CN103923559A - Paint with high ultraviolet and infrared ray shielding rates and preparation method thereof - Google Patents
Paint with high ultraviolet and infrared ray shielding rates and preparation method thereof Download PDFInfo
- Publication number
- CN103923559A CN103923559A CN201410188994.4A CN201410188994A CN103923559A CN 103923559 A CN103923559 A CN 103923559A CN 201410188994 A CN201410188994 A CN 201410188994A CN 103923559 A CN103923559 A CN 103923559A
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- ferrite
- blast
- powder
- furnace slag
- outside line
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Abstract
The invention discloses paint with high ultraviolet and infrared ray shielding rates and a preparation method of the paint. The paint comprises the following components by weight percent: 20-30% of alcohol, 2-3% of 2-hydroxy-4-octyloxy benzophenone, 1-3% of polyamide resin, 25-30% of ferrite composite powder, 5-8% of propylgallate and the balance of polyurethane. The paint has excellent ultraviolet and infrared electromagnetic energy attenuation effects, can be prepared without using a great deal of rare and precious elements, and adopts waste blast-furnace slag as raw material, is low in production raw material cost and simple in production process, and has very high application prospect.
Description
Technical field
The present invention relates to coating composition technical field, is a kind of high purplish red outside line shielding rate coating and preparation method thereof specifically.
Background technology
No. CN01102763.0 application relates to a kind of uvioresistant, infrared ray energy-saving coating.In this coating, add nano silicon NMSiO2-X.It is mainly by pure-acrylic emulsion or benzene emulsion, film coalescence aid, titanium dioxide, nanometer, dispersion agent, defoamer, mould inhibitor, flow agent, pigment, water composition, this coating can reflect ultraviolet ray, the infrared rays of the various wavelength of 75-80%, thereby can significantly reduce the destruction of ultraviolet ray to material, there is anti-aging, anti-losing lustre and heat insulation usefulness, save the consumption of energy.The problem that above-mentioned coating exists is that production cost is high, and the ultraviolet reflection degree of coating has much room for improvement, the demand of the higher anti-purplish red outside line requirement of can not satisfying the demand.
Summary of the invention
The object of the invention is for above-mentioned deficiency of the prior art, the purplish red outside line shielding rate of the height coating that low, the purplish red outside line shield effectiveness of a kind of cost is good is provided.
Another object of the present invention is to provide the preparation method of the purplish red outside line shielding rate of this height coating, and this preparation method's technique is simple, and production cost is low, is suitable for suitability for industrialized production.
The object of the invention is to be achieved through the following technical solutions:
A kind of high purplish red outside line shielding rate coating, the weight percent of each composition is: ethanol 20～30%, Octabenzone 2-3%, polyamide resin 1-3%, ferrite composite powder 25-30%, Tenox PG 5-8%, all the other are urethane;
Described ferrite composite powder is made up of by weight 1:0.2-0.4 ferrite doped calcium and blast-furnace slag, and wherein in ferrite doped calcium, the weight percent of each composition is ZnO3-13%, MnO30-40%, TiO
26-8%, CaCO
30.04-0.06%, Nb
2o
50.03-0.07%, SnO
2o.05-0.15%, Co
2o
3all the other are Fe for 0.01-0.03%
2o
3;
In described blast-furnace slag, the weight percent of each composition is CaO35-40%, Al
2o
312-15%, MgO7-9%, FeO0.3-0.5%, all the other SiO
2, the particle diameter of described ferrite composite powder is 150-170 micron.
The preparation method of the purplish red outside line shielding rate of above-mentioned height coating, comprises the following steps:
1) ferrite doped calcium powder is prepared
Each raw materials by weight: ZnO3-13%, MnO30-40%, TiO
26-8%, CaCO
30.04-0.06%, Nb
2o
50.03-0.07%, SnO
2o.05%, Co
2o
30.01-0.03%, all the other are Fe
2o
3prepare burden, each raw material is mixed in sand mill and carry out fragmentation, then at the temperature of 120-135 DEG C, dry, cross 180-200 mesh sieve, pre-burning 100-120 minute at the temperature of 930-980 DEG C, gained ferrite doped calcium after pre-burning is ground to form to ferrite doped calcium powder, and this diameter of particle is 500-700 micron;
2) blast-furnace slag powder is prepared
The blast-furnace slag of getting mentioned component grinds to form blast-furnace slag powder, and this diameter of particle is 500-700 micron;
3) prepare ferrite composite granule
According to the ratio of ferrite doped calcium and blast-furnace slag, the blast-furnace slag powder of the ferrite doped calcium powder of step (1) gained and step (2) gained is mixed, then at 1250-1300 DEG C of temperature, carry out sintering 4-5 hour, then pulverize and grind to form the ferrite composite powder that size is 150-170 micron;
4) prepare high purplish red outside line shielding rate coating
By each composition according to weight percent be: above-mentioned ferrite composite powder 25-30%, ethanol 20～30%, Octabenzone 2-3%, polyamide resin 1-3%, Tenox PG 5-8%, all the other mix for urethane, obtain high purplish red outside line shielding rate coating.
The purplish red outside line shielding rate of height of the present invention coating can be applied to the fields such as weaving, building, military affairs.
The present invention has following beneficial effect:
In the purplish red outside line shielding rate of height of the present invention coating, ferrite composite granule is made up of slag and the heterogeneous ferrite doped calcium of porous, has therefore formed many interfaces.These interfaces to ultraviolet ray reflect, reflection, scattering play strong effect.Ferric oxide in Octabenzone and ferrite doped calcium and slag, niobium oxides, cobalt oxide have the ultraviolet function of absorption.The effect that while ferrite doped calcium has strong attenuation electromagnetic energy has excellent ultraviolet and infra-red electromagnetic energy attenuation.Polyamide resin can play urethane cures.Tenox PG has antioxygenation, can reduce coating automatic oxidation reaction speed, delay paint aging degraded.
The purplish red outside line shielding rate of height of the present invention coating has excellent ultraviolet and infra-red electromagnetic energy attenuation and effect.In the present invention's preparation, not rare your element of a large amount of use, and adopt useless blast-furnace slag to do raw material, and raw materials for production cost is low, and preparation process condition is easy, and production process is simple, has very high application prospect.
Brief description of the drawings
Fig. 1 is that the purplish red outside line shielding rate of height coating prepared by the embodiment of the present invention one is coated in the organization chart on fabric;
As seen from the figure, homogeneous microstructure densification.
Embodiment
Below in conjunction with example, the invention will be further described: in following embodiment, in blast-furnace slag, the weight percent of each composition is CaO35-40%, Al
2o
312-15%, MgO7-9%, FeO0.3-0.5%, all the other SiO
2.
Embodiment mono-:
The high purplish red outside line shielding rate coating of the present invention, its preparation method is as follows:
1, ferrite doped calcium powder is prepared
Raw material weight per-cent is ZnO3%, MnO30%, TiO
28%, CaCO
30.06%, Nb
2o
50.07%, SnO
2o.05%, Co
2o
30.01%, all the other are Fe
2o
3the purity of each raw material is all greater than 99.9%, raw material is mixed in sand mill with fragmentation after at the temperature of 120 DEG C dry, cross 180 mesh sieves, then pre-burning 100 minutes at the temperature of 980 DEG C, grinds to form by gained ferrite doped calcium after pre-burning the ferrite doped calcium powder that particle diameter is 500-700 micron.
2, blast-furnace slag powder is prepared
Blast-furnace slag is ground to form to the blast-furnace slag powder that particle diameter is 500-700 micron.
3, prepare ferrite composite granule
Be 1:0.2 according to the weight ratio of ferrite doped calcium and blast-furnace slag, the blast-furnace slag powder of the ferrite doped calcium powder of step 1 gained and step 2 gained is mixed, then at 1300 DEG C of temperature, carry out sintering 5 hours, then pulverize and grind to form the ferrite composite powder that size is 150-170 micron.
4, prepare high purplish red outside line shielding rate coating
By each composition according to weight percent be: the ferrite composite powder 25% of step 3 gained, ethanol 20%, Octabenzone 2%, polyamide resin 1%, Tenox PG 5%, the ratio that all the other are urethane mix, and obtain high purplish red outside line shielding rate coating.
Embodiment bis-:
The high purplish red outside line shielding rate coating of the present invention, its preparation method is as follows:
1, ferrite doped calcium powder is prepared
Raw material weight per-cent is ZnO13%, MnO40%, TiO
26%, CaCO
30.04%, Nb
2o
50.03%, SnO
2o.15%, Co
2o
30.03%, all the other are Fe
2o
3the purity of each raw material is all greater than 99.9%, raw material is mixed in sand mill with fragmentation after at the temperature of 135 DEG C dry, cross 200 mesh sieves, then pre-burning 120 minutes at the temperature of 930 DEG C, grinds to form by gained ferrite doped calcium after pre-burning the ferrite doped calcium powder that particle diameter is 500-700 micron.
2, blast-furnace slag powder is prepared
Blast-furnace slag is ground to form to the blast-furnace slag powder that particle diameter is 500-700 micron.
3, prepare ferrite composite granule
Be 1:0.4 according to the weight ratio of ferrite doped calcium and blast-furnace slag, the blast-furnace slag powder of the ferrite doped calcium powder of step 1 gained and step 2 gained is mixed, then at 1250 DEG C of temperature, carry out sintering 4 hours, then pulverize and grind to form the ferrite composite powder that size is 150-170 micron.
4, prepare high purplish red outside line shielding rate coating
By each composition according to weight percent be: the ferrite composite powder 30% of step 3 gained, ethanol 30%, Octabenzone 3%, polyamide resin 3%, Tenox PG 8%, the ratio that all the other are urethane mix, and obtain high purplish red outside line shielding rate coating.
Embodiment tri-:
The high purplish red outside line shielding rate coating of the present invention, its preparation method is as follows:
1, ferrite doped calcium powder is prepared
Raw material weight per-cent is ZnO8%, MnO35%, TiO
27%, CaCO
30.05%, Nb
2o
50.05%, SnO
2o.05%, Co
2o
30.02%, all the other are Fe
2o
3the purity of each raw material is all greater than 99.9%, raw material is mixed in sand mill with fragmentation after at the temperature of 130 DEG C dry, cross 190 mesh sieves, then pre-burning 120 minutes at the temperature of 930 DEG C, grinds to form by gained ferrite doped calcium after pre-burning the ferrite doped calcium powder that particle diameter is 500-700 micron.
2, blast-furnace slag powder is prepared
Blast-furnace slag is ground to form to the blast-furnace slag powder that particle diameter is 500-700 micron.
3, prepare ferrite composite granule
Be 1:0.3 according to the weight ratio of ferrite doped calcium and blast-furnace slag, the blast-furnace slag powder of the ferrite doped calcium powder of step 1 gained and step 2 gained is mixed, then at 1250 DEG C of temperature, carry out sintering 4 hours, then pulverize and grind to form the ferrite composite powder that size is 150-170 micron.
4, prepare high purplish red outside line shielding rate coating
By each composition according to weight percent be: the ferrite composite powder 27% of step 3 gained, ethanol 26%, Octabenzone 2.5%, polyamide resin 2%, Tenox PG 7%, the ratio that all the other are urethane mix, and obtain high purplish red outside line shielding rate coating.
Embodiment tetra-(in step 4, proportioning components is not within the scope of design proportion of the present invention):
A kind of purplish red outside line shielding coating, its preparation method is as follows:
Step 1-3 is with the step 1-3 in embodiment 3.
4, prepare purplish red outside line shielding coating
By each composition according to weight percent be: the ferrite composite powder 20% of step 3 gained, ethanol 15%, Octabenzone 0.5%, polyamide resin 0.5%, Tenox PG 4%, the ratio that all the other are urethane mix, and obtain purplish red outside line shielding coating.
Embodiment five (in step 4, proportioning components is not within the scope of design proportion of the present invention):
A kind of purplish red outside line shielding coating, its preparation method is as follows:
Step 1-3 is with the step 1-3 in embodiment 3.
4, prepare purplish red outside line shielding coating
By each composition according to weight percent be: the ferrite composite powder 34% of step 3 gained, ethanol 35%, Octabenzone 4%, polyamide resin 4%, Tenox PG 10%, the ratio that all the other are urethane mix, and obtain purplish red outside line shielding coating.
Measure example:
The coating that embodiment mono-to five is obtained, respectively on TA1000 cotton poplin cloth fabric (100% cotton, J50XJ50,140X88), one side blade coating one time, coat-thickness is 300 microns of left and right, dries 5 minutes for 120 DEG C; Correspondence obtains coated fabric 1-5 respectively.
Adopt as above same fabric and coating method, the coating of No. CN01102763.0 application obtains contrasting coated fabric.
Each product is carried out respectively to ultraviolet infrared reflection rate and measure, measurement result is as table 1.
Table 1
| ? | Coating composition | Reflectivity % |
| Contrast coated fabric | Composition in No. CN01102763.0 application | 70-80 |
| Coated fabric 1 | The composition of embodiment mono-correspondence | 98 |
| Coated fabric 2 | The composition of embodiment bis-correspondences | 99 |
| Coated fabric 3 | The composition of embodiment tri-correspondences | 99 |
| Coated fabric 4 | The composition of embodiment tetra-correspondences | 96 |
| Coated fabric 5 | The composition of embodiment five correspondences | 95 |
As seen from the above table, the purplish red outside line shielding rate of height of the present invention coating can reach very high purplish red outside line reflectivity, has extraordinary purplish red outside line shield effectiveness.Meanwhile, in coating, the proportioning ratio of each component has certain influence to purplish red outside line shield effectiveness, and wherein, ethanol plays diluting effect, and urethane plays matrix effect, polyamide resin solidification, and very few coating is inhomogeneous, do not have intensity, too much reduces the reflection function of material.The very few reflection function of Octabenzone and ferrite composite material is not strong, too much weakens coating intensity, damages on the contrary reflection function.Tenox PG too much reduces the reflection function of material.
Be more than preferred embodiment of the present invention, all changes of doing according to technical solution of the present invention, when the function producing does not exceed the scope of technical solution of the present invention, all belong to protection scope of the present invention.
Claims (3)
1. a high purplish red outside line shielding rate coating, is characterized in that, in this coating, the weight percent of each composition is: ethanol 20～30%, Octabenzone 2-3%, polyamide resin 1-3%, ferrite composite powder 25-30%, Tenox PG 5-8%, all the other are urethane;
Described ferrite composite powder is made up of by weight 1:0.2-0.4 ferrite doped calcium and blast-furnace slag, and wherein in ferrite doped calcium, the weight percent of each composition is ZnO 3-13%, MnO 30-40%, TiO
26-8%, CaCO
30.04-0.06%, Nb
2o
50.03-0.07%, Sn0
2o.05-0.15%, Co
2o
3all the other are Fe for 0.01-0.03%
20
3;
In described blast-furnace slag, the weight percent of each composition is CaO 35-40%, Al
2o
312-15%, MgO 7-9%, FeO 0.3-0.5%, all the other SiO
2.
2. high purplish red outside line shielding rate coating according to claim 1, is characterized in that, the particle diameter of described ferrite composite powder is 150-170 micron.
3. the preparation method of high purplish red outside line shielding rate coating described in claim 1, is characterized in that, the method comprises the following steps:
1) ferrite doped calcium powder is prepared
Each raw materials by weight: ZnO 3-13%, MnO 30-40%, TiO
26-8%, CaCO
30.04-0.06%, Nb
2o
50.03-0.07%, Sn0
2o.05%, Co
2o
30.01-0.03%, all the other are Fe
20
3prepare burden, each raw material is mixed in sand mill and carry out fragmentation, then at the temperature of 120-135 DEG C, dry, cross 180-200 mesh sieve, pre-burning 100-120 minute at the temperature of 930-980 DEG C, gained ferrite doped calcium after pre-burning is ground to form to ferrite doped calcium powder, and this diameter of particle is 500-700 micron;
2) blast-furnace slag powder is prepared
The blast-furnace slag of getting mentioned component grinds to form blast-furnace slag powder, and this diameter of particle is 500-700 micron;
3) prepare ferrite composite granule
According to the ratio of ferrite doped calcium and blast-furnace slag, the blast-furnace slag powder of the ferrite doped calcium powder of step (1) gained and step (2) gained is mixed, then at 1250-1300 DEG C of temperature, carry out sintering 4-5 hour, then pulverize and grind to form the ferrite composite powder that size is 150-170 micron;
4) prepare high purplish red outside line shielding rate coating
By each composition according to weight percent be: above-mentioned ferrite composite powder 25-30%, ethanol 20～30%, Octabenzone 2-3%, polyamide resin 1-3%, Tenox PG 5-8%, all the other mix for urethane, obtain high purplish red outside line shielding rate coating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410188994.4A CN103923559B (en) | 2014-05-06 | 2014-05-06 | A kind of high purplish red outside line shielding rate coating and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410188994.4A CN103923559B (en) | 2014-05-06 | 2014-05-06 | A kind of high purplish red outside line shielding rate coating and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103923559A true CN103923559A (en) | 2014-07-16 |
| CN103923559B CN103923559B (en) | 2015-11-18 |
Family
ID=51141965
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410188994.4A Active CN103923559B (en) | 2014-05-06 | 2014-05-06 | A kind of high purplish red outside line shielding rate coating and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107502162A (en) * | 2017-08-14 | 2017-12-22 | 安徽信息工程学院 | Fabric antibacterial magnetic coupling coating and preparation method thereof and antibiotic fabric |
| CN109233623A (en) * | 2018-09-19 | 2019-01-18 | 南京禾鑫坊电子科技有限公司 | A kind of electronic component magnetic screen heat dissipating silicone grease coating |
| CN113943502A (en) * | 2021-11-03 | 2022-01-18 | 攀钢集团攀枝花钢铁研究院有限公司 | Method for preparing infrared coating paint by utilizing metallurgical solid wastes |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60141769A (en) * | 1983-12-28 | 1985-07-26 | Sumitomo Electric Ind Ltd | Ultraviolet-curable coating composition for shielding electromagnetic waves |
| CN1552777A (en) * | 2003-06-06 | 2004-12-08 | 上海君江新材料有限公司 | Absorbing screening material |
-
2014
- 2014-05-06 CN CN201410188994.4A patent/CN103923559B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60141769A (en) * | 1983-12-28 | 1985-07-26 | Sumitomo Electric Ind Ltd | Ultraviolet-curable coating composition for shielding electromagnetic waves |
| CN1552777A (en) * | 2003-06-06 | 2004-12-08 | 上海君江新材料有限公司 | Absorbing screening material |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107502162A (en) * | 2017-08-14 | 2017-12-22 | 安徽信息工程学院 | Fabric antibacterial magnetic coupling coating and preparation method thereof and antibiotic fabric |
| CN109233623A (en) * | 2018-09-19 | 2019-01-18 | 南京禾鑫坊电子科技有限公司 | A kind of electronic component magnetic screen heat dissipating silicone grease coating |
| CN113943502A (en) * | 2021-11-03 | 2022-01-18 | 攀钢集团攀枝花钢铁研究院有限公司 | Method for preparing infrared coating paint by utilizing metallurgical solid wastes |
| CN113943502B (en) * | 2021-11-03 | 2022-07-05 | 攀钢集团攀枝花钢铁研究院有限公司 | Method for preparing infrared coating paint by utilizing metallurgical solid wastes |
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| Publication number | Publication date |
|---|---|
| CN103923559B (en) | 2015-11-18 |
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Effective date of registration: 20181207 Address after: 224400 Sanzao Town Industrial Park 999, Funing County, Yancheng City, Jiangsu Province Patentee after: Jiangsu Hong Teng sports ground new material Co., Ltd. Address before: 210044 Ning six road, Pukou District, Nanjing, Jiangsu Province, No. 219 Patentee before: Nanjing University of Information Science and Technology |
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Effective date of registration: 20210322 Address after: 212300 Wanxin Road, glasses Industrial Park, Situ Town, Danyang City, Zhenjiang City, Jiangsu Province Patentee after: JIANGSU HANCHUANG NEW MATERIAL Co.,Ltd. Address before: 224400 Sanzao Town Industrial Park 999, Funing County, Yancheng City, Jiangsu Province Patentee before: JIANGSU HONGTENG SPORT FIELD NEW MATERIAL Co.,Ltd. |