CN103949651A - Preparation method for unleaded abrasion resistant and corrosion resistant alloy powder material - Google Patents
Preparation method for unleaded abrasion resistant and corrosion resistant alloy powder material Download PDFInfo
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- 239000000956 alloy Substances 0.000 title claims abstract description 51
- 229910045601 alloy Inorganic materials 0.000 title claims abstract description 50
- 239000000843 powder Substances 0.000 title claims abstract description 35
- 239000000463 material Substances 0.000 title claims abstract description 30
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- 238000005260 corrosion Methods 0.000 title abstract description 5
- 230000007797 corrosion Effects 0.000 title abstract description 5
- 238000005299 abrasion Methods 0.000 title abstract 2
- 239000002699 waste material Substances 0.000 claims abstract description 42
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 claims abstract description 33
- 229910000906 Bronze Inorganic materials 0.000 claims abstract description 27
- 239000010974 bronze Substances 0.000 claims abstract description 27
- 239000002893 slag Substances 0.000 claims abstract description 27
- 239000010949 copper Substances 0.000 claims abstract description 21
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000000203 mixture Substances 0.000 claims abstract description 19
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 17
- 238000000034 method Methods 0.000 claims abstract description 17
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229910052802 copper Inorganic materials 0.000 claims abstract description 16
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000004411 aluminium Substances 0.000 claims abstract description 14
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims abstract description 10
- 238000003723 Smelting Methods 0.000 claims abstract description 8
- 239000002994 raw material Substances 0.000 claims abstract description 6
- 238000007670 refining Methods 0.000 claims abstract description 4
- 239000007788 liquid Substances 0.000 claims description 36
- 238000000889 atomisation Methods 0.000 claims description 25
- 238000002844 melting Methods 0.000 claims description 22
- 230000008018 melting Effects 0.000 claims description 22
- 229910052710 silicon Inorganic materials 0.000 claims description 20
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 17
- 239000010703 silicon Substances 0.000 claims description 17
- 239000011135 tin Substances 0.000 claims description 13
- 238000013467 fragmentation Methods 0.000 claims description 12
- 238000006062 fragmentation reaction Methods 0.000 claims description 12
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 9
- 239000003610 charcoal Substances 0.000 claims description 9
- 239000011521 glass Substances 0.000 claims description 9
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 7
- 229910052760 oxygen Inorganic materials 0.000 claims description 7
- 239000001301 oxygen Substances 0.000 claims description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- 230000003064 anti-oxidating effect Effects 0.000 claims description 6
- 239000007789 gas Substances 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 6
- 238000012216 screening Methods 0.000 claims description 6
- 229910000838 Al alloy Inorganic materials 0.000 claims description 5
- 229910052698 phosphorus Inorganic materials 0.000 claims description 5
- 239000011574 phosphorus Substances 0.000 claims description 5
- 238000005275 alloying Methods 0.000 claims description 3
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 claims description 3
- 238000004321 preservation Methods 0.000 claims description 3
- 238000010334 sieve classification Methods 0.000 claims description 3
- 239000000377 silicon dioxide Substances 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 abstract description 4
- 229920001296 polysiloxane Polymers 0.000 abstract 2
- 238000013329 compounding Methods 0.000 abstract 1
- 238000007599 discharging Methods 0.000 abstract 1
- 230000007613 environmental effect Effects 0.000 abstract 1
- 238000007873 sieving Methods 0.000 abstract 1
- 229910052718 tin Inorganic materials 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000004364 calculation method Methods 0.000 description 3
- 239000000470 constituent Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000005245 sintering Methods 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- WIKSRXFQIZQFEH-UHFFFAOYSA-N [Cu].[Pb] Chemical compound [Cu].[Pb] WIKSRXFQIZQFEH-UHFFFAOYSA-N 0.000 description 1
- 238000012387 aerosolization Methods 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
Abstract
The embodiment of the invention discloses a preparation method for an unleaded abrasion resistant and corrosion resistant alloy powder material. The preparation method comprises the following steps: compounding; selecting waste copper wires and stannum wires, aluminium bronze waste materials, silicone bronze waste materials and phosphor bronze waste materials; calculating alloy composition; proportioning raw materials in accordance with the weight percentage of alloy elements, wherein Cu takes up 90.3-94 percent, Sn takes up 6-7 percent, Al takes up 0-2 percent, P takes up 0.1-0.5 percent and Si takes up 0-0.2 percent; smelting; adding the materials in accordance with material adding sequences, namely, firstly adding stanniferous waste materials, then adding aluminium waste materials and silicone waste materials; detecting alloy components; adding phosphorate waste materials for smelting; refining and slag discharging; atomizing and sieving. The preparation method provides a method for utilizing production waste to produce a copper-based alloy powder product that meets the requirement for environmental protection.
Description
Technical field
The invention belongs to alloy powder preparing technical field, relate to especially that five yuan of gold of a kind of aerosolization CuSnAlPSi are wear-resisting, the preparation method of corrosion resistant alloy powder.
Background technology
Traditional manufacture bearing, the copper-base alloy powder of bearing shell are made up of copper, tin, zinc, P elements.Owing to containing poisonous Element Lead in material, harmful, environment is had to pollution, unleaded as a kind of development trend.
Chinese patent ZL200910154059.5 discloses a kind of method of preparing lead-free copper-based alloy powder, and the method is owing to applying the raw material such as copper of high-quality comparatively, and it is limited that cheap material uses, and the prices of raw and semifnished materials are high, and manufacturing cost is high.Chinese Patent Application No. 200810072435.1 discloses a kind of novel alloy powder, weight consists of bismuth 1～15%, tin 0.5～10%, zinc 0.3～15%, and surplus is copper, has used expensive bismuth metal in this alloy composition, and the single extracting metals using, manufacturing cost is high.
Alloy powder prepared by the method more than using uses high-quality and expensive raw material more, for per capita resources, energy country not in plenty, reduction resource, energy resource consumption are the plans of country, therefore find a kind of low energy expenditure, resource regeneration fully utilizes rational technique for reducing enterprise's production cost, and the raising energy, level of resource utilization have profound significance.
Summary of the invention
For addressing the above problem, the object of the present invention is to provide a kind of preparation method of unleaded antifriction anticorrosion alloy dusty material, in order to there is the method for the copper-base alloy powder product that meets environment protection requirement by utilizing production waste to produce.
For achieving the above object, technical scheme of the present invention is:
A preparation method for unleaded antifriction anticorrosion alloy dusty material, comprises the following steps:
S10, batching, select copper scrap tin silk, aluminium bronze waste material, silicon bronze waste material, phosphor bronze waste material, calculate alloy composition, make composition meet the percentage by weight of alloying element composition, wherein copper Cu accounts for 90.3～94%, and tin Sn accounts for 6～7%, aluminium A1 accounts for 0～2%, phosphorus P account for 0.1～0.5% and silicon Si account for 0～0.2% raw material;
S20, melting, according to first add stanniferous waste material, after add containing aluminium, scrap silicon control charging sequence, alloy composition detects, smelting temperature is between 1100～1300 DEG C;
S30, adds phosphorous waste material and carries out melting;
S40, refining deslagging, adds charcoal and covers bath surface, makes Reduction of Oxide, limpid to melt, and glass deslagging, without slag inclusion, if any slag, is added in surface;
S50, atomization, pours alloy mixed liquor into bottom pour ladle, bottom pour ladle aperture is at 3.5～5.0mm, liquid stream flows into atomizing cup by bottom pour ladle hole, adopts air compressor machine generation high-speed gas to carry out fragmentation to mixed liquor liquid stream and forms drop, and the mixed liquor drop after fragmentation condenses and becomes spherical powder particle in dropping process;
S60, screening, carries out sieve classification by cooled spherical powder with bushing screen and can obtain unleaded antifriction anticorrosion alloy dusty material.
Preferably, in S20, in the time that generation composition Si, Al go beyond the scope, carry out oxygen blast slag making, make the Si of super scope and Al produce respectively silica and aluminium oxide.
Preferably, further, in S50, pour aluminium alloy into bottom pour ladle specific as follows, keep at any time the liquid level of tundish, and covering charcoal, anti-oxidation, before atomization finishes, tundish feed liquid top layer application glass deslagging, in the time that centre is surrounded by 1/3 feed liquid, stop atomization, feed liquid is toppled over, enter next melting, prevented that slag inclusion thing from entering atomized powder.
Preferably, in S50, nozzle bore is 2.0～4.0mm, and nozzle hole number is 6～14, and nozzle angle is 8～20 degree, air compressor machine pressure 0.6～1.3MPa.
Preferably, in described atomizing cup, Heat preservation height is 3～10 meters.
Compared with prior art, beneficial effect of the present invention is as follows: by selecting different waste materials, by adjusting alloy composition, realized the unleaded requirement of product, saved cost simultaneously, reduced resource, energy resource consumption; The bearing material that has used this product sintering, its wearability and bond strength can reach the requirement of sintering bimetallic.The present invention is the new material that substitutes CuPbSn alloy, is mainly used in the aspect such as component of machine, automobile bearing, has improved the impact of lead-containing materials on environment, has avoided plumbous harm, meanwhile, has also reduced energy resource consumption.
Brief description of the drawings
Fig. 1 is the preparation method's of the unleaded antifriction anticorrosion alloy dusty material of the embodiment of the present invention flow chart of steps.
Detailed description of the invention
In order to make object of the present invention, technical scheme and advantage clearer, below in conjunction with drawings and Examples, the present invention is further elaborated.Should be appreciated that specific embodiment described herein, only in order to explain the present invention, is not intended to limit the present invention.
On the contrary, the present invention contain any defined by claim in marrow of the present invention and scope, make substitute, amendment, equivalent method and scheme.Further, for the public is had a better understanding to the present invention, in below details of the present invention being described, detailed some specific detail sections of having described.Do not have for a person skilled in the art the description of these detail sections can understand the present invention completely yet.
Referring to Fig. 1, be depicted as the preparation method of a kind of unleaded antifriction anticorrosion alloy dusty material of the embodiment of the present invention, it is characterized in that, comprise the following steps:
S10, batching, select copper scrap tin silk, aluminium bronze waste material, silicon bronze waste material, phosphor bronze waste material, calculate alloy composition, make composition meet the percentage by weight of alloying element composition, wherein copper Cu accounts for 90.3～94%, and tin Sn accounts for 6～7%, aluminium Al accounts for 0～2%, phosphorus P account for 0.1～0.5% and silicon Si account for 0～0.2% raw material;
S20, melting, according to first add stanniferous waste material, after add containing aluminium, scrap silicon control charging sequence, alloy composition detects, smelting temperature is between 1100～1300 DEG C;
S30, adds phosphorous waste material and carries out melting;
S40, refining deslagging, adds charcoal and covers bath surface, makes Reduction of Oxide, limpid to melt, and glass deslagging, without slag inclusion, if any slag, is added in surface;
S50, atomization, pours alloy mixed liquor into bottom pour ladle, bottom pour ladle aperture is at 3.5～5.0mm, liquid stream flows into atomizing cup by bottom pour ladle hole, adopts air compressor machine generation high-speed gas to carry out fragmentation to mixed liquor liquid stream and forms drop, and the mixed liquor drop after fragmentation condenses and becomes spherical powder particle in dropping process;
In concrete application example, pour aluminium alloy into bottom pour ladle specific as follows, keep at any time the liquid level of tundish, and cover charcoal, anti-oxidation, before atomization finishes, tundish feed liquid top layer application glass deslagging, in the time that centre is surrounded by 1/3 feed liquid, stop atomization, feed liquid is toppled over, enter next melting, prevented that slag inclusion thing from entering atomized powder.
In concrete application example, nozzle bore is 2.0～4.0mm, and nozzle hole number is 6～14, and nozzle angle is 8～20 degree, air compressor machine pressure 0.6～1.3MPa.
In atomization process, broken aluminium alloy drop keeps in dropping process, there is the noncondensing height of 3 meters in atomizing cup, otherwise broken fine drop cannot be shunk balling-up.Therefore in concrete application example, in atomizing cup, Heat preservation height is 3～10 meters, and by increasing, atomizing cup is incubated, heated height can ensure that broken drop fully shrinks nodularization globulate powder.
S60, screening, carries out sieve classification by cooled spherical powder with bushing screen and can obtain unleaded antifriction anticorrosion alloy dusty material.
In concrete application example, the upper sieve network planning lattice of bushing screen are generally 30 orders, 40 orders, and 60 orders, 80 orders, 100 orders or 120 orders, lower screen specification is generally 140 orders, 160 orders or 180 orders.
In other application example, further, in S20, in the time that generation composition Si, Al go beyond the scope, carry out oxygen blast slag making, make the Si of super scope and Al produce respectively silica and aluminium oxide.By carrying out oxygen blast operation, make excessive Si and Al oxidation reaction produce corresponding oxide slag charge.
The implementation process of the embodiment of the present invention is described by concrete application example below.
Embodiment 1
(1) batching
In strict accordance with burdening calculation, take the copper tin silk waste material 15Kg containing Sn8%, containing the Al bronze scrap 50.0Kg of Al8%, containing the Si bronze scrap 10.0Kg of Si4.0%, containing the phosphor bronze waste material 125.0Kg of Sn10.24%, P0.32%, add up to furnace charge 200Kg.Make lead-free copper-based alloy powder constituent: Cu90.3%, Sn7%, Al2%, P0.5%, Si0.2% in batching.
(2) reinforced melting
According to first add copper tin waste material, after add containing the reinforced melting of aluminium waste order, smelting temperature is 1100 DEG C.
Because in the material of proportioning, there is not aluminium to exceed standard, therefore do not need to do oxygen blast processing.
(3) slag making, adds solvent slag making, drags for slag.
(4) add silicon bronze, the bronze scrap that finally phosphorates, melting finishes, and carries out atomization operation.
(5) atomization, pour alloy mixed liquor into bottom pour ladle, bottom pour ladle aperture is 5.0mm,, liquid stream flows into atomizing cup by bottom pour ladle hole, adopt air compressor machine to produce high-speed gas, by nozzle, mixed liquor liquid stream is carried out to fragmentation formation drop, mixed liquor drop after fragmentation condenses and becomes spherical powder particle in dropping process, and wherein nozzle bore is 4.0mm, and nozzle hole number is 14, nozzle angle is 8 degree, air compressor machine pressure 1.3MPa.
When atomization operation, keep at any time the liquid level of tundish, and cover charcoal, anti-oxidation.Before atomization finishes, tundish feed liquid top layer application glass deslagging, in the time that centre is surrounded by 1/3 feed liquid, stops atomization, and feed liquid is toppled over, and enters next melting, has prevented that slag inclusion thing from entering atomized powder.
(6) screening, requires to sieve according to order number the unleaded antifriction anticorrosion alloy powder that obtains the embodiment of the present invention.
Upper sieve network planning lattice are 120 orders, and lower screen specification is 180 orders.
The sintered bearing material serviceability detection table of the product of preparing by above embodiment is as follows:
Embodiment 2
(1) batching
In strict accordance with burdening calculation, take the copper tin silk waste material 13.2Kg containing Sn8%, containing the Al bronze scrap 35.0Kg of Al4.5%, containing the Si bronze scrap 13.0Kg of Si3.0%, containing the phosphor bronze waste material 150.0Kg of Sn8.0%, P0.17%, add up to furnace charge 211.2Kg.Make lead-free copper-based alloy powder constituent: Cu92.75%, Sn6.2%, Al0.75%, Si0.18%, P0.12% in batching, during furnace charge calculates, contain Al higher 0.25%.
(2) reinforced melting
According to first add copper tin waste material, after add containing the reinforced melting of aluminium waste order, smelting temperature is 1200 DEG C.
(3) the de-Al of oxygen blast, passes into compressed air at aluminium alloy, pressure 0.12Mpa, and flow 2m3/h takes off Al time 3min.
(4) slag making, adds solvent slag making, drags for slag.
(5) add silicon bronze, the bronze scrap that finally phosphorates, melting finishes, and carries out atomization operation.
(6) atomization, pour alloy mixed liquor into bottom pour ladle, bottom pour ladle aperture is 3.0mm,, liquid stream flows into atomizing cup by bottom pour ladle hole, adopt air compressor machine to produce high-speed gas, by nozzle, mixed liquor liquid stream is carried out to fragmentation formation drop, mixed liquor drop after fragmentation condenses and becomes spherical powder particle in dropping process, and wherein nozzle bore is 2.0mm, and nozzle hole number is 10, nozzle angle is 20 degree, air compressor machine pressure 0.6MPa
When atomization operation, keep at any time the liquid level of tundish, and cover charcoal, anti-oxidation.Before atomization finishes, tundish feed liquid top layer application glass deslagging, in the time that centre is surrounded by 1/3 feed liquid, stops atomization, and feed liquid is toppled over, and enters next melting, has prevented that slag inclusion thing from entering atomized powder.
(7) screening, requires to sieve according to order number the unleaded antifriction anticorrosion alloy powder that obtains the embodiment of the present invention.
Upper sieve network planning lattice are 30 orders, and lower screen specification is 160 orders.
The unleaded antifriction anticorrosion alloy powder of preparing by above embodiment is as shown in the table as sintered bearing material serviceability examining report:
Embodiment 3
(1) batching
In strict accordance with burdening calculation, take the copper tin silk waste material 13.2Kg containing Sn8%, containing the Al bronze scrap 35.0Kg of Al4.5%, containing the Si bronze scrap 13.0Kg of Si3.0%, containing the phosphor bronze waste material 150.0Kg of Sn8.0%, P0.17%, add up to furnace charge 211.2Kg.Make lead-free copper-based alloy powder constituent: Cu93.8%Sn5.9%Al0.1%, P0.1% in batching, %, Si0.1%.
(2) reinforced melting
According to first add copper tin waste material, after add containing the reinforced melting of aluminium waste order, smelting temperature is 1300 DEG C.
(3) slag making, adds solvent slag making, drags for slag.
(4) add silicon bronze, the bronze scrap that finally phosphorates, melting finishes, and carries out atomization operation.
(5) atomization, pour alloy mixed liquor into bottom pour ladle, bottom pour ladle aperture is 3.0mm,, liquid stream flows into atomizing cup by bottom pour ladle hole, adopt air compressor machine to produce high-speed gas, by nozzle, mixed liquor liquid stream is carried out to fragmentation formation drop, mixed liquor drop after fragmentation condenses and becomes spherical powder particle in dropping process, and wherein nozzle bore is 3.0mm, and nozzle hole number is 10, nozzle angle is 8 degree, air compressor machine pressure 1.0MPa.
When atomization operation, keep at any time the liquid level of tundish, and cover charcoal, anti-oxidation.Before atomization finishes, tundish feed liquid top layer application glass deslagging, in the time that centre is surrounded by 1/3 feed liquid, stops atomization, and feed liquid is toppled over, and enters next melting, has prevented that slag inclusion thing from entering atomized powder.
(6) screening, requires to sieve according to order number the unleaded antifriction anticorrosion alloy powder that obtains the embodiment of the present invention.
Upper sieve network planning lattice are 40 orders, and lower screen specification is 140 orders.
The unleaded antifriction anticorrosion alloy powder of preparing by above embodiment is as shown in the table as sintered bearing material serviceability examining report:
Those skilled in the art it should be understood that, the proportioning of adjusting respective metal element by calculating in concrete application example can realize the embodiment of the present invention.In the release sequence of aluminium bronze waste material, silicon bronze waste material, phosphor bronze waste material, strictly control according to aluminium bronze, the input order of silicon bronze and last phosphor bronze, when aluminium and silicon are when excessive, reduce the content of aluminium and silicon by oxygen blast slag practice, because phosphorus is more oxidizable, therefore in melting step, finally add, make it to be controlled at copper Cu and account for 90.3～94%, tin Sn accounts for 6～7%, and aluminium Al accounts for 0～2%, phosphorus P account for 0.1～0.5% and silicon Si account for 0～0.2%.
By adopting copper-lead bimetal powder body material to contrast, it is filled a prescription as following table:
The machinery of its sintered bearing and corrosion resistance detect as follows:
| Anti-bending strength | 470～565MPa |
| Tensile property | 5～18％ |
| Wearability | 0.08～0.14 |
| Decay resistance | Seawater corrosion speed 0.08mm/ |
Can find out by above comparative example, the unleaded novel alloy material property that the materials recycling method that the present invention adopts is produced reaches the performance of plumbous bimetallic material completely, even be better than its performance, but owing to adopting by selecting different waste materials, by adjusting alloy composition, realize the unleaded requirement of product, greatly saved cost, reduced resource, energy resource consumption simultaneously.
The foregoing is only preferred embodiment of the present invention, not in order to limit the present invention, all any amendments of doing within the spirit and principles in the present invention, be equal to and replace and improvement etc., within all should being included in protection scope of the present invention.
Claims (5)
1. a preparation method for unleaded antifriction anticorrosion alloy dusty material, is characterized in that, comprises the following steps:
S10, batching, select copper scrap tin silk, aluminium bronze waste material, silicon bronze waste material, phosphor bronze waste material, calculate alloy composition, make composition meet the percentage by weight of alloying element composition, wherein copper Cu accounts for 90.3～94%, and tin Sn accounts for 6～7%, aluminium A1 accounts for 0～2%, phosphorus P account for 0.1～0.5% and silicon Si account for 0～0.2% raw material;
S20, melting, according to first add stanniferous waste material, after add containing aluminium, scrap silicon control charging sequence, alloy composition detects, smelting temperature is between 1100～1300 DEG C;
S30, adds phosphorous waste material and carries out melting;
S40, refining deslagging, adds charcoal and covers bath surface, makes Reduction of Oxide, limpid to melt, and glass deslagging, without slag inclusion, if any slag, is added in surface;
S50, atomization, pours alloy mixed liquor into bottom pour ladle, bottom pour ladle aperture is at 3.5～5.0mm, liquid stream flows into atomizing cup by bottom pour ladle hole, adopts air compressor machine generation high-speed gas to carry out fragmentation to mixed liquor liquid stream and forms drop, and the mixed liquor drop after fragmentation condenses and becomes spherical powder particle in dropping process;
S60, screening, carries out sieve classification by cooled spherical powder with bushing screen and can obtain unleaded antifriction anticorrosion alloy dusty material.
2. the preparation method of unleaded antifriction anticorrosion alloy dusty material according to claim 1, is characterized in that, in S20, in the time that generation composition Si, A1 go beyond the scope, carries out oxygen blast slag making, makes the Si of super scope and A1 produce respectively silica and aluminium oxide.
3. the preparation method of unleaded antifriction anticorrosion alloy dusty material according to claim 1 and 2, is characterized in that, further, in S50, pour aluminium alloy into bottom pour ladle specific as follows, keep at any time the liquid level of tundish, and cover charcoal, anti-oxidation, before atomization finishes, tundish feed liquid top layer application glass deslagging, in the time that centre is surrounded by 1/3 feed liquid, stop atomization, feed liquid is toppled over, enter next melting, prevented that slag inclusion thing from entering atomized powder.
4. the preparation method of unleaded antifriction anticorrosion alloy dusty material according to claim 1 and 2, is characterized in that, in S50, nozzle bore is 2.0～4.0mm, and nozzle hole number is 6～14, and nozzle angle is 8～20 degree, air compressor machine pressure 0.6～1.3MPa.
5. the preparation method of unleaded antifriction anticorrosion alloy dusty material according to claim 1, is characterized in that, in described atomizing cup, Heat preservation height is 3～10 meters.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106191517A (en) * | 2016-08-10 | 2016-12-07 | 浙江旭德新材料有限公司 | A kind of preparation method of the copper and tin Ni-Bi alloy powder for producing bi-metal shaft bushing material |
| DE202022104646U1 (en) | 2022-08-16 | 2022-09-14 | Radhesh Atul Bobdey | Composition for the production of a high-strength composite material from waste from the aluminum industry |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1078674A (en) * | 1992-05-08 | 1993-11-24 | 北京粉末冶金研究所 | Produce the method for alloy powder |
| JPH10273750A (en) * | 1996-11-21 | 1998-10-13 | Hyundai Motor Co Ltd | Aluminum alloy for high temperature use and its production |
| KR20020096490A (en) * | 2001-06-20 | 2002-12-31 | 병 선 천 | Multi functional vacuum extrusion method for thermoelectric semiconductor materials and thereof apparatus |
| CN101633985A (en) * | 2009-05-21 | 2010-01-27 | 瑞科稀土冶金及功能材料国家工程研究中心有限公司 | Preparation method of RE-Fe-B part hydrogen storage alloy |
| CN102416480A (en) * | 2011-11-24 | 2012-04-18 | 浦江汇凯粉体科技有限公司 | Method for preparing copper-tin-nickel alloy powder by water atomization |
| CN103042220A (en) * | 2012-12-14 | 2013-04-17 | 浦江汇凯粉体科技有限公司 | Method for preparing aluminum bronze powder by water atomization |
| WO2013058074A1 (en) * | 2011-10-19 | 2013-04-25 | 東芝機械株式会社 | Ni-based corrosion-resistant wear-resistant alloy |
-
2014
- 2014-04-30 CN CN201410183891.9A patent/CN103949651B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1078674A (en) * | 1992-05-08 | 1993-11-24 | 北京粉末冶金研究所 | Produce the method for alloy powder |
| JPH10273750A (en) * | 1996-11-21 | 1998-10-13 | Hyundai Motor Co Ltd | Aluminum alloy for high temperature use and its production |
| KR20020096490A (en) * | 2001-06-20 | 2002-12-31 | 병 선 천 | Multi functional vacuum extrusion method for thermoelectric semiconductor materials and thereof apparatus |
| CN101633985A (en) * | 2009-05-21 | 2010-01-27 | 瑞科稀土冶金及功能材料国家工程研究中心有限公司 | Preparation method of RE-Fe-B part hydrogen storage alloy |
| WO2013058074A1 (en) * | 2011-10-19 | 2013-04-25 | 東芝機械株式会社 | Ni-based corrosion-resistant wear-resistant alloy |
| CN102416480A (en) * | 2011-11-24 | 2012-04-18 | 浦江汇凯粉体科技有限公司 | Method for preparing copper-tin-nickel alloy powder by water atomization |
| CN103042220A (en) * | 2012-12-14 | 2013-04-17 | 浦江汇凯粉体科技有限公司 | Method for preparing aluminum bronze powder by water atomization |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106191517A (en) * | 2016-08-10 | 2016-12-07 | 浙江旭德新材料有限公司 | A kind of preparation method of the copper and tin Ni-Bi alloy powder for producing bi-metal shaft bushing material |
| DE202022104646U1 (en) | 2022-08-16 | 2022-09-14 | Radhesh Atul Bobdey | Composition for the production of a high-strength composite material from waste from the aluminum industry |
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