CN104071906A - Efficient compound scale inhibitor - Google Patents
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- CN104071906A CN104071906A CN201410113749.7A CN201410113749A CN104071906A CN 104071906 A CN104071906 A CN 104071906A CN 201410113749 A CN201410113749 A CN 201410113749A CN 104071906 A CN104071906 A CN 104071906A
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- 150000001875 compounds Chemical class 0.000 title abstract description 14
- 239000002455 scale inhibitor Substances 0.000 title abstract description 12
- 230000007797 corrosion Effects 0.000 claims abstract description 25
- 238000005260 corrosion Methods 0.000 claims abstract description 25
- 239000003112 inhibitor Substances 0.000 claims abstract description 18
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 claims abstract description 13
- AFVFQIVMOAPDHO-UHFFFAOYSA-N Methanesulfonic acid Chemical compound CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000013543 active substance Substances 0.000 claims description 13
- 239000002131 composite material Substances 0.000 claims description 11
- 229920005552 sodium lignosulfonate Polymers 0.000 claims description 8
- 239000003643 water by type Substances 0.000 claims description 8
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 7
- 150000001565 benzotriazoles Chemical class 0.000 claims description 7
- 239000011734 sodium Substances 0.000 claims description 7
- 229910052708 sodium Inorganic materials 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 5
- RYSLUANJSRBGRV-UHFFFAOYSA-N C(CCCCCCCCCCC)C1=C(C=CC=C1)[P+](Br)(C)C Chemical compound C(CCCCCCCCCCC)C1=C(C=CC=C1)[P+](Br)(C)C RYSLUANJSRBGRV-UHFFFAOYSA-N 0.000 claims description 4
- REYJJPSVUYRZGE-UHFFFAOYSA-N Octadecylamine Chemical compound CCCCCCCCCCCCCCCCCCN REYJJPSVUYRZGE-UHFFFAOYSA-N 0.000 claims description 3
- KGOGNDXXUVELIQ-UHFFFAOYSA-N dioctadecylazanium;chloride Chemical compound Cl.CCCCCCCCCCCCCCCCCCNCCCCCCCCCCCCCCCCCC KGOGNDXXUVELIQ-UHFFFAOYSA-N 0.000 claims description 3
- SFVFIFLLYFPGHH-UHFFFAOYSA-M stearalkonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 SFVFIFLLYFPGHH-UHFFFAOYSA-M 0.000 claims description 3
- 239000004593 Epoxy Substances 0.000 claims description 2
- WOWHHFRSBJGXCM-UHFFFAOYSA-M cetyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 claims description 2
- 235000011044 succinic acid Nutrition 0.000 claims description 2
- 150000003444 succinic acids Chemical class 0.000 claims description 2
- 230000002401 inhibitory effect Effects 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 22
- 230000000694 effects Effects 0.000 abstract description 17
- 239000002253 acid Substances 0.000 abstract description 15
- 230000005764 inhibitory process Effects 0.000 abstract description 13
- 238000002360 preparation method Methods 0.000 abstract description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract description 6
- 239000000126 substance Substances 0.000 abstract description 6
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 abstract description 6
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract description 4
- 229910052725 zinc Inorganic materials 0.000 abstract description 4
- 239000011701 zinc Substances 0.000 abstract description 4
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 abstract description 3
- 239000012964 benzotriazole Substances 0.000 abstract description 3
- 229910052742 iron Inorganic materials 0.000 abstract description 3
- 229910052751 metal Inorganic materials 0.000 abstract description 3
- 239000002184 metal Substances 0.000 abstract description 3
- 239000004094 surface-active agent Substances 0.000 abstract description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract description 2
- 229910052802 copper Inorganic materials 0.000 abstract description 2
- 239000010949 copper Substances 0.000 abstract description 2
- 229910021645 metal ion Inorganic materials 0.000 abstract description 2
- 229910052573 porcelain Inorganic materials 0.000 abstract description 2
- XMVONEAAOPAGAO-UHFFFAOYSA-N sodium tungstate Chemical compound [Na+].[Na+].[O-][W]([O-])(=O)=O XMVONEAAOPAGAO-UHFFFAOYSA-N 0.000 abstract description 2
- 229910001220 stainless steel Inorganic materials 0.000 abstract description 2
- 239000010935 stainless steel Substances 0.000 abstract description 2
- 230000002195 synergetic effect Effects 0.000 abstract description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 abstract 2
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 abstract 2
- 230000007547 defect Effects 0.000 abstract 1
- 239000008367 deionised water Substances 0.000 abstract 1
- 229910021641 deionized water Inorganic materials 0.000 abstract 1
- 229940098779 methanesulfonic acid Drugs 0.000 abstract 1
- 230000000813 microbial effect Effects 0.000 abstract 1
- 229920001529 polyepoxysuccinic acid Polymers 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 description 8
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 7
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 6
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical class OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 5
- -1 phospho Chemical class 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- 229910000019 calcium carbonate Inorganic materials 0.000 description 4
- FGZBFIYFJUAETR-UHFFFAOYSA-N calcium;magnesium;silicate Chemical compound [Mg+2].[Ca+2].[O-][Si]([O-])([O-])[O-] FGZBFIYFJUAETR-UHFFFAOYSA-N 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000003814 drug Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 230000007062 hydrolysis Effects 0.000 description 3
- 238000006460 hydrolysis reaction Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 3
- UGZADUVQMDAIAO-UHFFFAOYSA-L zinc hydroxide Chemical compound [OH-].[OH-].[Zn+2] UGZADUVQMDAIAO-UHFFFAOYSA-L 0.000 description 3
- 229940007718 zinc hydroxide Drugs 0.000 description 3
- 229910021511 zinc hydroxide Inorganic materials 0.000 description 3
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical group [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- 239000000498 cooling water Substances 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 238000005755 formation reaction Methods 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000000116 mitigating effect Effects 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 235000011007 phosphoric acid Nutrition 0.000 description 2
- 241000282326 Felis catus Species 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- ALONTSSMLHXUSS-UHFFFAOYSA-N [Cr].[Zn].[P] Chemical compound [Cr].[Zn].[P] ALONTSSMLHXUSS-UHFFFAOYSA-N 0.000 description 1
- 230000008485 antagonism Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 239000001506 calcium phosphate Substances 0.000 description 1
- 229910000389 calcium phosphate Inorganic materials 0.000 description 1
- 235000011010 calcium phosphates Nutrition 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000012634 fragment Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 125000001165 hydrophobic group Chemical group 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- DCEMCPAKSGRHCN-UHFFFAOYSA-N oxirane-2,3-dicarboxylic acid Chemical compound OC(=O)C1OC1C(O)=O DCEMCPAKSGRHCN-UHFFFAOYSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 150000003016 phosphoric acids Chemical class 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 150000003017 phosphorus Chemical class 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000000837 restrainer Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
Landscapes
- Preventing Corrosion Or Incrustation Of Metals (AREA)
Abstract
The invention discloses an efficient compound scale inhibitor, which is mainly prepared from the following components in parts by weight: 16-20 parts of 1-hydroxy ethylidene-1,1-diphosphonic acid, 10-15 parts of sodium lignin sulfonate, 3-5 parts of benzotriazole, 2-5 parts of methanesulfonic acid, 5-8 parts of polyepoxysuccinic acid, 6-9 parts of sodium tungstate, 2-5 parts of thiourea, 7-12 parts of surfactant and 30-40 parts of deionized water. The efficient compound scale inhibitor has the characteristics of being stable in chemical property in water, not easy to hydrolyze and the like. The sodium lignin sulfonate is a compound preparation with a good synergistic treatment effect, and can effectively prevent water scale and a microbial sticky body from forming. An acid corrosion inhibitor thiourea is added, so that corrosion on porcelain, stainless steel and metal surfaces caused by the acid system is greatly reduced. The 1-hydroxy ethylidene-1,1-diphosphonic acid can form a stable complex together with a plurality of metal ions such as iron, copper and zinc, and the oxide on the metal surface can be dissolved. By adopting the efficient compound scale inhibitor, the defects of the existing scale inhibitor are improved, and the efficient compound scale inhibitor has a good scale inhibition effect and an obvious threshold effect.
Description
Technical field
The present invention relates to a kind of anti-incrustation corrosion inhibitor, particularly a kind of high-efficiency composite scale corrosion inhibitor.
Background technology
The Scale inhibitors being applied the earliest in water treatment approximately will be calculated polymeric phosphate.Polymeric phosphate, except having scale effect, also has corrosion inhibition concurrently.But its shortcoming is facile hydrolysis is orthophosphoric acid salt, if control improperly, can make original not too serious calcium carbonate scale problem change very serious calcium phosphate scale problem into.The appearance of the organic phosphoric acid sixties in 20th century (salt) Scale inhibitors, shows that in water, the mitigation and antiscaling technology of calcium carbonate has been obtained breakthrough progress.Also make the ultralow chromium treatment formulations of recirculated cooling water be applied.This ultralow chromium formula uses within the scope of the pH of 7.5-8.5 value.The utilization of high pH value makes the requirement of the chromate amount for inhibition be down to 5-10mg/L from the 15-25mg/L of traditional chromium-phosphorus-zinc formula, has greatly alleviated the disadvantageous effect to environment.Why can do like this, be because the application of organic phospho acid (salt) Scale inhibitors, makes to cause dirty salt calcium carbonate in water and obtain in the cathodic area of metallic surface the deposition of control.This controlledly calcium carbonate of deposition, has played the effect of cathodic corrosion inhibitor.
The application of organic phospho acid (salt) Scale inhibitors, also making this phosphorus of recirculated cooling water poly-phosphate-organic phospho acid (salt)-polyacrylic acid (salt) is that basic treatment formula is used widely.But in existing composite water conditioner, due to the unsuitable composite effect of creating antagonism of each component, cause effect to reduce or the phenomenon lost happens occasionally, the increasing to such an extent as to cost of the consumption of water body medicament inferior increases obviously.And for water bodys inferior such as calcium sulfate scale and barium sulfate scale, calcium magnesium silicate, ironic hydroxide dirt, zinc hydroxide dirts, also there is no so specific Scale inhibitors in addition at present, due to medicament long-term storage, run into the unfavorable factors such as oxygen, moisture, each component interaction, the drug effect of composite water conditioner can be scattered and disappeared gradually.
Summary of the invention
The object of the invention is to provide a kind of high-efficiency composite scale corrosion inhibitor, become assignment system unreasonable to solve existing anti-incrustation corrosion inhibitor, wide spectrum, water body reagent cost inferior do not increase obviously, to the water body poor effect inferior such as calcium magnesium silicate, ironic hydroxide dirt, zinc hydroxide dirt, calcium sulfate scale and barium sulfate scale, the technical problem such as should not put for a long time.
For solving the problems of the technologies described above, technical scheme of the present invention is: a kind of high-efficiency composite scale corrosion inhibitor, and this anti-incrustation corrosion inhibitor is mainly made up of following compositions in weight percentage:
10～15 parts of 1-Hydroxy Ethylidene-1,1-Diphosphonic Acid, 10～15 parts of sodium lignosulfonates, 3～5 parts of benzotriazoles, 2～5 parts of methylsulfonic acids, 5～8 parts of poly-epoxy succinic acids, 6～9 parts of sodium wolframates, 2～5 parts of thiocarbamides, 7～12 parts, tensio-active agent, 30～40 parts of deionized waters.
As preferably, described tensio-active agent is one or several mixtures of octadecyl amine hydrochlorate, dioctadecylamine hydrochloride, stearyl dimethyl benzyl ammonium chloride, palmityl trimethyl ammonium chloride, dodecyl dimethyl phenyl bromo-phosphonium.
In the present invention's formula, on its structural unit of sodium lignosulfonate, contain phenolic hydroxyl group and carboxyl, can generate insoluble protein complex, be used for controlling suspended substance and iron dirt, there is dispersive ability.Being a kind of dispersion agent and integrated agent, is also a kind of inhibiter.In circulating water treatment agent, utilize the complexing action of this product and zinc, the zinc in water is laid in, a certain amount of zine ion can be constantly provided, suppress the corrosion of water system.
Benzotriazole can stabilizing water quality, suppress the corrosion of water system.
Acid restrainer thiocarbamide, reduces the corrosion of acid system to porcelain, stainless steel, metallic surface greatly, is conducive to keeping device crust, can make cleaned any surface finish as newly.
1-Hydroxy Ethylidene-1,1-Diphosphonic Acid is a kind of organophosphorus acids anti-incrustation corrosion inhibitor, can form stable complex compound with the many kinds of metal ions such as iron, copper, zinc, oxide compound that can dissolution of metals surface.1-Hydroxy Ethylidene-1,1-Diphosphonic Acid still can play good corrosion-mitigation scale-inhibition effect at 250 DEG C, still very stable under high pH value, and not facile hydrolysis is difficult for decomposing under general light and heat condition.Resistance to acids and bases, resistance to oxychlorination performance are good compared with other organic phosphoric acid (salt).1-Hydroxy Ethylidene-1,1-Diphosphonic Acid can belong to ion with underwater gold, especially calcium ion forms six annulus inner complexs, thereby the good scale inhibition effect of 1-Hydroxy Ethylidene-1,1-Diphosphonic Acid tool the obvious threshold effect of tool, when with the scope of the invention in the compound use such as benzotriazole, poly-epoxy succinic acid, sodium wolframate time, show desirable synergistic effect.
Even if tensio-active agent is a class also remarkable material of reduction table (boundary) surface tension in the time of very low concentrations.Along with going deep into of Surfactant research, it is generally acknowledged at present if under low concentration the remarkable material of change table (boundary) surface properties or character related to this, that derive from thus, can incorporate tensio-active agent category into.No matter which kind of tensio-active agent, its molecular structure forms by two portions.One end of molecule is the hydrophobic group of non-utmost point oleophylic, sometimes also referred to as oleophilic group; The other end of molecule is the hydrophilic hydrophilic group of polarity, sometimes also referred to as lipophobic group or be called visually hydrophilic head.Two class formations divide the two ends in same molecule and are connected with chemical bond with the diametrically opposite molecular fragment of performance or group, form a kind of structure of asymmetric, polarity, thereby given not only hydrophilic, but also oleophylic of such particular molecule, not again just the characteristic of the hydrophilic or oleophylic of entirety.This peculiar structure of tensio-active agent is referred to as " amphiphilic structure " (amphiphilic structure) conventionally, surfactant molecule thereby be also often known as " parents' molecule ".What the present invention adopted is cats product.
The each component of the present invention performance synergy, has scale inhibition, inhibition lasting medicine, efficient, stable chemical nature, not facile hydrolysis etc., the low feature of cost in water.It is better to water body effects inferior such as calcium magnesium silicate, ironic hydroxide dirt, zinc hydroxide dirt, calcium sulfate scale and barium sulfate scales, be applicable to Different Waters scale inhibitor.This invention is applied in the water system such as boiler, pipeline, and its Heat stability is good even still keeps good dispersing property at 250 DEG C, and scale inhibition, corrosion inhibition are good.And in poor-quality water, disperse hydrous oxide and organic dirt etc. also very effective.Can effectively prevent the formation of incrustation scale, the sticky body of microorganism, thereby the good scale inhibition effect of tool the obvious threshold effect of tool.
Embodiment
Embodiment 1: by mass percentage by 10 parts of 1-Hydroxy Ethylidene-1,1-Diphosphonic Acid, 10 parts of sodium lignosulfonates, 3 parts of benzotriazoles, 5 parts of methylsulfonic acids, 8 parts of succsinic acids, 9 parts of sodium wolframates, 5 parts of thiocarbamides, 7 parts, tensio-active agent (dodecyl dimethyl phenyl bromo-phosphonium), 30 parts of deionized waters carry out compound preparation, stirring at normal temperature, until all dissolve, then filter by 300 mesh filter screens, make finished product.
Embodiment 2: by mass percentage by 12 parts of 1-Hydroxy Ethylidene-1,1-Diphosphonic Acid, 13 parts of sodium lignosulfonates, 4 parts of benzotriazoles, 4 parts of methylsulfonic acids, 7 parts of succsinic acids, 8 parts of sodium wolframates, 4 parts of thiocarbamides, 10 parts, tensio-active agent (dodecyl dimethyl phenyl bromo-phosphonium), 30 parts of deionized waters carry out compound preparation, stirring at normal temperature, until all dissolve, then filter by 300 mesh filter screens, make finished product.
Embodiment 3: by mass percentage by 13 parts of 1-Hydroxy Ethylidene-1,1-Diphosphonic Acid, 11 parts of sodium lignosulfonates, 4 parts of benzotriazoles, 2 parts of methylsulfonic acids, 5 parts of succsinic acids, 7 parts of sodium wolframates, 3 parts of thiocarbamides, 8 parts, tensio-active agent (dioctadecylamine hydrochloride), 30 parts of deionized waters carry out compound preparation, stirring at normal temperature, until all dissolve, then filter by 300 mesh filter screens, make finished product.
Embodiment 4: by mass percentage by 14 parts of 1-Hydroxy Ethylidene-1,1-Diphosphonic Acid, 12 parts of sodium lignosulfonates, 3 parts of benzotriazoles, 3 parts of methylsulfonic acids, 6 parts of succsinic acids, 6 parts of sodium wolframates, 4 parts of thiocarbamides, 10 parts, tensio-active agent (octadecyl amine hydrochlorate), 30 parts of deionized waters carry out compound preparation, stirring at normal temperature, until all dissolve, then filter by 300 mesh filter screens, make finished product.
Embodiment 5: by mass percentage by 15 parts of 1-Hydroxy Ethylidene-1,1-Diphosphonic Acid, 15 parts of sodium lignosulfonates, 5 parts of benzotriazoles, 2 parts of methylsulfonic acids, 5 parts of succsinic acids, 8 parts of sodium wolframates, 2 parts of thiocarbamides, 12 parts, tensio-active agent (stearyl dimethyl benzyl ammonium chloride), 30 parts of deionized waters carry out compound preparation, stirring at normal temperature, until all dissolve, then filter by 300 mesh filter screens, make finished product.
In order to verify effect of the present invention, under identical dosage, high-efficiency composite scale corrosion inhibitor prepared by embodiment 1-5 and existing organophosphorus acids anti-incrustation corrosion inhibitor carry out the simultaneous test of scale inhibition, corrosion mitigating effect: test raw water quality pH6.1, turbidity is 31 degree (NTU), and calcium ion is 1220.5mg/L.In antisludging test, the added amount of chemical of embodiment 1-5 is 30mg/L, and test temperature is 80 DEG C, concentrated 3.0 times.In inhibition (rotary hanging plate) test, the added amount of chemical of embodiment 1-7 is 30mg/L, and test temperature is 50 DEG C, and lacing film speed of rotation is 75 revs/min, and test period is 216 hours.Its result is as shown in table 1.
Table 1 anti-incrustation corrosion inhibitor performance comparison test result
[0020] the result shows: compare existing organic phosphoric acid class anti-incrustation corrosion inhibitor product, adopt the present invention fill a prescription preparation anti-incrustation corrosion inhibitor, its scale inhibition and inhibition better effects if.
Finally, it should be pointed out that above embodiment is only the more representational example of the present invention.Obviously, the invention is not restricted to above-mentioned embodiment.Any simple modification, equivalent variations and modification that every foundation technical spirit of the present invention is done above embodiment, all should think and belong to protection scope of the present invention.
Claims (2)
1. a high-efficiency composite scale corrosion inhibitor, is characterized in that this composite scale-inhibiting corrosion inhibitor is mainly made up of following compositions in weight percentage:
10～15 parts of 1-Hydroxy Ethylidene-1,1-Diphosphonic Acid, 10～15 parts of sodium lignosulfonates, 3～5 parts of benzotriazoles, 2～5 parts of methylsulfonic acids, 5～8 parts of poly-epoxy succinic acids, 6～9 parts of sodium wolframates, 2～5 parts of thiocarbamides, 7～12 parts, tensio-active agent, 30～40 parts of deionized waters.
2. high-efficiency composite scale corrosion inhibitor according to claim 1, is characterized in that described tensio-active agent is one or more mixtures in octadecyl amine hydrochlorate, dioctadecylamine hydrochloride, stearyl dimethyl benzyl ammonium chloride, palmityl trimethyl ammonium chloride, dodecyl dimethyl phenyl bromo-phosphonium.
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| CN201410113749.7A CN104071906B (en) | 2013-04-01 | 2014-03-26 | High-efficiency composite scale corrosion inhibitor |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104276676A (en) * | 2014-10-22 | 2015-01-14 | 山东华亚环保科技有限公司 | Scale inhibitor for boiler circulating water |
| CN105169954A (en) * | 2015-09-10 | 2015-12-23 | 韩功篑 | Reverse osmosis scale inhibitor for desalting seawater and preparation method thereof |
| CN105314744A (en) * | 2015-12-12 | 2016-02-10 | 沧州泓海化工有限公司 | Novel corrosion and scale inhibitor |
| CN106242086A (en) * | 2016-08-29 | 2016-12-21 | 山东胜伟园林科技有限公司 | A kind of carbonate bases ground antisludging agent and preparation method thereof |
| CN106396137A (en) * | 2016-11-09 | 2017-02-15 | 山东英联化学科技有限公司 | Corrosion and scale inhibitor used for circulating cooling water and preparation method of corrosion and scale inhibitor |
| CN108914104A (en) * | 2018-06-25 | 2018-11-30 | 杨飞 | A kind of octadecylamine shutdown protection solution and preparation method thereof |
| CN110157391A (en) * | 2019-05-28 | 2019-08-23 | 司能石油化工有限公司 | A kind of engine coolant composite corrosion inhibitor and preparation method thereof |
| CN110818104A (en) * | 2019-12-23 | 2020-02-21 | 王其芬 | Method for preparing corrosion and scale inhibition adsorbent by taking lignin in papermaking wastewater as raw material |
| CN113149239A (en) * | 2021-04-06 | 2021-07-23 | 重庆电力高等专科学校 | Preparation of corrosion and scale inhibitor for circulating cooling water |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1085525A (en) * | 1992-10-15 | 1994-04-20 | 聂新宇 | Automatic scale removing agent for water tank of vehicle |
| CN1139650A (en) * | 1995-07-05 | 1997-01-08 | 刘春光 | Multi-function water quality treating agent for cooling water system |
| JP2003080294A (en) * | 2001-09-11 | 2003-03-18 | Japan Organo Co Ltd | Scaling inhibitor and method for preventing scaling |
| CN101759307A (en) * | 2009-12-08 | 2010-06-30 | 武汉科技大学 | Compound scale inhibitor for desalting vanadium extracting waste water of shale containing vanadium and use method |
| US20110315168A1 (en) * | 2010-06-29 | 2011-12-29 | Jean-Alex Laffitte | Acid Compositions for Removing Oxalates |
| US20120067579A1 (en) * | 2010-09-20 | 2012-03-22 | S.P.C.M. Sa | Process for enhanced oil recovery using the asp technique |
-
2014
- 2014-03-26 CN CN201410113749.7A patent/CN104071906B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1085525A (en) * | 1992-10-15 | 1994-04-20 | 聂新宇 | Automatic scale removing agent for water tank of vehicle |
| CN1139650A (en) * | 1995-07-05 | 1997-01-08 | 刘春光 | Multi-function water quality treating agent for cooling water system |
| JP2003080294A (en) * | 2001-09-11 | 2003-03-18 | Japan Organo Co Ltd | Scaling inhibitor and method for preventing scaling |
| CN101759307A (en) * | 2009-12-08 | 2010-06-30 | 武汉科技大学 | Compound scale inhibitor for desalting vanadium extracting waste water of shale containing vanadium and use method |
| US20110315168A1 (en) * | 2010-06-29 | 2011-12-29 | Jean-Alex Laffitte | Acid Compositions for Removing Oxalates |
| US20120067579A1 (en) * | 2010-09-20 | 2012-03-22 | S.P.C.M. Sa | Process for enhanced oil recovery using the asp technique |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104276676A (en) * | 2014-10-22 | 2015-01-14 | 山东华亚环保科技有限公司 | Scale inhibitor for boiler circulating water |
| CN104276676B (en) * | 2014-10-22 | 2016-08-17 | 佛山鹏德科技有限公司 | A kind of antisludging agent for boiler recirculated water |
| CN105169954A (en) * | 2015-09-10 | 2015-12-23 | 韩功篑 | Reverse osmosis scale inhibitor for desalting seawater and preparation method thereof |
| CN105314744A (en) * | 2015-12-12 | 2016-02-10 | 沧州泓海化工有限公司 | Novel corrosion and scale inhibitor |
| CN106242086A (en) * | 2016-08-29 | 2016-12-21 | 山东胜伟园林科技有限公司 | A kind of carbonate bases ground antisludging agent and preparation method thereof |
| CN106396137A (en) * | 2016-11-09 | 2017-02-15 | 山东英联化学科技有限公司 | Corrosion and scale inhibitor used for circulating cooling water and preparation method of corrosion and scale inhibitor |
| CN108914104A (en) * | 2018-06-25 | 2018-11-30 | 杨飞 | A kind of octadecylamine shutdown protection solution and preparation method thereof |
| CN110157391A (en) * | 2019-05-28 | 2019-08-23 | 司能石油化工有限公司 | A kind of engine coolant composite corrosion inhibitor and preparation method thereof |
| CN110818104A (en) * | 2019-12-23 | 2020-02-21 | 王其芬 | Method for preparing corrosion and scale inhibition adsorbent by taking lignin in papermaking wastewater as raw material |
| CN113149239A (en) * | 2021-04-06 | 2021-07-23 | 重庆电力高等专科学校 | Preparation of corrosion and scale inhibitor for circulating cooling water |
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