CN104026221A - Preservative bag applicable to fruits, vegetables and flowers and plants - Google Patents
Preservative bag applicable to fruits, vegetables and flowers and plants Download PDFInfo
- Publication number
- CN104026221A CN104026221A CN201410289260.5A CN201410289260A CN104026221A CN 104026221 A CN104026221 A CN 104026221A CN 201410289260 A CN201410289260 A CN 201410289260A CN 104026221 A CN104026221 A CN 104026221A
- Authority
- CN
- China
- Prior art keywords
- cinnamic acid
- inclusion compound
- oil
- fruits
- beta
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
The invention provides a preservative bag applicable to fruits, vegetables and flowers and plants. The preservative bag comprises a biological environment-friendly type natural biocide mildewcide, an ethylene inhibitor and auxiliary materials. The preservative bag applicable to fruits, vegetables and flowers and plants is a novel environment-friendly product which is good in preservation effect, wide in range of application, safe and harmless to a human body and the environment.
Description
Technical field
The present invention relates to the fresh-keeping bag of a kind of fruit, vegetables and flower freshness.
Background technology
At present mostly antistaling agent is fungus and mildew resistance and the function of anti-ethene not, or only has anti-ethene there is no antimycotic antiseptic effect, and has anti-ethene, has again a fungus and mildew resistance, and particularly also environment friendly preservation agent free from environmental pollution is still few.
Fruit, vegetables, flowers fresh-keeping comprises two aspects.First fungus and mildew resistance, it two is anti-ethene.At present, the antisepsis antistaling agent using in the storing of China fruit mainly contains carbendazim, probenazole, thiophanate-methyl, benomyl, imazalil, sec-butylamine, iprodione, sulfur dioxide etc. more than 20 and plants, but these anticorrisive agents all exist that valency is high, residual toxicity or the problem such as effect is bad.Find low toxicity, safe, efficient, easy to use and cheap vegetables and fruits flowers antisepsis antistaling agent, just seem important and urgent.
For environmental protection, avoid using chemical sterilization and mould inhibitor, use the fungus and mildew resistance product of plant origin instead.For example, cinnamic acid-Benexate Hydrochloride is sterilizing anticorrisive agent, particularly fungi is had to remarkable result.To Escherichia coli, hay bacillus and golden yellow staphylococcus, staphylococcus albus, Shigella shigae, Typhoid and paratyphoid first bacillus, pneumococcus, aerobacteria, proteus, bacillus anthracis, Bacterium enteritidis, comma bacillus etc. have inhibitory action.And remarkable to gram-positive bacteria bactericidal effect.Japan medical science expert studies discovery recently, and cinnamic acid has obvious sterilizing effect to fungi.
Cinnamic acid has low toxicity, safety, cost is low and the advantage such as aromatic odor, as a kind of safe natural source material, < < state food safety standard food additives use standard > > GB27602011 version to other antiseptic and fresh-keeping agent for fruits strict regulations limit the quantity of, cinnamic acid is but just said to " by producing required appropriate use ", also have no restriction.In view of the above-mentioned advantage of cinnamic acid, its using method can be soaked fruit, fumigated and adopt the flexibilities such as front spraying in addition, and expert pronounced cinnamic acid is expected into the most general fruit and vegetable preserving antistaling agent.
Mustard oil-Benexate Hydrochloride: it is the cyclodextrin inclusion compound of the total ester of the organic isothiocyanic acid of slow release, is used as flavor enhancement and bactericide in food.Because the contained sterilization component of mustard can kill the bacteriums such as coliform, Staphylococcus aureus, and suppress the growth of mould and other poisonous bacteriums in food.In agricultural, can be used as biocide mildewcide.
Garlic oil-Benexate Hydrochloride: garlic is described as " natural broad-spectrum antibiotic ".The Main Ingredients and Appearance of garlic oil is: pi-allyl propyl disulfide compound, diallyl disulfide, diallyl trisulfide, allicin etc.Garlic oil antimicrbial power is strong, has the multiple fresh-keeping function of sterilization, mildew-resistant, expelling parasite.It has and kills or inhibitory action various pathogens such as soft rotten coccus, staphylococcus, Escherichia coli.Garlic oil also has good bactericidal action to multiple fungi in addition.
Above-mentioned biocide mildewcide not only bactericidal mould proof effect is good, to people and environmental sound, and cut, with cyclodextrin encapsulated, rear volatile substances is played to slow releasing function, is convenient to preserve and use.
Fruits and vegetables flower antistaling agent is towards natural, nontoxic, environmental protection, efficient, multi-functional future development.What praised highly most is 1-methyl cyclopropene.1-methyl cyclopropene can be blocked the combination of fruits and vegetables flowers Inner portion and outside ethene and fruits and vegetables flowers, reduces the activity of its breathing, transpiration and catabolic enzyme, delays senility, and reaches fresh-keeping object.Its consumption is extremely low in addition, be generally 1,000,000/, even part per billion, just can play fresh-keeping effect.It has advantages of efficient, nontoxic.The preservation technique of comparative maturity is stifling in fruits and vegetables depots at present.But fruits and vegetables will be put processing in storage, in transit fresh-keeping very inconvenient of fruits and vegetables, increased again cost.For the ease of fruits and vegetables flowers transportation fresh-retaining, in tote box, Bian is the most convenient with fresh-keeping bag.
The fit applications of natural disinfection mould inhibitor and cyclopropylene is the most perfect environment-friendly type scheme.
Invention Inner holds
The object of this invention is to provide a kind of fruits and vegetables flower freshness bag, be applicable to fruits and vegetables stock and transportation in fresh-keeping, product is widely applicable, good refreshing effect, more environmental protection.
Technical scheme of the present invention is: a kind of fruits and vegetables flower freshness bag, it is characterized in that: this fresh-keeping bag is made by following substances in percentage by weight: the inclusion compound 1-10% of biocide mildewcide and cyclodextrin, ethylene inhibitor 0.1-10%, auxiliary material is mended and is reached 100%, and wherein biocide mildewcide and cyclodextrin inclusion compound are: one or more in cinnamic acid-Benexate Hydrochloride, mustard oil-Benexate Hydrochloride or garlic oil-Benexate Hydrochloride; Ethylene inhibitor is that weight content is 0.01% 1-methyl cyclopropene; Described auxiliary material is: one or more in talcum powder, diatom scholar, odium stearate or glucose.
Preferably, this fresh-keeping bag is made by following substances in percentage by weight: the inclusion compound 2-3% of biocide mildewcide and cyclodextrin, and ethylene inhibitor 1-6%, auxiliary material mends enough 100%; Wherein biocide mildewcide and cyclodextrin inclusion compound are: one or more in cinnamic acid-Benexate Hydrochloride, mustard oil-Benexate Hydrochloride or garlic oil-Benexate Hydrochloride; Ethylene inhibitor is that weight content is 0.01% 1-methyl cyclopropene; Described auxiliary material is: one or more in talcum powder, diatom scholar, odium stearate or glucose.
The method of wherein preparing beta-cyclodextrin inclusion compound cinnamic acid, mustard oil and garlic oil is:
Step 1, in the equipment of stirring is installed, add 120 grams of 1 liter of deionized water and beta-schardinger dextrin-s, under stirring condition, be heated to 70-75 ℃, beta-schardinger dextrin-is dissolved completely, the saturated solution of beta-schardinger dextrin-;
Step 2, in 95% ethanolic solution 70ml, add 30ml cinnamic acid or mustard oil or garlic oil, be made into 30% ethanolic solution;
Step 3, above-mentioned 30ml is slowly added drop-wise in saturated beta-schardinger dextrin-saturated solution containing the ethanolic solution of cinnamic acid or mustard oil or garlic oil, high degree of agitation approximately 1 hour, stops insulation, continue to stir 1 hour, stop stirring, naturally cool to room temperature, obtain inclusion compound suspension;
Step 4, inclusion compound suspension is spent the night below in 10 ℃, then filtering precipitate, in 30-40 ℃ of oven dry or air-dry, obtain cinnamic acid or mustard oil or garlic oil-Benexate Hydrochloride, in inclusion compound, the weight content of cinnamic acid or mustard oil or garlic oil is 9-10%.
The present invention adopts cinnamic acid-beta-schardinger dextrin-, mustard oil-beta-schardinger dextrin-and garlic oil-beta-schardinger dextrin-, and slowly-releasing volatility biocide mildewcide, avoids using chemicals, can play preservation like this to the insensitive fruits and vegetables flowers of ethene.And use 1-methyl cyclopropene, can look after again the fruits and vegetables flowers to ethene sensitivity.Safer, more environmental protection.
The present invention is a kind of fresh-keeping bag that is applicable to most of fruits, vegetables and flower freshness.This fresh-keeping bag can not only fungus and mildew resistance, and can also resist ethene, has dual-use function.It is not only applicable to the fruits and vegetables flowers of ethene sensitivity but also is applicable to the fruits and vegetables flowers non-sensitive to ethene, applied widely, easy to use.
The specific embodiment
Embodiment 1
By following percentage by weight, make
0.01% 1-methyl cyclopropene 6%; Cinnamic acid-beta-schardinger dextrin-3%; Talcum powder 91%; Be distributed into 0.5 gram of every bag.
Embodiment 2
By following percentage by weight, make
0.01% 1-methyl cyclopropene 2%; Cinnamic acid-beta-schardinger dextrin-2%; Mustard oil-beta-schardinger dextrin-1%; Odium stearate 5%; Talcum powder 90%; Be distributed into 0.5 gram of every bag.
Embodiment 3
By following percentage by weight, make
0.01% 1-methyl cyclopropene 3%; Cinnamic acid-beta-schardinger dextrin-1%, garlic oil-beta-schardinger dextrin-2%, diatom scholar 94%; Be distributed into 0.5 gram of every bag.
Embodiment 4
By following percentage by weight, make
0.01% 1-methyl cyclopropene 5%; Cinnamic acid-beta-schardinger dextrin-1%; Mustard oil-beta-schardinger dextrin-1%, garlic oil-beta-schardinger dextrin-1%, diatomite 92%; Be distributed into 0.5 gram of every bag.
Embodiment 5
By following percentage by weight, make
0.01% 1-methyl cyclopropene 6%, cinnamic acid-beta-schardinger dextrin-3%, glucose 91%; Be distributed into 0.5 gram of every bag.
The method of wherein preparing beta-cyclodextrin inclusion compound cinnamic acid, mustard oil and garlic oil is:
Step 1, in the equipment of stirring is installed, add 120 grams of 1 liter of deionized water and beta-schardinger dextrin-s, under stirring condition, be heated to 70-75 ℃, beta-schardinger dextrin-is dissolved completely, the saturated solution of beta-schardinger dextrin-;
Step 2, in 95% ethanolic solution 70ml, add 30ml cinnamic acid or mustard oil or garlic oil, be made into 30% ethanolic solution;
Step 3, above-mentioned 30ml is slowly added drop-wise in saturated beta-schardinger dextrin-saturated solution containing the ethanolic solution of cinnamic acid or mustard oil or garlic oil, high degree of agitation approximately 1 hour, stops insulation, continue to stir 1 hour, stop stirring, naturally cool to room temperature, obtain inclusion compound suspension;
Step 4, inclusion compound suspension is spent the night below in 10 ℃, then filtering precipitate, in 30-40 ℃ of oven dry or air-dry, obtain cinnamic acid or mustard oil or garlic oil-Benexate Hydrochloride, in inclusion compound, the weight content of cinnamic acid or mustard oil or garlic oil is 9-10%.
Claims (3)
1. a fruits and vegetables flower freshness bag, it is characterized in that: this fresh-keeping bag is made by following substances in percentage by weight: the inclusion compound 1-10% of biocide mildewcide and cyclodextrin, ethylene inhibitor 0.1-10%, auxiliary material is mended and is reached 100%, and wherein biocide mildewcide and cyclodextrin inclusion compound are: one or more in cinnamic acid-Benexate Hydrochloride, mustard oil-Benexate Hydrochloride or garlic oil-Benexate Hydrochloride; Ethylene inhibitor is that weight content is 0.01% 1-methyl cyclopropene; Described auxiliary material is: one or more in talcum powder, diatom scholar, odium stearate or glucose.
2. a kind of fruits and vegetables flower freshness bag as claimed in claim 1, is characterized in that: this fresh-keeping bag is made by following substances in percentage by weight: the inclusion compound 2-3% of biocide mildewcide and cyclodextrin, ethylene inhibitor 1-6%, auxiliary material benefit enough 100%; Wherein biocide mildewcide and cyclodextrin inclusion compound are: one or more in cinnamic acid-Benexate Hydrochloride, mustard oil-Benexate Hydrochloride or garlic oil-Benexate Hydrochloride; Ethylene inhibitor is that weight content is 0.01% 1-methyl cyclopropene; Described auxiliary material is: one or more in talcum powder, diatom scholar, odium stearate or glucose.
3. a kind of fruits and vegetables flower freshness bag as claimed in claim 1, is characterized in that: the method for preparing beta-cyclodextrin inclusion compound cinnamic acid, mustard oil and garlic oil is:
Step 1, in the equipment of stirring is installed, add 120 grams of 1 liter of deionized water and beta-schardinger dextrin-s, under stirring condition, be heated to 70-75 ℃, beta-schardinger dextrin-is dissolved completely, the saturated solution of beta-schardinger dextrin-;
Step 2, in 95% ethanolic solution 70ml, add 30ml cinnamic acid or mustard oil or garlic oil, be made into 30% ethanolic solution;
Step 3, above-mentioned 30ml is slowly added drop-wise in saturated beta-schardinger dextrin-saturated solution containing the ethanolic solution of cinnamic acid or mustard oil or garlic oil, high degree of agitation approximately 1 hour, stops insulation, continue to stir 1 hour, stop stirring, naturally cool to room temperature, obtain inclusion compound suspension;
Step 4, inclusion compound suspension is spent the night below in 10 ℃, then filtering precipitate, in 30-40 ℃ of oven dry or air-dry, obtain cinnamic acid or mustard oil or garlic oil-Benexate Hydrochloride, in inclusion compound, the weight content of cinnamic acid or mustard oil or garlic oil is 9-10%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410289260.5A CN104026221B (en) | 2014-06-25 | 2014-06-25 | Fruits and vegetables flower freshness bag |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410289260.5A CN104026221B (en) | 2014-06-25 | 2014-06-25 | Fruits and vegetables flower freshness bag |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104026221A true CN104026221A (en) | 2014-09-10 |
| CN104026221B CN104026221B (en) | 2016-03-02 |
Family
ID=51457390
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410289260.5A Active CN104026221B (en) | 2014-06-25 | 2014-06-25 | Fruits and vegetables flower freshness bag |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104026221B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107212051A (en) * | 2017-06-13 | 2017-09-29 | 蚌埠市金旺食品有限公司 | A kind of preparation method for improving cake shelf-life and the close property of matter |
| CN110012934A (en) * | 2019-04-17 | 2019-07-16 | 贵州大学 | A kind of dedicated bacteriostasis, preservation paper of cherry and its preservation method |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1505992A (en) * | 2002-12-13 | 2004-06-23 | 国家农产品保鲜工程技术研究中心(天津 | Cyclopropene preservative with double functions of anticorrosion and keeping freshness |
| CN1505933A (en) * | 2002-12-13 | 2004-06-23 | 国家农产品保鲜工程技术研究中心(天津 | Method of suppressing after-pick senility of agricultural product |
| WO2007103336A2 (en) * | 2006-03-06 | 2007-09-13 | The Board Of Trustees Operating | Micro-encapsulation of volatile compounds into cyclodextrins |
| WO2009032199A1 (en) * | 2007-08-31 | 2009-03-12 | The Board Of Trustees Operating | Beta-cyclodextrins as nucleating agents for poly(lactic acid) |
| CN103229830A (en) * | 2013-04-03 | 2013-08-07 | 广东工业大学 | Gas-phase sustained-release mildew-resistant antistaling agent, and preparation method and application thereof |
-
2014
- 2014-06-25 CN CN201410289260.5A patent/CN104026221B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1505992A (en) * | 2002-12-13 | 2004-06-23 | 国家农产品保鲜工程技术研究中心(天津 | Cyclopropene preservative with double functions of anticorrosion and keeping freshness |
| CN1505933A (en) * | 2002-12-13 | 2004-06-23 | 国家农产品保鲜工程技术研究中心(天津 | Method of suppressing after-pick senility of agricultural product |
| WO2007103336A2 (en) * | 2006-03-06 | 2007-09-13 | The Board Of Trustees Operating | Micro-encapsulation of volatile compounds into cyclodextrins |
| WO2009032199A1 (en) * | 2007-08-31 | 2009-03-12 | The Board Of Trustees Operating | Beta-cyclodextrins as nucleating agents for poly(lactic acid) |
| CN103229830A (en) * | 2013-04-03 | 2013-08-07 | 广东工业大学 | Gas-phase sustained-release mildew-resistant antistaling agent, and preparation method and application thereof |
Non-Patent Citations (1)
| Title |
|---|
| 彭雪萍等: "《肉桂醛与β-环糊精包合前后对抗氧化性及抑菌的影响》", 《食品工业科技》, vol. 33, no. 1, 31 January 2012 (2012-01-31), pages 138 - 140 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107212051A (en) * | 2017-06-13 | 2017-09-29 | 蚌埠市金旺食品有限公司 | A kind of preparation method for improving cake shelf-life and the close property of matter |
| CN110012934A (en) * | 2019-04-17 | 2019-07-16 | 贵州大学 | A kind of dedicated bacteriostasis, preservation paper of cherry and its preservation method |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104026221B (en) | 2016-03-02 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US11632971B2 (en) | Compositions and methods of treating edible matter and substrates therefor | |
| EP3217800B1 (en) | Method of sanitizing edible seeds, particularly mucilage producing seeds | |
| Jemni et al. | Combined effect of UV-C, ozone and electrolyzed water for keeping overall quality of date palm | |
| JP5870101B2 (en) | Antimicrobial combination of pillion compounds and polyethyleneimine | |
| CA2848761A1 (en) | Antimicrobial mixture of aldehydes, organic acids and organic acid esters | |
| KR102100359B1 (en) | Method for preparing natural antimicrobial composition comprising fermentated plum and natural antimicrobial composition prepared by the same | |
| CN104026221B (en) | Fruits and vegetables flower freshness bag | |
| AU2016282319B2 (en) | Antimicrobial compositions comprising food approved antimicrobials and zinc pyrithione | |
| Behlau et al. | Chlorine dioxide, peroxyacetic acid, and calcium oxychloride for post-harvest decontamination of citrus fruit against Xanthomonas citri subsp. citri, causal agent of citrus canker | |
| US20230121474A1 (en) | Sterilization compositions and methods for using thereof | |
| ES2326717A1 (en) | Use of antimicrobial agents derived from alliaceous plants for the prevention and control of crop diseases, post-harvest rot and as environmental disinifectant products | |
| Gupta et al. | Safety of fresh fruits and vegetables | |
| Saucedo‐Alderete et al. | Cetylpyridinium chloride direct spray treatments reduce Salmonella on cantaloupe rough surfaces | |
| CN111617063B (en) | Washing-free disinfectant | |
| WO2013014316A1 (en) | Fungicidal and bactericidal composition that comprises volatile organic compounds of natural origin | |
| Wu | Chlorine Dioxide (ClO 2) | |
| MX2013014626A (en) | Phytochemical disinfectants for lettuce (lactuca sativa). | |
| CN103585056A (en) | Bergamot composite essential oil | |
| MX2012014363A (en) | Combinations of pyrimethanil and monoterpenes. | |
| US20170245505A1 (en) | Herbal essential oil for biomaterial preservation | |
| JP2009019011A (en) | Powdery mildew controller and control method | |
| KR100862401B1 (en) | Antibiotic liquid for food | |
| Mohammad et al. | Sanitizers for Decontamination of Fresh Produce: Alternative to Chlorine | |
| CN103585060A (en) | Cedar compound essential oil | |
| MX2013014625A (en) | Phytochemical compositions for disinfecting chili (capsicum annuum). |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |