CN103968244B - Hydrogen-storing device prepared by a kind of Agcdo composite - Google Patents
Hydrogen-storing device prepared by a kind of Agcdo composite Download PDFInfo
- Publication number
- CN103968244B CN103968244B CN201410134566.3A CN201410134566A CN103968244B CN 103968244 B CN103968244 B CN 103968244B CN 201410134566 A CN201410134566 A CN 201410134566A CN 103968244 B CN103968244 B CN 103968244B
- Authority
- CN
- China
- Prior art keywords
- hydrogen
- hydrogen storage
- storing device
- storage bottle
- solid state
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/32—Hydrogen storage
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P90/00—Enabling technologies with a potential contribution to greenhouse gas [GHG] emissions mitigation
- Y02P90/45—Hydrogen technologies in production processes
Abstract
Hydrogen-storing device prepared by a kind of Agcdo composite.A kind of solid state hydrogen TRT, including hydrogen-storing device, hydrogen feeding mechanism, generating battery device etc..Described hydrogen-storing device, including hydrogen storage bottle, hydrogen storage bottle is contained within hydrogen storage granule, and the average diameter of this hydrogen storage granule is 20 microns to 200 microns, has by the internal cavities of porous wall cincture；One end of hydrogen storage bottle is provided with pore, in pore, is provided with filter；The housing of described hydrogen storage bottle includes inner bag and the fibre reinforced layer prepared by silver cadmium oxide material.
Description
Technical field
The present invention relates to a kind of novel energy, especially a kind of solid state hydrogen battery, be specifically related to hydrogen-storing device.
Background technology
The power of automobile commonly uses fuel oil at present, and owing to petroleum resources are limited, people have to seek new alternative energy source, such as electric energy, solar energy etc..As the substitute of vehicle fuel, including known liquefied petroleum gas and liquefied natural gas.The harmful gas using the motor vehicle emission of these substitutes is relatively fewer, but the problem still failing to fundamentally solve the energy and pollution.
Hydrogen increasingly comes into one's own as the application of fuel, and the hydrogen of gaseous state is very easy to blast.In hydrogen powered vehicle field, hydrogen can be stored in the on-board high-voltage container of the vehicles.Such storage system is inefficient in volume level, and due to storage hypertonia, such as 5,000-10,000psi(about 350-700 Bar) air pressure, thus there is potential safety hazard.
Summary of the invention
In order to realize object above, the present invention proposes a kind of solid state hydrogen TRT, using solid state hydrogen as the energy, solid state hydrogen is converted into electric energy, does work with electrical energy drive motor.This solid state hydrogen TRT passes through supporting relevant auxiliary device, such as hydrogen-storing device, hydrogen feeding mechanism, generating battery device etc., it is achieved save fuel oil and the purpose of fall low exhaust gas emission.
Described hydrogen-storing device includes that hydrogen storage bottle, hydrogen storage bottle are contained within hydrogen storage granule, and the hydrogen after activation can be stored by this hydrogen storage granule in solid form, and disengages the hydrogen of storage when heat absorption.Described hydrogen storage granule has by the internal cavities of porous wall cincture.One end of hydrogen storage bottle is provided with pore, is provided with filter in pore.Filter is made by metal powder sintered molding or by the micro-close net of rustless steel, and hydrogen circulation can be allowed to filter in other gas of prevention and impurity entrance hydrogen storage bottle.When hydrogen being injected hydrogen storage bottle, hydrogen enters inside hydrogen storage bottle through filter, the hydrogen storage granule that now hydrogen storage bottle is contained within absorbs rapidly hydrogen, after overactivation, a large amount of hydrogen molecules are changed into solid state hydrogen and is stored in inside hydrogen storage bottle, make hydrogen no longer store with the form of high-pressure gaseous, thus reach safety in transportation and storage purpose.
The solid state hydrogen that hydrogen storage granule stores can be disengaged with Gaseous Hydrogen molecular path by described hydrogen feeding mechanism by the airway at hydrogen storage bottle pore, sends into generating battery device.
Described generating battery device is similar with general battery structure, and the material simply used is different.This device overlaps to form generating battery device with Porous hydrogen fuel pole (anode) and air pole (negative electrode) and polymer dielectric film.At anode, hydrogen is decomposed into hydrion (proton) and electronics, and polymer dielectric film only allows proton to pass and the negative electrode that arrives, and electronics moves on to negative electrode along external circuit, carries out chemical reaction at negative electrode and oxygen and becomes water (H2O).Electric energy is obtained in electronics moving process.
Hydrogen storage technology and TRT that the present invention provides efficiently solve the series of problems existing for gaseous state storing mode, have replenished the blank of this technical field, have had novelty.This hydrogen storage technology and TRT can be used for the various vehicles, the feature such as, transitory efficient safe and reliable with it, economic convenient, environmental protection and energy saving, have vast potential for future development.Use solid state hydrogen can solve, as the energy, the environmental pollution that oil discharge waste gas causes, and use solid state hydrogen can reduce cost as the energy.
Hydrogen storage bottle described in above-mentioned hydrogen-storing device is contained within hydrogen storage granule, and the average diameter of this hydrogen storage granule is 20 microns to 200 microns, has by the internal cavities of porous wall cincture.One end of hydrogen storage bottle is provided with pore, in pore, is provided with filter.The housing of described hydrogen storage bottle includes inner bag and the fibre reinforced layer prepared by silver cadmium oxide material, the wall thickness 1-10 millimeter of described inner bag, preferably 7-9 millimeter.
Further, the average diameter of described hydrogen storage granule is 50 microns to 80 microns.
Further, described hydrogen storage granule is CNT, nano-glass ball, nano ceramics.The mixture of nano zeolite, nanofiber or these materials.
Further, described hydrogen storage granule has the wall thickness of 1 to 30 micron, the wall thickness of preferably 1 to 10 micron.
Further, the wall of described hydrogen storage granule is porous wall, and the aperture in described porous wall is 50 angstroms-1000 angstroms, and the preferably aperture in porous wall is 200 angstroms-500 angstroms.
Further, described filter is made up of metal powder sintered molding, or is made up of the micro-close net of rustless steel, and containing Metal Palladium.
Further, the thickness of described fibre reinforced layer is 0.5-5mm.
Accompanying drawing explanation
Fig. 1 is solid state hydrogen TRT schematic diagram of the present invention.
1 hydrogen storage bottle in figure, 2 oxygen-storage devices, 3 generating battery devices, 12 hydrogen storage bottle pores, 13 filters, 22 oxygen-storage device pores, the electric energy delivery outlet of 31 generating battery devices.
Detailed description of the invention
Below in conjunction with the accompanying drawings, the present invention is described in more detail.
Fig. 1 show solid state hydrogen TRT schematic diagram of the present invention.This device includes hydrogen storage bottle 1, oxygen-storage device 2 and generating battery device 3.Hydrogen storage bottle 1 and oxygen-storage device 2 are connected with generating battery device 3 by hydrogen storage bottle pore 12 and oxygen-storage device pore 22 respectively, arrange filter 13 in hydrogen storage bottle pore 12, and the electric energy delivery outlet 31 of generating battery device is connected with motor.
Described hydrogen storage bottle 1 is contained within hydrogen storage granule, and hydrogen storage bottle 1 pore 12 is connected with generating battery device 3.
Described oxygen-storage device 2 internal reservoir oxygen, oxygen-storage device 2 pore 22 is connected with generating battery device 3.
Described generating battery device 3 is built up generating battery device with Porous hydrogen fuel pole (anode) and air pole (negative electrode) and polymer dielectric film, and electric energy is connected with motor by electric energy delivery outlet 31.
The average diameter of described hydrogen storage granule is 20 microns to 200 microns, preferably 50 microns to 80 microns.
Described hydrogen storage granule can be CNT, nano-glass ball, nano ceramics.The mixture of nano zeolite, nanofiber or these materials.This hydrogen storage granule has 1 to 30 micron, the wall thickness of preferably 1 to 10 micron.
The wall of described hydrogen storage granule is porous wall, and the aperture in described porous wall is 50 angstroms-1000 angstroms, preferably 200 angstroms-500 angstroms.
Described filter 13 is made up of metal powder sintered molding or is made up of the micro-close net of rustless steel, and described filter contains Metal Palladium.
The housing of described hydrogen storage bottle includes inner bag and the fibre reinforced layer prepared by silver cadmium oxide material, the wall thickness 1-10 millimeter of described inner bag, preferably 7-9 millimeter.
Hydrogen can be reduced cost as the energy by solid state hydrogen TRT of the present invention, solves the environmental pollution that oil discharge waste gas causes.Described hydrogen-storing device can reach safety in transportation and storage purpose, for using hydrogen energy source to provide technical guarantee.
Embodiment 1
The silver cadmium oxide material containing following wt% chemical element is used to prepare the hydrogen storage bottle inner bag of solid state hydrogen hydrogen-storing device of the present invention, silver 85, cadmium 13, nickel 0.5, stannum 1, lanthanum 0.5.The wall thickness of hydrogen storage bottle inner bag is 9 millimeters.Carbon fibre reinforcement is attached on inner bag solidify to form the housing of hydrogen storage bottle, and described fibre reinforced layer thickness is 0.5mm.
Embodiment 2
Repeating the operation of embodiment 1, simply the wt% of chemical element is revised as silver 97, cadmium 2, nickel 0.25, stannum 0.25.The wall thickness of hydrogen storage bottle inner bag is 7mm.Described fibre reinforced layer thickness is 2.5mm.
Embodiment 3
Repeating the operation of embodiment 1, simply the wt% of some chemical element is revised as silver 90, cadmium 8, cerium 0.5.The wall thickness of hydrogen storage bottle inner bag is revised as 1mm.Described fibre reinforced layer thickness is 5mm.
Claims (5)
1. a hydrogen-storing device for solid state hydrogen, including hydrogen storage bottle, hydrogen storage bottle is contained within hydrogen storage granule, this hydrogen storage granule average straight
Footpath is 50 microns to 80 microns, has by the internal cavities of porous wall cincture, and the aperture in described porous wall is 200 angstrom-500
Angstrom；Described hydrogen storage granule has the wall thickness of 1 to 30 micron;One end of hydrogen storage bottle is provided with pore, in pore, is provided with filtration
Device, described filter is made up of the micro-close net of rustless steel；The housing of described hydrogen storage bottle includes the inner bag prepared by silver cadmium oxide material
With fibre reinforced layer, the wall thickness 1-10 millimeter of described inner bag.
The hydrogen-storing device of solid state hydrogen the most according to claim 1, it is characterised in that described hydrogen storage granule is CNT, receives
Rice glass bead, nano ceramics, nano zeolite, nanofiber or the mixture of these materials.
The hydrogen-storing device of solid state hydrogen the most according to claim 1 or claim 2, it is characterised in that described filter is burnt by metal dust
Form type to make.
The hydrogen-storing device of solid state hydrogen the most according to claim 1 or claim 2, it is characterised in that the thickness of described fibre reinforced layer
For 0.5-5mm.
The hydrogen-storing device of solid state hydrogen the most according to claim 1 or claim 2, it is characterised in that the wall thickness 7-9 millimeter of described inner bag.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410134566.3A CN103968244B (en) | 2014-04-03 | 2014-04-03 | Hydrogen-storing device prepared by a kind of Agcdo composite |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410134566.3A CN103968244B (en) | 2014-04-03 | 2014-04-03 | Hydrogen-storing device prepared by a kind of Agcdo composite |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103968244A CN103968244A (en) | 2014-08-06 |
| CN103968244B true CN103968244B (en) | 2016-09-14 |
Family
ID=51238080
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410134566.3A Active CN103968244B (en) | 2014-04-03 | 2014-04-03 | Hydrogen-storing device prepared by a kind of Agcdo composite |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103968244B (en) |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4225051A (en) * | 1977-04-15 | 1980-09-30 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Containers for storing fluids under pressure |
| CN1752506A (en) * | 2005-09-30 | 2006-03-29 | 天津海蓝德能源技术发展有限公司 | Method hydride hydrogen-storing cylinder and preparing method thereof |
| CN101680601A (en) * | 2007-06-06 | 2010-03-24 | 株式会社丰田自动织机 | Hydrogen storage tank |
| CN201487536U (en) * | 2009-05-19 | 2010-05-26 | 无锡尚弗能源科技有限公司 | Metal hydride hydrogen storage device with safeguarding structure |
| CN202048351U (en) * | 2010-12-23 | 2011-11-23 | 广州有色金属研究院 | Solid hydrogen storage device for metal hydride |
| CN102596451A (en) * | 2009-09-04 | 2012-07-18 | 株式会社渥美精机 | Hydrogen storage alloy and hydrogen storage unit using same |
| CN203500844U (en) * | 2013-04-03 | 2014-03-26 | 北京浩运金能科技有限公司 | Metal hydride hydrogen storage device capable of quickly absorbing and desorbing hydrogen |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7666807B2 (en) * | 2004-09-21 | 2010-02-23 | Savannah River Nuclear Solutions, Llc | Hollow porous-wall glass microspheres for hydrogen storage |
| CN100436928C (en) * | 2006-11-06 | 2008-11-26 | 哈尔滨工业大学 | High pressure nitrogen storage bottle made of kevlar fiber and carbon fiber mixed composite material and its preparation method |
| CN100430640C (en) * | 2006-11-06 | 2008-11-05 | 哈尔滨工业大学 | High pressure nitrogen storage bottle made of PBO fiber and carbon fiber composite material and its preparation method |
| US8628609B2 (en) * | 2008-03-03 | 2014-01-14 | Fredy Ornath | Hydrogen storage tank |
| CN101777438B (en) * | 2010-01-26 | 2014-08-13 | 上海中希合金有限公司 | High-performance silver cadmium oxide material and manufacturing method thereof |
| CN202807518U (en) * | 2012-09-07 | 2013-03-20 | 上海华篷防爆科技有限公司 | Fiber reinforced container |
-
2014
- 2014-04-03 CN CN201410134566.3A patent/CN103968244B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4225051A (en) * | 1977-04-15 | 1980-09-30 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Containers for storing fluids under pressure |
| CN1752506A (en) * | 2005-09-30 | 2006-03-29 | 天津海蓝德能源技术发展有限公司 | Method hydride hydrogen-storing cylinder and preparing method thereof |
| CN101680601A (en) * | 2007-06-06 | 2010-03-24 | 株式会社丰田自动织机 | Hydrogen storage tank |
| CN201487536U (en) * | 2009-05-19 | 2010-05-26 | 无锡尚弗能源科技有限公司 | Metal hydride hydrogen storage device with safeguarding structure |
| CN102596451A (en) * | 2009-09-04 | 2012-07-18 | 株式会社渥美精机 | Hydrogen storage alloy and hydrogen storage unit using same |
| CN202048351U (en) * | 2010-12-23 | 2011-11-23 | 广州有色金属研究院 | Solid hydrogen storage device for metal hydride |
| CN203500844U (en) * | 2013-04-03 | 2014-03-26 | 北京浩运金能科技有限公司 | Metal hydride hydrogen storage device capable of quickly absorbing and desorbing hydrogen |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103968244A (en) | 2014-08-06 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103968244B (en) | Hydrogen-storing device prepared by a kind of Agcdo composite | |
| CN103972583B (en) | Solid state hydrogen energy source device with polymer dielectric film | |
| CN103972571A (en) | Solid hydrogen power generation device containing polymer electrolyte membrane | |
| CN103972546B (en) | TRT with rustless steel hydrogen storage bottle | |
| CN103968231A (en) | Hydrogen storage device made of iron-based porous metal material | |
| CN103972548B (en) | TRT with nonmetallic materials hydrogen storage bottle | |
| CN103972572B (en) | With the Blast Furnace Top Gas Recovery Turbine Unit (TRT) of Agcdo composite material storage hydrogen bottle | |
| CN204201458U (en) | A kind of hydrogen-storing device comprising Agcdo composite material | |
| CN103972543B (en) | With the Blast Furnace Top Gas Recovery Turbine Unit (TRT) of Agcdo storage hydrogen bottle | |
| CN204204967U (en) | A kind of hydrogen-storing device comprising stainless steel composite material storage hydrogen bottle | |
| CN103972542B (en) | With the solid state hydrogen Blast Furnace Top Gas Recovery Turbine Unit (TRT) of polymer dielectric film | |
| CN204204959U (en) | A kind of hydrogen-storing device comprising composite material storage hydrogen bottle | |
| CN204204963U (en) | A kind of hydrogen-storing device comprising Ti-Ni alloy composite material storage hydrogen bottle | |
| CN204204960U (en) | A kind of hydrogen-storing device comprising ferrous alloy composite material storage hydrogen bottle | |
| CN204204961U (en) | A kind of hydrogen-storing device containing composite material storage hydrogen bottle | |
| CN204201472U (en) | A kind of hydrogen-storing device comprising nonmetallic material storage hydrogen bottle | |
| CN204201459U (en) | A kind of hydrogen-storing device with composite material storage hydrogen bottle | |
| CN103972531A (en) | Hydrogen storage device prepared by silver cadmium oxide material | |
| CN103972565A (en) | Power generation device provided with hydrogen storage bottle made of stainless steel composite material | |
| CN103968243A (en) | Hydrogen storage device made of iron-based porous metal composite material | |
| CN103972561A (en) | Hydrogen storage device made of stainless steel composite material | |
| CN103972554A (en) | Hydrogen storage device made of Ti-Ni alloy composite material | |
| CN103972533A (en) | Solid-state hydrogen energyresource device containing polymerelectrolyte membrane | |
| CN103972553A (en) | Hydrogen storage device made of iron-base alloy composite material | |
| CN103972532A (en) | Solid-state hydrogen energy device provided with polymer electrolyte membrane |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Hydrogen storage device prepared by silver cadmium oxide composite material Effective date of registration: 20180508 Granted publication date: 20160914 Pledgee: CITIC Bank Tangshan branch Pledgor: Shanghai Huapeng Explosion-Proof Technology Co., Ltd. Registration number: 2018110000006 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right |