, toughener, stirring reaction 40min, add antistripping agent, react 30min, reaction cools down after terminating, and i.e. makes Obtain modified pitch.
(2) preparation of Graphene/natural rubber nano composite material: by graphene dispersion in aqueous phase, then with rubber glue Breast mixing, obtains composite through flocculation, drying, mixing preparing.
(3) preparation of waterproof material: nonwoven layer tire basic unit is launched, respectively coats one layer of modification in tire basic unit upper and lower surface Bitumen layer, coating thickness is 1.5mm;At SBS modified asphalt layer surface-coated electricity rubber layer, i.e. Graphene/natural rubber nano Composite layer, coating thickness 0.5mm, PE film is covered on conductive rubber layer surface.
The waterproof roll with electromagnetic shielding action of the present invention, uses Graphene/natural rubber nano composite wood Material is as conductive layer, owing to Graphene has higher electrical conductivity, radius-thickness ratio and bigger surface area so that waterproof roll has There is preferable electromagnetic shielding benefit;It is compound that Graphene and natural rubber carry out crosslinking, is greatly improved the mechanical property of rubber, has Excellent anti tear and crocking resistance;Described waterproof roll, between each layer, cohesive is good, and preparation technology is simple, it is possible to significantly Improve the effectiveness of polymer modified asphalt waterproof roll, meet the demand in current building trade and market, have relatively High using value.
Above the specific embodiment of the present invention is described.It is to be appreciated that the invention is not limited in above-mentioned Particular implementation, those skilled in the art can make various deformation or amendment within the scope of the claims, this not shadow Ring the flesh and blood of the present invention.

Claims (8)

1. a waterproof roll with electromagnetic shielding action, it is characterised in that: include tire basic unit, the upper surface of described tire basic unit Being provided with the first waterproof layer, the lower surface of tire basic unit is provided with the second waterproof layer, and the upper surface of described first waterproof layer is provided with first and leads Electricity rubber layer, the lower surface of described second waterproof layer is provided with the second conductive rubber layer, and described first conductive rubber layer and second is led Another surface of electricity rubber layer is provided with sealer.
The waterproof roll with electromagnetic shielding action the most according to claim 1, it is characterised in that: described tire basic unit is nothing Spin layer of cloth.
The waterproof roll with electromagnetic shielding action the most according to claim 1, it is characterised in that: described first waterproof layer It is SBS modified asphalt layer with the second waterproof layer.
The waterproof roll with electromagnetic shielding action the most according to claim 3, it is characterised in that: described SBS modification drips Cyan layer includes the chemical composition of following weight fraction: bitumen base 30 ~ 70 parts, SBS 10 ~ 20 parts, modifying agent 5 ~ 15 parts, fills Expect 15 ~ 30 parts, antioxidant 0.5 ~ 2 part, antistripping agent 0.1 ~ 1 part, softening agent 5 ~ 15 parts, toughener 0.5 ~ 2 part.
The waterproof roll with electromagnetic shielding action the most according to claim 4, it is characterised in that: described modifying agent is fourth One in base rubber, butadiene-styrene rubber.
The waterproof roll with electromagnetic shielding action the most according to claim 4, it is characterised in that: described inserts is for sliding One or more in stone powder, calcium carbonate, calcium phosphate.
The waterproof roll with electromagnetic shielding action the most according to claim 1, it is characterised in that: described first conduction rubber Glue-line and the second conductive rubber layer are Graphene/natural rubber nano composite material.
The waterproof roll with electromagnetic shielding action the most according to claim 1, it is characterised in that: described sealer For PE film.
CN201610631130.4A 2016-08-04 2016-08-04 A kind of waterproof roll with electromagnetic shielding action Withdrawn CN106079738A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106868884A (en) * 2017-02-27 2017-06-20 合肥中科富华新材料有限公司 A kind of waterproof roll and preparation method with radiation protection
CN107059422A (en) * 2017-02-27 2017-08-18 合肥中科富华新材料有限公司 A kind of high-strength abrasion-proof waterproof roll and preparation method
CN108728002A (en) * 2018-06-11 2018-11-02 鞍山科顺建筑材料有限公司 A kind of adhesive waterproof coil and preparation method thereof with electro-magnetic screen function
WO2019136616A1 (en) * 2018-01-10 2019-07-18 海安科皓纺织有限公司 Waterproof coiled material capable of shielding electromagnetic signal, and manufacturing method therefor

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CN102321379A (en) * 2011-07-13 2012-01-18 青岛科技大学 Electroconductive graphene/polymer composite material
CN202139765U (en) * 2011-06-09 2012-02-08 广东科顺化工实业有限公司 High-efficiency root-resistance waterproof coiled material
CN104640249A (en) * 2015-01-23 2015-05-20 北京东方雨虹防水技术股份有限公司 Electrically-induced-heating functional composite water-proof material and preparation method thereof
CN105584173A (en) * 2015-12-21 2016-05-18 潍坊市宏源防水材料有限公司 Waterproof roll with electromagnetic shielding function and preparation method thereof
CN205853482U (en) * 2016-08-04 2017-01-04 合肥中科富华新材料有限公司 A kind of waterproof roll with electromagnetic shielding action

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2142391Y (en) * 1992-11-20 1993-09-22 石首市建筑防水堵漏工程公司 Radiation protection color multilayer composite waterproffing material
CN202139765U (en) * 2011-06-09 2012-02-08 广东科顺化工实业有限公司 High-efficiency root-resistance waterproof coiled material
CN102321379A (en) * 2011-07-13 2012-01-18 青岛科技大学 Electroconductive graphene/polymer composite material
CN104640249A (en) * 2015-01-23 2015-05-20 北京东方雨虹防水技术股份有限公司 Electrically-induced-heating functional composite water-proof material and preparation method thereof
CN105584173A (en) * 2015-12-21 2016-05-18 潍坊市宏源防水材料有限公司 Waterproof roll with electromagnetic shielding function and preparation method thereof
CN205853482U (en) * 2016-08-04 2017-01-04 合肥中科富华新材料有限公司 A kind of waterproof roll with electromagnetic shielding action

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106868884A (en) * 2017-02-27 2017-06-20 合肥中科富华新材料有限公司 A kind of waterproof roll and preparation method with radiation protection
CN107059422A (en) * 2017-02-27 2017-08-18 合肥中科富华新材料有限公司 A kind of high-strength abrasion-proof waterproof roll and preparation method
WO2019136616A1 (en) * 2018-01-10 2019-07-18 海安科皓纺织有限公司 Waterproof coiled material capable of shielding electromagnetic signal, and manufacturing method therefor
CN108728002A (en) * 2018-06-11 2018-11-02 鞍山科顺建筑材料有限公司 A kind of adhesive waterproof coil and preparation method thereof with electro-magnetic screen function

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Application publication date: 20161109