CN103985803A - Nitride LED component - Google Patents

Nitride LED component Download PDF

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Publication number
CN103985803A
CN103985803A CN201410183738.6A CN201410183738A CN103985803A CN 103985803 A CN103985803 A CN 103985803A CN 201410183738 A CN201410183738 A CN 201410183738A CN 103985803 A CN103985803 A CN 103985803A
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CN
China
Prior art keywords
layer
contact layer
iii
light emitting
emitting devices
Prior art date
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Pending
Application number
CN201410183738.6A
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Chinese (zh)
Inventor
蓝永凌
张家宏
卓昌正
林兓兓
谢翔麟
谢祥彬
徐志波
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Anhui Sanan Optoelectronics Co Ltd
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Anhui Sanan Optoelectronics Co Ltd
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Publication date
Application filed by Anhui Sanan Optoelectronics Co Ltd filed Critical Anhui Sanan Optoelectronics Co Ltd
Priority to CN201410183738.6A priority Critical patent/CN103985803A/en
Publication of CN103985803A publication Critical patent/CN103985803A/en
Pending legal-status Critical Current

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L33/00Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L33/36Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the electrodes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L33/00Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L33/02Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor bodies
    • H01L33/20Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor bodies with a particular shape, e.g. curved or truncated substrate
    • H01L33/22Roughened surfaces, e.g. at the interface between epitaxial layers

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Led Devices (AREA)

Abstract

With expansion of application of nitride semiconductor components, except high brightness, importance of lowering component operating voltage and improving static voltage withstanding is improved too. The invention provides a nitride LED component, a highly-doped conical contact layer grows on a p-type gallium nitride contact layer, the conical contact layer discontinuously grows and provides low contact resistance, component operating voltage is lowered, and the static voltage withstanding ability is improved.

Description

Iii-nitride light emitting devices assembly
Technical field
The present invention relates to nitride semiconductor light electric device, relate in particular to a kind of nitride semiconductor light electric device that improves p-type contact layer structure that has.
Background technology
In recent years, light-emitting diode (LED) assembly focuses on luminance raising, and expectation can be applied to lighting field, to bring into play effect of carbon reduction.In general, LED assembly comprises: have and in Sapphire Substrate, form nitride resilient coating, by the N-shaped contact layer of Si Doped GaN, by multi-layer quantum well construction (the MQW:Multi-Quant μ m-Well) active layer with InGaN, the AlGaN electronic barrier layer being adulterated by Mg, the p-type nitride contact layer being adulterated by Mg stacks gradually the structure forming, and this structure has the semiconductor subassembly characteristic of higher brightness.
Along with nitride-based semiconductor component application expands, except having high brightness, reduce assembly operation voltage and also improve with the importance that improves electrostatic withstand voltage thereupon.
Summary of the invention
For prior art, for lower assembly operation voltage and raising electrostatic withstand voltage is provided, nitride-based semiconductor assembly object of the present invention is: provide a kind of highly doped taper contact layer as p-type contact layer, to reduce the contact resistance between electrode and p-type layer, this highly doped taper contact layer and electrode form good ohmic contact, to improve component characteristic.
In order to achieve the above object, above-mentioned p-type layer comprises the first p-type layer and the second p-type layer, and wherein the second p-type layer growth is on the first p-type layer.Further, the second p-type layer comprises smooth contact layer and taper contact layer from bottom to up, and its taper contact layer is highly doped taper portion, is discontinuous growth.
Preferably, the second p-type layer doping content is compared with the first p-type floor height.
Preferably, the first p-type layer doping content is 1 × 10 18/ cm 3~ 5 × 10 19/ cm 3.
Preferably, the second p-type layer doping content is greater than 5 × 10 19/ cm 3, be no more than 5 × 10 21/ cm 3.
Preferably, the thickness of highly doped taper contact layer is less than or equal to 200, so that forward voltage does not rise.
Preferably, in order to obtain good p-type electric-conducting, highly doped its doped chemical of taper contact layer is preferably Mg.
Preferably, the tapered diameter (a) of highly doped taper contact layer, lateral dimension is between 0.1 μ m and 2 μ m.
Preferably, the tapered height (b) of highly doped taper contact layer, longitudinal size is between 0.1nm and 10nm.
Preferably, the coverage rate of highly doped taper contact layer is 5% to 100%, and it accounts for the area ratio of the smooth contact layer of described the second p-type layer.
Preferably, the operative tip of taper contact layer is platform.
Brief description of the drawings
Accompanying drawing is used to provide a further understanding of the present invention, and forms a part for specification, for explaining the present invention, is not construed as limiting the invention together with embodiments of the present invention.In addition, accompanying drawing data are to describe summary, are not to draw in proportion.
Fig. 1 is the iii-nitride light emitting devices end view of the embodiment of the present invention.
Fig. 2 is the 2D analysis chart of Atomic force microscopy (AFM) 20 × 20 μ m of the embodiment of the present invention.
Fig. 3 is the 3D analysis chart of Atomic force microscopy (AFM) 20 × 20 μ m of the embodiment of the present invention.
In figure, indicate
1. substrate; 2. resilient coating; 3.n type layer; 4. stress release layer; 5. Multiple Quantum Well active area (active layer); 61. first p-type layers; 62. second p-type layers; The smooth contact layer of 62a.; 62b. taper contact layer; A. tapered diameter; B. tapered height.
Embodiment
Below in conjunction with drawings and Examples, the specific embodiment of the present invention is elaborated.
Embodiment
Please refer to accompanying drawing 1, grown buffer layer 2 on substrate 1, then growing n-type layer 3 on resilient coating 2, growth stress releasing layer 4 on N-shaped layer 3 again, then the Multiple Quantum Well active area 5 of growing on stress release layer 4, then first p-type layer 61, the second p-type layer 62 of growing on Multiple Quantum Well active area 5 grow on the first p-type layer 61, and wherein the second p-type layer 62 comprises smooth contact layer 62a and taper contact layer 62b from bottom to up.
Specifically, substrate 1 material can be selected alumina single crystal (Sapphire) or SiC (6H-SiC or 4H-SiC) or Si or GaAs or GaN etc., lattice constant (lattice constant) also comprises wherein close to the monocrystalline oxide of nitride-based semiconductor, preferably uses Sapphire.
And then, resilient coating 2 is positioned on described substrate 1, and its material is aluminum indium gallium nitride (Al 1-x-yga xin yn), 0≤x <, 1,0≤y < 1 wherein, be positioned at the N-shaped gallium nitride layer 3 on resilient coating 2, be positioned at the stress release layer 4 on N-shaped gallium nitride layer 3, this stress release layer 4 is InGaN or InGaN/gallium nitride superlattice structure, be positioned at the active layer 5 on stress release layer 4, its material is InGaN, be positioned at the first p-type layer 6 on active layer 5, its material is the gallium nitride of magnesium doping (Mg-doped), thickness is between 100 to 4000, growth temperature is between 800 DEG C to 1000 DEG C, be positioned at the second p-type layer 62 on the first p-type layer 61, its growth temperature is between 700 DEG C to 900 DEG C, the second p-type layer 62 thickness are less than or equal to 200.
The nitride-based semiconductor assembly of present embodiment is the first p-type layer 61 by magnesium doping (Mg-doped) GaN by its material, and its growth temperature is between 800 DEG C to 1000 DEG C, and doping content is preferably 1 × 10 18/ cm 3to 5 × 10 19/ cm 3, its material of the present invention is by the 2nd P type layer 62 of magnesium doping (Mg-doped) GaN, and its growth temperature is between 700 DEG C to 900 DEG C, and doping content is preferably greater than 5 × 10 19/ cm 3, but be no more than 5 × 10 21/ cm 3, gallium nitride light-emitting diode carries out Atomic force microscopy(AFM after growing up) scanning analysis, scanning length and width are 20 × 20 μ m, depth is positive and negative 7nm, as shown in Figure 2, the irregular bright spot on the second p-type layer 62 surface is taper contact layer 62b, as shown in the 3D schematic diagram of Fig. 3, known protrusion is that taper (it is to be noted, because taper thing occurs continuously, may form at random platform, the operative tip that is taper portion forms platform), this taper thing contact layer is discontinuous growth as shown in Figure 2, its coverage rate is 5% to 100%, account for the area ratio of the smooth contact layer 61a of described the second p-type layer, this taper contact layer provides lower contact resistance, apply this taper thing contact layer in nitride light-emitting assembly, except having high brightness, reduce assembly positive operation voltage and improve electrostatic withstand voltage.
According to the gallium nitride of tool low-resistance value p-type contact layer of the present invention, can comprise the p-type electrode layer being positioned on the second p-type layer, it can comprise Ni/Au, Ni/pd, Ni/Pt, Pd/ Au, Pt/Au, Ti/Au, Cr/Au, TiN, TiWNx, the metal conducting layer of WSix or ITO, ZnO, NiO, the oxidic, transparent, conductive layers of CTO.
Should be understood that, above-mentioned specific embodiments is the preferred embodiments of the present invention, and scope of the present invention is not limited to this embodiment, and all any changes of doing according to the present invention, within all belonging to protection scope of the present invention.

Claims (10)

1. an iii-nitride light emitting devices assembly, comprise N-shaped layer, active layer, p-type layer, wherein p-type layer comprises the first p-type layer and the second p-type layer, it is characterized in that: described the second p-type layer comprises smooth contact layer and taper contact layer from bottom to up, its taper contact layer is highly doped taper portion, is discontinuous growth.
2. iii-nitride light emitting devices assembly according to claim 1, is characterized in that: described the second p-type layer doping content is compared with the first p-type floor height.
3. iii-nitride light emitting devices assembly according to claim 1, is characterized in that: described the first p-type layer doping content is 1 × 10 18/ cm 3~ 5 × 10 19/ cm 3.
4. iii-nitride light emitting devices assembly according to claim 1, is characterized in that: described the second p-type layer doping content is greater than 5 × 10 19/ cm 3, be no more than 5 × 10 21/ cm 3.
5. iii-nitride light emitting devices assembly according to claim 1, is characterized in that: the concentration of described taper contact layer is greater than 5 × 10 19/ cm 3.
6. iii-nitride light emitting devices assembly according to claim 1, is characterized in that: the tapered diameter (a) of described taper contact layer, its scope is 0.1 μ m≤a≤2 μ m.
7. iii-nitride light emitting devices assembly according to claim 1, is characterized in that: the tapered height (b) of described taper contact layer, its scope is 0.1nm≤b≤10nm.
8. iii-nitride light emitting devices assembly according to claim 1, is characterized in that: the thickness of described taper contact layer is less than or equal to 200.
9. iii-nitride light emitting devices assembly according to claim 1, is characterized in that: the area ratio that described taper contact layer accounts for described smooth contact layer is 5% to 100%.
10. iii-nitride light emitting devices assembly according to claim 1, is characterized in that: the operative tip of described taper contact layer is platform.
CN201410183738.6A 2014-05-04 2014-05-04 Nitride LED component Pending CN103985803A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105390575A (en) * 2014-08-20 2016-03-09 Lg伊诺特有限公司 light emitting device and lighting system
CN105591000A (en) * 2014-10-24 2016-05-18 比亚迪股份有限公司 LED structure and formation method thereof
CN110459658A (en) * 2018-05-08 2019-11-15 山东浪潮华光光电子股份有限公司 A kind of UV LED chip of p-type GaN layer and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2012114389A (en) * 2010-11-29 2012-06-14 Toshiba Corp Semiconductor light-emitting element
CN103682010A (en) * 2012-09-17 2014-03-26 比亚迪股份有限公司 LED chip and preparation method

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2012114389A (en) * 2010-11-29 2012-06-14 Toshiba Corp Semiconductor light-emitting element
CN103682010A (en) * 2012-09-17 2014-03-26 比亚迪股份有限公司 LED chip and preparation method

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105390575A (en) * 2014-08-20 2016-03-09 Lg伊诺特有限公司 light emitting device and lighting system
CN105390575B (en) * 2014-08-20 2019-11-26 Lg伊诺特有限公司 Luminescent device and lighting system
CN105591000A (en) * 2014-10-24 2016-05-18 比亚迪股份有限公司 LED structure and formation method thereof
CN110459658A (en) * 2018-05-08 2019-11-15 山东浪潮华光光电子股份有限公司 A kind of UV LED chip of p-type GaN layer and preparation method thereof

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Application publication date: 20140813