CN104023795A - Transparent hair care composition comprising a base oil and a silicone - Google Patents

Transparent hair care composition comprising a base oil and a silicone Download PDF

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Publication number
CN104023795A
CN104023795A CN201280027115.9A CN201280027115A CN104023795A CN 104023795 A CN104023795 A CN 104023795A CN 201280027115 A CN201280027115 A CN 201280027115A CN 104023795 A CN104023795 A CN 104023795A
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China
Prior art keywords
approximately
care composition
hair care
mineral oil
volatile
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Pending
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CN201280027115.9A
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Chinese (zh)
Inventor
奥泰介
上原伸晃
长谷川润
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Procter and Gamble Co
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Procter and Gamble Co
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Publication of CN104023795A publication Critical patent/CN104023795A/en
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/31—Hydrocarbons
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/896—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
    • A61K8/898—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/12—Preparations containing hair conditioners
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
    • A61K2800/26—Optical properties
    • A61K2800/262—Transparent; Translucent
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
    • A61K2800/30—Characterized by the absence of a particular group of ingredients
    • A61K2800/33—Free of surfactant
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59—Mixtures
    • A61K2800/592—Mixtures of compounds complementing their respective functions
    • A61K2800/5922—At least two compounds being classified in the same subclass of A61K8/18

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)

Abstract

The present invention discloses a non-aqueous hair care composition comprising by weight: from about 65% to about 99.9% of a base oil consisting of: a volatile isoparaffin; a first non-volatile mineral oil having a lower viscosity and density; and a second non-volatile mineral oil having a higher viscosity and density; and (b) from about 0.1% to about 15% of a non-volatile silicone conditioning agent.

Description

The transparent hair care composition that comprises base oil and siloxanes
Technical field
The present invention relates to non-aqueous hair care composition, it comprises by weight: (a) approximately 65% to approximately 99.9% base oil, and described base oil is by volatility isoparaffin; There is the first non-volatile mineral oil compared with low viscosity and density; And the second non-volatile mineral oil with viscosity higher and density forms; (b) approximately 0.1% to approximately 15% non-volatile siloxane conditioner.
Background technology
Owing to contacting with surrounding and due to scalp sebum secreted, people's hair can be dirty.Dirty hair causes and makes it have dirty sense and look not attractive in appearance.Dirty hair needs frequent shampoo to send out.
Shampoo cleans hair by removing excessive dirt and sebum.But shampoo is sent out and can be made hair in state moist, that tangle and be conventionally difficult for arranging.Once hair becomes dry, owing to having removed natural oil and other natural conditioning and the moisturizing component of hair, hair is often in dry, fluffy and disorderly, matt or curling state.When dry, also can make hair have the static degree increasing, this may hinder combing and cause being commonly referred to the state of " hair dispersing ", or causes worthless " hair bifurcated " phenomenon.In addition, chemical treatment is for example permed, is decoloured or has hair dyed and also can destroy hair, and makes it dry, fluffy and disorderly, matt and damaged.
Develop several different methods and carried out conditioning hair.To hair, providing the conventional method of conditioning beneficial effect is by using using of hair care composition.Conditioner preparation can be the form of rinse-off products or leave product, and can be the form of emulsion, cream, gel, spray, mousse, oil preparation, liquid and serosity.
A kind of in leave product is hair oil product, and it comprises relatively large oiliness compound and is generally non-aqueous liquid product.For example, WO 2010/087004 relates to oiliness hair cosmetic composition, the ester compounds that it comprises binary acid and one or more oil, and described grease separation is from ethereal oil, ester oil, hydrocarbon ils, animal or plant oil and silicone oil.It is said, oiliness hair cosmetic composition has the effect of highly improving to damaged hair, and has in use excellent sensation.This WO patent is published in and in example 1, discloses a kind of hair oil, and it comprises two (diethylene glycol ethyl) ether of succinic acid of 5.0%, 45% Fancol ID, 3.0% isopropyl palmitate, 10% mineral oil, 10% ring-type polymethyl siloxane (cyclomethicone), 2.5% polydimethylsiloxane (10mPas) and 20% ethanol.WO patent is announced and also in example 3, to be disclosed a kind of hair oil, and it comprises two (diethylene glycol ethyl) ether of succinic acid of 15%, 40% 2-Methylpentadecane, 20.45% mineral oil, 2% squalane and 3% Camellia oil.
Need such composition that the dry conditioning beneficial effect of improvement is provided.One of method of improving dry conditioning beneficial effect can be and adds non-volatile siloxane conditioner.
Yet the present inventor is surprised to find, when adding non-volatile siloxane conditioner, in some hair oil compositionss, observe foam, especially between transportation and/or operating period.This type of foaminess thinks that for some this type of foaminess is that the consumer of clean beneficial effect signal is worthless.Therefore, need this type of hair oil compositions that dry conditioning beneficial effect is provided, reduce this type of foaminess simultaneously.
Also need this type of hair oil compositions that conditioning sense and the gluing sense/greasy feeling reducing are provided, and there is transparent product appearance.
Without any prior art, provide all advantages of the present invention and beneficial effect.
Summary of the invention
The present invention relates to non-aqueous hair care composition, it comprises by weight:
Approximately 65% to approximately 99.9% base oil, described base oil by:
Volatility isoparaffin;
At 37.8 ℃, there is about 5mm 2s -1to about 30mm 2s -1viscosity and at 25 ℃, there is approximately 0.80 to approximately 0.84 relative density; With
At 37.8 ℃, there is about 45mm 2s -1to about 100mm 2s -1viscosity and the second non-volatile mineral oil at 25 ℃ with approximately 0.847 to approximately 0.89 relative density form; With
Approximately 0.1% to approximately 15% at 25 ℃, there is about 200mm 2s -1the non-volatile siloxane conditioner of viscosity.
Hair care composition of the present invention provides the foaminess of reduction, and the dry conditioning effect of improvement is provided because comprising silicone conditioning agent simultaneously.Hair care composition of the present invention also provides conditioning sense and the gluing sense/greasy feeling reducing, and has transparent product appearance.
By reading description and appending claims below, can understand better these and other feature, aspect and advantage of the present invention.
The specific embodiment
Although this description by particularly point out and clearly claimed claims of the present invention draw a conclusion, should believe by following explanation and can understand better the present invention.
Herein, " comprise/comprise " and refer to add and do not affect other step of final result and other composition.This term contain term " by ... form " and " substantially by ... composition ".
Except as otherwise noted, all percentage ratio, umber and ratio are all in the gross weight of the present composition.All this type of weight relevant to ingredients listed is all with the content meter of active substance, and therefore do not comprise carrier or the by-product in the material that may be included in commercially available acquisition.
Herein, " mixture " refers to and comprises the material of simple combination and any compound being produced by their combination.
compositions
Compositions of the present invention is non-aqueous hair care composition, and it comprises by weight:
Approximately 65% to approximately 99.9% base oil, described base oil by:
Volatility isoparaffin;
At 37.8 ℃, there is about 5mm 2s -1to about 30mm 2s -1viscosity and at 25 ℃, there is the first non-volatile mineral oil of approximately 0.80 to approximately 0.84 relative density; With
At 37.8 ℃, there is about 45mm 2s -1to about 100mm 2s -1viscosity and the second non-volatile mineral oil at 25 ℃ with approximately 0.847 to approximately 0.89 relative density form; With
Approximately 0.1% to approximately 15% at 25 ℃, there is about 200mm 2s -1the non-volatile siloxane conditioner of viscosity.
It is believed that, with other base oil if do not compared containing a kind of those in above-mentioned volatility isoparaffin, the first non-volatile mineral oil and the second non-volatile mineral oil, due to this specific base oil, the present composition has the foaminess of reduction, comprise silicone conditioning agent simultaneously, and the balance between the conditioning sense that the gluing sense/greasy feeling of reduction is provided and can be sent by viscosity higher, and there is transparent product appearance.
Also it is believed that, the non-volatile mineral oil with use with intermediate viscosity and density is compared, the the first/the second non-volatile mineral oil of use has lower/viscosity higher and density provides the foaminess of reduction, make silicone conditioning agent solubilising simultaneously, and provide the siloxanes dissolubility improving under stability, the especially lower temperature of improvement.
non-aqueous composition
Compositions of the present invention is non-aqueous composition.Non-aqueous composition refers to that compositions does not basically contain water herein.In the present invention, " compositions does not basically contain water " refers to: compositions is not moisture; If or compositions comprises water, the content of water is very low.In the present invention, if comprised, the content of water is 1% or lower by weight of the composition, preferably 0.5% or lower, more preferably 0.3% or lower, also more preferably 0.1% or lower, even more preferably 0%.
turbidity
Compositions of the present invention has the product appearance of homogeneous transparent, i.e. the product appearance of homogeneous transparent.
Preferably, compositions of the present invention has 2.0NTU or lower at 25 ℃, 1.5NTU or lower, more preferably 1.0NTU or lower, also more preferably 0.7NTU or lower turbidity.Also preferably, even if compositions of the present invention stored after at least 1 hour at 5 ℃, still at 25 ℃, there is this type of above-mentioned turbidity.By measuring transmittance with HACH2100N scopometer.
According to the product appearance of homogeneous transparent, preferably control is insoluble to the content of the component of the present composition substantially.So-called " substantially insoluble " compound refers to:
Compound is substantially insoluble in compositions under consumption; And
When comprising during the compound of consumption, said composition: (i) inhomogeneous because being for example separated; Or (ii) even, but have higher turbidity, the turbidity at 25 ℃ does not comprise 2.0NTU higher than 2.0NTU(), preferably higher than 1.5NTU(, do not comprise 1.5NTU), more preferably higher than 1.0NTU(, do not comprise 1.0NTU), also more preferably higher than 0.7NTU(, do not comprise 0.7NTU).
This type of substantially insoluble compound also comprise aliphatic compound, for example comprise: there is 25 ℃ or more dystectic fatty alcohol, as spermol and stearyl alcohol; There is 25 ℃ or more dystectic fatty acid, as stearic acid; Derivant has 25 ℃ or more dystectic fatty alcohol derivative and derivative of fatty acid, as their ester and ether; And their mixture.
More preferably, compositions of the present invention does not basically contain this type of insoluble compound substantially.In the present invention, compositions " does not basically contain " substantially insoluble compound and refers to: compositions is containing substantially insoluble compound; Or if compositions comprises substantially insoluble compound, this type of content of insoluble compound is very low substantially.In the present invention, if comprised, this type of substantially the content of insoluble compound be 1.0% or lower, preferably 0.5% or lower, more preferably 0.3% or lower, also more preferably 0.1% or lower, even more preferably 0%.
do not basically contain surfactant
Preferably, according to the inadvisable foaminess of the product of product transparency and/or reduction, compositions of the present invention does not basically contain surfactant.
This type of surfactant comprises: anion surfactant; Cationic surfactant; Amphoteric surfactant; Zwitterionic surfactant; HLB is 5 or higher non-ionic surface active agent; And their mixture.HLB be 5 or this type of higher ionic surfactant pack for example draw together: the ether of fatty alcohol, as the ether of lauryl alcohol, comprises that laureth-3(HLB is approximately 8); The ester of fatty alcohol, as the ester of lauryl alcohol.
In the present invention, " compositions does not basically contain surfactant " refers to: compositions is not containing surfactant; If or compositions comprises surfactant, the content of this type of surfactant is very low.In the present invention, if comprised, the total content of this type of surfactant is preferably 0.1% or lower by weight of the composition, and more preferably 0.01% or lower, also more preferably 0.001% or lower, even more preferably 0.0005%.
base oil
Compositions of the present invention comprises base oil.The content of base oil is approximately 65% to approximately 99.9% by weight of the composition, approximately 70% to approximately 99.8%, more preferably from about 75% to approximately 99.5%, also more preferably from about 80% to approximately 99%, also more preferably from about 85% to approximately 98%.
Be used for base oil herein by volatility isoparaffin; The first non-volatile mineral oil; Form with the second non-volatile mineral oil, they are described in more detail below.
In the present invention, preferably the weight ratio of volatility isoparaffin and the first non-volatile mineral oil and the second non-volatile mineral oil sum at about 1:0.2 to about 1:2, more preferably from about 1:0.5 is to about 1:1.5, also more preferably from about 1:0.75 to the scope of about 1:1.2.
In the present invention, preferably the weight ratio of the first non-volatile mineral oil and the second non-volatile mineral oil at about 1:0.05 to about 1:5, more preferably from about 1:0.1 is to about 1:2, and also more preferably from about 1:0.2 is to about 1:1.5, and even more preferably from about 1:0.2 is to the scope of about 1:0.8.
volatility isoparaffin
The content of volatility isoparaffin is preferably approximately 30% to approximately 90% by weight of the composition, and more preferably from about 40% to approximately 75%, also more preferably from about 40% to approximately 60%.
For volatility isoparaffin herein, at 37.8 ℃, there is preferred about 0.5mm 2s -1to about 50mm 2s -1, 0.8mm more preferably from about 2s -1to about 40mm 2s -1, 1mm more preferably from about also 2s -1to about 30mm 2s -1, 1.5mm even more preferably from about 2s -1to about 20mm 2s -1, 1.5mm more preferably from about also 2s -1to about 10mm 2s -1viscosity.When using two or more isoparaffic solvents, preferably the mixture of isoparaffic solvent has above-mentioned viscosity.
Preferably, for volatility isoparaffin herein, be to there are approximately 8 to approximately 20 carbon atoms, 8 to approximately 16 carbon atoms more preferably from about, 8 to approximately 12 carbon atoms more preferably from about also, even more preferably from about those of 10 to approximately 12 carbon atoms.
In the present invention, preferred volatility isoparaffin for example comprises trimer, tetramer and the pentamer of isobutene. and their mixture.The isoparaffin of commercially available acquisition can have its degree of polymerization distribution, and can be for example mixture of trimer, tetramer and pentamer.Herein, tetramer refers to that tetramer wherein has the isoparaffin of the commercially available acquisition of high-load, and the content of tetramer is preferably 70% or higher, more preferably 80% or higher, also more preferably 85% or higher.
the first non-volatile mineral oil
The content of the first non-volatile mineral oil is preferably approximately 5% to approximately 55% by weight of the composition, and more preferably from about 15% to approximately 50%, also more preferably from about 25% to approximately 45%, even more preferably from about 30% to approximately 40%.
For the first non-volatile mineral oil herein, at 37.8 ℃, there is about 5mm 2s -1to about 30mm 2s -1, preferred about 8mm 2s -1to about 20mm 2s -1, 10mm more preferably from about 2s -1to about 15mm 2s -1viscosity.For the first non-volatile mineral oil herein, at 25 ℃, also have approximately 0.80 to approximately 0.84, preferably approximately 0.81 to approximately 0.836,0.815 to approximately 0.834 relative density more preferably from about.
the second non-volatile mineral oil
The content of the second non-volatile mineral oil is preferably approximately 1% to approximately 25% by weight of the composition, and more preferably from about 5% to approximately 20%, also more preferably from about 7% to approximately 18%.
For the second non-volatile mineral oil herein, at 37.8 ℃, there is about 45mm 2s -1to about 100mm 2s -1, preferred about 55mm 2s -1to about 85mm 2s -1, 65mm more preferably from about 2s -1to about 75mm 2s -1viscosity.For the second non-volatile mineral oil herein, at 25 ℃, also have approximately 0.847 to approximately 0.89, preferably approximately 0.85 to approximately 0.885,0.850 to approximately 0.875 relative density more preferably from about.
ester
Compositions of the present invention also can comprise ester.According to the balance between conditioning sense and product stability, the content of described ester in described compositions be approximately 0.1% to approximately 25% by weight, preferred approximately 0.5% to approximately 15%, more preferably from about 1% to approximately 10%, also more preferably from about 1% to approximately 5%.
For ester herein, be that HLB is 3 or lower and be at room temperature those of liquid.For ester herein, be those of methyl ester and composition thereof that are for example selected from C12-18 fatty acid.This type of ester comprises for example methyl hexadecanoate, methyl stearate, methyl oleate, methyl linoleate and methyl laurate.Wherein, methyl stearate is preferred in the present invention.It is believed that this type of ester contributes to silicone conditioning agent to be dissolved in base oil of the present invention.
silicone conditioning agent
Compositions of the present invention comprises silicone conditioning agent.For providing dry conditioning beneficial effect as reduced friction, the content of silicone conditioning agent is approximately 0.1% by weight of the composition, preferred approximately 0.2%, more preferably from about 0.5%, and according to conditioning beneficial effect and/or product transparency, the content of silicone conditioning agent is by weight of the composition to approximately 15%, preferably to approximately 10%, more preferably to approximately 8%, also more preferably to approximately 5%.
For silicone conditioning agent herein, be nonvolatile, and be preferably liquid at 25 ℃.For conditioning beneficial effect is provided, for silicone conditioning agent herein, at 25 ℃, there is about 200mm 2s - 1, preferably approximately 200 to approximately 300,000mm 2s -1, more preferably from about 200 to approximately 50,000mm 2s -1apparent viscosity.
For silicone conditioning agent herein, be hydrophobic, and be that HLB is approximately 8 or lower, preferably 5 or lower those.
For silicone conditioning agent herein, be preferably non-emulsion form.
amino silicone
In the present invention, silicone conditioning agent is preferably amino silicone.Preferably, for the minimizing beneficial effect that rubs, for amino silicone herein, have and be less than about 0.12m mol/g, be more preferably less than about 0.1m mol/g, be also more preferably less than about 0.08m mol/g, be even more preferably less than the amine content of about 0.06mmol/g.Being surprised to find nitrogen (amine functional group) content in amino silicone, higher to be tending towards causing friction to reduce fewer, and it is lower therefore to derive from the conditioning beneficial effect of amino silicone.
For amino silicone herein for meeting those of general formula (I):
(R 1) aG 3-a-Si-(-OSiG 2) n-(-OSiG b(R 1) 2-b) m-O-SiG 3-a(R 1) a
Wherein G is hydrogen, phenyl, hydroxyl or C 1-C 8alkyl, preferable methyl; A is for having 1 to 3, preferably the integer of 1 value; B is 0,1 or 2, preferably 1; N is 1 to 2,000, preferably 100 to 1,800, more preferably 300 to 800, and the more preferably number of 500-600 also; M is 0; R 1for meeting general formula CqH 2qthe univalent perssad of L, wherein q is the integer with 2 to 8 value, and L is selected from following group :-N (R 2) CH 2-CH 2-N (R 2) 2;-N (R 2) 2;-N (R 2) 3a -;-N (R 2) CH 2-CH 2-NR 2h 2a -; R wherein 2hydrogen, phenyl, benzyl or saturated hydrocarbyl, preferred about C 1to about C 20alkyl; A -it is halogen ion.L You Xuan Wei – N (CH 3) 2huo – NH 2, Geng You Xuan – NH 2.
A kind of highly preferred amino silicone is corresponding to those of formula (I), m=0 wherein, and a=1, q=3, G=methyl, n is preferably approximately 1400 to approximately 1700, and more preferably about 1600; And L Wei – N (CH 3) 2huo – NH 2, Geng You Xuan – NH 2.Another kind of further highly preferred amino silicone is corresponding to those of formula (I), m=0 wherein, and a=1, q=3, G=methyl, n is preferably approximately 400 to approximately 800, and more preferably from about 500 to about 600; And L Wei – N (CH 3) 2huo – NH 2, Geng You Xuan – NH 2.
This type of preferred amino silicone can be called as terminal amino group siloxanes, because the one or both ends of siloxane chain are by nitrogen-containing group end-blocking.Also be surprised to find and compare this type of terminal amino group siloxanes with grafting amino silicone and provide the friction of improvement to reduce.
annexing ingredient
Compositions of the present invention can comprise other annexing ingredient, described annexing ingredient can be selected by those skilled in the art according to the required characteristic of end product, and it is suitable for making said composition in the attractive in appearance or aesthetic acceptance that has more, or for they provide additional use beneficial effect.This type of other annexing ingredient is conventionally with by weight of the composition approximately 0.001% to approximately 10%, and preferably approximately 5% content is used separately at most.
Various other annexing ingredients can be formulated in compositions of the present invention.These comprise: other conditioner, as with trade name Peptein2000 purchased from the hydrolytic collagen of Hormel, with trade name Emix-d purchased from the vitamin E of Eisai, purchased from the pantothenylol of Roche, purchased from the panthenyl ethyl ether of Roche, hydrolysis of keratin, protein, plant extract and nutrient substance; Antiseptic, as benzylalcohol, methyl parahydroxybenzoate, propyl p-hydroxybenzoate and imidazolidinyl urea; Coloring agent, as any in FD & C or D & C dyestuff; Spice; And dandruff agent, as Zinc Pyrithione and salicylic acid.
product form
Hair care composition of the present invention can be hair-conditioning and/or hair styling product etc.
Hair care composition of the present invention is preferably the form of leave product, and can be mixed with various product forms, includes but not limited to gel, spray, oil preparation, liquid and serosity.Preferably, compositions of the present invention is liquid form, as oil preparation, liquid and serosity.
using method
For disposable form, preferably hair care composition is applied to moistening or moist hair, then dry hair.This type of hair care composition is being applied to after hair, according to the hobby of user by trichoxerosis and sizing.In replacement scheme, it can be applied to the hair of drying, then by hair combing or sizing, and be dried according to the hobby of user.
example
Following instance has further described and demonstrated the embodiment in the scope of the invention.The example providing is only for illustrative purposes, and not can be regarded as is limitation of the present invention, because can make many modification under the condition that does not depart from the spirit and scope of the invention.Unless below explanation in addition, applicable composition is all identified with chemical name or CTFA name herein.
[compositions]
component definition
* 1 volatility isoparaffin: there is 1.4mm at 37.8 ℃ 2s -1the isobutylene trimer of viscosity
* 2 first non-volatile mineral oil: there is about 11-14mm at 37.8 ℃ 2s -1viscosity, and at 25 ℃, there is the relative density of about 0.820-0.831
* 3 second non-volatile mineral oil: there is about 65-75mm at 37.8 ℃ 2s -1viscosity, and at 25 ℃, there is the relative density of about 0.852-0.872
* 4 non-volatile mineral oil: there is about 40mm at 37.8 ℃ 2s -1viscosity, and at 25 ℃, there is the relative density of about 0.838-0.853
* 5 amino silicones: purchased from the terminal amino group siloxanes of GE, it has approximately 10 at 25 ℃, 000mm 2s -1viscosity and there is following formula:
(R 1) aG 3-a-Si-(-OSiG 2) n-(-OSiG b(R 1) 2-b) m-O-SiG 3-a(R 1) a
Wherein G is methyl; A is integer 1; N is 400 to approximately 600 number; M is integer 0; R 1for meeting general formula CqH 2qthe univalent perssad of L, wherein q is integer 3, and L Wei – NH 2
* 6 polydimethylsiloxane fluids: there is 18,000,000mm at 25 ℃ 2s -1the polydimethylsiloxane of viscosity and there is 200mm 2s -115%/85% mixture of the polydimethylsiloxane of viscosity
* 7 esters: methyl stearate
preparation method
The hair care composition of " example 1 " as implied above to " example 4 " and " example i " to " example iii " can be prepared by any conventional method well known in the art.They can suitably be prepared as follows:
Silicone conditioning agent and ester (if comprising) are joined in base oil, and at room temperature stir, until evenly.If comprised, under agitation by other component as spice join as described in mixture.
characteristic and conditioning beneficial effect
By said method, measure turbidity.For some in above-mentioned composition, by following methods evaluation foaminess and/or stability.Evaluation result is as implied above.
foaminess
When described in using 10ml during compositions, by 6 group members, evaluate foaminess.
C: tester
C1: be equal to tester
Δ: 1 to 2 group member answers, and compares with tester, and described compositions causes foaming.
*: 3 to 6 group members answer, and compare with tester, and described compositions causes foaming.
stability
Described compositions stored after 1 hour at 5 ℃, by the compositions outward appearance at 25 ℃, evaluated stability.
Zero: do not observe and be separated and/or record turbidity lower than 2.0
*: observe and be separated and/or record turbidity higher than 5.0
Example 1 to 4 is for especially can be used for the hair care composition of the present invention of leave purposes.Embodiment open by aforementioned " example 1 " to " example 4 " and representative has many advantages.For example, they provide the foaminess of reduction, and the dry conditioning effect of improvement is provided because comprising silicone conditioning agent simultaneously.They also provide conditioning sense and the gluing sense/greasy feeling reducing, and have transparent product appearance.They also provide the stability of improvement, the siloxanes dissolubility especially improving under lower temperature.
By the comparison between example of the present invention and comparative example " example i " to " example iii ", can understand this type of advantage.For example, compare to the compositions of " example 3 " with the present invention's " example 1 ", the compositions of comparative example " example i " has the foaminess of raising.For example, the compositions of comparative example " example ii " does not have transparent product appearance.For example, compare with the compositions of comparative example " example iii ", the present composition " example 1 " has the stability of improvement to " example 4 ".
Dimension disclosed herein and value should not be understood to be strictly limited to quoted exact value.On the contrary, except as otherwise noted, each such dimension is intended to represent described value and around the scope being equal in this value function.For example, disclosed dimension " 40mm " is intended to represent " about 40mm ".Dimension disclosed herein and value should not be understood to be strictly limited to described exact numerical values recited.Size disclosed herein and numerical value should not be understood to be strictly limited to quoted exact value.On the contrary, except as otherwise noted, each such dimension is intended to represent described value and around the scope being equal in this value function.For example, disclosed dimension " 40mm " is intended to represent " about 40mm ".
Unless expressly excluded or otherwise limited, every piece of document quoting herein, comprises patent any cross reference or relevant or patent application, is all hereby incorporated herein by reference in full.The quoting of any document is not it as disclosed herein or be subject to the prior art of any invention of claims protection; or its individually or with any combination of any other list of references, or with reference to, propose, suggestion or disclose the approval of any this type of invention.In addition, in the present invention, any implication of term or while defining contradiction in any implication of term or definition and the file that is incorporated to way of reference, should obey implication or the definition of giving in the present invention this term.
Although illustrated and described specific embodiments of the invention, it is obvious for those of skill in the art that, in the situation that not departing from the spirit and scope of the invention, can make many other change and modification.Therefore, the claims of enclosing are intended to contain all these changes and the modification in the scope of the invention.

Claims (10)

1. a non-aqueous hair care composition, comprises by weight:
Approximately 65% to approximately 99.9% base oil, described base oil by:
Volatility isoparaffin;
At 37.8 ℃, there is about 5mm 2s -1to about 30mm 2s -1viscosity and at 25 ℃, there is the first non-volatile mineral oil of approximately 0.80 to approximately 0.84 relative density; With
At 37.8 ℃, there is about 45mm 2s -1to about 100mm 2s -1viscosity and the second non-volatile mineral oil at 25 ℃ with approximately 0.847 to approximately 0.89 relative density form; With
Approximately 0.1% to approximately 15% at 25 ℃, there is about 200mm 2s -1the non-volatile siloxane conditioner of viscosity.
2. hair care composition according to claim 1, the weight ratio of wherein said volatility isoparaffin and described the first non-volatile mineral oil and the second non-volatile mineral oil sum is that about 1:0.2 is to about 1:2.
3. hair care composition according to claim 1, the weight ratio of wherein said the first non-volatile mineral oil and described the second non-volatile mineral oil is that about 1:0.1 is to about 1:2.
4. hair care composition according to claim 1, the weight ratio of wherein said the first non-volatile mineral oil and described the second non-volatile mineral oil is that about 1:0.2 is to about 1:0.8.
5. hair care composition according to claim 1, wherein said non-volatile siloxane compound is amino silicone.
6. hair care composition according to claim 5, wherein said amino silicone has following formula:
(R 1) aG 3-a-Si-(-OSiG 2) n-(-OSiG b(R 1) 2-b) m-O-SiG 3-a(R 1) a
Wherein G is hydrogen, phenyl, hydroxyl or C 1-C 8alkyl; A is 1; N is 100 to 1,800 number; M is 0; R 1for meeting general formula CqH 2qthe univalent perssad of L, wherein q is the integer with 2 to 8 value, and L is-N (R 2) 2; R wherein 2for hydrogen, phenyl, benzyl or saturated hydrocarbyl, and A -for halogen ion.
7. hair care composition according to claim 6, wherein L Wei – N (CH 3) 2huo – NH 2.
8. hair care composition according to claim 1, wherein said compositions does not basically contain surfactant.
9. hair care composition according to claim 1, wherein said compositions is for leave purposes.
10. hair care composition according to claim 1, wherein said compositions has 2.0NTU or lower turbidity at 25 ℃.
CN201280027115.9A 2011-06-03 2012-05-24 Transparent hair care composition comprising a base oil and a silicone Pending CN104023795A (en)

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MX2013014219A (en) 2014-01-20
JP5866438B2 (en) 2016-02-17
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EP2714199B1 (en) 2017-04-19

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