CN103937624A - Pipeline dredging agent with stable oxygenation effect and preparation method of pipeline dredging agent - Google Patents
Pipeline dredging agent with stable oxygenation effect and preparation method of pipeline dredging agent Download PDFInfo
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Abstract
The invention discloses a pipeline dredging agent with a stable oxygenation effect and a preparation method of the pipeline dredging agent. The pipeline dredging agent comprises strong base, a non-volatile liquid, special powder, an oxygen bleaching agent and a chlorine bleach, and can further comprises an additive, and is prepared through a special feeding process. The combination of the non-volatile liquid and the special powder is innovatively introduced, so that the oxygenation stability and the anti-caking property of a product in a storage process are greatly improved, and the dust amount and the nose chocking feeling are reduced and alleviated. The product disclosed by the invention also has the advantages of rapid dissolution, stable heat radiation, low chloride smell, low metal corrosion, easy production and machining and the like, is applicable to dredging or cleaning and maintaining drainage pipelines, and has a good application prospect.
Description
Technical field
The present invention relates to a kind of pipe-dredging agent, particularly relate to a kind of formula and technology of preparing of pipe-dredging agent of high oxidative stability alive.
Background technology
The chemical mode of dredging cleanser conduit is generally by enzyme (or microorganism) or highly basic, dissolves organic tamper such as grease, hair, and killing microorganisms keeps duct cleaning unimpeded.With enzyme (or microorganism), cost is higher conventionally, and effect is slow, and the low effect of cost is fast to use highly basic.Therefore strong basicity product is still the main flow of current pipe-dredging agent.
At present, strong basicity pipe-dredging agent can be summarized as following five classes by main core effect composition of its formula system.
The one, merely using highly basic as main composition, not chlorine-containing bleaching and metal.Early stage pipe-dredging agent adopts this class more, and its formulation composition is simple, handling ease, cost are low, but product dissolves slow, poor performance.
The 2nd, highly basic and chlorine float the combination of agent.Introducing chlorine floats agent and can obviously improve product to the organic removing effect of line clogging, and patent CN02138426.6, CN03115938.9, CN20110330367.6 belong to this class.But it is high that chlorine floats agent consumption, there is the deficiencies such as Odor stimulation, large to metal protection, product dissolving is slow.
The 3rd, the combination of highly basic and active metal.After highly basic and active metal chance water, vigorous reaction heat release can improve the low temperature result of use of product, produces hydrogen simultaneously and plays " boiling " effect, can accelerate the dissolving diffusion of highly basic.The active metals such as use aluminium alive, zinc, magnesium, it is strict that its production process requires moistureproof and waterproof, and product in use heat release is violent, more easily causes the distortion of pipeline local softening, and generation hydrogen has certain security risk.
The 4th, highly basic, oxygen float agent or chlorine and float agent, active metal three's combination.This class system stability is difficult point, and process for processing, packing and storing require strict to the control of water, and heat release is violent in use also produces hydrogen and oxygen simultaneously, and danger is larger, has adopted respectively this two kinds of modes in patent CN90108009.8 and CN95111481.6.
The 5th, on the basis of the above, also add other effect composition, as patent CN95111633.9 has also adopted S-WAT, rare earth.
Highly basic and oxygen float agent combination, and its stability that coexists is an industry difficult problem.Because solid alkali (as sodium hydroxide) has very strong moisture absorption ability and moisture absorption heat release, easily caking; Oxygen floats meeting in agent (as SPC-D) storage process and when slowly decomposition discharges efficient oxygen, produces water; And highly basic itself will significantly accelerate oxygen and float the decomposition of agent.Therefore, solid alkali and oxygen float agent very difficult stable coexisting conventionally.When formula or inappropriate technology, the two very easily occurs living, and oxygen loss is too fast, product caking equistability problem.
The oxygen of living can provide the bleaching bacteria-eliminating efficacy of environmental protection gentleness, and the oxidative stability of living has very large direct or indirect impact to the performance of this product.Oxygen raw material alive too quick decomposition in product shelf life, the one, make product cannot play in use foaming, dissolution, the degerming texts of expection; The 2nd, after the water that decomposition produces is absorbed by highly basic, generate crystal water, cause its solution heat significantly to reduce, dissolve and the decline of dredging effect; The 3rd, produce water and also can cause product caking when more when decomposing, the serious problems such as cannot use.
Summary of the invention
The object of the present invention is to provide a kind of dredging agent for solid pipeline with the stable oxygen effect of living, the oxidative stability alive that it has obviously improved product stock has greatly reduced the airborne dust of product and the nose sense of choking simultaneously.
Another object of the present invention is to, a kind of preparation method of the above-mentioned dredging agent for solid pipeline with the stable oxygen effect of living is provided.
The object of the invention to solve the technical problems realizes by the following technical solutions.A kind of dredging agent for solid pipeline with the stable oxygen effect of living proposing according to the present invention, its formula material component comprises: highly basic, non-volatile liquid, extraordinary powder, oxygen float agent, chlorine floats agent, can further comprise auxiliary agent.
The pipe-dredging agent with the stable oxygen effect of living of the present invention, by weight percentage, its feed composition comprises that highly basic 40～85%, non-volatile liquid 0.5～8%, extraordinary powder 1～40%, oxygen float agent 5～30%, chlorine floats agent 1～8%, auxiliary agent surplus.
Described highly basic is that purity is not less than 85% technical grade sodium hydroxide or potassium hydroxide; It is the particulate state of median size 0.3～3.5mm or the sheet of median size 0.5～15mm.
Described non-volatile liquid is one or more composite in C8-C40 alkane, C5-C20 fatty alcohol, vegetables oil, animal oil, polydimethylsiloxane.
Described its fusing point of non-volatile liquid is not higher than 35 DEG C, and boiling point is not less than 150 DEG C, and moisture content is not higher than 5%.
Described extraordinary powder is one or more composite in sodium alkyl benzene sulfonate, α-sodium olefin sulfonate, sodium alkyl sulfate, soap powder, Xylo-Mucine, stone flour, talcum powder, soda ash, and its outward appearance is powdery.
It is one or more composite in SPC-D, peroxosulphuric sodium, Sodium peroxoborate that described oxygen floats agent, is solid granular or Powdered.
It is one or more composite in Surchlor GR 60, sodium trichloro-isocyanurate, Losantin that described chlorine floats agent, is solid granular or Powdered.
Described auxiliary agent refers to that dredging detergency ability to this product or stability, without the direct raw material of contribution, can comprise: one or more in sodium sulfate, sodium-chlor, water glass, Starso, silicon-dioxide, zeolite, clay, wilkinite, diatomite, tripoly phosphate sodium STPP, Trisodium Citrate, ethylenediamine tetraacetic acid (EDTA) or its salt, 1-Hydroxy Ethylidene-1,1-Diphosphonic Acid or its salt, tetraacetyl ethylene diamine, triclocarban, colored particle, essence are composite.
The present invention has the preparation method of the pipe-dredging agent of the stable oxygen effect of living, and it is to drop into highly basic in relatively airtight feed proportioning system, then adds non-volatility liquid, mixes thoroughly; Add again extraordinary powder, mix thoroughly; Add again chlorine to float agent and auxiliary agent, mix thoroughly; Finally add oxygen to float agent, fully mix thoroughly, be up to the standards and can pack to obtain product.
By technique scheme, advantage and beneficial effect that the present invention has are:
1) the present invention introduces non-volatile liquid innovatively, make liquid first be coated on highly basic particle surface by blend, add subsequently extraordinary powder, powder is adhered on it, like this highly basic is played to well coated buffer action, reduce it and the distance that contacts of the oxygen raw material of living, thereby obviously improved the oxidative stability alive of product stock.
2), by adding suitable non-volatile liquid, the dust of product and the nose sense of choking have obviously been reduced.
3) adopt room temperature preparation technology, without complicated technologies such as heating, pulverizing, granulations, greatly reduce production energy consumption and cost.
Embodiment
The invention provides a kind of pipe-dredging agent with the stable oxygen effect of living, its formula material component comprises: highly basic, non-volatile liquid, extraordinary powder, oxygen float agent, chlorine floats agent, auxiliary agent.Wherein, highly basic, non-volatile liquid, extraordinary powder, oxygen float agent, chlorine and float agent for essential composition, and auxiliary agent is for may be selected to point.In relatively airtight feed proportioning system, drop into highly basic, then add non-volatility liquid, mix thoroughly; Add again extraordinary powder, mix thoroughly; Add again chlorine to float agent and auxiliary agent, mix thoroughly; Finally add oxygen to float agent, fully mix thoroughly, be up to the standards, pack to such an extent that there is the pipe-dredging agent product of the stable oxygen effect of living.
The present invention adopts non-volatile liquid and powder combination first, by specific technique, can make in product storage and transport process, powder relatively firmly remains on around the raw material of oxygen raw material alive or impact oxidative stability alive, the raw material of live oxygen raw material and impact oxidative stability alive is kept apart, thereby improve the oxidative stability alive of product, and the anti-caking performance of improving product.
Select to optimize by the kind to non-volatile liquid, extraordinary powder and consumption, can make product obtain good oxidative stability alive and anti-caking performance, obviously reduce the dust that product produces in the time producing and use simultaneously.
The present invention does not need heating, and product adopts physical blending mode to carry out, easy and simple to handle.Because a little less than the obstruct relative thin of liquid, when use, original structure can be destroyed, the normal release of the oxygen of living while therefore not affecting product use.
The introducing liquid of the invention, by optimizing proportioning, adjusting process, obviously improved product the oxidative stability alives of storage, the airborne dust that has simultaneously greatly reduced product with choke nose sense.
In a word, product of the present invention has other all advantages containing the pipe-dredging agent of the oxygen raw material of living: product dissolves fast, and smell is little, discharges the oxygen of living rapid, little to pipeline injury, cost is low.Also tool has clear improvement simultaneously oxidative stability alive and anti-caking performance, can support the shelf-lives more grown and better use properties, also greatly reduces the dust producing when product uses and the nose sense of choking.Therefore, there is good DEVELOPMENT PROSPECT.
Below, by concrete preferred embodiment, the present invention is described in further detail, but the present invention is not limited in following embodiment.
embodiment 1
A kind of pipe-dredging agent with the stable oxygen effect of living, adopt following raw materials according to be mixed by weight ratio, every kind of raw material percentage ratio (%) meter by weight, wherein: sodium hydroxide 78, polydimethylsiloxane (10cSt) 1, α-sodium olefin sulfonate 1.5, soda ash 5, SPC-D 12, Surchlor GR 60 2, colour particles 0.5.
In relatively airtight feed proportioning system, drop into sodium hydroxide, then add polydimethylsiloxane (10cSt), mix thoroughly; Add again α-sodium olefin sulfonate, soda ash, mix thoroughly; Add again Surchlor GR 60 and colour particles, mix thoroughly; Finally add SPC-D, fully mix thoroughly, be up to the standards and can pack to obtain product.
embodiment 2
A kind of pipe-dredging agent with the stable oxygen effect of living, adopt following raw materials according to be mixed by weight ratio, every kind of raw material percentage ratio (%) meter by weight, wherein: sodium hydroxide 70, whiteruss 2, sodium lauryl sulphate 1, stone flour 3, soda ash 6.1, SPC-D 15, Surchlor GR 60 2, essence 0.1, blue particles 0.8.
In relatively airtight feed proportioning system, drop into sodium hydroxide, then add whiteruss, mix thoroughly; Add again sodium lauryl sulphate, stone flour, soda ash, mix thoroughly; Add again Surchlor GR 60, essence, blue particles, mix thoroughly; Finally add SPC-D, fully mix thoroughly, be up to the standards and can pack to obtain product.
embodiment 3
A kind of pipe-dredging agent with the stable oxygen effect of living, adopt following raw materials according to be mixed by weight ratio, every kind of raw material percentage ratio (%) meter by weight, wherein: sodium hydroxide 62.5, kerosene 1, sodium lauryl sulphate 1, stone flour 3, soda ash 14.6, SPC-D 15, Surchlor GR 60 2, essence 0.1, colour particles 0.8.
In relatively airtight feed proportioning system, drop into sodium hydroxide, then add kerosene, mix thoroughly; Add again sodium lauryl sulphate, stone flour, soda ash, mix thoroughly; Add again Surchlor GR 60, essence, colour particles, mix thoroughly; Finally add SPC-D, fully mix thoroughly, be up to the standards and can pack to obtain product.
embodiment 4
There is the pipe-dredging agent of the stable oxygen effect of living, adopt following raw materials according to be mixed by weight ratio, every kind of raw material percentage ratio (%) meter by weight, wherein: sodium hydroxide 55, soybean oil 2, soap powder 2, talcum powder 3, soda ash, 9.5, SPC-D 20, Losantin 5, Starso 2, blue particles 1.5.
In relatively airtight feed proportioning system, drop into sodium hydroxide, then add soybean oil, mix thoroughly; Add again soap powder, talcum powder, soda ash, mix thoroughly; Add again Losantin, Starso, blue particles, mix thoroughly; Finally add SPC-D, fully mix thoroughly, be up to the standards and can pack to obtain product.
embodiment 5
A kind of pipe-dredging agent with the stable oxygen effect of living, adopt following raw materials according to be mixed by weight ratio, every kind of raw material percentage ratio (%) meter by weight, wherein: wherein: potassium hydroxide 50, lauryl alcohol 3, Xylo-Mucine 2, talcum powder 3, soda ash, 24, Sodium peroxoborate 15, sodium trichloro-isocyanurate 3, tripoly phosphate sodium STPP 1.
In relatively airtight feed proportioning system, drop into potassium hydroxide, then add lauryl alcohol, mix thoroughly; Add again Xylo-Mucine, talcum powder, soda ash, mix thoroughly; Add again sodium trichloro-isocyanurate, tripoly phosphate sodium STPP, mix thoroughly; Finally add Sodium peroxoborate, fully mix thoroughly, be up to the standards and can pack to obtain product.
embodiment 6
There is the pipe-dredging agent of the stable oxygen effect of living, adopt following raw materials according to be mixed by weight ratio, every kind of raw material percentage ratio (%) meter by weight, wherein: potassium hydroxide 40, white oil 6, α-sodium olefin sulfonate 2, stone flour 3, soda ash 26, Sodium peroxoborate 15, Surchlor GR 60 4.
In relatively airtight feed proportioning system, drop into potassium hydroxide, then add white oil, mix thoroughly; Add again α-sodium olefin sulfonate, stone flour, soda ash, mix thoroughly; Add again Surchlor GR 60, mix thoroughly; Finally add Sodium peroxoborate, fully mix thoroughly, be up to the standards and can pack to obtain product.
It is below implementation result experimental example of the present invention.
effect experimental example 1: the oxidative stability alive of product
Test shows, product of the present invention has the oxidative stability of obviously living preferably.Store 90 days through high temperature (50 DEG C-20%RH) storage 90 days or hot and humid (40 DEG C-70%RH), product still has good oxygen conservation rate alive.Store 60 days oxygen alive with respect to the product of other inventions at high temperature (50 DEG C-20%RH) and lose totally, this product has obvious advantage, can support the longer shelf-lives of product and better use properties.Test result is in table 1.
The oxidative stability test result alive of table 1 pipe-dredging agent of the present invention and contrast product
effect experimental example 2: the anti-caking stability of product
Product splendid attire is carried out in packing bag to the test of high temperature (50 DEG C-20%RH) stability test, result shows that product of the present invention has good agglomeration preventing performance, and conglomeration caking phenomenon does not appear for 90 days in high temperature.Test result is in table 2.
The stability test result that table 2 product stores under high temperature (50 DEG C-20%RH) condition
| Sample title | 30 days | 60 days | 90 days |
| Embodiment 2 | Loose without caking | Loose without caking | Loose without caking |
| Embodiment 3 | Loose without caking | Loose without caking | Loose without caking |
| Contrast product 1 | Loose without caking | Loose without caking | Bottom connects agglomerate |
| Contrast product 2 | Loose without caking | Loose without caking | Bottom connects agglomerate |
effect experimental example 3: the dust of product
Test shows product of the present invention in use, and the dust of generation and the nose sense of choking are obviously lighter than the product of other inventions.
effect experimental example 4: other performances of product
Contrast test shows, the dissolution rate of product, bacteria-eliminating efficacy, decontamination dredging effect are all better than contrast product, and the corrodibility of product to pipeline quite (is all corroded without obvious) with contrast product, and these performances show some main product being obviously better than on the market.
In sum, pipe-dredging agent of the present invention has good oxidative stability alive, and dust is little, and dredging clean effect is good.Product simultaneously of the present invention dissolves quick and stable, active oxygen degerming safety and environmental protection, also can not produce the hydrogen that fires hidden danger, can not cause the problems such as plastic cement pipe deforming gets loose, and its production technique is simple, and cost is low, has good application prospect.
The above, it is only preferred embodiment of the present invention, not the present invention is done to any pro forma restriction, do not depart from technical solution of the present invention content therefore every, any simple modification, equivalent variations and the modification above embodiment done according to technical spirit of the present invention, all still belong in the scope of technical solution of the present invention.
Claims (10)
1. a pipe-dredging agent with the stable oxygen effect of living, is characterized in that: its formula material component comprises that highly basic, non-volatile liquid, extraordinary powder, oxygen float agent, chlorine floats agent; Can further comprise auxiliary agent.
2. the pipe-dredging agent with the stable oxygen effect of living according to claim 1, it is characterized in that: by weight percentage, its feed composition comprises that highly basic 40～85%, non-volatile liquid 0.5～8%, extraordinary powder 1～40%, oxygen float agent 5～30%, chlorine floats agent 1～8%, auxiliary agent surplus.
3. the pipe-dredging agent with the stable oxygen effect of living according to claim 1, is characterized in that: described highly basic is that purity is not less than 85% technical grade sodium hydroxide or potassium hydroxide; It is the particulate state of median size 0.3～3.5mm or the sheet of median size 0.5～15mm.
4. the pipe-dredging agent with the stable oxygen effect of living according to claim 1, is characterized in that: described non-volatile liquid is one or more composite in C8-C40 alkane, C5-C20 fatty alcohol, vegetables oil, animal oil, polydimethylsiloxane.
5. the pipe-dredging agent with the stable oxygen effect of living according to claim 4, is characterized in that: described its fusing point of non-volatile liquid is not higher than 35 DEG C, and boiling point is not less than 150 DEG C, and moisture content is not higher than 5%.
6. the pipe-dredging agent with the stable oxygen effect of living according to claim 1, it is characterized in that: described extraordinary powder is one or more composite in sodium alkyl benzene sulfonate, α-sodium olefin sulfonate, sodium alkyl sulfate, soap powder, Xylo-Mucine, stone flour, talcum powder, soda ash, and its outward appearance is powdery.
7. the pipe-dredging agent with the stable oxygen effect of living according to claim 1, is characterized in that: it is one or more composite in SPC-D, peroxosulphuric sodium, Sodium peroxoborate that described oxygen floats agent, is solid particulate or Powdered.
8. the pipe-dredging agent with the stable oxygen effect of living according to claim 1, is characterized in that: it is one or more composite in Surchlor GR 60, sodium trichloro-isocyanurate, Losantin that described chlorine floats agent, is solid granular or Powdered.
9. the pipe-dredging agent with the stable oxygen effect of living according to claim 1, is characterized in that: it is composite that described auxiliary agent comprises one or more in sodium sulfate, sodium-chlor, water glass, Starso, silicon-dioxide, zeolite, clay, wilkinite, diatomite, tripoly phosphate sodium STPP, Trisodium Citrate, ethylenediamine tetraacetic acid (EDTA) or its salt, 1-Hydroxy Ethylidene-1,1-Diphosphonic Acid or its salt, tetraacetyl ethylene diamine, triclocarban, colored particle, essence.
10. the preparation method of the pipe-dredging agent with the stable oxygen effect of living described in any one in claim 1-9, is characterized in that: in relatively airtight feed proportioning system, drop into highly basic, then add non-volatility liquid, mix thoroughly; Add again extraordinary powder, mix thoroughly; Add again chlorine to float agent and auxiliary agent, mix thoroughly; Finally add oxygen to float agent, fully mix thoroughly, be up to the standards and can pack to obtain product.
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| CN201410146096.2A CN103937624B (en) | 2014-04-11 | 2014-04-11 | It is a kind of have stablize pipe-dredging agent of ozone effect and preparation method thereof |
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| CN201410146096.2A CN103937624B (en) | 2014-04-11 | 2014-04-11 | It is a kind of have stablize pipe-dredging agent of ozone effect and preparation method thereof |
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| CN104479928A (en) * | 2014-11-24 | 2015-04-01 | 成都顺发消洗科技有限公司 | Drainage pipe detergent for cleaning tool |
| CN104560460A (en) * | 2015-01-27 | 2015-04-29 | 重庆莘苒化工科技有限公司 | High-efficiency descaling agent |
| CN104694286A (en) * | 2015-02-28 | 2015-06-10 | 江苏高科物流科技股份有限公司 | Pipe dredging agent |
| CN104911045A (en) * | 2015-05-15 | 2015-09-16 | 储顺庆 | Pipe curing agent |
| CN105112171A (en) * | 2015-06-13 | 2015-12-02 | 周彩球 | Sewer cleaning agent |
| CN105199883A (en) * | 2015-10-24 | 2015-12-30 | 黄宇松 | Cleaning gel for flushing closestool and preparation method thereof |
| CN105623932A (en) * | 2016-01-29 | 2016-06-01 | 安徽三环水泵有限责任公司 | Regular pump washing agent for domestic sewage pipeline pumps |
| CN105624692A (en) * | 2016-01-29 | 2016-06-01 | 安徽三环水泵有限责任公司 | Pump washing agent for regularly washing dyeing wastewater pipeline pump |
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| CN104479928A (en) * | 2014-11-24 | 2015-04-01 | 成都顺发消洗科技有限公司 | Drainage pipe detergent for cleaning tool |
| CN104560460A (en) * | 2015-01-27 | 2015-04-29 | 重庆莘苒化工科技有限公司 | High-efficiency descaling agent |
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| CN104911045A (en) * | 2015-05-15 | 2015-09-16 | 储顺庆 | Pipe curing agent |
| CN105112171A (en) * | 2015-06-13 | 2015-12-02 | 周彩球 | Sewer cleaning agent |
| CN105199883A (en) * | 2015-10-24 | 2015-12-30 | 黄宇松 | Cleaning gel for flushing closestool and preparation method thereof |
| CN105733863A (en) * | 2016-01-29 | 2016-07-06 | 安徽三环水泵有限责任公司 | Oilfield sewage pipeline pump periodical pump washing agent |
| CN105624692A (en) * | 2016-01-29 | 2016-06-01 | 安徽三环水泵有限责任公司 | Pump washing agent for regularly washing dyeing wastewater pipeline pump |
| CN105623932A (en) * | 2016-01-29 | 2016-06-01 | 安徽三环水泵有限责任公司 | Regular pump washing agent for domestic sewage pipeline pumps |
| CN105624692B (en) * | 2016-01-29 | 2018-06-29 | 安徽三环水泵有限责任公司 | A kind of dyeing and printing sewage pipeline pump periodically pumps lotion |
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| CN106635438A (en) * | 2016-09-22 | 2017-05-10 | 长兴净安环保科技有限公司 | Powdered pipeline dredge agent and preparation method thereof |
| CN106675803A (en) * | 2016-12-21 | 2017-05-17 | 江西宜信堂医疗科技有限公司 | Liquid-stage pipeline drainage agent and preparation method thereof |
| CN106635455A (en) * | 2016-12-24 | 2017-05-10 | 叶宗耀 | Liquid pipeline dredging agent and production method thereof |
| CN107937175A (en) * | 2017-11-08 | 2018-04-20 | 深圳市前海荣格生物技术有限公司 | A kind of thick pipe-dredging agent composition of strong basicity and preparation method thereof |
| CN109652217A (en) * | 2019-01-17 | 2019-04-19 | 湖北煜韩环境科技有限公司 | A kind of pipe-dredging agent that ozone sterilization eliminates the unusual smell |
| CN110923074A (en) * | 2019-11-29 | 2020-03-27 | 陕西速源节能科技有限公司 | Pipeline dredging cleaning agent and preparation method thereof |
| CN114181789A (en) * | 2020-09-12 | 2022-03-15 | 大城县宇昊卫生用品有限公司 | Pipeline dredging agent with strong oxidizing property |
| CN112616852A (en) * | 2020-12-09 | 2021-04-09 | 青岛桥成消毒净化工程有限公司 | Formula of sterilizing and cleaning preparation for drinking water pipelines of farm and preparation method thereof |
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