CN103928551A - Heterogeneous double-face fluorine-containing solar battery backboard - Google Patents

Heterogeneous double-face fluorine-containing solar battery backboard Download PDF

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Publication number
CN103928551A
CN103928551A CN201310007990.7A CN201310007990A CN103928551A CN 103928551 A CN103928551 A CN 103928551A CN 201310007990 A CN201310007990 A CN 201310007990A CN 103928551 A CN103928551 A CN 103928551A
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CN
China
Prior art keywords
fluorine
heterogeneous
adhesive
solar cell
type solar
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201310007990.7A
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Chinese (zh)
Inventor
薛济萍
王强
姚元毅
蒋贤明
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhong Tian Photovoltaic Materials Co Ltd
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Zhong Tian Photovoltaic Materials Co Ltd
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Publication date
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Priority to CN201310007990.7A priority Critical patent/CN103928551A/en
Publication of CN103928551A publication Critical patent/CN103928551A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/10Interconnection of layers at least one layer having inter-reactive properties
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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  • Laminated Bodies (AREA)
  • Photovoltaic Devices (AREA)

Abstract

The invention discloses a heterogeneous double-face fluorine-containing solar battery backboard comprising a fluorine film, an adhesive layer, a thin film layer, a primary coat and a coating layer connected in sequence. The fluorine film is a polyvinylidene fluoride film or a polyvinyl fluoride film; the adhesive layer is a polyurethane two-component adhesive; the thin film layer is a PET film; the primary coat is a polyurethane adhesive; and the coating layer is a coating paint formed by dispersing base resin and microparticles like polytetrafluoroethylene or polyvinylidene fluoride in a solvent. The invention also discloses a production technology thereof. The adhesive and a primary paint are applied on two surfaces of the thin film layer respectively, and the fluorine film and the coating layer are finally formed on the adhesive and the primary paint. The heterogeneous double-face fluorine-containing solar battery backboard combines a conventional compound type backboard with a coating type backboard, is low in production cost, alleviates aging speed, improves effective service life of the backboard, and simultaneously improves bonding intensity with an EVA backboard glue film.

Description

A kind of heterogeneous two-sided fluorine-containing type solar cell backboard
Technical field
The present invention relates to a kind of solar cell photovoltaic assembly, be specifically related to a kind of heterogeneous two-sided fluorine-containing type solar cell backboard.
Background technology
Solar cell backboard in the market mainly contains application type and compound two large classes, compound backboard belongs to the advantages such as technology maturation, ageing-resistant performance be good, but its cost is high, main raw material(s) source limited (import), exists and low, the unsettled weakness of solar module packaging adhesive film caking property simultaneously; And application type backboard has certain price (cost) advantage, production technology simple, but its permanence operation is poor, and especially large at ultraviolet irradiation intensity or wind less larger its shortcoming of region is completely exposed.For guaranteeing that backboard possesses certain ageing-resistant performance, reduce costs simultaneously, there is one side fluorine film back plate design, the more two-sided fluorine-containing type of its weather resistance is poor, can not meet the long-term use in district badly of outdoor weather.
Summary of the invention
Goal of the invention: the object of the invention is in order to solve deficiency of the prior art, provide that a kind of production cost is low, the heterogeneous two-sided fluorine-containing type solar cell backboard of long service life.
Technical scheme: a kind of heterogeneous two-sided fluorine-containing type solar cell backboard of the present invention, described backboard comprises fluorine rete, adhesive layer, thin layer, priming coat and the coat connecting successively.
As preferably, described fluorine rete is polyvinylidene fluoride film or pvf film.
As preferably, the thickness of described fluorine rete is 20-30 micron.
As preferably, described adhesive layer is polyurethane bicomponent adhesive.
As preferably, the thickness of described adhesive layer is 5-30 micron.
As preferably, described thin layer is pet film, and the thickness of described thin layer is 100-400 micron.
As preferably, described priming coat is class adhesive for polyurethane, and the thickness of described priming coat is 5-30 micron.
As preferably, described coat is that the molecule of polytetrafluoroethylene or Kynoar is dispersed in the coating coating forming in solvent together with base resin.
As preferably, the thickness of described coat is 10-40 micron.
The invention also discloses a kind of method of manufacturing above-mentioned heterogeneous two-sided fluorine-containing type solar cell backboard, comprise the steps:
A. the one side at thin layer is coated with last layer adhesive, after gluing completes, is dried;
B. compound one deck fluorine rete on the adhesive of steps A, carries out rolling after compound, forms semi-finished product;
C. step B gained semi-finished product are carried out to precuring;
D. the another side of the half-finished thin layer after above-mentioned solidify is smeared bottom-coating, forms priming coat, is dried after smearing end;
E. on priming coat, be coated with fluoro-containing coating, coating is dried after finishing, rolling, cutting edge, go to give up, and finally carries out product inspection, packing shipment.
Beneficial effect: the present invention combines traditional compound and application type backboard, and production cost is low, slows down aging speed, has improved the Acceptable life of backboard, has improved the adhesion strength with EVA backboard glued membrane simultaneously.
Accompanying drawing explanation
Fig. 1 is the sectional structure chart of backboard of the present invention.
Fig. 2 is the production technological process of a face of the present invention.
Fig. 3 is the production technological process of another face of the present invention.
Embodiment
Below in conjunction with accompanying drawing, the present invention will be further described:
A kind of heterogeneous two-sided fluorine-containing type solar cell backboard as shown in Figure 1, backboard comprises the fluorine rete 1 connecting successively, adhesive layer 2, thin layer 3, priming coat 4 and coat 5, wherein fluorine rete is polyvinylidene fluoride film or pvf film, the thickness of fluorine rete is 20-30 micron, adhesive layer is polyurethane bicomponent adhesive, the thickness of adhesive layer is 5-30 micron, thin layer is pet film, the thickness of thin layer is 100-400 micron, priming coat is class adhesive for polyurethane, the thickness of priming coat is 5-30 micron, coat is that the molecule of polytetrafluoroethylene or Kynoar is dispersed in the coating coating forming in solvent together with base resin, the thickness of coat is 10-40 micron.
The method of the above-mentioned heterogeneous two-sided fluorine-containing type solar cell backboard of manufacture as shown in Figures 2 and 3, comprises the steps:
A. the one side at thin layer 3 is coated with last layer adhesive, after gluing completes, is dried;
B. compound one deck fluorine rete 1 on the adhesive of steps A, carries out rolling after compound, forms semi-finished product;
C. step B gained semi-finished product are carried out to precuring;
D. the another side of the half-finished thin layer 3 after above-mentioned solidify is smeared bottom-coating, forms priming coat 4, is dried after smearing end;
E. on priming coat, be coated with fluoro-containing coating, coating is dried after finishing, rolling, cutting edge, go to give up, and finally carries out product inspection, packing shipment.
The present invention has following outstanding advantages:
A. PVDF or PVF thin layer are placed on to outside, accept the destruction of external environment, coat is placed on to innermost layer, to improve the adhesion strength with EVA glued membrane;
B. application type layer contains fluorine atom, weatherability aspect is better than PEVA film certainly, in addition coated side has a large amount of tiny pin holes, the interior heat that can guarantee cell panel is outwards discharged, in addition because EVA glued membrane self thermal stability causes after aging again crosslinked and decompose, the little molecule meeting corrosion cell plate producing, gets rid of therefore the larger permeability of coated side can guarantee these little molecules;
C. in order to meet the requirement of 25 years useful life, only have at present KPK type composite back plate energy up to standard, and PEVA film main component is polyethylene in KPE backboard, ultraviolet ageing speed is fast, PET protection duration to internal layer is shorter, this has directly caused the useful life of backboard short, yet the destruction that fluorine-containing coating to a certain extent can block ultraviolet has been slowed down rate of ageing;
D. the whole world constantly reduction storm make the survival ability of photovoltaic industry more and more lower, become for survival basic meeting price under the prerequisite of instructions for use, and coat is lower compared with PVDF film price.

Claims (10)

1. a heterogeneous two-sided fluorine-containing type solar cell backboard, is characterized in that: described backboard comprises fluorine rete (1), adhesive layer (2), thin layer (3), priming coat (4) and the coat (5) connecting successively.
2. a kind of heterogeneous two-sided fluorine-containing type solar cell backboard according to claim 1, is characterized in that: described fluorine rete (1) is polyvinylidene fluoride film or pvf film.
3. a kind of heterogeneous two-sided fluorine-containing type solar cell backboard according to claim 1, is characterized in that: the thickness of described fluorine rete (1) is 20-30 micron.
4. a kind of heterogeneous two-sided fluorine-containing type solar cell backboard according to claim 1, is characterized in that: described adhesive layer (2) is polyurethane bicomponent adhesive.
5. a kind of heterogeneous two-sided fluorine-containing type solar cell backboard according to claim 1, is characterized in that: the thickness of described adhesive layer (2) is 5-30 micron.
6. a kind of heterogeneous two-sided fluorine-containing type solar cell backboard according to claim 1, is characterized in that: described thin layer (3) is pet film, and the thickness of described thin layer (3) is 100-400 micron.
7. a kind of heterogeneous two-sided fluorine-containing type solar cell backboard according to claim 1, is characterized in that: described priming coat (4) is class adhesive for polyurethane, and the thickness of described priming coat (4) is 5-30 micron.
8. a kind of heterogeneous two-sided fluorine-containing type solar cell backboard according to claim 1, is characterized in that: described coat (5) is that the molecule of polytetrafluoroethylene or Kynoar is dispersed in the coating coating forming in solvent together with base resin.
9. a kind of heterogeneous two-sided fluorine-containing type solar cell backboard according to claim 1, is characterized in that: the thickness of described coat (5) is 10-40 micron.
10. manufacture a method for above-mentioned heterogeneous two-sided fluorine-containing type solar cell backboard, it is characterized in that: comprise the steps:
A. the one side at thin layer (3) is coated with last layer adhesive, after gluing completes, is dried;
B. compound one deck fluorine rete (1) on the adhesive of steps A, carries out rolling after compound, forms semi-finished product;
C. step B gained semi-finished product are carried out to precuring;
D. the another side of the half-finished thin layer (3) after above-mentioned solidify is smeared bottom-coating, forms priming coat (4), is dried after smearing end;
E. on priming coat, be coated with fluoro-containing coating, coating is dried after finishing, rolling, cutting edge, go to give up, and finally carries out product inspection, packing shipment.
CN201310007990.7A 2013-01-10 2013-01-10 Heterogeneous double-face fluorine-containing solar battery backboard Pending CN103928551A (en)

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Cited By (37)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105720124A (en) * 2015-09-16 2016-06-29 中天光伏材料有限公司 Glue-free solar battery backboard and preparation method
CN105977347A (en) * 2016-07-27 2016-09-28 无锡中洁能源技术有限公司 High-reflective-coating solar backboard manufacturing process
CN106024953A (en) * 2016-07-27 2016-10-12 无锡中洁能源技术有限公司 Solar energy backboard with high-reflectivity coating layer
CN106024952A (en) * 2016-07-27 2016-10-12 无锡中洁能源技术有限公司 Solar energy backboard with transparent coating layer
CN106024942A (en) * 2016-07-27 2016-10-12 无锡中洁能源技术有限公司 Fluorine-containing solar cell backboard
CN106024993A (en) * 2016-07-29 2016-10-12 无锡中洁能源技术有限公司 Production technology for high-heat-dissipation dirt-resistant solar energy backboard
CN106057978A (en) * 2016-07-29 2016-10-26 无锡中洁能源技术有限公司 Production technology of solar backboard with high heat dissipation performance
CN106057977A (en) * 2016-07-29 2016-10-26 无锡中洁能源技术有限公司 Production technology of solar backboard with high reflection performance
CN106057946A (en) * 2016-07-27 2016-10-26 无锡中洁能源技术有限公司 Method of producing fluorine-containing solar backboard
CN106057948A (en) * 2016-07-29 2016-10-26 无锡中洁能源技术有限公司 Production process of multilayer solar energy backboard
CN106129179A (en) * 2016-07-28 2016-11-16 无锡中洁能源技术有限公司 A kind of production technology of hydrolysis solar energy backboard
CN106129178A (en) * 2016-07-27 2016-11-16 无锡中洁能源技术有限公司 A kind of production technology from solar energy backboard of lowering the temperature
CN106159039A (en) * 2016-07-27 2016-11-23 无锡中洁能源技术有限公司 A kind of production technology with clear coat solar energy backboard
CN106159016A (en) * 2016-08-27 2016-11-23 无锡中洁能源技术有限公司 A kind of production technology of high-efficiency solar backboard
CN106206846A (en) * 2016-07-29 2016-12-07 无锡中洁能源技术有限公司 A kind of production technology of self-cleaning solar energy backboard
CN106206843A (en) * 2016-07-28 2016-12-07 无锡中洁能源技术有限公司 A kind of production technology of high water vapor transmittance solar energy backboard
CN106206844A (en) * 2016-07-28 2016-12-07 无锡中洁能源技术有限公司 A kind of production technology of weather-proof high thermal conductivity solar energy backboard
CN106206804A (en) * 2016-08-27 2016-12-07 无锡中洁能源技术有限公司 A kind of production technology of organic insulation type solar energy backboard
CN106206842A (en) * 2016-07-26 2016-12-07 无锡中洁能源技术有限公司 A kind of production technology of high-insulativity solar cell backboard
CN106206851A (en) * 2016-08-27 2016-12-07 无锡中洁能源技术有限公司 A kind of production technology of application type solar energy backboard
CN106206791A (en) * 2016-08-27 2016-12-07 无锡中洁能源技术有限公司 A kind of production technology with high-cooling property solar cell backboard
CN106206799A (en) * 2016-07-28 2016-12-07 无锡中洁能源技术有限公司 A kind of production technology of the solar energy of resistance to scraped finish backboard
CN106206802A (en) * 2016-08-27 2016-12-07 无锡中洁能源技术有限公司 A kind of production technology of quake-proof type solar energy backboard
CN106206852A (en) * 2016-08-27 2016-12-07 无锡中洁能源技术有限公司 A kind of production technology of high mechanical properties solar energy backboard
CN106229380A (en) * 2016-08-27 2016-12-14 无锡中洁能源技术有限公司 A kind of production technology of band coating solar energy backboard
CN106229374A (en) * 2016-07-27 2016-12-14 无锡中洁能源技术有限公司 Solar cell backboard production technology
CN106252461A (en) * 2016-08-27 2016-12-21 无锡中洁能源技术有限公司 A kind of production technology of resist processing solar energy backboard
CN106299005A (en) * 2016-08-27 2017-01-04 无锡中洁能源技术有限公司 A kind of quake-proof type solar energy backboard
CN106328762A (en) * 2016-08-27 2017-01-11 无锡中洁能源技术有限公司 Process for producing self-cooling solar back plate
CN106328745A (en) * 2016-08-27 2017-01-11 无锡中洁能源技术有限公司 Solar back plate with high mechanical strength
CN106328761A (en) * 2016-08-27 2017-01-11 无锡中洁能源技术有限公司 Process for producing environment-friendly solar cell back plate
CN106328744A (en) * 2016-08-27 2017-01-11 无锡中洁能源技术有限公司 Solar cell back plate with high heat dissipation performance
CN106328760A (en) * 2016-08-27 2017-01-11 无锡中洁能源技术有限公司 Process for producing solar cell back plate with low cost
CN106409950A (en) * 2016-07-29 2017-02-15 无锡中洁能源技术有限公司 Production technology of pollution-resistant solar backboard
CN106393928A (en) * 2016-08-27 2017-02-15 无锡中洁能源技术有限公司 Production technology of moisture absorption type solar backboard
CN107591458A (en) * 2017-08-31 2018-01-16 合肥风生水起信息科技有限公司 A kind of novel fluorine solar panel backboard and preparation method thereof
CN108336031A (en) * 2018-02-12 2018-07-27 崔金益 A kind of power module package structure

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CN102637763A (en) * 2012-05-08 2012-08-15 江苏科技大学 Solar cell backboard with excellent weathering resistance and preparation method thereof
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CN105720124A (en) * 2015-09-16 2016-06-29 中天光伏材料有限公司 Glue-free solar battery backboard and preparation method
CN106206842A (en) * 2016-07-26 2016-12-07 无锡中洁能源技术有限公司 A kind of production technology of high-insulativity solar cell backboard
CN106024952A (en) * 2016-07-27 2016-10-12 无锡中洁能源技术有限公司 Solar energy backboard with transparent coating layer
CN106024942A (en) * 2016-07-27 2016-10-12 无锡中洁能源技术有限公司 Fluorine-containing solar cell backboard
CN106229374A (en) * 2016-07-27 2016-12-14 无锡中洁能源技术有限公司 Solar cell backboard production technology
CN106024953A (en) * 2016-07-27 2016-10-12 无锡中洁能源技术有限公司 Solar energy backboard with high-reflectivity coating layer
CN106057946A (en) * 2016-07-27 2016-10-26 无锡中洁能源技术有限公司 Method of producing fluorine-containing solar backboard
CN105977347A (en) * 2016-07-27 2016-09-28 无锡中洁能源技术有限公司 High-reflective-coating solar backboard manufacturing process
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CN106057948A (en) * 2016-07-29 2016-10-26 无锡中洁能源技术有限公司 Production process of multilayer solar energy backboard
CN106409950A (en) * 2016-07-29 2017-02-15 无锡中洁能源技术有限公司 Production technology of pollution-resistant solar backboard
CN106206846A (en) * 2016-07-29 2016-12-07 无锡中洁能源技术有限公司 A kind of production technology of self-cleaning solar energy backboard
CN106024993A (en) * 2016-07-29 2016-10-12 无锡中洁能源技术有限公司 Production technology for high-heat-dissipation dirt-resistant solar energy backboard
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CN106252461A (en) * 2016-08-27 2016-12-21 无锡中洁能源技术有限公司 A kind of production technology of resist processing solar energy backboard
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CN106206802A (en) * 2016-08-27 2016-12-07 无锡中洁能源技术有限公司 A kind of production technology of quake-proof type solar energy backboard
CN106328745A (en) * 2016-08-27 2017-01-11 无锡中洁能源技术有限公司 Solar back plate with high mechanical strength
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CN106328761A (en) * 2016-08-27 2017-01-11 无锡中洁能源技术有限公司 Process for producing environment-friendly solar cell back plate
CN106328760A (en) * 2016-08-27 2017-01-11 无锡中洁能源技术有限公司 Process for producing solar cell back plate with low cost
CN106206851A (en) * 2016-08-27 2016-12-07 无锡中洁能源技术有限公司 A kind of production technology of application type solar energy backboard
CN106393928A (en) * 2016-08-27 2017-02-15 无锡中洁能源技术有限公司 Production technology of moisture absorption type solar backboard
CN107591458A (en) * 2017-08-31 2018-01-16 合肥风生水起信息科技有限公司 A kind of novel fluorine solar panel backboard and preparation method thereof
CN107591458B (en) * 2017-08-31 2020-02-14 陈德言 Novel fluorine-containing solar cell panel back plate and preparation method thereof
CN108336031A (en) * 2018-02-12 2018-07-27 崔金益 A kind of power module package structure
CN108336031B (en) * 2018-02-12 2019-11-01 南通鸿图健康科技有限公司 A kind of power module package structure

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