CN103974927A - 通过使二氧化碳与氢气反应制备甲酸的方法 - Google Patents
通过使二氧化碳与氢气反应制备甲酸的方法 Download PDFInfo
- Publication number
- CN103974927A CN103974927A CN201280059095.3A CN201280059095A CN103974927A CN 103974927 A CN103974927 A CN 103974927A CN 201280059095 A CN201280059095 A CN 201280059095A CN 103974927 A CN103974927 A CN 103974927A
- Authority
- CN
- China
- Prior art keywords
- phase
- formic acid
- mixture
- lower floor
- tertiary amine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0201—Oxygen-containing compounds
- B01J31/0202—Alcohols or phenols
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
- B01J31/0235—Nitrogen containing compounds
- B01J31/0237—Amines
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
- B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
- B01J31/2414—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom comprising aliphatic or saturated rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/02—Preparation of carboxylic acids or their salts, halides or anhydrides from salts of carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/41—Preparation of salts of carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
- C07C51/48—Separation; Purification; Stabilisation; Use of additives by liquid-liquid treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/60—Reduction reactions, e.g. hydrogenation
- B01J2231/62—Reductions in general of inorganic substrates, e.g. formal hydrogenation, e.g. of N2
- B01J2231/625—Reductions in general of inorganic substrates, e.g. formal hydrogenation, e.g. of N2 of CO2
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/821—Ruthenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/90—Catalytic systems characterized by the solvent or solvent system used
- B01J2531/98—Phase-transfer catalysis in a mixed solvent system containing at least 2 immiscible solvents or solvent phases
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP11184297 | 2011-10-07 | ||
EP11184297.7 | 2011-10-07 | ||
PCT/EP2012/069458 WO2013050367A2 (de) | 2011-10-07 | 2012-10-02 | Verfahren zur herstellung von ameisensäure durch umsetzung von kohlendioxid mit wasserstoff |
Publications (1)
Publication Number | Publication Date |
---|---|
CN103974927A true CN103974927A (zh) | 2014-08-06 |
Family
ID=46963751
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201280059095.3A Pending CN103974927A (zh) | 2011-10-07 | 2012-10-02 | 通过使二氧化碳与氢气反应制备甲酸的方法 |
Country Status (10)
Country | Link |
---|---|
EP (1) | EP2763950A2 (de) |
JP (1) | JP2014530216A (de) |
KR (1) | KR20140074373A (de) |
CN (1) | CN103974927A (de) |
BR (1) | BR112014008338A2 (de) |
CA (1) | CA2851175A1 (de) |
IN (1) | IN2014DN03122A (de) |
RU (1) | RU2014118032A (de) |
SG (1) | SG11201400997TA (de) |
WO (1) | WO2013050367A2 (de) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB201112231D0 (en) * | 2011-07-15 | 2011-08-31 | Verdant Bioproducts Ltd | Micro-organism |
US8596013B2 (en) | 2012-04-04 | 2013-12-03 | Valinge Innovation Ab | Building panel with a mechanical locking system |
US9428438B2 (en) | 2012-11-27 | 2016-08-30 | Basf Se | Process for preparing formic acid |
WO2016024293A1 (en) | 2014-08-12 | 2016-02-18 | Council Of Scientific & Industrial Research | Metal catalyzed process for reduction of co2 to sodium formate and formic acid |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0095321A2 (de) * | 1982-05-22 | 1983-11-30 | BP Chemicals Limited | Produktion von Formiat-Salzen |
EP0329337A2 (de) * | 1988-02-17 | 1989-08-23 | BP Chemicals Limited | Herstellung von Ameisensäure aus einer Stickstoffbase, Kohlendioxyd und Wasserstoff |
WO2010149507A2 (de) * | 2009-06-26 | 2010-12-29 | Basf Se | Verfahren zur herstellung von ameisensäure |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB8424672D0 (en) | 1984-09-29 | 1984-11-07 | Bp Chem Int Ltd | Production of formic acid |
DE102004040789A1 (de) | 2004-08-23 | 2006-03-02 | Basf Ag | Verfahren zur Herstellung von Ameisensäure |
WO2008116799A1 (de) * | 2007-03-23 | 2008-10-02 | Basf Se | Verfahren zur herstellung von ameisensäure |
-
2012
- 2012-10-02 BR BR112014008338A patent/BR112014008338A2/pt not_active IP Right Cessation
- 2012-10-02 KR KR1020147011873A patent/KR20140074373A/ko not_active Application Discontinuation
- 2012-10-02 WO PCT/EP2012/069458 patent/WO2013050367A2/de active Application Filing
- 2012-10-02 JP JP2014533856A patent/JP2014530216A/ja not_active Withdrawn
- 2012-10-02 CN CN201280059095.3A patent/CN103974927A/zh active Pending
- 2012-10-02 CA CA2851175A patent/CA2851175A1/en not_active Abandoned
- 2012-10-02 IN IN3122DEN2014 patent/IN2014DN03122A/en unknown
- 2012-10-02 EP EP12766684.0A patent/EP2763950A2/de not_active Withdrawn
- 2012-10-02 RU RU2014118032/04A patent/RU2014118032A/ru not_active Application Discontinuation
- 2012-10-02 SG SG11201400997TA patent/SG11201400997TA/en unknown
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0095321A2 (de) * | 1982-05-22 | 1983-11-30 | BP Chemicals Limited | Produktion von Formiat-Salzen |
EP0329337A2 (de) * | 1988-02-17 | 1989-08-23 | BP Chemicals Limited | Herstellung von Ameisensäure aus einer Stickstoffbase, Kohlendioxyd und Wasserstoff |
WO2010149507A2 (de) * | 2009-06-26 | 2010-12-29 | Basf Se | Verfahren zur herstellung von ameisensäure |
Also Published As
Publication number | Publication date |
---|---|
BR112014008338A2 (pt) | 2017-04-18 |
JP2014530216A (ja) | 2014-11-17 |
WO2013050367A2 (de) | 2013-04-11 |
RU2014118032A (ru) | 2015-11-20 |
EP2763950A2 (de) | 2014-08-13 |
CA2851175A1 (en) | 2013-04-11 |
SG11201400997TA (en) | 2014-09-26 |
IN2014DN03122A (de) | 2015-05-22 |
KR20140074373A (ko) | 2014-06-17 |
WO2013050367A3 (de) | 2013-10-03 |
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Legal Events
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C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20140806 |