CN103952549B - Alkali leaching, pickling and reverse flotation is utilized to select the method for v-ti magnetite concentrate again - Google Patents
Alkali leaching, pickling and reverse flotation is utilized to select the method for v-ti magnetite concentrate again Download PDFInfo
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Abstract
The present invention discloses a kind of method utilizing alkali leaching, pickling and reverse flotation to select v-ti magnetite concentrate again, comprise the steps: v-ti magnetite concentrate to be placed in the alkaline solution that mass concentration is 5 ~ 52%, at 280 ~ 370 DEG C, alkali leaching reaction 0.5 ~ 5 hour, filters, obtains filtrate and alkali leaching cake A; A is added water and is mixed with the ore pulp that solid-liquid mass ratio is 1: 1 ~ 10, then be placed in the H that mass concentration is 1 ~ 10%
2sO
4in solution, pickling 5 ~ 60 minutes at 50 ~ 90 DEG C, filters, obtains filtrate and acidleach filter cake B; The ore pulp making mass concentration 25 ~ 30% that added water by B again carries out reverse flotation, and obtaining TFe content is respectively 65 ~ 69.5% iron ore concentrates and TiO
2content is 40 ~ 80% ilmenite concentrates.Advantage of the present invention is: achieve and efficiently sort v-ti magnetite concentrate, and alkaline consumption is low, reduces and enters impurity, the especially TiO such as blast furnace Al and Si
2, S content, improve the capacity factor of a blast furnace, reduce the quantity discharged of blast furnace slag, reduce ironmaking cost, improve titanium resource comprehensive utilization ratio simultaneously.
Description
Technical field
The present invention relates to a kind of ore-dressing technique of v-ti magnetite concentrate, particularly relate to a kind of method utilizing alkali leaching, pickling and reverse flotation to select v-ti magnetite concentrate again.
Background technology
Vanadium titano-magnetite is a kind of complex ore of multiple metallic element, is based on the magnetite of the symbiosis of iron content, vanadium, titanium.And one of v-ti magnetite concentrate product that to be vanadium titano-magnetite obtain through ore dressing, wherein vanadium is composed with isomorph and is stored in titanomagnetite, displacement ferric ion.Titanomagnetite is oikocryst mineral (Fe
3o
4) and chadacryst ore deposit [ulvite 2FeOTiO
2, ilmenite FeOTiO
2, aluminum-spinel (Mg, Fe) (Al, Fe)
2o
4] complex body that formed.Such as, Chinese Panzhihua Region Midi Concentrator v-ti magnetite green ore and the chemistry of the v-ti magnetite concentrate after selecting iron multielement analysis the results are shown in Table 1, and v-ti magnetite green ore and vanadium titano-magnetite concentrate material phase analysis result are respectively in table 2 and table 3.
Table 1 Chinese Panzhihua Region Midi Concentrator raw ore and v-ti magnetite concentrate chemistry multielement analysis result
| Element | TFe | FeO | mFe | S | Fe 2O 3 | TiO 2 | V 2O 5 |
| Raw ore | 29.53 | 21.36 | 20.20 | 0.631 | 17.70 | 10.54 | 0.278 |
| Concentrate | 54.01 | 32.42 | 51.16 | 0.574 | 40.97 | 12.67 | 0.61 |
| Element | SiO 2 | Al 2O 3 | CaO | MgO | Co | P | As |
| Raw ore | 22.80 | 7.65 | 6.36 | 7.23 | 0.02 | 0.015 | <0.01 |
| Concentrate | 3.21 | 3.30 | 0.98 | 2.90 | 0.02 | 0.008 | <0.010 |
Table 2 Chinese Panzhihua Region Midi Concentrator v-ti magnetite green ore titanium, iron chemical phase analysis result
Table 3 Chinese Panzhihua Region Midi Concentrator vanadium titano-magnetite concentrate titanium, iron chemical phase analysis result
Vanadium titano-magnetite aboundresources in the world, whole world reserves reach more than 40,000,000,000 tons, and reserves in China reaches 98.3 hundred million tons.In v-ti magnetite ore, iron is mainly composed and is stored in titanomagnetite, the TiO in ore
2main tax is stored in granular ilmenite and titanomagnetite.Generally, the titanium of about 57% is composed and is stored in titanomagnetite (mFeTiO
3nFe
3o
4) in, the titanium of about 40% is composed and is stored in ilmenite (FeTiO
3) in, because vanadium titano-magnetite ore composition is complicated, character is special, and thus the comprehensive utilization of this kind of ore is the international a great problem always thoroughly do not solved.This occurrence characteristics of vanadium titano-magnetite mineral determines the effective separation adopting physical concentration method cannot realize titanium, iron from the source of ore, cause v-ti magnetite ore after physical concentration, iron concentrate grade low (TFe<55%), the titanium in iron ore concentrate enters blast furnace slag (TiO completely at iron manufacturing process
2content reaches more than 22%) form vitreum, TiO
2lose activity and cannot economic recovery, meanwhile, titanium recovery rate is low only has 18%.Therefore sort titanium iron ore by the beneficiation method of physics and greatly reduce the value that titanium and iron utilizes separately.
China is first country comprehensively extracting iron, vanadium, titanium with technical scale from complicated vanadium titano-magnetite in the world, but due to general physical method fundamentally can not change iron, the tax of the fine and close symbiosis of titanium deposits characteristic, therefore, adopt the physical concentration methods such as common gravity separation method, magnetic method, flotation process to carry out titanium, iron is separated, efficiency is low, is difficult to select of high grade and the ilmenite concentrate that impurity is few or iron ore concentrate; Meanwhile, TiO
2organic efficiency is not high, v-ti magnetite green ore after Mineral separation, the TiO of about 54%
2enter iron ore concentrate, these TiO
2after blast-furnace smelting, almost all enter slag phase, form TiO
2the blast furnace slag of content 20 ~ 24%; In addition, because the foreign matter contents such as S, Si, the Al in iron ore concentrate are also too high, above-mentioned reason not only causes that steelmaking furnace utilization coefficient is low, energy consumption is large, titanium resource waste, and amount of slag is large, environmental pollution is serious.
CN2011100879566 discloses " a kind of beneficiation method of ilmenite ", is the magnetic separation after ore grinding, alkaline pretreatment, filtration, again ore grinding of v-ti magnetite green ore is obtained the method for ilmenite concentrate and iron ore concentrate.The method is by iron content 32.16% with containing TiO
2the v-ti magnetite green ore of 12.11%, by magnetic separation process after ore grinding, alkaline pretreatment, filtration, again ore grinding, defines iron content 59.30% iron ore concentrate and contains TiO
2the ilmenite concentrate of 20.15%.Because the method is for ilmenite raw ore, raw ore SiO
2, Al
2o
3, the gangue mineral content such as CaO, MgO is high, the process of alkali leaching preferentially will occur in SiO
2, Al
2o
3with it mineral, define the alkali leaching rear compound similar to titanium in the dipped journey of alkali, the NaOH alkali number of alkali leaching ferrotianium raw ore consumption is 469Kg/t raw ore, and cost is high; And the titanium compound formed after the leaching of ferrotianium raw ore alkali, the compound of the silicon formed after soaking with the gangue mineral alkali such as quartz, it is very difficult for wanting to realize effectively being separated in follow-up magnetic separation, and this also constrains the raising of the rear iron concentrate grade of ferrotianium raw ore alkali leaching and ilmenite concentrate grade.Meanwhile, the method adopts twice grinding process to change mineral surface physicochemical property, adds complexity and the process cost of the method.In a word, by this kind of procedure complexity, and in treating processes, quantity of alkali consumption is large, cost is high; Meanwhile, more high-grade iron ore concentrate and ilmenite concentrate cannot be obtained.
CN201310183580.8 discloses " a kind of wet processing sefstromite concentrate prepares the method for titanium liquid ", proposes the method with salt pickling separating titanium iron.This invention is the method that wet processing v-ti magnetite concentrate prepares titanium liquid, comprise v-ti magnetite concentrate hydrochloric acid leaching, molten salt react ion, again pickling, sulfuric acid solution, filtration etc. and obtain the processes such as titanium liquid, the method is mainly for extraction ilmenite concentrate, its complex technical process, need in hydrochloric acid leaching process to react with hydrochloric acid and iron and vanadium to dissolve in filtrate, consume a large amount of hydrochloric acid, cost is high; Meanwhile, NaOH and titanium and pasc reaction is used to consume alkali in fused salt process.In addition, owing to employing hydrochloric acid in the method leaching process, in hydrochloric acid, chlorion is large to equipment corrosion, not easily suitability for industrialized production.The method is mainly applicable to the recycling of titanium in the low poor v-ti magnetite concentrate of high vanadium low iron content.
Summary of the invention
In order to overcome the deficiency of above-mentioned beneficiation method, technical problem to be solved by this invention is on the basis that physics and chemistry beneficiation method effectively combines, there is provided a kind of cost low, reclaim quality and efficiency is high, technique is simple, and good operability utilize alkali leaching, method that pickling, reverse flotation select v-ti magnetite concentrate again, achieve and high efficiency separation is carried out to titanium, iron in v-ti magnetite concentrate, improve into stokehold Iron grade, reduce and enter blast furnace TiO
2, the impurity such as S, Si, Al content, improve the capacity factor of a blast furnace, reduce the quantity discharged of blast furnace slag, reduce ironmaking cost, improve TiO simultaneously
2comprehensive resource utilization rate, reduces environmental pollution.
In order to realize object of the present invention, technical scheme of the present invention is achieved in that
A kind of method utilizing alkali leaching, pickling and reverse flotation to select v-ti magnetite concentrate more of the present invention, is characterized in that comprising the steps:
1) alkali leaching
Be 50% ~ 55%, TiO by TFe content range
2content range is 10% ~ 15%, SiO
2content is 3% ~ 6%, Al
2o
3content is 3% ~ 6%, the v-ti magnetite concentrate of S content >0.5%, be placed in the alkaline solution that mass concentration is 5% ~ 52%, alkali leaching reaction 0.5 ~ 5 hour at the temperature of 280 DEG C ~ 370 DEG C, reactant is filtered, obtain filtrate and alkali leaching cake A, described filtrate feeds recovery and processing system;
2) pickling
By step 1) in alkali leaching cake A add water and make the ore pulp that solid-liquid mass ratio is 1:1 ~ 10, then be placed in the H that mass concentration is 1% ~ 10%
2sO
4in solution, under 50 ~ 90 DEG C of conditions, pickling 5 ~ 60 minutes, filters pickling reactant, and obtain filtrate and acidleach filter cake B, described filtrate feeds recovery and processing system;
3) reverse flotation
With H
2sO
4for activator and the pH value adjusting agent of titanium compound, fatty acid is collecting agent, diesel oil is the reverse flotation work that supplementary catching agent carries out thick, an essence, secondary and scans, in reverse flotation work, one thick pH value controls 5.0 ~ 5.3, one smart pH value controls 4.9 ~ 5.2, and once purging selection, secondary scan equal control ph 4.5 ~ 4.6, and concrete steps are as follows:
By step 2) in acidleach filter cake B add water and be mixed with the ore pulp of mass concentration 25% ~ 30%, feed reverse flotation and roughly select operation, obtain slightly floating smart C and thick floating tail D;
Feed selected operation by slightly floating smart C, carry out primary cleaning and obtain selected concentrate E and cleaner tailings F, described selected concentrate E is the final iron ore concentrate of TFe content 65% ~ 69.5%;
Slightly floating tail D is fed and scans operation, carry out scanning for twice, after twice is scanned two to wind up G and sweep smart H1, two and sweep smart H2, two wind up G as containing TiO
2the final ilmenite concentrate of 40% ~ 80%;
Chats product F, H1, H2 order of each section of operation return last operation.
Described alkaline solution is any one in NaOH or the KOH aqueous solution, NaOH and KOH mixed aqueous solution.
Advantage of the present invention is:
Method synthesis of the present invention uses the method process v-ti magnetite concentrate of alkali leaching, pickling, reverse flotation, achieves titanium in v-ti magnetite concentrate, iron high efficiency separation; In isolated iron ore concentrate, S content significantly reduces simultaneously, is down to is less than 0.10%, SiO by more than 0.50%
2content is down to less than 3%, Al by 3% ~ 6%
2o
3content is down to less than 3% by 3% ~ 6%, for subsequent smelting creates better condition.
The process of alkali leaching has carried out chemical reaction to elements such as Ti, S, Si, Al in v-ti magnetite concentrate, defines corresponding salt.With v-ti magnetite concentrate unlike, SiO in ilmenite raw ore
2content (>20%) and Al
2o
3content (>7%) is far away higher than SiO in v-ti magnetite concentrate
2content (<6%) and Al
2o
3content (<6%), in alkali leaching ilmenite raw ore process, because the process of alkali leaching preferentially will occur in SiO
2, Al
2o
3deng on mineral, alkali is made to soak v-ti magnetite concentrate more less than alkali leaching ferrotianium raw ore alkali consumption, better effects if.Such as, when soaking with NaOH alkali, the alkali number that the present invention consumes is less than 100kg/t concentrate, reduces more than 4.6 times than the alkali number 469kg/t raw ore of alkali leaching raw ore consumption.
Acid cleaning process has dissolved oxysalt and the sulfide such as Ti, Si, Al after alkali leaching effectively, makes it to dissociate with iron ore concentrate.In addition because the present invention adopts sulfuric acid to carry out pickling, reaction conditions is gentle, and little to equipment corrosion, cost is low, is more conducive to suitability for industrialized production.
Add reverse flotation, make iron concentrate grade bring up to 65% ~ 69.5% by 50% ~ 55%, be less than 0.1%, SiO containing S amount in iron ore concentrate simultaneously
2and Al
2o
3content is all less than 3%, TiO
2content is down to less than 6% by 12%.Meanwhile, TiO can also be obtained
2content is the ilmenite concentrate of 40% ~ 80%.Adopt the method, achieve and titanium, iron are effectively separated, reduce and enter blast furnace TiO
2, the impurity such as S, Si, Al content, improve the capacity factor of a blast furnace, reduce the quantity discharged of blast furnace slag, reduce ironmaking cost, improve titanium resource comprehensive utilization ratio simultaneously.
Accompanying drawing explanation
Fig. 1 is present invention process schema.
Fig. 2 is the process flow sheet of reverse flotation work of the present invention.
Embodiment
Below in conjunction with accompanying drawing, the specific embodiment of the present invention is described further:
As shown in Figure 1.
Embodiment 1:
1) alkali leaching
Be 51.0%, TiO by TFe content
2content is 13.8%, SiO
2content is 3.85%, Al
2o
3content is 4.30%, the v-ti magnetite concentrate of S content 0.59%, be placed in the NaOH alkaline solution that mass concentration is 50%, alkali leaching reaction 2.5 hours at the temperature of 360 DEG C, reactant is filtered, obtain filtrate and alkali leaching cake A, NaOH consumption 81kg/t is to ore deposit, and described filtrate feeds recovery and processing system, and its chemical equation is:
mFeTiO
3+2NaOH
mFeO↓+Na
2O·(TiO
2)
m↓+H
2Om≥1
pFe
3O
4·q(FeO·TiO
2)+2rNaOH
pFe
3O
4↓+qFeO↓+(Na
2O)
r·(TiO
2)
q↓+rH
2O
Al
2O
3+2NaOH
2NaAlO
2+H
2O
tSiO
2+2NaOH
Na
2O·(SiO
2)
t↓+H
2O
3FeS
2+6NaOH
3FeS↓+Na
2SO
3+2Na
2S+3H
2O
2) pickling
By step 1) in alkali leaching cake A add water and make the ore pulp that quality solid-to-liquid ratio is 1:6, then be placed in the H that mass concentration is 5%
2sO
4in, 70 DEG C of pickling 40 minutes, filtered by pickling reactant, obtain filtrate and acidleach filter cake B, described filtrate feeds recovery and processing system, and its chemical equation is:
Na
2o (TiO
2)
x+ H
+ heating(H
2o) (TiO
2)
x↓+Na
+x>=1
Na
2otSiO
2+ H
+ heating(H
2o) (SiO
2)
t↓+Na
+
3) reverse flotation
With H
2sO
4for activator and the pH value adjusting agent of titanium compound, fatty acid is collecting agent, diesel oil is the reverse flotation work that supplementary catching agent carries out thick, an essence, secondary and scans, in reverse flotation work, one thick pH value controls 5.1, one smart pH value controls 4.9, and sweep, two sweep equal control ph 4.5, concrete steps are as follows:
By step 2) in acidleach filter cake B add water and be mixed with the ore pulp of mass concentration 25%, feed reverse flotation and roughly select operation, obtain slightly floating smart C and thick floating tail D;
Feed selected operation by slightly floating smart C, carry out primary cleaning and obtain selected concentrate E and cleaner tailings F, described selected concentrate E is the iron ore concentrate (SiO of TFe content 65.5%
2content is 0.36%, Al
2o
3content is 1.15%, S content is 0.01%);
Slightly floating tail D is fed and scans operation, after twice is scanned two to wind up G and sweep smart H1, two and sweep smart H2, two wind up G for containing TiO
2the final ilmenite concentrate of 79.5%;
Chats product F, H1, H2 order of each section of operation return last operation.
Embodiment 2:
1) alkali leaching
Be 51.2%, TiO by TFe content
2content is 13.6%, SiO
2content is 3.85%, Al
2o
3content is 4.31%, the v-ti magnetite concentrate of S content 0.59%, be placed in the NaOH alkaline solution that mass concentration is 40%, alkali leaching reaction 3.5 hours at the temperature of 300 DEG C, reactant is filtered, obtain filtrate and alkali leaching cake A, NaOH consumption 78kg/t is to ore deposit, and described filtrate feeds recovery and processing system, and its chemical equation is with embodiment 1.
2) pickling
By step 1) in alkali leaching cake A add water and make the ore pulp that quality solid-to-liquid ratio is 1:5, then be placed in the H that mass concentration is 4%
2sO
4in, 75 DEG C of pickling 30 minutes, filtered by pickling reactant, obtain filtrate and acidleach filter cake B, described filtrate feeds recovery and processing system, and its chemical equation is with embodiment 1.
3) reverse flotation
With H
2sO
4for activator and the pH value adjusting agent of titanium compound, fatty acid is collecting agent, diesel oil is the reverse flotation work that supplementary catching agent carries out thick, an essence, secondary and scans, in reverse flotation work, one thick pH value controls 5.0, one smart pH value controls 5.0, and sweep, two sweep equal control ph 4.6, concrete steps are as follows:
By step 2) in acidleach filter cake B add water and be mixed with the ore pulp of mass concentration 27%, feed reverse flotation and roughly select operation, obtain slightly floating smart C and thick floating tail D;
Feed selected operation by slightly floating smart C, carry out primary cleaning and obtain selected concentrate E and cleaner tailings F, described selected concentrate E is the final iron ore concentrate (SiO of TFe content 65.9%
2content is 0.75%, Al
2o
3content is 1.65%, S content is 0.02%);
Slightly floating tail D is fed and scans operation, after twice is scanned two to wind up G and sweep smart H1, two and sweep smart H2, two wind up G for containing TiO
2the final ilmenite concentrate of 60.5%;
Chats product F, H1, H2 order of each section of operation return last operation.
Embodiment 3:
1) alkali leaching
Be 53.5%, TiO by TFe content
2content is 11.2%, SiO
2content is 3.25%, Al
2o
3content is 4.39%, the v-ti magnetite concentrate of S content 0.61%, be placed in the NaOH alkaline solution that mass concentration is 30%, alkali leaching reaction 1.5 hours at the temperature of 350 DEG C, reactant is filtered, obtain filtrate and alkali leaching cake A, NaOH consumption 82kg/t is to ore deposit, and described filtrate feeds recovery and processing system, and its chemical equation is with embodiment 1.
2) pickling
By step 1) in alkali leaching cake A add water and make the ore pulp that quality solid-to-liquid ratio is 1:3, then be placed in the H that mass concentration is 2%
2sO
4in, 70 DEG C of pickling 50 minutes, filtered by pickling reactant, obtain filtrate and acidleach filter cake B, described filtrate feeds recovery and processing system, and its chemical equation is with embodiment 1.
3) reverse flotation
With H
2sO
4for activator and the pH value adjusting agent of titanium compound, fatty acid is collecting agent, diesel oil is the reverse flotation work that supplementary catching agent carries out thick, an essence, secondary and scans, in reverse flotation work, one thick pH value controls 5.2, one smart pH value controls 5.1, and sweep, two sweep equal control ph 4.5, concrete steps are as follows:
By step 2) in acidleach filter cake B add water and be mixed with the ore pulp of mass concentration 25.5%, feed reverse flotation and roughly select operation, obtain slightly floating smart C and thick floating tail D;
Feed selected operation by slightly floating smart C, carry out primary cleaning and obtain selected concentrate E and cleaner tailings F, described selected concentrate E is the final iron ore concentrate (SiO of TFe content 69.3%
2content is 0.31%, Al
2o
3content is 1.02%, S content is 0.01%);
Slightly floating tail D is fed and scans operation, after twice is scanned two to wind up G and sweep smart H1, two and sweep smart H2, two wind up G for containing TiO
2the final ilmenite concentrate of 41.8%;
The chats product order of each section of operation returns last operation.
Embodiment 4:
1) alkali leaching
Be 54.0%, TiO by TFe content
2content is 10.3%, SiO
2content is 4.00%, Al
2o
3content is 4.20%, the v-ti magnetite concentrate of S content 0.59%, be placed in the NaOH alkaline solution that mass concentration is 20%, alkali leaching reaction 4.5 hours at the temperature of 330 DEG C, reactant is filtered, obtain filtrate and alkali leaching cake A, NaOH consumption 83kg/t is to ore deposit, and described filtrate feeds recovery and processing system, and its chemical equation is with embodiment 1.
2) pickling
By step 1) in alkali leaching cake A add water and make the ore pulp that quality solid-to-liquid ratio is 1:2, then be placed in the H that mass concentration is 6%
2sO
4in, 80 DEG C of pickling 25 minutes, filtered by pickling reactant, obtain filtrate and acidleach filter cake B, described filtrate feeds recovery and processing system, and its chemical equation is with embodiment 1.
3) reverse flotation
With H
2sO
4for activator and the pH value adjusting agent of titanium compound, fatty acid is collecting agent, diesel oil is the reverse flotation work that supplementary catching agent carries out thick, an essence, secondary and scans, in reverse flotation work, one thick pH value controls 5.3, one smart pH value controls 5.2, and sweep, two sweep equal control ph 4.6, concrete steps are as follows:
By step 2) in acidleach filter cake B add water and be mixed with the ore pulp of mass concentration 28.0%, feed reverse flotation and roughly select operation, obtain slightly floating smart C and thick floating tail D;
Feed selected operation by slightly floating smart C, carry out primary cleaning and obtain selected concentrate E and cleaner tailings F, described selected concentrate E is the final iron ore concentrate (SiO of TFe content 67.5%
2content is 0.40%, Al
2o
3content is 1.35%, S content is 0.01%);
Slightly floating tail D is fed and scans operation, after twice is scanned two to wind up G and sweep smart H1, two and sweep smart H2, two wind up G for containing TiO
2the final ilmenite concentrate of 50.7%;
The chats product order of each section of operation returns last operation.
Embodiment 5:
1) alkali leaching
Be 54.5%, TiO by TFe content
2content is 10.1%, SiO
2content is 3.95%, Al
2o
3content is 3.80%, the v-ti magnetite concentrate of S content 0.55%, be placed in the KOH alkaline solution that mass concentration is 15%, alkali leaching reaction 4.0 hours at the temperature of 280 DEG C, reactant is filtered, obtain filtrate and alkali leaching cake A, NaOH consumption 80kg/t is to ore deposit, and described filtrate feeds recovery and processing system, and its chemical equation is:
mFeTiO
3+2KOH
mFeO↓+K
2O·(TiO
2)
m↓+H2Om≥1
pFe
3O
4·q(FeO·TiO
2)+2rKOH
pFe
3O
4↓+qFeO↓+(K
2O)
r·(TiO
2)
q↓+rH
2O
Al
2O
3+2KOH
2KAlO
2+H
2O
tSiO
2+2KOH
K
2O·(SiO
2)
t↓+H
2O
3FeS
2+6KOH
3FeS↓+K
2SO
3+2K
2S+3H
2O
2) pickling
By step 1) in alkali leaching cake A add water and make the ore pulp that quality solid-to-liquid ratio is 1:4, then be placed in the H that mass concentration is 7%
2sO
4in, 80 DEG C of pickling 9 minutes, filtered by pickling reactant, obtain filtrate and acidleach filter cake B, described filtrate feeds recovery and processing system, and its chemical equation is:
K
2o (TiO
2)
x+ H
+ heating(H
2o) (TiO
2)
x↓+K
+x>=1
K
2otSiO
2+ H
+ heating(H
2o) (SiO
2)
t↓+K
+
3) reverse flotation
With H
2sO
4for activator and the pH value adjusting agent of titanium compound, fatty acid is collecting agent, diesel oil is that supplementary catching agent carries out thick, an essence, two reverse flotation works swept, in reverse flotation work, one thick pH value controls 5.3, one smart pH value controls 5.0, and sweep, two sweep equal control ph 4.6, concrete steps are as follows:
By step 2) in acidleach filter cake B add water and be mixed with the ore pulp of mass concentration 29.0%, feed reverse flotation and roughly select operation, obtain slightly floating smart C and thick floating tail D;
Feed selected operation by slightly floating smart C, carry out primary cleaning and obtain selected concentrate E and cleaner tailings F, described selected concentrate E is the final iron ore concentrate (SiO of TFe content 67.9%
2content is 0.45%, Al
2o
3content is 1.56%, S content is 0.01%);
Slightly floating tail D is fed and scans operation, after twice is scanned two to wind up G and sweep smart H1, two and sweep smart H2, two wind up G for containing TiO
2the final ilmenite concentrate of 75.8%;
The chats product order of each section of operation returns last operation.
Embodiment 6:
1) alkali leaching
Be 52.5%, TiO by TFe content
2content is 13.1%, SiO
2content is 3.60%, Al
2o
3content is 3.71%, the v-ti magnetite concentrate of S content 0.65%, be placed in the KOH alkaline solution that mass concentration is 9%, alkali leaching reaction 4.5 hours at the temperature of 290 DEG C, reactant is filtered, obtain filtrate and alkali leaching cake A, NaOH consumption 90kg/t is to ore deposit, and described filtrate feeds recovery and processing system, and its chemical equation is with embodiment 5.
2) pickling
By step 1) in alkali leaching cake A add water and make the ore pulp that quality solid-to-liquid ratio is 1:3.5, then be placed in the H that mass concentration is 3%
2sO
4in, 70 DEG C of pickling 20 minutes, filtered by pickling reactant, obtain filtrate and acidleach filter cake B, described filtrate feeds recovery and processing system, and its chemical equation is with embodiment 5.
3) reverse flotation
With H
2sO
4for activator and the pH value adjusting agent of titanium compound, fatty acid is collecting agent, diesel oil is that supplementary catching agent carries out thick, an essence, two reverse flotation works swept, in reverse flotation work, one thick pH value controls 5.2, one smart pH value controls 4.8, and sweep, two sweep equal control ph 4.7, concrete steps are as follows:
By step 2) in acidleach filter cake B add water and be mixed with the ore pulp of mass concentration 30.0%, feed reverse flotation and roughly select operation, obtain slightly floating smart C and thick floating tail D;
Feed selected operation by slightly floating smart C, carry out primary cleaning and obtain selected concentrate E and cleaner tailings F, described selected concentrate E is the final iron ore concentrate (SiO of TFe content 68.5%
2content is 0.39%, Al
2o
3content is 1.16%, S content is 0.01%);
Slightly floating tail D is fed and scans operation, after twice is scanned two to wind up G and sweep smart H1, two and sweep smart H2, two wind up G for containing TiO
2the final ilmenite concentrate of 70.3%;
The chats product order of each operation returns last operation.
Embodiment 7:
1) alkali leaching
Be 52.5%, TiO by TFe content
2content is 13.1%, SiO
2content is 3.60%, Al
2o
3content is 3.71%, the v-ti magnetite concentrate of S content 0.65%, be placed in that NaOH mass concentration is 20%, KOH mass concentration is the alkaline solution of 5%, alkali leaching reaction 4.5 hours at the temperature of 285 DEG C, reactant is filtered, filtrate and alkali leaching cake A, NaOH consumption 30kg/t to ore deposit, KOH consumption 50kg/t is to ore deposit, described filtrate feeds recovery and processing system, and its chemical equation is with embodiment 1 and embodiment 5.
2) pickling
By step 1) in alkali leaching cake A add water and make the ore pulp that quality solid-to-liquid ratio is 1:3.0, then be placed in the H that mass concentration is 3%
2sO
4in, 75 DEG C of pickling 15 minutes, filtered by pickling reactant, obtain filtrate and acidleach filter cake B, described filtrate feeds recovery and processing system, embodiment 1 and embodiment 5.
3) reverse flotation
With H
2sO
4for activator and the pH value adjusting agent of titanium compound, fatty acid is collecting agent, diesel oil is that supplementary catching agent carries out thick, an essence, two reverse flotation works swept, in reverse flotation work, one thick pH value controls 5.1, one smart pH value controls 4.9, and sweep, two sweep equal control ph 4.7, concrete steps are as follows:
By step 2) in acidleach filter cake B add water and be mixed with the ore pulp of mass concentration 30.0%, feed reverse flotation and roughly select operation, obtain slightly floating smart C and thick floating tail D;
Feed selected operation by slightly floating smart C, carry out primary cleaning and obtain selected concentrate E and cleaner tailings F, described selected concentrate E is the final iron ore concentrate (SiO of TFe content 68.0%
2content is 0.37%, Al
2o
3content is 1.13%, S content is 0.01%);
Slightly floating tail D is fed and scans operation, after twice is scanned two to wind up G and sweep smart H1, two and sweep smart H2, two wind up G for containing TiO
2the final ilmenite concentrate of 70.0%;
The chats product order of each section of operation returns last operation.
Claims (1)
1. utilize alkali leaching, pickling and reverse flotation to select a method for v-ti magnetite concentrate again, it is characterized in that comprising the steps:
1) alkali leaching
Be 50% ~ 55%, TiO by TFe content range
2content range is 10% ~ 15%, SiO
2content is 3% ~ 6%, Al
2o
3content is 3% ~ 6%, the v-ti magnetite concentrate of S content >0.5%, be placed in mass concentration be 5% ~ 52% NaOH alkaline solution, KOH alkaline solution or NaOH and KOH mixed ammonium/alkali solutions any one, alkali leaching reaction 0.5 ~ 5 hour at the temperature of 280 DEG C ~ 370 DEG C, reactant is filtered, obtain filtrate and alkali leaching cake A, described filtrate feeds recovery and processing system;
2) pickling
Alkali leaching cake A in step 1) is added water and makes the ore pulp that solid-liquid mass ratio is 1:1 ~ 10, then be placed in the H that mass concentration is 1% ~ 10%
2sO
4in solution, under 50 ~ 90 DEG C of conditions, pickling 5 ~ 60 minutes, filters pickling reactant, and obtain filtrate and acidleach filter cake B, described filtrate feeds recovery and processing system;
3) reverse flotation
With H
2sO
4for the activator of titanium compound and the adjusting agent of pH value, fatty acid is collecting agent, diesel oil is the reverse flotation work that supplementary catching agent carries out thick, an essence, secondary and scans, in reverse flotation work, one thick pH value controls 5.0 ~ 5.3, one smart pH value controls 4.9 ~ 5.2, and once purging selection, secondary scan equal control ph 4.5 ~ 4.6, and concrete steps are as follows:
By step 2) in acidleach filter cake B add water and be mixed with the ore pulp of mass concentration 25% ~ 30%, feed reverse flotation and roughly select operation, slightly floated concentrate C and thick floating mine tailing D;
Feed selected operation by slightly floating concentrate C, carry out primary cleaning and obtain selected concentrate E and cleaner tailings F, described selected concentrate E is the final iron ore concentrate of TFe content 65% ~ 69.5%;
Slightly floating mine tailing D is fed and scans operation, carry out scanning for twice, after twice is scanned two to wind up ore deposit G and sweep concentrate H1, two and sweep concentrate H2, two wind up ore deposit G as containing TiO
2the final ilmenite concentrate of 40% ~ 80%;
Chats product F, H1, H2 order of each section of operation return last operation.
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101812595A (en) * | 2010-05-06 | 2010-08-25 | 北京矿冶研究总院 | Method for producing artificial rutile from titanium slag |
| CN102294306A (en) * | 2011-09-13 | 2011-12-28 | 昆明理工大学 | Method for improving grade of protogenic titanium concentrate |
| CN103691550A (en) * | 2013-12-18 | 2014-04-02 | 广西科晟达机械制造有限公司 | Beneficiation method of ilmenite |
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2014
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101812595A (en) * | 2010-05-06 | 2010-08-25 | 北京矿冶研究总院 | Method for producing artificial rutile from titanium slag |
| CN102294306A (en) * | 2011-09-13 | 2011-12-28 | 昆明理工大学 | Method for improving grade of protogenic titanium concentrate |
| CN103691550A (en) * | 2013-12-18 | 2014-04-02 | 广西科晟达机械制造有限公司 | Beneficiation method of ilmenite |
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Address after: 114001 Anshan District, Liaoning, No. 219 Road, No. 39, Tiedong Patentee after: Anshan Iron and Steel Group Mining Co., Ltd. Address before: 114001 Anshan District, Liaoning, No. 219 Road, No. 39, Tiedong Patentee before: Anshan Iron & Steel Group Mining Co., Ltd. |