CN103952532B - Utilize the method that alkali soaks, v-ti magnetite concentrate is selected in classification again - Google Patents
Utilize the method that alkali soaks, v-ti magnetite concentrate is selected in classification again Download PDFInfo
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Abstract
The present invention discloses and a kind ofly utilizes that alkali soaks, the method for v-ti magnetite concentrate is selected in classification again, comprise the steps: v-ti magnetite concentrate to be placed in the alkaline solution that mass concentration is 5 ~ 52%, at 280 ~ 370 DEG C, alkali leaching reaction 0.5 ~ 5 hour, filters, obtains filtrate and alkali leaching cake A; The ore pulp that is mixed with mass concentration 20% ~ 25% of being added water by A feeds swirler and carries out classification, and obtaining TFe content is respectively 60 ~ 68% iron ore concentrates and TiO
2content is 35 ~ 50% ilmenite concentrates.Advantage of the present invention is: achieve and efficiently sort v-ti magnetite concentrate, and alkaline consumption is low, reduces and enters the foreign matter contents such as blast furnace Al and Si, especially minimizing detrimental impurity TiO
2, S content, improve the capacity factor of a blast furnace, reduce the quantity discharged of blast furnace slag, reduce ironmaking cost, solve smelting process S content high, with serious pollution problem; Improve titanium resource comprehensive utilization ratio simultaneously.
Description
Technical field
The present invention relates to a kind of ore-dressing technique of v-ti magnetite concentrate, particularly relate to and a kind ofly utilize that alkali soaks, the method for v-ti magnetite concentrate is selected in classification again.
Background technology
Vanadium titano-magnetite is a kind of complex ore of multiple metallic element, is based on the magnetite of the symbiosis of iron content, vanadium, titanium.And one of v-ti magnetite concentrate product that to be vanadium titano-magnetite obtain through ore dressing, wherein vanadium is composed with isomorph and is stored in titanomagnetite, displacement ferric ion.Titanomagnetite is oikocryst mineral (Fe
3o
4) and chadacryst ore deposit [ulvite 2FeOTiO
2, ilmenite FeOTiO
2, aluminum-spinel (Mg, Fe) (Al, Fe)
2o
4] complex body that formed.Such as, Chinese Panzhihua Region Midi Concentrator v-ti magnetite green ore and the chemistry of the v-ti magnetite concentrate after selecting iron multielement analysis the results are shown in Table 1, and v-ti magnetite green ore and vanadium titano-magnetite concentrate material phase analysis result are respectively in table 2 and table 3.
Table 1 Chinese Panzhihua Region Midi Concentrator raw ore and v-ti magnetite concentrate chemistry multielement analysis result
| Element | TFe | FeO | mFe | S | Fe 2O 3 | TiO 2 | V 2O 5 |
| Raw ore | 29.53 | 21.36 | 20.20 | 0.631 | 17.70 | 10.54 | 0.278 |
| Concentrate | 54.01 | 32.42 | 51.16 | 0.574 | 40.97 | 12.67 | 0.61 |
| Element | SiO 2 | Al 2O 3 | CaO | MgO | Co | P | As |
| Raw ore | 22.80 | 7.65 | 6.36 | 7.23 | 0.02 | 0.015 | <0.01 |
| Concentrate | 3.21 | 3.30 | 0.98 | 2.90 | 0.02 | 0.008 | <0.010 |
Table 2 Chinese Panzhihua Region Midi Concentrator v-ti magnetite green ore titanium, iron chemical phase analysis result
Table 3 Chinese Panzhihua Region Midi Concentrator vanadium titano-magnetite concentrate titanium, iron chemical phase analysis result
Vanadium titano-magnetite aboundresources in the world, whole world reserves reach more than 40,000,000,000 tons, and reserves in China reaches 98.3 hundred million tons.In v-ti magnetite ore, iron is mainly composed and is stored in titanomagnetite, the TiO in ore
2main tax is stored in granular ilmenite and titanomagnetite.Generally, the titanium of about 57% is composed and is stored in titanomagnetite (mFeTiO
3nFe
3o
4) in, the titanium of about 40% is composed and is stored in ilmenite (FeTiO
3) in, because vanadium titano-magnetite ore composition is complicated, character is special, and thus the comprehensive utilization of this kind of ore is the international a great problem always thoroughly do not solved.This occurrence characteristics of vanadium titano-magnetite mineral determines the effective separation adopting physical concentration method cannot realize titanium, iron from the source of ore, cause v-ti magnetite ore after physical concentration, iron concentrate grade low (TFe<55%), the titanium in iron ore concentrate enters blast furnace slag (TiO completely at iron manufacturing process
2content reaches more than 22%) form vitreum, TiO
2lose activity and cannot economic recovery, meanwhile, titanium recovery rate is low only has 18%.Therefore sort titanium iron ore by the beneficiation method of physics and greatly reduce the value that titanium and iron utilizes separately.
China is first country comprehensively extracting iron, vanadium, titanium with technical scale from complicated vanadium titano-magnetite in the world, but due to general physical method fundamentally can not change iron, the tax of the fine and close symbiosis of titanium deposits characteristic, therefore, adopt the physical concentration methods such as common gravity separation method, magnetic method, flotation process to carry out titanium, iron is separated, efficiency is low, is difficult to select of high grade and the ilmenite concentrate that impurity is few or iron ore concentrate; Meanwhile, TiO
2organic efficiency is not high, v-ti magnetite green ore after Mineral separation, the TiO of about 54%
2enter iron ore concentrate, these TiO
2after blast-furnace smelting, almost all enter slag phase, form TiO
2the blast furnace slag of content 20 ~ 24%; In addition, because the foreign matter contents such as S, Si, the Al in iron ore concentrate are also too high, above-mentioned reason not only causes that steelmaking furnace utilization coefficient is low, energy consumption is large, titanium resource waste, and amount of slag is large, environmental pollution is serious.
CN2011100879566 discloses " a kind of beneficiation method of ilmenite ", is the magnetic separation after ore grinding, alkaline pretreatment, filtration, again ore grinding of v-ti magnetite green ore is obtained the method for ilmenite concentrate and iron ore concentrate.The method is by iron content 32.16% with containing TiO
2the v-ti magnetite green ore of 12.11%, by magnetic separation process after ore grinding, alkaline pretreatment, filtration, again ore grinding, defines iron content 59.30% iron ore concentrate and contains TiO
2the ilmenite concentrate of 20.15%.Because the method is for ilmenite raw ore, raw ore SiO
2, Al
2o
3, the gangue mineral content such as CaO, MgO is high, the process of alkali leaching preferentially will occur in SiO
2, Al
2o
3with it mineral, define the alkali leaching rear compound similar to titanium in the dipped journey of alkali, the NaOH alkali number of alkali leaching ferrotianium raw ore consumption is 469Kg/t raw ore, and cost is high; And the titanium compound formed after the leaching of ferrotianium raw ore alkali, the compound of the silicon formed after soaking with the gangue mineral alkali such as quartz, it is very difficult for wanting to realize effectively being separated in follow-up magnetic separation, and this also constrains the raising of the rear iron concentrate grade of ferrotianium raw ore alkali leaching and ilmenite concentrate grade.Meanwhile, the method adopts twice grinding process to change mineral surface physicochemical property, adds complexity and the process cost of the method.In a word, by this kind of procedure complexity, and in treating processes, quantity of alkali consumption is large, cost is high; Meanwhile, more high-grade iron ore concentrate and ilmenite concentrate cannot be obtained.
CN201310183580.8 discloses " a kind of wet processing sefstromite concentrate prepares the method for titanium liquid ", proposes the method with salt pickling separating titanium iron.This invention is the method that wet processing v-ti magnetite concentrate prepares titanium liquid, comprise v-ti magnetite concentrate hydrochloric acid leaching, molten salt react ion, again pickling, sulfuric acid solution, filtration etc. and obtain the processes such as titanium liquid, the method is mainly for extraction ilmenite concentrate, its complex technical process, need in hydrochloric acid leaching process to react with hydrochloric acid and iron and vanadium to dissolve in filtrate, consume a large amount of hydrochloric acid, cost is high; Meanwhile, NaOH and titanium and pasc reaction is used to consume alkali in fused salt process.In addition, owing to employing hydrochloric acid in the method leaching process, in hydrochloric acid, chlorion is large to equipment corrosion, not easily suitability for industrialized production.The method is mainly applicable to the recycling of titanium in the low poor v-ti magnetite concentrate of high vanadium low iron content.
Summary of the invention
In order to overcome the deficiency of above-mentioned beneficiation method, technical problem to be solved by this invention is on the basis that physics and chemistry beneficiation method effectively combines, there is provided a kind of cost low, reclaim quality and efficiency is high, technique is simple, and good operability utilize that alkali soaks, the method for v-ti magnetite concentrate is selected in classification again, achieve and high efficiency separation is carried out to titanium, iron in v-ti magnetite concentrate, improve into stokehold Iron grade, reduce and enter blast furnace TiO
2, the impurity such as S, Si, Al content, improve the capacity factor of a blast furnace, reduce the quantity discharged of blast furnace slag, reduce ironmaking cost, improve TiO simultaneously
2comprehensive resource utilization rate, reduces environmental pollution.
In order to realize object of the present invention, technical scheme of the present invention is achieved in that
Of the present inventionly utilize that alkali soaks, the method for v-ti magnetite concentrate is selected in classification again, it is characterized in that comprising the steps:
1) alkali leaching
Be 50% ~ 55%, TiO by TFe content range
2content range is 10% ~ 15%, SiO
2content is 3% ~ 6%, Al
2o
3content is 3% ~ 6%, the v-ti magnetite concentrate of S content >0.5%, be placed in the alkaline solution that mass concentration is 5% ~ 52%, alkali leaching reaction 0.5 ~ 5 hour at the temperature of 280 DEG C ~ 370 DEG C, reactant is filtered, obtain filtrate and alkali leaching cake A, described filtrate feeds recovery and processing system;
2) classification
By step 1) in alkali leaching cake A add water, the ore pulp forming mass concentration 20% ~ 25% feeds swirler and carries out classification, classification goes out sand setting B and overflow C, described sand setting B to be TFe content range be 60% ~ 68% final iron ore concentrate, described overflow C simmer down to TiO
2content range is the ilmenite concentrate of 35% ~ 50%.
Described alkaline solution is any one in NaOH or the KOH aqueous solution, NaOH and KOH mixed aqueous solution.
Advantage of the present invention is:
Method synthesis of the present invention uses the method process v-ti magnetite concentrate of alkali leaching, classification, achieves titanium in v-ti magnetite concentrate, iron high efficiency separation; In isolated iron ore concentrate, S content significantly reduces simultaneously, is down to is less than 0.10%, SiO by more than 0.50%
2content is down to less than 3%, Al by 3% ~ 6%
2o
3content is down to less than 3% by 3% ~ 6%, for subsequent smelting creates better condition.
The process of alkali leaching has carried out chemical reaction to elements such as Ti, S, Si, Al in v-ti magnetite concentrate, defines corresponding salt.With v-ti magnetite concentrate unlike, SiO in ilmenite raw ore
2content (>20%) and Al
2o
3content (>7%) is far away higher than SiO in v-ti magnetite concentrate
2content (6%) and Al
2o
3content (<6%), in alkali leaching ilmenite raw ore process, because the process of alkali leaching preferentially will occur in SiO
2, Al
2o
3deng on mineral, alkali is made to soak v-ti magnetite concentrate more less than alkali leaching ferrotianium raw ore alkali consumption, better effects if.Such as, when soaking with NaOH alkali, the alkali number that the present invention consumes is less than 100kg/t concentrate, reduces more than 4.6 times than the alkali number 469kg/t raw ore of alkali leaching raw ore consumption.
Swirler presses granularity and the gravity grading of mineral, and the titanium compound generated after alkali leaching is than the fine size of iron mineral, and proportion is little, and the difference of specific gravity of titanium, iron is comparatively large, achieves effective separation of titanium, iron.Add that classification makes iron concentrate grade bring up to 60% ~ 68% by 50% ~ 55%, be less than 0.1%, SiO containing S amount in iron ore concentrate simultaneously
2and Al
2o
3content is all less than 3%, TiO
2content is down to less than 6% by 12.91%; Meanwhile, TiO can also be obtained
2content is the ilmenite concentrate of 35% ~ 50%.Employing the method achieves and is effectively separated titanium, iron, reduces and enters blast furnace TiO
2, the impurity such as S, Si, Al content, improve the capacity factor of a blast furnace, reduce the quantity discharged of blast furnace slag, reduce ironmaking cost, improve titanium resource comprehensive utilization ratio simultaneously.
Accompanying drawing explanation
Fig. 1 is present invention process schema.
Embodiment
Below in conjunction with accompanying drawing, the specific embodiment of the present invention is described further:
As shown in Figure 1.
Embodiment 1:
1) alkali leaching
Be 50.9%, TiO by TFe content
2content is 14.5%, SiO
2content is 3.62%, Al
2o
3content is 4.40%, the v-ti magnetite concentrate of S content 0.58%, be placed in the NaOH alkaline solution that mass concentration is 20%, alkali leaching reaction 4.0 hours at the temperature of 280 DEG C, reactant is filtered, obtain filtrate and alkali leaching cake A, NaOH consumption 79kg/t is to ore deposit, and described filtrate feeds recovery and processing system, and its chemical equation is:
2) classification
By step 1) in alkali leaching cake A add water, form the ore pulp of mass concentration 20% and feed swirler and carry out classification, classification goes out sand setting B and overflow C, and sand setting B is the final iron ore concentrate (SiO of TFe content 60.2%
2content is 0.80%, Al
2o
3content is 1.90%, S content is 0.02%), overflow C simmer down to TiO
2content is the final ilmenite concentrate of 40.1%.
Embodiment 2:
1) alkali leaching
Be 53.5%, TiO by TFe content
2content is 11.3%, SiO
2content is 3.56%, Al
2o
3content is 5.50%, the v-ti magnetite concentrate of S content 0.72%, be placed in the NaOH alkaline solution that mass concentration is 8%, alkali leaching reaction 3.5 hours at the temperature of 310 DEG C, reactant is filtered, obtain filtrate and alkali leaching cake A, NaOH consumption 75kg/t is to ore deposit, and described filtrate feeds recovery and processing system, and its chemical equation is with embodiment 1.
2) classification
By step 1) in alkali leaching cake A add water, form the ore pulp of mass concentration 21% and feed swirler and carry out classification, classification goes out sand setting B and overflow C, and sand setting B is the final iron ore concentrate (SiO of TFe content 63.1%
2content is 0.53%, Al
2o
3content is 1.86%, S content is 0.01%), overflow C simmer down to TiO
2content is the final ilmenite concentrate of 36.2%.
Embodiment 3:
1) alkali leaching
Be 52.5%, TiO by TFe content
2content is 12.3%, SiO
2content is 3.95%, Al
2o
3content is 5.48%, the v-ti magnetite concentrate of S content 0.69%, is placed in the N that mass concentration is 30%
ain OH alkaline solution, alkali leaching reaction 2.5 hours at the temperature of 300 DEG C, filtered by reactant, obtain filtrate and alkali leaching cake A, NaOH consumption 80kg/t is to ore deposit, and described filtrate feeds recovery and processing system, and its chemical equation is with embodiment 1.
2) classification
By step 1) in alkali leaching cake A add water, form the ore pulp of mass concentration 22% and feed swirler and carry out classification, classification goes out sand setting B and overflow C, and sand setting B is the final iron ore concentrate (SiO of TFe content 64.5%
2content is 0.52%, Al
2o
3content is 1.84%, S content is 0.01%), overflow C simmer down to TiO
2content is the final ilmenite concentrate of 35.5%.
Embodiment 4:
1) alkali leaching
Be 54.3%, TiO by TFe content
2content is 10.5%, SiO
2content is 3.60%, Al
2o
3content is 5.40%, the v-ti magnetite concentrate of S content 0.70%, be placed in the NaOH alkaline solution that mass concentration is 48%, alkali leaching reaction 1.5 hours at the temperature of 370 DEG C, reactant is filtered, obtain filtrate and alkali leaching cake A, NaOH consumption 75kg/t is to ore deposit, and described filtrate feeds recovery and processing system, and its chemical equation is with embodiment 1.
2) classification
By step 1) in alkali leaching cake A add water, form the ore pulp of mass concentration 23% and feed swirler and carry out classification, classification goes out sand setting B and overflow C, and sand setting B is the final iron ore concentrate (SiO of TFe content 67.8%
2content is 0.48%, Al
2o
3content is 1.36%, S content is 0.01%), overflow C simmer down to TiO
2content is the final ilmenite concentrate of 45.2%.
Embodiment 5:
1) alkali leaching
Be 53.2%, TiO by TFe content
2content is 12.1%, SiO
2content is 3.90%, Al
2o
3content is 4.71%, the v-ti magnetite concentrate of S content 0.68%, be placed in the KOH alkaline solution that mass concentration is 15%, alkali leaching reaction 2.0 hours at the temperature of 290 DEG C, reactant is filtered, obtain filtrate and alkali leaching cake A, KOH consumption 75kg/t is to ore deposit, and described filtrate feeds recovery and processing system, and its chemical equation is:
2) classification
By step 1) in alkali leaching cake A add water, form the ore pulp of mass concentration 24% and feed swirler and carry out classification, classification goes out sand setting B and overflow C, and sand setting B is the final iron ore concentrate (SiO of TFe content 65.1%
2content is 0.43%, Al
2o
3content is 1.66%, S content is 0.01%), overflow C simmer down to TiO
2content is the final ilmenite concentrate of 47.3%.
Embodiment 6:
1) alkali leaching
Be 53.8%, TiO by TFe content
2content is 11.5%, SiO
2content is 3.85%, Al
2o
3content is 4.72%, the v-ti magnetite concentrate of S content 0.59%, be placed in the KOH alkaline solution that mass concentration is 25%, alkali leaching reaction 4.5 hours at the temperature of 300 DEG C, reactant is filtered, obtain filtrate and alkali leaching cake A, KOH consumption 95kg/t is to ore deposit, and described filtrate feeds recovery and processing system, and its chemical equation is with embodiment 5.
2) classification
By step 1) in alkali leaching cake A add water, form the ore pulp of mass concentration 25% and feed swirler and carry out classification, classification goes out sand setting B and overflow C, and sand setting B is the final iron ore concentrate (SiO of TFe content 66.7%
2content is 0.33%, Al
2o
3content is 1.42%, S content is 0.01%), overflow C simmer down to TiO
2content is the final ilmenite concentrate of 49.2%.
Embodiment 7:
1) alkali leaching
Be 53.4%, TiO by TFe content
2content is 11.7%, SiO
2content is 3.82%, Al
2o
3content is 4.70%, the v-ti magnetite concentrate of S content 0.60%, be placed in that NaOH mass concentration is 20%, KOH mass concentration is the alkaline solution of 5%, alkali leaching reaction 5.0 hours at the temperature of 295 DEG C, reactant is filtered, filtrate and alkali leaching cake A, NaOH consumption 40kg/t to ore deposit, KOH consumption 50kg/t is to ore deposit, described filtrate feeds recovery and processing system, embodiment 1 and embodiment 5.
2) classification
By step 1) in alkali leaching cake A add water, form the ore pulp of mass concentration 25% and feed swirler and carry out classification, classification goes out sand setting B and overflow C, and sand setting B is the final iron ore concentrate (SiO of TFe content 66.4%
2content is 0.35%, Al
2o
3content is 1.42%, S content is 0.01%), overflow C simmer down to TiO
2content is the final ilmenite concentrate of 49.5%.
Claims (1)
1. utilize the method that alkali soaks, v-ti magnetite concentrate is selected in classification again, it is characterized in that comprising the steps:
1) alkali leaching
Be 50% ~ 55%, TiO by TFe content range
2content range is 10% ~ 15%, SiO
2content is 3% ~ 6%, Al
2o
3content is 3% ~ 6%, the v-ti magnetite concentrate of S content >0.5%, be placed in mass concentration be 5% ~ 52% NaOH alkaline solution, KOH alkaline solution or NaOH and KOH mixed ammonium/alkali solutions any one, alkali leaching reaction 0.5 ~ 5 hour at the temperature of 280 DEG C ~ 370 DEG C, reactant is filtered, obtain filtrate and alkali leaching cake A, described filtrate feeds recovery and processing system;
2) classification
Added water by alkali leaching cake A in step 1), form the ore pulp of mass concentration 20% ~ 25% and feed swirler and carry out classification, classification goes out sand setting B and overflow C, described sand setting B to be TFe content range be 60% ~ 68% final iron ore concentrate, described overflow C simmer down to TiO
2content range is the ilmenite concentrate of 35% ~ 50%.
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| CN104878221A (en) * | 2015-06-12 | 2015-09-02 | 鞍钢集团矿业公司 | Method for utilizing oxidation alkaline leaching and desliming to re-concentrate vanadium-titanium magnetite concentrates |
| CN104858047A (en) * | 2015-06-12 | 2015-08-26 | 鞍钢集团矿业公司 | Method for recleaning vanadium-titanium magnetite concentrates by oxidation alkaline leaching, grading and magnetic separation |
| CN113318865B (en) * | 2021-05-17 | 2022-08-26 | 宜宾天原海丰和泰有限公司 | Flotation reagent for high-calcium magnesium vanadium titano-magnetite and method for preparing chlorinated titanium-rich material from high-calcium magnesium vanadium titano-magnetite |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102181626A (en) * | 2011-04-08 | 2011-09-14 | 北京矿冶研究总院 | Beneficiation method of ilmenite |
| CN103691550A (en) * | 2013-12-18 | 2014-04-02 | 广西科晟达机械制造有限公司 | Beneficiation method of ilmenite |
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| BR9704435A (en) * | 1997-10-17 | 2000-06-06 | Vale Do Rio Doce Co | Process for the production of titanium concentrate with a chemical composition similar to ilmenite from anatase ores with high content of impurities |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102181626A (en) * | 2011-04-08 | 2011-09-14 | 北京矿冶研究总院 | Beneficiation method of ilmenite |
| CN103691550A (en) * | 2013-12-18 | 2014-04-02 | 广西科晟达机械制造有限公司 | Beneficiation method of ilmenite |
Non-Patent Citations (1)
| Title |
|---|
| 高碱度下钒钛磁铁精矿烧结制度探讨;林千谷等;《四川冶金》;20081231;第30卷(第6期);第1-4页 * |
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Address after: 114001 Anshan District, Liaoning, No. 219 Road, No. 39, Tiedong Patentee after: Anshan Iron and Steel Group Mining Co., Ltd. Address before: 114001 Anshan District, Liaoning, No. 219 Road, No. 39, Tiedong Patentee before: Anshan Iron & Steel Group Mining Co., Ltd. |