CN103923772A - Activated carbon toilet cleaner and preparation method thereof - Google Patents
Activated carbon toilet cleaner and preparation method thereof Download PDFInfo
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- CN103923772A CN103923772A CN201410181029.4A CN201410181029A CN103923772A CN 103923772 A CN103923772 A CN 103923772A CN 201410181029 A CN201410181029 A CN 201410181029A CN 103923772 A CN103923772 A CN 103923772A
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Abstract
The invention discloses an activated carbon toilet cleaner and a preparation method thereof. The activated carbon toilet cleaner comprises the following components in percentage by weight: 15-50% of activated carbon (powdery coal activated carbon in particular), 8-20% of sodium stearate, 2-10% of sodium silicate, 10-18% of sodium dodecyl benzene sulfonate and 3-8% of sodium bicarbonate. The preparation method mainly comprises the steps of mixing, stirring, cooling, molding and drying. The greases, dirt, off-flavors and the like of a toilet bowl can be effectively eliminated by using the strong adsorption performance of the activated carbon. Compared with a conventional toilet cleaner, the activated carbon toilet cleaner is more convenient, more effective and faster, has a good slow-release effect, is simple in formula, low in construction cost, high in reproducibility, safe and environment-friendly, and has a certain water purification function.
Description
Technical field
The invention belongs to activated carbon application field, be specifically related to a kind of gac toilet cleaner and preparation method thereof.
Background technology
Coal mass active carbon is widely used in industrial or agricultural each side, as the alkali-free sweetening of petrochemical industry, ethene de-salted water (refining filler), support of the catalyst (palladium, platinum, rhodium etc.), water purify and sewage disposal; Power plant's water conditioning and the protection of power industry; The decolouring of the chemical catalyst of chemical industry and carrier, gas sweetening, solvent recuperation and grease etc., refining; The decolouring of the beverage of food service industry, brewery, sodium glutamate mother liquid and food; The gold of gold industry extracts, tail washings reclaims; The sewage disposal of environmental protection industry (epi) and the improvement of obnoxious flavour, purification; And the cigaratte filter of relevant industries, timber floor moistureproof, inhale taste etc.
Now widely used traditional toilet cleaner mainly be take cleaning as main, exists weak point, cannot remove grease and dirt comprehensively, be difficult to eliminate peculiar smell, and be easily decomposed into particulate matter and swept away by water, do not have the effect of slowly-releasing, the effect that can make scale removal deodorize is like this not satisfactory.
Summary of the invention
In view of this, the object of the present invention is to provide that a kind of to receive dirt, taste removal effective, there is gac toilet cleaner of slowly releasing effect and preparation method thereof.
For achieving the above object, the invention provides following technical scheme: a kind of gac toilet cleaner, comprise gac, sodium stearate, water glass, Sodium dodecylbenzene sulfonate and sodium bicarbonate, wherein gac is powdery coal mass active carbon, content accounts for 15～50%, and the content of sodium stearate accounts for 8-20%, and the content of water glass accounts for 2-10%, the content of Sodium dodecylbenzene sulfonate accounts for 10-18%, and the content of sodium bicarbonate accounts for 3-8%.
Further, also comprise polyoxyethylene glycol, diethyl phthalate and essence, wherein the content of polyoxyethylene glycol accounts for 10-20%.
Further, also comprise box body, in described box body, be divided into six sectors, wherein in four sectors, fill the mixing briquetting material I mainly being formed by sodium stearate, water glass, Sodium dodecylbenzene sulfonate, sodium bicarbonate, polyoxyethylene glycol and diethyl phthalate, remain the mixing briquetting material II that in two sectors, filling is mainly comprised of gac and polyoxyethylene glycol.
Further, described mixing briquetting material II interval is filled in and mixes between briquetting material I.
A preparation method for gac toilet cleaner, is characterized in that mainly comprising the following steps:
(1) powdery coal mass active carbon 15～50%, sodium stearate 8-20%, water glass 2-10%, Sodium dodecylbenzene sulfonate 10-18% and sodium bicarbonate 3-8% are mixed, stir 5-10 minute;
(2) add again diethyl phthalate and essence, stir 3-5 minute;
(3) heating and melting polyoxyethylene glycol, pours in the mixture of step (2) gained, continues to be uniformly mixed;
(4) after cooling, extrusion molding, dry.
The content of the polyoxyethylene glycol further, adding in described step (3) is 10-20%.
Further, when mixture is cooled to 40-60 ℃ in described step (4), push again, reshaping while continuing to be cooled to 20-30 ℃, dry.
A preparation method for gac toilet cleaner, is characterized in that mainly comprising the following steps:
(1), by sodium stearate 8-20%, water glass 2-10%, Sodium dodecylbenzene sulfonate 10-18%, sodium bicarbonate 3-8%, diethyl phthalate and essence, stir it is mixed;
(2) in the mixture of step (1) gained, add the polyoxyethylene glycol through heating and melting, mix rear cooling; In powdery coal mass active carbon, add the polyoxyethylene glycol through heating and melting, mix rear cooling;
(3) while two kinds of mixed solutions of gained in step (2) being cooled to 40-60 ℃, corresponding each sector of injecting box body, continues cooling;
(4) moulding when two kinds of mixed solutions are cooled to 20-30 ℃, dries.
Beneficial effect of the present invention is: take coal mass active carbon as raw material, add stronger other of stability batching simultaneously, utilize the strong absorption property of gac, effectively remove the grease, dirt, peculiar smell of closet etc.; Compare with traditional toilet cleaner, more convenient effectively quick, had good sustained release effect; Formula is simple, and cheap, reproducibility is strong; Safety and environmental protection, the stable in properties of gac and without other toxic side effect, not can with other composition generation chemical reactions, with thering is certain water purification function after water discharge.
Embodiment
To be described in detail the preferred embodiments of the present invention below.
Gac toilet cleaner of the present invention, comprises powdery coal mass active carbon 15～50%, sodium stearate 8-20%, water glass 2-10%, Sodium dodecylbenzene sulfonate 10-18%, sodium bicarbonate 3-8%; Gac has abundant pore texture, has good absorption property, and easily repeated regeneration, cheap; Add 10-20% polyoxyethylene glycol, appropriate diethyl phthalate and a small amount of essence simultaneously, be convenient to condense into blocks, in slowly-releasing, clean, degerming, absorption, discharge fragrance.
The preparation method of above-mentioned this kind of gac toilet cleaner mainly comprises the following steps:
(1) powdery coal mass active carbon 15～50%, sodium stearate 8-20%, water glass 2-10%, Sodium dodecylbenzene sulfonate 10-18% and sodium bicarbonate 3-8% are mixed, stir 5-10 minute;
(2) add again diethyl phthalate and essence, stir 3-5 minute;
(3) in the mixture of step (2) gained, add the polyoxyethylene glycol through heating and melting, the content of polyoxyethylene glycol accounts between the 10-20% of total umber, continues to be uniformly mixed; When thing to be mixed is cooled to 40-60 ℃, push again, reshaping while continuing to be cooled to 20-30 ℃, dry.
Certainly, also can carry out the improvement on morphological structure to above-mentioned toilet cleaner, the content of each composition is identical with the content of above-mentioned toilet cleaner, but array mode is distinguished to some extent, by a plastic box body, in described box body, be divided into six sectors, wherein in four sectors, fill mainly by sodium stearate, water glass, Sodium dodecylbenzene sulfonate, sodium bicarbonate, the mixing briquetting material I that polyoxyethylene glycol and diethyl phthalate form, remain the mixing briquetting material II that in two sectors, filling is mainly comprised of gac and polyoxyethylene glycol, wherein mixing briquetting material II interval is filled between mixing briquetting material I, guarantee that each material mixes in water, the higher situation of local certain material concentration of unlikely appearance, by the different sectors on box body, gac and other material are made a distinction, can avoid or prevent that gac from adsorbing in advance to part activeconstituents, after use, box body is reclaimed.
The preparation method of this kind of gac toilet cleaner mainly comprises the following steps:
(1), by sodium stearate 8-20%, water glass 2-10%, Sodium dodecylbenzene sulfonate 10-18%, sodium bicarbonate 3-8%, diethyl phthalate and essence, stir it is mixed;
(2) in the mixture of step (1) gained, add the polyoxyethylene glycol through heating and melting, mix rear cooling; In powdery coal mass active carbon, add the polyoxyethylene glycol through heating and melting, mix rear cooling;
(3) while two kinds of mixed solutions of gained in step (2) being cooled to 40-60 ℃, corresponding each sector of injecting box body, continues cooling;
(4) moulding when two kinds of mixed solutions are cooled to 20-30 ℃, dries.
Because this toilet cleaner is by box body splendid attire, therefore compare with the preparation method of the first toilet cleaner, can omit extrusion process.
Each component content of above-mentioned two kinds of gac toilet cleaners has the multiple mode of choosing, specific as follows:
Embodiment mono-
Powdery coal mass active carbon 26%, sodium stearate 18%, water glass 4%, Sodium dodecylbenzene sulfonate 18%, sodium bicarbonate 8%, essence 2%, diethyl phthalate 4%, polyoxyethylene glycol 20%.
Embodiment bis-
Powdery coal mass active carbon 20%, sodium stearate 20%, water glass 10%, Sodium dodecylbenzene sulfonate 18%, sodium bicarbonate 8%, essence 2%, diethyl phthalate 4%, polyoxyethylene glycol 18%.
Embodiment tri-
Powdery coal mass active carbon 25%, sodium stearate 16%, water glass 8%, Sodium dodecylbenzene sulfonate 18%, sodium bicarbonate 8%, essence 2%, diethyl phthalate 4%, polyoxyethylene glycol 19%.
Embodiment tetra-
Powdery coal mass active carbon 35%, sodium stearate 16%, water glass 9%, Sodium dodecylbenzene sulfonate 16%, sodium bicarbonate 6%, essence 2%, diethyl phthalate 4%, polyoxyethylene glycol 12%.
Embodiment five
Powdery coal mass active carbon 45%, sodium stearate 12%, water glass 10%, Sodium dodecylbenzene sulfonate 12%, sodium bicarbonate 5%, essence 2%, diethyl phthalate 4%, polyoxyethylene glycol 10%.
Embodiment six
Powdery coal mass active carbon 50%, sodium stearate 10%, water glass 6%, Sodium dodecylbenzene sulfonate 10%, sodium bicarbonate 3%, essence 2%, diethyl phthalate 4%, polyoxyethylene glycol 15%.
Finally explanation is, above preferred embodiment is only unrestricted in order to technical scheme of the present invention to be described, although the present invention is described in detail by above preferred embodiment, but those skilled in the art are to be understood that, can to it, make various changes in the form and details, and not depart from the claims in the present invention book limited range.
Claims (8)
1. a gac toilet cleaner, it is characterized in that: comprise gac, sodium stearate, water glass, Sodium dodecylbenzene sulfonate and sodium bicarbonate, wherein gac is powdery coal mass active carbon, content accounts for 15～50%, the content of sodium stearate accounts for 8-20%, the content of water glass accounts for 2-10%, and the content of Sodium dodecylbenzene sulfonate accounts for 10-18%, and the content of sodium bicarbonate accounts for 3-8%.
2. gac toilet cleaner according to claim 1, is characterized in that: also comprise polyoxyethylene glycol, diethyl phthalate and essence, wherein the content of polyoxyethylene glycol accounts for 10-20%.
3. according to the gac toilet cleaner described in claim 1-2 any one, it is characterized in that: also comprise box body, in described box body, be divided into six sectors, wherein in four sectors, fill the mixing briquetting material I mainly being formed by sodium stearate, water glass, Sodium dodecylbenzene sulfonate, sodium bicarbonate, polyoxyethylene glycol and diethyl phthalate, remain the mixing briquetting material II that in two sectors, filling is mainly comprised of gac and polyoxyethylene glycol.
4. gac toilet cleaner according to claim 3, is characterized in that: described mixing briquetting material II interval is filled in mixes between briquetting material I.
5. a preparation method for the gac toilet cleaner as described in claim 2, is characterized in that mainly comprising the following steps:
(1) powdery coal mass active carbon 15～50%, sodium stearate 8-20%, water glass 2-10%, Sodium dodecylbenzene sulfonate 10-18% and sodium bicarbonate 3-8% are mixed, stir 5-10 minute;
(2) add again diethyl phthalate and essence, stir 3-5 minute;
(3) heating and melting polyoxyethylene glycol, pours in the mixture of step (2) gained, continues to be uniformly mixed;
(4) after cooling, extrusion molding, dry.
6. the preparation method of gac toilet cleaner according to claim 5, is characterized in that: the content of the polyoxyethylene glycol adding in described step (3) is 10-20%.
7. the preparation method of gac toilet cleaner according to claim 5, is characterized in that: when mixture is cooled to 40-60 ℃ in described step (4), push again, reshaping while continuing to be cooled to 20-30 ℃, dry.
8. a preparation method for gac toilet cleaner as claimed in claim 4, is characterized in that mainly comprising the following steps:
(1), by sodium stearate 8-20%, water glass 2-10%, Sodium dodecylbenzene sulfonate 10-18%, sodium bicarbonate 3-8%, diethyl phthalate and essence, stir it is mixed;
(2) in the mixture of step (1) gained, add the polyoxyethylene glycol through heating and melting, mix rear cooling; In powdery coal mass active carbon, add the polyoxyethylene glycol through heating and melting, mix rear cooling;
(3) while two kinds of mixed solutions of gained in step (2) being cooled to 40-60 ℃, corresponding each sector of injecting box body, continues cooling;
(4) moulding when two kinds of mixed solutions are cooled to 20-30 ℃, dries.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410181029.4A CN103923772A (en) | 2014-04-30 | 2014-04-30 | Activated carbon toilet cleaner and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410181029.4A CN103923772A (en) | 2014-04-30 | 2014-04-30 | Activated carbon toilet cleaner and preparation method thereof |
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| CN103923772A true CN103923772A (en) | 2014-07-16 |
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| CN201410181029.4A Pending CN103923772A (en) | 2014-04-30 | 2014-04-30 | Activated carbon toilet cleaner and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105124754A (en) * | 2015-07-17 | 2015-12-09 | 云南中烟工业有限责任公司 | Non-polar spice carrying core for cigarettes and application of non-polar spice carrying core |
| CN105820884A (en) * | 2016-04-18 | 2016-08-03 | 河南大学 | Cheep, efficient and pollution-free sodium ferrate toilet cleaning antibacterial sustained-release material and preparation method thereof |
| CN115895796A (en) * | 2022-11-17 | 2023-04-04 | 江苏腾旷生物科技有限公司 | Environment-friendly acid-free toilet cleaning liquid |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1065289A (en) * | 1992-04-28 | 1992-10-14 | 抚顺石油学院 | Toilet cleaner |
| CN1124284A (en) * | 1994-09-30 | 1996-06-12 | 王翔 | Producing method for solid multifunctional cleaning agent |
| EP0912708B1 (en) * | 1996-05-17 | 2002-09-11 | S.C. Johnson & Son, Inc. | Toilet cleansing block |
| CN102382720A (en) * | 2011-09-21 | 2012-03-21 | 西安理工大学 | Toilet cleaning agent |
-
2014
- 2014-04-30 CN CN201410181029.4A patent/CN103923772A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1065289A (en) * | 1992-04-28 | 1992-10-14 | 抚顺石油学院 | Toilet cleaner |
| CN1124284A (en) * | 1994-09-30 | 1996-06-12 | 王翔 | Producing method for solid multifunctional cleaning agent |
| EP0912708B1 (en) * | 1996-05-17 | 2002-09-11 | S.C. Johnson & Son, Inc. | Toilet cleansing block |
| CN102382720A (en) * | 2011-09-21 | 2012-03-21 | 西安理工大学 | Toilet cleaning agent |
Non-Patent Citations (1)
| Title |
|---|
| 郑富源编译: "《合成洗涤剂生产技术》", 31 July 1996, 北京：中国轻工业出版社 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105124754A (en) * | 2015-07-17 | 2015-12-09 | 云南中烟工业有限责任公司 | Non-polar spice carrying core for cigarettes and application of non-polar spice carrying core |
| CN105124754B (en) * | 2015-07-17 | 2019-06-04 | 云南中烟工业有限责任公司 | A kind of cigarette nonpolar fragrance load core and application |
| CN105820884A (en) * | 2016-04-18 | 2016-08-03 | 河南大学 | Cheep, efficient and pollution-free sodium ferrate toilet cleaning antibacterial sustained-release material and preparation method thereof |
| CN115895796A (en) * | 2022-11-17 | 2023-04-04 | 江苏腾旷生物科技有限公司 | Environment-friendly acid-free toilet cleaning liquid |
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Application publication date: 20140716 |
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