CN103938030B - A kind of preparation method of Ni-based soft magnetic materials - Google Patents
A kind of preparation method of Ni-based soft magnetic materials Download PDFInfo
- Publication number
- CN103938030B CN103938030B CN201410177145.9A CN201410177145A CN103938030B CN 103938030 B CN103938030 B CN 103938030B CN 201410177145 A CN201410177145 A CN 201410177145A CN 103938030 B CN103938030 B CN 103938030B
- Authority
- CN
- China
- Prior art keywords
- soft magnetic
- melting
- alloy
- remelting
- magnetic materials
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000696 magnetic material Substances 0.000 title claims abstract description 22
- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- 239000000956 alloy Substances 0.000 claims abstract description 30
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 28
- 238000002844 melting Methods 0.000 claims abstract description 23
- 230000008018 melting Effects 0.000 claims abstract description 23
- 238000000034 method Methods 0.000 claims abstract description 5
- 238000007669 thermal treatment Methods 0.000 claims abstract description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 13
- 239000002184 metal Substances 0.000 claims description 10
- 229910052751 metal Inorganic materials 0.000 claims description 10
- 230000006698 induction Effects 0.000 claims description 9
- 238000012360 testing method Methods 0.000 claims description 9
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 8
- 239000002994 raw material Substances 0.000 claims description 8
- 229910052710 silicon Inorganic materials 0.000 claims description 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 4
- 229910000551 Silumin Inorganic materials 0.000 claims description 4
- 238000003723 Smelting Methods 0.000 claims description 4
- 238000013019 agitation Methods 0.000 claims description 4
- 238000000137 annealing Methods 0.000 claims description 4
- 229910052786 argon Inorganic materials 0.000 claims description 4
- 230000015572 biosynthetic process Effects 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 4
- 229910052802 copper Inorganic materials 0.000 claims description 4
- 239000010949 copper Substances 0.000 claims description 4
- 238000009413 insulation Methods 0.000 claims description 4
- 238000005339 levitation Methods 0.000 claims description 4
- 239000000155 melt Substances 0.000 claims description 4
- 150000002739 metals Chemical class 0.000 claims description 4
- IKBUJAGPKSFLPB-UHFFFAOYSA-N nickel yttrium Chemical compound [Ni].[Y] IKBUJAGPKSFLPB-UHFFFAOYSA-N 0.000 claims description 4
- 239000010703 silicon Substances 0.000 claims description 4
- 238000010792 warming Methods 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 239000000463 material Substances 0.000 abstract description 8
- 229910052758 niobium Inorganic materials 0.000 abstract description 2
- 239000002699 waste material Substances 0.000 abstract description 2
- 229910052727 yttrium Inorganic materials 0.000 abstract description 2
- 229910052725 zinc Inorganic materials 0.000 abstract description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 5
- 230000035699 permeability Effects 0.000 description 5
- 229910001030 Iron–nickel alloy Inorganic materials 0.000 description 2
- 238000004891 communication Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 241000024287 Areas Species 0.000 description 1
- 229910000967 As alloy Inorganic materials 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 230000005389 magnetism Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
Landscapes
- Soft Magnetic Materials (AREA)
Abstract
The present invention relates to a kind of preparation method of Ni-based soft magnetic materials, it is characterized in that this soft magnetic materials is made up of the alloy of following atom ratio: (Ni
1-x-yti
xzn
y)
1-a-b-c(Si
1-zal
z)
ay
bnb
cwherein x=0.08-0.16, y=0.25-0.32, z=0.42-0.46, a=0.15-0.18, b=0.02-0.03, c=0.04-0.05, the method comprises the steps: (1) prepares burden, (2) melting ingot, (3) alloy strip is prepared, (4) thermal treatment.Soft magnetic materials prepared by the present invention, adopt Ti and Zn Substitute For Partial Ni to improve the soft magnetic performance of material, doping Y and Nb improves the magnetic saturation intensity of material, and doping Si improves the resistivity of material.Therefore, this material be used for various equipment time in particular for having good soft magnetic performance and lower energy waste during high-frequency apparatus.
Description
Art
The present invention relates to a kind of preparation method of Ni-based soft magnetic materials.
Background technology
Along with the development of electron and electrician and ICT (information and communication technology), the application of soft magnetic materials is more and more extensive, especially in Application Areass such as all kinds of transformer, inductance element, filtering devices.At present, be that the soft magnetic metal of representative and alloy material thereof have irreplaceable effect with its high magnetic permeability and saturation induction density in some Application Areas above-mentioned with iron.
Fe-Ni alloy/C is a kind of important metal soft magnetic material; owing to having the features such as high magnetic permeability, low-coercivity, low-loss; be widely used in various iron core and the magnetic shielding part of electron device; the magnetic head etc. of the iron core of the highly sensitive miniature transformer used under being particularly suitable for manufacturing low-intensity magnetic field condition, amplifier, rly., earth leakage circuit-breaker, reactance coil and magnetic recording, sound-track engraving apparatus, becomes the industrial indispensable base mateirals such as communication, broadcast, radar, aerospace, computer and precision meter.
But due to the magnetic strength of Fe-Ni system soft magnetic materials and magnetic permeability counter stress very responsive, the magnetic property of its alloy system is not high, and particularly coercive force and magnetic permeability performance can not meet performance requriements.
Summary of the invention
The invention provides a kind of preparation method of Ni-based soft magnetic materials, soft magnetic materials tool high magnetic permeability, low-coercivity and high resistivity prepared by the method.
To achieve these goals, the preparation method of a kind of above-mentioned Ni-based soft magnetic materials provided by the invention, is characterized in that this soft magnetic materials is made up of the alloy of following atom ratio: (Ni
1-x-yti
xzn
y)
1-a-b-c(Si
1-zal
z)
ay
bnb
c, wherein x=0.08-0.16, y=0.25-0.32, z=0.42-0.46, a=0.15-0.18, b=0.02-0.03, c=0.04-0.05, the method comprises the steps:
(1) prepare burden
Prepare raw material according to above-mentioned atom ratio, wherein the purity of all raw metals is all greater than 99.9%, and silicon is prepared burden in the mode of silumin, and Y prepares burden in the mode of yttrium nickel master alloy;
(2) melting ingot
Mixed by raw material, be placed in the melting of magnetic levitation melting stove, melting is carried out under vacuo, melting vacuum 1 × 10
-4-10
-3pa, smelting temperature 1560-1620 DEG C, melt back 3-5 time, each magnetic agitation 1-3min, obtains alloy cast ingot in note to water cooled copper mould after melting completes;
(3) alloy strip is prepared
Above-mentioned alloy cast ingot is put into remelting tubular type crucible and carry out remelting, described remelting tubular type crucible is placed in vacuum induction forming furnace, remelting temperature is 1540-1560 DEG C, then remelting body is blown down through test tube aperture, the speed of rotation adjusting single roller spun furnace is 1500-2000 rev/min, makes the melt fallen be frozen into banded formation continuous print metal strip once the roll surface touching high speed rotating at once;
(4) thermal treatment
Preformed member is cut into by stacking for above-mentioned alloy strip size; under argon shield, be warming up to 750-800 DEG C with the heat-up rate of 5-10 DEG C/min, after insulation 4-6h; with the cooling rate isothermal annealing of 12-15 DEG C/min to room temperature, obtain soft magnetic materials of the present invention.
Soft magnetic materials prepared by the present invention, adopt Ti and Zn Substitute For Partial Ni to improve the soft magnetic performance of material, doping Y and Nb improves the magnetic saturation intensity of material, and doping Si improves the resistivity of material.Therefore, this material be used for various equipment time in particular for having good soft magnetic performance and lower energy waste during high-frequency apparatus.
Embodiment
Embodiment one
The Ni-based soft magnetic materials of the present embodiment is made up of the alloy of following atom ratio: (Ni
0.67ti
0.08zn
0.25)
0.79(Si
0.58al
0.42)
0.15y
0.02nb
0.04.
Prepare raw material according to above-mentioned atom ratio, wherein the purity of all raw metals is all greater than 99.9%, and silicon is prepared burden in the mode of silumin, and Y prepares burden in the mode of yttrium nickel master alloy.
Mixed by raw material, be placed in the melting of magnetic levitation melting stove, melting is carried out under vacuo, melting vacuum 1 × 10
-4pa, smelting temperature 1560 DEG C, melt back 5 times, each magnetic agitation 3min, obtains alloy cast ingot in note to water cooled copper mould after melting completes.
Above-mentioned alloy cast ingot is put into remelting tubular type crucible and carry out remelting, described remelting tubular type crucible is placed in vacuum induction forming furnace, remelting temperature is 1540 DEG C, then remelting body is blown down through test tube aperture, the speed of rotation adjusting single roller spun furnace is 1500 revs/min, makes the melt fallen be frozen into banded formation continuous print metal strip once the roll surface touching high speed rotating at once.
Cut into preformed member by stacking for above-mentioned alloy strip size, under argon shield, be warming up to 750 DEG C with the heat-up rate of 5 DEG C/min, after insulation 6h, with the cooling rate isothermal annealing of 12 DEG C/min to room temperature, obtain soft magnetic materials of the present invention.
Embodiment two
The Ni-based soft magnetic materials of the present embodiment is made up of the alloy of following atom ratio: (Ni
0.52ti
0.16zn
0.32)
0.74(Si
0.54al
0.46)
0.18y
0.03nb
0.05.
Prepare raw material according to above-mentioned atom ratio, wherein the purity of all raw metals is all greater than 99.9%, and silicon is prepared burden in the mode of silumin, and Y prepares burden in the mode of yttrium nickel master alloy.
Mixed by raw material, be placed in the melting of magnetic levitation melting stove, melting is carried out under vacuo, melting vacuum 1 × 10
-3pa, smelting temperature 1620 DEG C, melt back 3 times, each magnetic agitation 1min, obtains alloy cast ingot in note to water cooled copper mould after melting completes.
Above-mentioned alloy cast ingot is put into remelting tubular type crucible and carry out remelting, described remelting tubular type crucible is placed in vacuum induction forming furnace, remelting temperature is 1560 DEG C, then remelting body is blown down through test tube aperture, the speed of rotation adjusting single roller spun furnace is 2000 revs/min, makes the melt fallen be frozen into banded formation continuous print metal strip once the roll surface touching high speed rotating at once.
Cut into preformed member by stacking for above-mentioned alloy strip size, under argon shield, be warming up to 800 DEG C with the heat-up rate of 10 DEG C/min, after insulation 4h, with the cooling rate isothermal annealing of 15 DEG C/min to room temperature, obtain soft magnetic materials of the present invention.
Comparative example
Adopt following batching: be: 3.16%Si, 1.90%Ni, 0.41%Al and 1.24%Ti that surplus is Fe by weight percentage.Technical process is: composition proportion-vacuum-melting-preparation alloy strip-stacking excision forming.
Carry out magnetism testing and loss test to same shape and the embodiment 1-2 of size and the soft magnetic materials of comparative example, test at 25 DEG C, (1) loss measurement adopts SY8232B-H tester, and test condition is magnetic strength 1.5T, and frequency is 200Hz.(2) the saturation induction density B of alloy
sadopting static magnetic performance survey meter, take magnetic field as the saturation induction density B of the magnetic induction density under 1000A/m as alloy
s.Test result shows: the loss relatively example reduction by more than 25% of embodiment 1-2, saturation induction density relatively example improves more than 25-30%.
Claims (1)
1. a preparation method for Ni-based soft magnetic materials, is characterized in that this soft magnetic materials is made up of the alloy of following atom ratio: (Ni
1-x-yti
xzn
y)
1-a-b-c(Si
1-zal
z)
ay
bnb
c, wherein x=0.08-0.16, y=0.25-0.32, z=0.42-0.46, a=0.15-0.18, b=0.02-0.03, c=0.04-0.05, the method comprises the steps:
(1) prepare burden
Prepare raw material according to above-mentioned atom ratio, wherein the purity of all raw metals is all greater than 99.9%, and silicon is prepared burden in the mode of silumin, and Y prepares burden in the mode of yttrium nickel master alloy;
(2) melting ingot
Mixed by raw material, be placed in the melting of magnetic levitation melting stove, melting is carried out under vacuo, melting vacuum 1 × 10
-4-10
-3pa, smelting temperature 1560-1620 DEG C, melt back 3-5 time, each magnetic agitation 1-3min, obtains alloy cast ingot in note to water cooled copper mould after melting completes;
(3) alloy strip is prepared
Above-mentioned alloy cast ingot is put into remelting tubular type crucible and carry out remelting, described remelting tubular type crucible is placed in vacuum induction forming furnace, remelting temperature is 1540-1560 DEG C, then remelting body is blown down through test tube aperture, the speed of rotation adjusting single roller spun furnace is 1500-2000 rev/min, makes the melt fallen be frozen into banded formation continuous print metal strip once the roll surface touching high speed rotating at once;
(4) thermal treatment
Preformed member is cut into by stacking for above-mentioned alloy strip size; under argon shield, be warming up to 750-800 DEG C with the heat-up rate of 5-10 DEG C/min, after insulation 4-6h; with the cooling rate isothermal annealing of 12-15 DEG C/min to room temperature, obtain described magnetically soft alloy material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410177145.9A CN103938030B (en) | 2014-04-29 | 2014-04-29 | A kind of preparation method of Ni-based soft magnetic materials |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410177145.9A CN103938030B (en) | 2014-04-29 | 2014-04-29 | A kind of preparation method of Ni-based soft magnetic materials |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103938030A CN103938030A (en) | 2014-07-23 |
| CN103938030B true CN103938030B (en) | 2015-12-09 |
Family
ID=51185895
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410177145.9A Expired - Fee Related CN103938030B (en) | 2014-04-29 | 2014-04-29 | A kind of preparation method of Ni-based soft magnetic materials |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103938030B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104439235B (en) * | 2014-12-20 | 2017-03-29 | 珠海嘉磁电子有限公司 | A kind of preparation method of compound soft magnetic material |
| CN104451216B (en) * | 2015-01-17 | 2017-05-31 | 佛山市三水精英五金制品有限公司 | A kind of preparation method of resistant to elevated temperatures nickel cobalt base soft magnetic materials |
| CN106011506B (en) * | 2016-07-01 | 2017-10-20 | 河南理工大学 | A kind of Ni-based hydrogen bearing alloy of boron containing rare earth magnesium prepares manufacturing process |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101886192A (en) * | 2010-06-23 | 2010-11-17 | 北京科技大学 | Method for preparing high-performance iron nickel magnetically soft alloy by using powder metallurgy process |
| CN103221999A (en) * | 2010-11-22 | 2013-07-24 | 山阳特殊制钢株式会社 | Alloy for seed layer of magnetic recording medium, and sputtering target material |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH07180003A (en) * | 1993-12-21 | 1995-07-18 | Nippon Steel Corp | Fe-ni magnetic alloy excellent in hot workability and magnetic property |
| JP2005150381A (en) * | 2003-11-14 | 2005-06-09 | Daido Steel Co Ltd | Dust core |
-
2014
- 2014-04-29 CN CN201410177145.9A patent/CN103938030B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101886192A (en) * | 2010-06-23 | 2010-11-17 | 北京科技大学 | Method for preparing high-performance iron nickel magnetically soft alloy by using powder metallurgy process |
| CN103221999A (en) * | 2010-11-22 | 2013-07-24 | 山阳特殊制钢株式会社 | Alloy for seed layer of magnetic recording medium, and sputtering target material |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103938030A (en) | 2014-07-23 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Takenaka et al. | Industrialization of nanocrystalline Fe–Si–B–P–Cu alloys for high magnetic flux density cores | |
| CN105047348B (en) | A kind of current transformer core of amorphous and nanocrystalline soft magnetic alloy and preparation method thereof | |
| CN104485192B (en) | A kind of iron-based amorphous and nanocrystalline soft magnetic alloy and preparation method thereof | |
| CN107393673B (en) | Iron-based amorphous nanocrystalline magnetically soft alloy and preparation method thereof | |
| CN109440022A (en) | One kind (FeaSibBcCudNbe)xMySoft magnetic materials and preparation method thereof | |
| CN104934179A (en) | Fe-based nanocrystalline soft magnetic alloy with strong amorphous forming ability and preparing method of Fe-based nanocrystalline soft magnetic alloy | |
| CN104878324A (en) | Soft-magnetic high-entropy block amorphous alloy FeCoNiMB and preparation method thereof | |
| CN103938030B (en) | A kind of preparation method of Ni-based soft magnetic materials | |
| CN104451465B (en) | A kind of preparation method for industrial iron-based amorphous and nanocrystalline soft magnetic alloy | |
| CN106566987A (en) | Fe-B-Si system block nanocrystalline soft magnetic alloy and preparation method thereof | |
| CN106756644A (en) | A kind of iron-based amorphous and nanocrystalline soft magnetic alloy based on element silicon and preparation method thereof | |
| JP6245392B1 (en) | Soft magnetic alloy | |
| CN103820741B (en) | A kind of mu-metal material for energy-saving electric machine and preparation method thereof | |
| CN105825991A (en) | Iron-based soft-magnet amorphous alloy with less components, low cost and high saturation magnetic induction intensity and manufacturing process thereof | |
| CN110670001A (en) | Preparation method of silicon-rich P-containing iron-based amorphous nanocrystalline alloy and iron-based amorphous alloy nanocrystalline magnetic core | |
| CN110400670A (en) | High squareness ratio cobalt base amorphous alloy iron core and preparation method thereof | |
| CN103943297B (en) | The preparation method of a kind of cobalt nickel base soft magnetic materials | |
| CN105957674B (en) | A kind of Nd-Ce-Pr-Fe-B alloy thin band permanent-magnet materials of high-coercive force and preparation method thereof | |
| CN104087840B (en) | A kind of preparation method of iron based soft magnetic materials | |
| CN113789487B (en) | High-carbon high-resistivity soft magnetic iron-based amorphous alloy and preparation method thereof | |
| CN103928206B (en) | A kind of preparation method of the Ni-based soft magnetic materials of iron | |
| CN105702408B (en) | A kind of preparation method of nano crystal soft magnetic material | |
| CN109207871A (en) | A kind of amorphous-nano-crystalline magnetically soft alloy and preparation method thereof | |
| CN104538144A (en) | Preparing method for gadolinium-doped iron-nickel-based soft magnetic materials | |
| CN105913989B (en) | High remanent magnetism material and preparation method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| CB03 | Change of inventor or designer information |
Inventor after: Cui Huanyao Inventor before: Wang Yang |
|
| COR | Change of bibliographic data | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20151104 Address after: 518000, No. twenty-second, No. 406, No. 1 Industrial Zone, Hing Wai, Fuyong street, Baoan District, Guangdong, Shenzhen Applicant after: SHENZHEN TIANRUI TECHNOLOGY Co.,Ltd. Address before: 518000, Lianhua Road 1116, Lianhua Road, Futian District, Guangdong, Shenzhen, 34-505 Applicant before: Wang Yang |
|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20161017 Address after: The 723200 group of South Shaanxi Chenggu County in Shaanxi Province five 3 building 502 room Patentee after: Cui Huanyao Address before: 518000, No. twenty-second, No. 406, No. 1 Industrial Zone, Hing Wai, Fuyong street, Baoan District, Guangdong, Shenzhen Patentee before: SHENZHEN TIANRUI TECHNOLOGY Co.,Ltd. |
|
| TR01 | Transfer of patent right |
Effective date of registration: 20211125 Address after: 312000 room 1, ground floor, No. 117, duchangfang Road, Yuecheng District, Shaoxing City, Zhejiang Province Patentee after: ZHEJIANG YINUO WEISHENG INFORMATION TECHNOLOGY Co.,Ltd. Address before: Room 502, building 3, zone 5, Southern District, Shaanxi flying group, Chenggu County, Shaanxi Province, 723200 Patentee before: Cui Huanyao |
|
| TR01 | Transfer of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20151209 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |