CN109232944A - A kind of preparation method of heat insulation type vehicle explosion-proof film - Google Patents
A kind of preparation method of heat insulation type vehicle explosion-proof film Download PDFInfo
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Abstract
The invention discloses a kind of preparation methods of heat insulation type vehicle explosion-proof film, belong to explosion-proof technical field of membrane.Ethyl acetate, polyvinyl butyral resin, levelling agent, light stabilizer, antioxidant, low-melting alloy, modified glass-fiber powder are stirred by the present invention, obtain No. 1 mixed slurry；According to parts by weight, by butyl acetate, silver powder, organic siliconresin, pretreated glass microballon, modified bamboo fiber powder, light stabilizer, ultraviolet absorber, acrylic resin is stirred, and obtains No. 2 mixed slurries；No. 1 mixed slurry is coated on polyester film front, No. 2 mixed slurries are coated on polyester film reverse side, high-temperature baking is to get heat insulation type vehicle explosion-proof film by baking sizing.Heat insulation type vehicle explosion-proof film provided by the invention has excellent explosion-proof performance, wear-resisting property and heat-proof quality.
Description
Technical field
The invention discloses a kind of preparation methods of heat insulation type vehicle explosion-proof film, belong to explosion-proof technical field of membrane.
Background technique
Currently, automobile front-window and side vehicle window are all to have good translucency, the visual field is good, helps made of glass
In safe driving.But the sunlight outside glass will affect the vision of driver, and can make the temperature short time in automobile
Interior rapid raising, more serious, when accident occurs, broken glass, which is dispersed, can injure interior driver and passenger and people from periphery
Member.Therefore, it is necessary to stick one layer of rupture pressure disc on vehicle glass, good heat-proof quality is played, while can be improved glass of automobile
The security performance of glass.
Vehicle explosion-proof film refers to that the substrate of use is clear enough, even if the film that color is deep, it will be seen that the scenery gone is also wanted
It thoroughly, cannot dim, deformation；Vehicle explosion-proof film color persistence is high.At present product there are the problem of: poor transparency, weatherability
Difference, antiultraviolet is inadequate, heat insulation is poor, cannot according to external light source strong and weak adjustment internal light, surface hardness it is low intolerant to
Mill etc..For traditional heat insulation type vehicle explosion-proof film at present there is also wear-resisting property, explosion-proof performance and heat-proof quality are bad
Problem also needs further to study it.
Summary of the invention
The present invention solves the technical problem of: for traditional heat insulation type vehicle explosion-proof film wear-resisting property, explosion-proof performance
The bad problem with heat-proof quality provides a kind of preparation method of heat insulation type vehicle explosion-proof film.
In order to solve the above-mentioned technical problem, the technical scheme adopted by the invention is that:
(1) according to parts by weight, by 30~50 parts of ethyl acetate, 30~40 parts of polyvinyl butyral resins, 3~5 parts of levellings
Agent, 3~5 parts of light stabilizers, 1~2 part of antioxidant, 5~8 parts of low-melting alloys, 8~10 parts of modified glass-fiber powder stirrings are mixed
It closes, obtains No. 1 mixed slurry；
(2) according to parts by weight, by 30~50 parts of butyl acetates, 10~20 parts of silver powder, 10~20 parts of organic siliconresins, 8~10
Part pretreated glass microballon, 8~10 parts of modified bamboo fiber powder, 3~5 parts of light stabilizers, 0.1~0.3 part of ultraviolet absorber, 30~
50 parts of acrylic resins are stirred, and obtain No. 2 mixed slurries；
(3) No. 1 mixed slurry is coated on polyester film front, it is anti-to be coated on polyester film by baking sizing for No. 2 mixed slurries
Face, high-temperature baking is to get heat insulation type vehicle explosion-proof film.
Step (1) levelling agent is any one in Lauxite or melamine resin.
Step (1) antioxidant is butylated hydroxy anisole, in dibutyl hydroxy toluene or tert-butyl hydroquinone
Any one.
Step (1) low-melting alloy is bismuth alloy, tin alloy, any one in sodium alloy or indium alloy.
The preparation process of step (1) the modified glass-fiber powder are as follows: by glass fibre ball milling, cross the sieve of 100 mesh, obtain glass
Glass fiber powder and hydrofluoric acid 1:10~1:20 in mass ratio are stirred to react by glass fiber powder, are filtered, and washing obtains single treatment
Glass fiber powder, according to parts by weight, by 20~30 parts of single treatment glass fiber powders, 5~8 parts of potato starch, 0.1~
0.5~0.8 times of potato starch quality of ferric chloride solution and horse is then added dropwise in 0.2 part of biogas slurry, 30~40 parts of water mixed fermentations
The Fluorinse of 0.2~0.3 times of bell sweet potato starch quality, is stirred, and is concentrated under reduced pressure, dry, and charing heats up step by step, high temperature
Reaction cools down to get modified glass-fiber powder.
Step (2) organic siliconresin is poly- methylsiloxane resin, and poly- ethyl organic siliconresin or poly- aryl are organic
Any one in silicone resin.
The preparation process of step (2) the pretreated glass microballon are as follows: in mass ratio by glass microballoon and dopamine solution
1:10~1:20 is stirred, and is filtered to get pretreated glass microballon.
The preparation process of step (2) the modified bamboo fiber powder are as follows: bamboo fibre is crushed, the sieve of 80 mesh is crossed, obtains bamboo fibre
Powder, according to parts by weight, by 10~20 bamboo fibre powder, 2~3 parts of biogas slurries, 20~30 parts of water mixed fermentations, filtering is dry to containing
Water rate is 5~8%, obtains single treatment bamboo fibre powder, by single treatment bamboo fibre powder and ethyl orthosilicate 1:10~1 in mass ratio:
20 are stirred, and filtering, liquid nitrogen frozen, ball milling obtains secondary treatment bamboo fibre powder, by secondary treatment bamboo fibre powder and sodium hydroxide
Solution 1:10~1:20 constant temperature in mass ratio is stirred to react, and is filtered, and is washed, dry, obtains modified bamboo fiber powder.
Step (2) ultraviolet absorber is resorcinol monobenzoate or 2-(2'- hydroxyl -5' t-octyl phenyl) benzene
And any one in triazole.
The beneficial effects of the present invention are:
(1) present invention is by addition modified glass-fiber powder and low-melting alloy, during the preparation process, firstly, glass fiber powder
By hydrofluoric acid dips, so that defect occurs in surface, then by single treatment glass fiber powder, potato starch, biogas slurry and water are mixed
Fermentation is closed, during the fermentation, bacterium breeds in fiberglass surfacing fault location, then by the way that ferric chloride solution and fluorination is added dropwise
Sodium solution, since bacterial cell surface is negatively charged, can enriched obtain iron ion, charing is then passed through, so that glass fibers
The organic matter charing on powder surface is tieed up, as temperature increases, carbonaceous makes the iron ion on glass fiber powder surface be reduced into fe,
Then under the catalytic action of fe and sodium fluoride, the silicon dioxde reaction of carbonaceous and fiberglass surfacing generates silicon carbide,
The silicon nitride of generation is distributed and is fixed on glass fiber powder surface, so that the wear-resisting property of system gets a promotion, is using
In the process, by adding low-melting alloy, since low-melting alloy has lower fusing point, before resin is fully cured just
Fusing, alloy particle can penetrate into glass fiber powder surface layer after melting, and be wrapped in simple substance iron surface, after alloy graining,
It can make to form metallurgical bonding between glass fibre powder particles, the modified glass-fiber net of connection be formed on system surface, heated outer
When boundary impacts, impact force can uniformly be spread in modified glass-fiber net, effectively avoid glass for vehicle window from occurring quick-fried broken, so that
The explosion-proof performance of system is further promoted；
(2) present invention is by addition pretreated glass microballon, silver powder and organic siliconresin, in use, due to pretreatment
Glass microballoon is impregnated by dopamine solution, improves the absorption property on its surface, glass microballoon surface is inhaled
Attached a large amount of silver powder, then, during high-temperature baking, the silicon oxygen bond fission of organic siliconresin is decomposed, and post-rift silicon oxygen is strong
In conjunction with the silver powder on glass microballoon surface, silicon oxygen alloy layer is formed, silicon oxygen alloy layer has good heat-proof quality, is wrapped in glass
Glass bead surface, so that the heat-proof quality of system is further promoted.
Specific embodiment
Glass fibre is placed in ball milling in ball mill, the sieve of 100 mesh is crossed, glass fiber powder is obtained, by glass fiber powder and matter
Amount score be 30~35% hydrofluoric acid 1:10~1:20 in mass ratio be placed in reaction kettle, in revolving speed be 300~500r/min,
Under the conditions of temperature is 40~60 DEG C, after being stirred to react 40~60min, filtering obtains filter residue, then with ammonium hydroxide by residue washing to washing
Liquid is washed as neutrality, obtains single treatment glass fiber powder, according to parts by weight, by 20~30 parts of single treatment glass fiber powders, 5~
8 parts of potato starch, 0.1~0.2 part of biogas slurry, 30~40 parts of water are placed in No. 1 fermentation cauldron, in temperature be 30~35 DEG C, revolving speed
Under the conditions of 200~300r/min, mixed fermentation 3~5 days, then into No. 1 fermentation cauldron be added dropwise potato starch quality 0.5~
0.2~0.3 times of mass fraction of ferric chloride solution and potato starch quality that 0.8 times of mass fraction is 10~20% is 3~5%
Fluorinse is stirred 40~60min, obtains mixed serum, will then mix under the conditions of revolving speed is 300~500r/min
Close slurries be placed in Rotary Evaporators, in temperature be 60~80 DEG C, pressure be 500~800Pa under the conditions of, be concentrated under reduced pressure 40~
60min obtains concentrate, then concentrate is placed in baking oven, dry to constant weight under the conditions of temperature is 105~110 DEG C, obtains
Dried feed is then placed in tube furnace by dried feed, and nitrogen is filled with into furnace with 80~120mL/min rate, is in temperature
Under the conditions of 550~750 DEG C, after carbonizing 1~3h, and 8~10 DEG C/min rate is warming up to 1350~1550 DEG C, and pyroreaction 3~
After 5h, room temperature is down to get modified glass-fiber powder with furnace；Glass microballoon is molten for the dopamine of 2.6mg/mL with mass concentration
Liquid 1:10~1:20 in mass ratio is placed in No. 1 beaker, under the conditions of revolving speed is 300~500r/min, it is stirred 40~
After 60min, filter to get pretreated glass microballon；Bamboo fibre is placed in pulverizer and is crushed, the sieve of 80 mesh is crossed, obtains bamboo fibre
Powder, according to parts by weight, by 10~20 bamboo fibre powder, 2~3 parts of biogas slurries, 20~30 parts of water are placed in No. 2 fermentation cauldrons, in temperature
It is 30~35 DEG C, under the conditions of revolving speed is 100~300r/min, after mixed fermentation 3~5 days, filtering obtains No. 1 filter cake, then by 1
Number filter cake is placed in baking oven, and under the conditions of temperature is 105~110 DEG C, dry to moisture content is 5~8%, and it is fine to obtain single treatment bamboo
Powder is tieed up, single treatment bamboo fibre powder and ethyl orthosilicate 1:10~1:20 in mass ratio are placed in No. 2 beakers, are in revolving speed
Under the conditions of 400~600r/min, after being stirred 40~60min, filtering obtains No. 2 filter cakes, then by No. 2 filter cake liquid nitrogen frozens,
Material must be freezed, freezing pellet is then ground into 30~50min, secondary treatment bamboo fibre powder is obtained, by secondary treatment bamboo fibre powder and matter
Amount score be 20~30% sodium hydroxide solution 1:10~1:20 in mass ratio be placed in three-necked flask, in temperature be 40~50
DEG C, under the conditions of revolving speed is 300~500r/min, after constant temperature is stirred to react 1~2h, filtering obtains No. 3 filter cakes, then uses glacial acetic acid
By No. 3 Washing of Filter Cake to cleaning solution be neutrality, then No. 3 filter cakes after washing are placed in baking oven, in temperature be 105~110
It is dry to constant weight under the conditions of DEG C, obtain modified bamboo fiber powder；According to parts by weight, by 30~50 parts of ethyl acetate, 30~40 parts poly-
Vinyl butyral resin, 3~5 parts of levelling agents, 3~5 parts of light stabilizers, 1~2 part of antioxidant, 5~8 parts of low-melting alloys,
8~10 parts of modified glass-fiber powder are placed in No. 1 batch mixer, under the conditions of revolving speed is 200~300r/min, it is stirred 40~
60min obtains No. 1 mixed slurry；According to parts by weight, by 30~50 parts of butyl acetates, 10~20 parts of silver powder, 10~20 parts organic
Silicone resin, 8~10 parts of pretreated glass microballons, 8~10 parts of modified bamboo fiber powder, 3~5 parts of light stabilizers, 0.1~0.3 part of purple
Outer absorbent, 30~50 parts of acrylic resins are placed in No. 1 batch mixer, and under the conditions of revolving speed is 200~300r/min, stirring is mixed
40~60min is closed, No. 2 mixed slurries are obtained；By No. 1 mixed slurry be coated on polyester film front, in temperature be 130~160 DEG C
Under the conditions of, No. 2 mixed slurries are coated on polyester film reverse side by baking sizing, under the conditions of temperature is 400~460 DEG C, high temperature
Baking sizing is to get heat insulation type vehicle explosion-proof film.The levelling agent is any in Lauxite or melamine resin
It is a kind of.The antioxidant is butylated hydroxy anisole, any one in dibutyl hydroxy toluene or tert-butyl hydroquinone.
The low-melting alloy is bismuth alloy, tin alloy, any one in sodium alloy or indium alloy.The organic siliconresin is poly- first
Any one in base organic siliconresin, poly- ethyl organic siliconresin or poly- aryl organic siliconresin.Between the ultraviolet absorber is
Resorcinol monobenzoate or 2-(2'- hydroxyl -5' t-octyl phenyl) any one in benzotriazole.
Example 1
Glass fibre is placed in ball milling in ball mill, the sieve of 100 mesh is crossed, obtains glass fiber powder, by glass fiber powder and quality point
Number is placed in reaction kettle for 35% hydrofluoric acid 1:20 in mass ratio, is that 500r/min is stirred under the conditions of temperature is 60 DEG C in revolving speed
After mixing reaction 60min, filtering obtains filter residue, is then neutrality by residue washing to cleaning solution with ammonium hydroxide, obtains single treatment glass fibers
Powder is tieed up, according to parts by weight, by 30 parts of single treatment glass fiber powders, 8 parts of potato starch, 0.2 part of biogas slurry, 40 parts of water are placed in
In No. 1 fermentation cauldron, it is 35 DEG C in temperature, under the conditions of revolving speed is 300r/min, mixed fermentation 5 days, is then dripped into No. 1 fermentation cauldron
0.3 times of mass fraction of ferric chloride solution and potato starch quality that 0.8 times of mass fraction of potato starch quality is 20% is added to be
5% Fluorinse is stirred 60min, obtains mixed serum, then by mixed serum under the conditions of revolving speed is 500r/min
It is placed in Rotary Evaporators, is 80 DEG C in temperature, under the conditions of pressure is 800Pa, 60min is concentrated under reduced pressure, obtains concentrate, then will
Concentrate is placed in baking oven, dry to constant weight under the conditions of temperature is 110 DEG C, obtains dried feed, dried feed is then placed in tubular type
In furnace, and nitrogen is filled with into furnace with 120mL/min rate, under the conditions of temperature is 750 DEG C, after carbonizing 3h, and 10 DEG C/min
Rate is warming up to 1550 DEG C, after pyroreaction 5h, is down to room temperature with furnace to get modified glass-fiber powder；By glass microballoon and matter
The dopamine solution 1:20 in mass ratio that amount concentration is 2.6mg/mL is placed in No. 1 beaker, under the conditions of revolving speed is 500r/min,
After being stirred 60min, filter to get pretreated glass microballon；Bamboo fibre is placed in pulverizer and is crushed, the sieve of 80 mesh is crossed,
Bamboo fibre powder, according to parts by weight, by 20 bamboo fibre powder, 3 parts of biogas slurries, 30 parts of water are placed in No. 2 fermentation cauldrons, in temperature be 35
DEG C, under the conditions of revolving speed is 300r/min, after mixed fermentation 5 days, filtering obtains No. 1 filter cake, then No. 1 filter cake is placed in baking oven,
Under the conditions of temperature is 110 DEG C, dry to moisture content is 8%, obtains single treatment bamboo fibre powder, by single treatment bamboo fibre powder with
Ethyl orthosilicate 1:20 in mass ratio is placed in No. 2 beakers, under the conditions of revolving speed is 600r/min, after being stirred 60min, and mistake
Filter, obtains No. 2 filter cakes, then by No. 2 filter cake liquid nitrogen frozens, must freeze material, and freezing pellet is then ground 50min, obtains secondary treatment
The sodium hydroxide solution 1:20 in mass ratio that secondary treatment bamboo fibre powder and mass fraction are 30% is placed in three mouthfuls by bamboo fibre powder
It is 50 DEG C in temperature, under the conditions of revolving speed is 500r/min, after constant temperature is stirred to react 2h, filtering obtains No. 3 filter cakes, then in flask
By No. 3 Washing of Filter Cake to cleaning solutions be with glacial acetic acid it is neutral, then No. 3 filter cakes after washing are placed in baking oven, are in temperature
It is dry to constant weight under the conditions of 110 DEG C, obtain modified bamboo fiber powder；According to parts by weight, by 50 parts of ethyl acetate, 40 parts of polyethylene
Polyvinyl butyral resin, 5 parts of levelling agents, 5 parts of light stabilizers, 2 parts of antioxidants, 8 parts of low-melting alloys, 10 parts of modified glass-fibers
Powder is placed in No. 1 batch mixer, under the conditions of revolving speed is 300r/min, is stirred 60min, is obtained No. 1 mixed slurry；By weight
Number meter, by 50 parts of butyl acetates, 20 parts of silver powder, 20 parts of organic siliconresins, 10 parts of pretreated glass microballons, 10 parts of modified bamboo fiber
Powder, 5 parts of light stabilizers, 0.3 part of ultraviolet absorber, 50 parts of acrylic resins are placed in No. 1 batch mixer, in revolving speed be 300r/min
Under the conditions of, it is stirred 60min, obtains No. 2 mixed slurries；No. 1 mixed slurry is coated on polyester film front, is in temperature
Under the conditions of 160 DEG C, No. 2 mixed slurries are coated on polyester film reverse side by baking sizing, under the conditions of temperature is 460 DEG C, high temperature
Baking sizing is to get heat insulation type vehicle explosion-proof film.The levelling agent is Lauxite.The antioxidant is butylhydroxy fennel
Ether.The low-melting alloy is bismuth alloy.The organic siliconresin is poly- methylsiloxane resin.Between the ultraviolet absorber is
Resorcinol monobenzoate.
Example 2
Glass fibre is placed in ball milling in ball mill, the sieve of 100 mesh is crossed, obtains glass fiber powder, by glass fiber powder and quality point
Number is placed in reaction kettle for 35% hydrofluoric acid 1:20 in mass ratio, is that 500r/min is stirred under the conditions of temperature is 60 DEG C in revolving speed
After mixing reaction 60min, filtering obtains filter residue, is then neutrality by residue washing to cleaning solution with ammonium hydroxide, obtains single treatment glass fibers
Powder is tieed up, according to parts by weight, by 30 parts of single treatment glass fiber powders, 8 parts of potato starch, 0.2 part of biogas slurry, 40 parts of water are placed in
In No. 1 fermentation cauldron, it is 35 DEG C in temperature, under the conditions of revolving speed is 300r/min, mixed fermentation 5 days, is then dripped into No. 1 fermentation cauldron
0.3 times of mass fraction of ferric chloride solution and potato starch quality that 0.8 times of mass fraction of potato starch quality is 20% is added to be
5% Fluorinse is stirred 60min, obtains mixed serum, then by mixed serum under the conditions of revolving speed is 500r/min
It is placed in Rotary Evaporators, is 80 DEG C in temperature, under the conditions of pressure is 800Pa, 60min is concentrated under reduced pressure, obtains concentrate, then will
Concentrate is placed in baking oven, dry to constant weight under the conditions of temperature is 110 DEG C, obtains dried feed, dried feed is then placed in tubular type
In furnace, and nitrogen is filled with into furnace with 120mL/min rate, under the conditions of temperature is 750 DEG C, after carbonizing 3h, and 10 DEG C/min
Rate is warming up to 1550 DEG C, after pyroreaction 5h, is down to room temperature with furnace to get modified glass-fiber powder；By glass microballoon and matter
The dopamine solution 1:20 in mass ratio that amount concentration is 2.6mg/mL is placed in No. 1 beaker, under the conditions of revolving speed is 500r/min,
After being stirred 60min, filter to get pretreated glass microballon；Bamboo fibre is placed in pulverizer and is crushed, the sieve of 80 mesh is crossed,
Bamboo fibre powder, according to parts by weight, by 20 bamboo fibre powder, 3 parts of biogas slurries, 30 parts of water are placed in No. 2 fermentation cauldrons, in temperature be 35
DEG C, under the conditions of revolving speed is 300r/min, after mixed fermentation 5 days, filtering obtains No. 1 filter cake, then No. 1 filter cake is placed in baking oven,
Under the conditions of temperature is 110 DEG C, dry to moisture content is 8%, obtains single treatment bamboo fibre powder, by single treatment bamboo fibre powder with
Ethyl orthosilicate 1:20 in mass ratio is placed in No. 2 beakers, under the conditions of revolving speed is 600r/min, after being stirred 60min, and mistake
Filter, obtains No. 2 filter cakes, then by No. 2 filter cake liquid nitrogen frozens, must freeze material, and freezing pellet is then ground 50min, obtains secondary treatment
The sodium hydroxide solution 1:20 in mass ratio that secondary treatment bamboo fibre powder and mass fraction are 30% is placed in three mouthfuls by bamboo fibre powder
It is 50 DEG C in temperature, under the conditions of revolving speed is 500r/min, after constant temperature is stirred to react 2h, filtering obtains No. 3 filter cakes, then in flask
By No. 3 Washing of Filter Cake to cleaning solutions be with glacial acetic acid it is neutral, then No. 3 filter cakes after washing are placed in baking oven, are in temperature
It is dry to constant weight under the conditions of 110 DEG C, obtain modified bamboo fiber powder；According to parts by weight, by 50 parts of ethyl acetate, 40 parts of polyethylene
Polyvinyl butyral resin, 5 parts of levelling agents, 5 parts of light stabilizers, 2 parts of antioxidants, 10 parts of modified glass-fiber powder are placed in No. 1 mixing
In machine, under the conditions of revolving speed is 300r/min, it is stirred 60min, obtains No. 1 mixed slurry；According to parts by weight, by 50 parts of second
Acid butyl ester, 20 parts of silver powder, 20 parts of organic siliconresins, 10 parts of pretreated glass microballons, 10 parts of modified bamboo fiber powder, 5 parts of light are stablized
Agent, 0.3 part of ultraviolet absorber, 50 parts of acrylic resins are placed in No. 1 batch mixer, under the conditions of revolving speed is 300r/min, stirring
60min is mixed, No. 2 mixed slurries are obtained；No. 1 mixed slurry is coated on polyester film front, under the conditions of temperature is 160 DEG C,
No. 2 mixed slurries are coated on polyester film reverse side by baking sizing, under the conditions of temperature is 460 DEG C, high-temperature baking sizing, i.e.,
Obtain heat insulation type vehicle explosion-proof film.The levelling agent is Lauxite.The antioxidant is butylated hydroxy anisole.It is described organic
Silicone resin is poly- methylsiloxane resin.The ultraviolet absorber is resorcinol monobenzoate.
Example 3
Glass fibre is placed in ball milling in ball mill, the sieve of 100 mesh is crossed, obtains glass fiber powder；By glass microballoon and mass concentration
It is placed in No. 1 beaker for the dopamine solution 1:20 in mass ratio of 2.6mg/mL, under the conditions of revolving speed is 500r/min, stirring is mixed
After closing 60min, filter to get pretreated glass microballon；Bamboo fibre is placed in pulverizer and is crushed, the sieve of 80 mesh is crossed, obtains bamboo fibre
Powder is tieed up, according to parts by weight, by 20 bamboo fibre powder, 3 parts of biogas slurries, 30 parts of water are placed in No. 2 fermentation cauldrons, are 35 DEG C in temperature, are turned
Under the conditions of speed is 300r/min, after mixed fermentation 5 days, filtering obtains No. 1 filter cake, then No. 1 filter cake is placed in baking oven, Yu Wen
Under the conditions of degree is 110 DEG C, drying to moisture content is 8%, single treatment bamboo fibre powder is obtained, by single treatment bamboo fibre powder and positive silicon
Acetoacetic ester 1:20 in mass ratio is placed in No. 2 beakers, under the conditions of revolving speed is 600r/min, after being stirred 60min, and filtering,
Material must be freezed then by No. 2 filter cake liquid nitrogen frozens by obtaining No. 2 filter cakes, and freezing pellet is then ground 50min, it is fine to obtain secondary treatment bamboo
Powder is tieed up, the sodium hydroxide solution 1:20 in mass ratio that secondary treatment bamboo fibre powder and mass fraction are 30% is placed in three-necked flask
In, it is 50 DEG C in temperature, under the conditions of revolving speed is 500r/min, after constant temperature is stirred to react 2h, filtering obtains No. 3 filter cakes, then uses ice
Acetic acid by No. 3 Washing of Filter Cake to cleaning solution be neutrality, then No. 3 filter cakes after washing are placed in baking oven, in temperature be 110 DEG C
Under the conditions of, it is dry to constant weight, obtain modified bamboo fiber powder；According to parts by weight, by 50 parts of ethyl acetate, 40 parts of polyvinyl alcohol contracting fourths
Urea formaldehyde, 5 parts of levelling agents, 5 parts of light stabilizers, 2 parts of antioxidants, 8 parts of low-melting alloys, 10 parts of glass fiber powders are placed in No. 1
In batch mixer, under the conditions of revolving speed is 300r/min, it is stirred 60min, obtains No. 1 mixed slurry；According to parts by weight, by 50
Part butyl acetate, 20 parts of silver powder, 20 parts of organic siliconresins, 10 parts of pretreated glass microballons, 10 parts of modified bamboo fiber powder, 5 parts of light
Stabilizer, 0.3 part of ultraviolet absorber, 50 parts of acrylic resins are placed in No. 1 batch mixer, under the conditions of revolving speed is 300r/min,
It is stirred 60min, obtains No. 2 mixed slurries；By No. 1 mixed slurry be coated on polyester film front, in temperature be 160 DEG C of conditions
Under, No. 2 mixed slurries are coated on polyester film reverse side by baking sizing, under the conditions of temperature is 460 DEG C, high-temperature baking sizing,
Up to heat insulation type vehicle explosion-proof film.The levelling agent is Lauxite.The antioxidant is butylated hydroxy anisole.It is described low
Melting alloy is bismuth alloy.The organic siliconresin is poly- methylsiloxane resin.The ultraviolet absorber is resorcinol list
Benzoic ether.
Example 4
Glass fibre is placed in ball milling in ball mill, the sieve of 100 mesh is crossed, obtains glass fiber powder, by glass fiber powder and quality point
Number is placed in reaction kettle for 35% hydrofluoric acid 1:20 in mass ratio, is that 500r/min is stirred under the conditions of temperature is 60 DEG C in revolving speed
After mixing reaction 60min, filtering obtains filter residue, is then neutrality by residue washing to cleaning solution with ammonium hydroxide, obtains single treatment glass fibers
Powder is tieed up, according to parts by weight, by 30 parts of single treatment glass fiber powders, 8 parts of potato starch, 0.2 part of biogas slurry, 40 parts of water are placed in
In No. 1 fermentation cauldron, it is 35 DEG C in temperature, under the conditions of revolving speed is 300r/min, mixed fermentation 5 days, is then dripped into No. 1 fermentation cauldron
0.3 times of mass fraction of ferric chloride solution and potato starch quality that 0.8 times of mass fraction of potato starch quality is 20% is added to be
5% Fluorinse is stirred 60min, obtains mixed serum, then by mixed serum under the conditions of revolving speed is 500r/min
It is placed in Rotary Evaporators, is 80 DEG C in temperature, under the conditions of pressure is 800Pa, 60min is concentrated under reduced pressure, obtains concentrate, then will
Concentrate is placed in baking oven, dry to constant weight under the conditions of temperature is 110 DEG C, obtains dried feed, dried feed is then placed in tubular type
In furnace, and nitrogen is filled with into furnace with 120mL/min rate, under the conditions of temperature is 750 DEG C, after carbonizing 3h, and 10 DEG C/min
Rate is warming up to 1550 DEG C, after pyroreaction 5h, is down to room temperature with furnace to get modified glass-fiber powder；By glass microballoon and matter
The dopamine solution 1:20 in mass ratio that amount concentration is 2.6mg/mL is placed in No. 1 beaker, under the conditions of revolving speed is 500r/min,
After being stirred 60min, filter to get pretreated glass microballon；Bamboo fibre is placed in pulverizer and is crushed, the sieve of 80 mesh is crossed,
Bamboo fibre powder, according to parts by weight, by 20 bamboo fibre powder, 3 parts of biogas slurries, 30 parts of water are placed in No. 2 fermentation cauldrons, in temperature be 35
DEG C, under the conditions of revolving speed is 300r/min, after mixed fermentation 5 days, filtering obtains No. 1 filter cake, then No. 1 filter cake is placed in baking oven,
Under the conditions of temperature is 110 DEG C, dry to moisture content is 8%, obtains single treatment bamboo fibre powder, by single treatment bamboo fibre powder with
Ethyl orthosilicate 1:20 in mass ratio is placed in No. 2 beakers, under the conditions of revolving speed is 600r/min, after being stirred 60min, and mistake
Filter, obtains No. 2 filter cakes, then by No. 2 filter cake liquid nitrogen frozens, must freeze material, and freezing pellet is then ground 50min, obtains secondary treatment
The sodium hydroxide solution 1:20 in mass ratio that secondary treatment bamboo fibre powder and mass fraction are 30% is placed in three mouthfuls by bamboo fibre powder
It is 50 DEG C in temperature, under the conditions of revolving speed is 500r/min, after constant temperature is stirred to react 2h, filtering obtains No. 3 filter cakes, then in flask
By No. 3 Washing of Filter Cake to cleaning solutions be with glacial acetic acid it is neutral, then No. 3 filter cakes after washing are placed in baking oven, are in temperature
It is dry to constant weight under the conditions of 110 DEG C, obtain modified bamboo fiber powder；According to parts by weight, by 50 parts of ethyl acetate, 40 parts of polyethylene
Polyvinyl butyral resin, 5 parts of levelling agents, 5 parts of light stabilizers, 2 parts of antioxidants, 8 parts of low-melting alloys, 10 parts of modified glass-fibers
Powder is placed in No. 1 batch mixer, under the conditions of revolving speed is 300r/min, is stirred 60min, is obtained No. 1 mixed slurry；By weight
Number meter, by 50 parts of butyl acetates, 20 parts of organic siliconresins, 10 parts of pretreated glass microballons, 10 parts of modified bamboo fiber powder, 5 parts of light
Stabilizer, 0.3 part of ultraviolet absorber, 50 parts of acrylic resins are placed in No. 1 batch mixer, under the conditions of revolving speed is 300r/min,
It is stirred 60min, obtains No. 2 mixed slurries；By No. 1 mixed slurry be coated on polyester film front, in temperature be 160 DEG C of conditions
Under, No. 2 mixed slurries are coated on polyester film reverse side by baking sizing, under the conditions of temperature is 460 DEG C, high-temperature baking sizing,
Up to heat insulation type vehicle explosion-proof film.The levelling agent is Lauxite.The antioxidant is butylated hydroxy anisole.It is described low
Melting alloy is bismuth alloy.The organic siliconresin is poly- methylsiloxane resin.The ultraviolet absorber is resorcinol list
Benzoic ether.
Example 5
Glass fibre is placed in ball milling in ball mill, the sieve of 100 mesh is crossed, obtains glass fiber powder, by glass fiber powder and quality point
Number is placed in reaction kettle for 35% hydrofluoric acid 1:20 in mass ratio, is that 500r/min is stirred under the conditions of temperature is 60 DEG C in revolving speed
After mixing reaction 60min, filtering obtains filter residue, is then neutrality by residue washing to cleaning solution with ammonium hydroxide, obtains single treatment glass fibers
Powder is tieed up, according to parts by weight, by 30 parts of single treatment glass fiber powders, 8 parts of potato starch, 0.2 part of biogas slurry, 40 parts of water are placed in
In No. 1 fermentation cauldron, it is 35 DEG C in temperature, under the conditions of revolving speed is 300r/min, mixed fermentation 5 days, is then dripped into No. 1 fermentation cauldron
0.3 times of mass fraction of ferric chloride solution and potato starch quality that 0.8 times of mass fraction of potato starch quality is 20% is added to be
5% Fluorinse is stirred 60min, obtains mixed serum, then by mixed serum under the conditions of revolving speed is 500r/min
It is placed in Rotary Evaporators, is 80 DEG C in temperature, under the conditions of pressure is 800Pa, 60min is concentrated under reduced pressure, obtains concentrate, then will
Concentrate is placed in baking oven, dry to constant weight under the conditions of temperature is 110 DEG C, obtains dried feed, dried feed is then placed in tubular type
In furnace, and nitrogen is filled with into furnace with 120mL/min rate, under the conditions of temperature is 750 DEG C, after carbonizing 3h, and 10 DEG C/min
Rate is warming up to 1550 DEG C, after pyroreaction 5h, is down to room temperature with furnace to get modified glass-fiber powder；By glass microballoon and matter
The dopamine solution 1:20 in mass ratio that amount concentration is 2.6mg/mL is placed in No. 1 beaker, under the conditions of revolving speed is 500r/min,
After being stirred 60min, filter to get pretreated glass microballon；Bamboo fibre is placed in pulverizer and is crushed, the sieve of 80 mesh is crossed,
Bamboo fibre powder, according to parts by weight, by 20 bamboo fibre powder, 3 parts of biogas slurries, 30 parts of water are placed in No. 2 fermentation cauldrons, in temperature be 35
DEG C, under the conditions of revolving speed is 300r/min, after mixed fermentation 5 days, filtering obtains No. 1 filter cake, then No. 1 filter cake is placed in baking oven,
Under the conditions of temperature is 110 DEG C, dry to moisture content is 8%, obtains single treatment bamboo fibre powder, by single treatment bamboo fibre powder with
Ethyl orthosilicate 1:20 in mass ratio is placed in No. 2 beakers, under the conditions of revolving speed is 600r/min, after being stirred 60min, and mistake
Filter, obtains No. 2 filter cakes, then by No. 2 filter cake liquid nitrogen frozens, must freeze material, and freezing pellet is then ground 50min, obtains secondary treatment
The sodium hydroxide solution 1:20 in mass ratio that secondary treatment bamboo fibre powder and mass fraction are 30% is placed in three mouthfuls by bamboo fibre powder
It is 50 DEG C in temperature, under the conditions of revolving speed is 500r/min, after constant temperature is stirred to react 2h, filtering obtains No. 3 filter cakes, then in flask
By No. 3 Washing of Filter Cake to cleaning solutions be with glacial acetic acid it is neutral, then No. 3 filter cakes after washing are placed in baking oven, are in temperature
It is dry to constant weight under the conditions of 110 DEG C, obtain modified bamboo fiber powder；According to parts by weight, by 50 parts of ethyl acetate, 40 parts of polyethylene
Polyvinyl butyral resin, 5 parts of levelling agents, 5 parts of light stabilizers, 2 parts of antioxidants, 8 parts of low-melting alloys, 10 parts of modified glass-fibers
Powder is placed in No. 1 batch mixer, under the conditions of revolving speed is 300r/min, is stirred 60min, is obtained No. 1 mixed slurry；By weight
Number meter, by 50 parts of butyl acetates, 20 parts of silver powder, 10 parts of pretreated glass microballons, 10 parts of modified bamboo fiber powder, 5 parts of light stabilizers,
0.3 part of ultraviolet absorber, 50 parts of acrylic resins are placed in No. 1 batch mixer, under the conditions of revolving speed is 300r/min, are stirred
60min obtains No. 2 mixed slurries；No. 1 mixed slurry is coated on polyester film front, under the conditions of temperature is 160 DEG C, baking
Sizing, No. 2 mixed slurries are coated on polyester film reverse side, in temperature be 460 DEG C under the conditions of, high-temperature baking sizing to get every
Heat type vehicle explosion-proof film.The levelling agent is Lauxite.The antioxidant is butylated hydroxy anisole.The low melting point is closed
Gold is bismuth alloy.The ultraviolet absorber is resorcinol monobenzoate.
Example 6
Glass fibre is placed in ball milling in ball mill, the sieve of 100 mesh is crossed, obtains glass fiber powder, by glass fiber powder and quality point
Number is placed in reaction kettle for 35% hydrofluoric acid 1:20 in mass ratio, is that 500r/min is stirred under the conditions of temperature is 60 DEG C in revolving speed
After mixing reaction 60min, filtering obtains filter residue, is then neutrality by residue washing to cleaning solution with ammonium hydroxide, obtains single treatment glass fibers
Powder is tieed up, according to parts by weight, by 30 parts of single treatment glass fiber powders, 8 parts of potato starch, 0.2 part of biogas slurry, 40 parts of water are placed in
In No. 1 fermentation cauldron, it is 35 DEG C in temperature, under the conditions of revolving speed is 300r/min, mixed fermentation 5 days, is then dripped into No. 1 fermentation cauldron
0.3 times of mass fraction of ferric chloride solution and potato starch quality that 0.8 times of mass fraction of potato starch quality is 20% is added to be
5% Fluorinse is stirred 60min, obtains mixed serum, then by mixed serum under the conditions of revolving speed is 500r/min
It is placed in Rotary Evaporators, is 80 DEG C in temperature, under the conditions of pressure is 800Pa, 60min is concentrated under reduced pressure, obtains concentrate, then will
Concentrate is placed in baking oven, dry to constant weight under the conditions of temperature is 110 DEG C, obtains dried feed, dried feed is then placed in tubular type
In furnace, and nitrogen is filled with into furnace with 120mL/min rate, under the conditions of temperature is 750 DEG C, after carbonizing 3h, and 10 DEG C/min
Rate is warming up to 1550 DEG C, after pyroreaction 5h, is down to room temperature with furnace to get modified glass-fiber powder；Bamboo fibre is placed in powder
It is crushed in broken machine, crosses the sieve of 80 mesh, obtain bamboo fibre powder, according to parts by weight, by 20 bamboo fibre powder, 3 parts of biogas slurries, 30 parts of water are placed in
It is 35 DEG C in temperature, under the conditions of revolving speed is 300r/min, after mixed fermentation 5 days, filtering obtains No. 1 filter cake, connects in No. 2 fermentation cauldrons
No. 1 filter cake is placed in baking oven, under the conditions of temperature is 110 DEG C, dry to moisture content is 8%, obtains single treatment bamboo fibre
Single treatment bamboo fibre powder and ethyl orthosilicate 1:20 in mass ratio are placed in No. 2 beakers by powder, in revolving speed be 600r/min item
Under part, after being stirred 60min, filtering obtains No. 2 filter cakes, then by No. 2 filter cake liquid nitrogen frozens, must freeze material, then will freezing
Pellet grinds 50min, obtains secondary treatment bamboo fibre powder, and secondary treatment bamboo fibre powder is molten for 30% sodium hydroxide with mass fraction
Liquid 1:20 in mass ratio is placed in three-necked flask, is 50 DEG C in temperature, under the conditions of revolving speed is 500r/min, constant temperature is stirred to react 2h
Afterwards, it filters, obtains No. 3 filter cakes, be then neutrality by No. 3 Washing of Filter Cake to cleaning solutions with glacial acetic acid, then by No. 3 filters after washing
Cake is placed in baking oven, dry to constant weight under the conditions of temperature is 110 DEG C, obtains modified bamboo fiber powder；According to parts by weight, by 50
Part ethyl acetate, 40 parts of polyvinyl butyral resins, 5 parts of levelling agents, 5 parts of light stabilizers, 2 parts of antioxidants, 8 parts of low melting points
Alloy, 10 parts of modified glass-fiber powder are placed in No. 1 batch mixer, under the conditions of revolving speed is 300r/min, are stirred 60min,
Obtain No. 1 mixed slurry；According to parts by weight, by 50 parts of butyl acetates, 20 parts of silver powder, 20 parts of organic siliconresins, 10 parts of glass are micro-
Pearl, 10 parts of modified bamboo fiber powder, 5 parts of light stabilizers, 0.3 part of ultraviolet absorber, 50 parts of acrylic resins are placed in No. 1 batch mixer
In, under the conditions of revolving speed is 300r/min, it is stirred 60min, obtains No. 2 mixed slurries；No. 1 mixed slurry is coated on polyester
Film front, under the conditions of temperature is 160 DEG C, No. 2 mixed slurries are coated on polyester film reverse side, in temperature by baking sizing
Under the conditions of 460 DEG C, high-temperature baking is formed to get heat insulation type vehicle explosion-proof film.The levelling agent is Lauxite.The antioxygen
Agent is butylated hydroxy anisole.The low-melting alloy is bismuth alloy.The organic siliconresin is poly- methylsiloxane resin.
The ultraviolet absorber is resorcinol monobenzoate.
Example 7
Glass fibre is placed in ball milling in ball mill, the sieve of 100 mesh is crossed, obtains glass fiber powder, by glass fiber powder and quality point
Number is placed in reaction kettle for 35% hydrofluoric acid 1:20 in mass ratio, is that 500r/min is stirred under the conditions of temperature is 60 DEG C in revolving speed
After mixing reaction 60min, filtering obtains filter residue, is then neutrality by residue washing to cleaning solution with ammonium hydroxide, obtains single treatment glass fibers
Powder is tieed up, according to parts by weight, by 30 parts of single treatment glass fiber powders, 8 parts of potato starch, 0.2 part of biogas slurry, 40 parts of water are placed in
In No. 1 fermentation cauldron, it is 35 DEG C in temperature, under the conditions of revolving speed is 300r/min, mixed fermentation 5 days, is then dripped into No. 1 fermentation cauldron
0.3 times of mass fraction of ferric chloride solution and potato starch quality that 0.8 times of mass fraction of potato starch quality is 20% is added to be
5% Fluorinse is stirred 60min, obtains mixed serum, then by mixed serum under the conditions of revolving speed is 500r/min
It is placed in Rotary Evaporators, is 80 DEG C in temperature, under the conditions of pressure is 800Pa, 60min is concentrated under reduced pressure, obtains concentrate, then will
Concentrate is placed in baking oven, dry to constant weight under the conditions of temperature is 110 DEG C, obtains dried feed, dried feed is then placed in tubular type
In furnace, and nitrogen is filled with into furnace with 120mL/min rate, under the conditions of temperature is 750 DEG C, after carbonizing 3h, and 10 DEG C/min
Rate is warming up to 1550 DEG C, after pyroreaction 5h, is down to room temperature with furnace to get modified glass-fiber powder；By glass microballoon and matter
The dopamine solution 1:20 in mass ratio that amount concentration is 2.6mg/mL is placed in No. 1 beaker, under the conditions of revolving speed is 500r/min,
After being stirred 60min, filter to get pretreated glass microballon；Bamboo fibre is placed in pulverizer and is crushed, the sieve of 80 mesh is crossed,
Obtain bamboo fibre powder；According to parts by weight, by 50 parts of ethyl acetate, 40 parts of polyvinyl butyral resins, 5 parts of levelling agents, 5 parts of light
Stabilizer, 2 parts of antioxidants, 8 parts of low-melting alloys, 10 parts of modified glass-fiber powder are placed in No. 1 batch mixer, are in revolving speed
Under the conditions of 300r/min, it is stirred 60min, obtains No. 1 mixed slurry；According to parts by weight, by 50 parts of butyl acetates, 20 parts of silver
Powder, 20 parts of organic siliconresins, 10 parts of pretreated glass microballons, 10 parts of bamboo fibre powder, 5 parts of light stabilizers, 0.3 part of UV absorption
Agent, 50 parts of acrylic resins are placed in No. 1 batch mixer, under the conditions of revolving speed is 300r/min, are stirred 60min, are obtained No. 2 and are mixed
Close slurry；No. 1 mixed slurry is coated on polyester film front, under the conditions of temperature is 160 DEG C, baking sizing mixes No. 2
Slurry is coated on polyester film reverse side, and under the conditions of temperature is 460 DEG C, high-temperature baking is formed to get heat insulation type vehicle explosion-proof film.
The levelling agent is Lauxite.The antioxidant is butylated hydroxy anisole.The low-melting alloy is bismuth alloy.It is described
Organic siliconresin is poly- methylsiloxane resin.The ultraviolet absorber is resorcinol monobenzoate.
Comparative example: the vehicle explosion-proof film of Beijing energy conservation Science and Technology Ltd. production.
1 to 7 gained vehicle explosion-proof film of example and comparative example product are subjected to performance detection, the specific detection method is as follows:
Impact resistance, wear rate and the heat-insulated rate of above-mentioned rupture pressure disc are detected, specific testing result is as shown in table 1:
Table 1: performance detection table
By 1 testing result of table it is found that the present invention gained heat insulation type vehicle explosion-proof film have excellent explosion-proof performance, wear-resisting property and
Heat-proof quality.
Claims (9)
1. a kind of preparation method of heat insulation type vehicle explosion-proof film, it is characterised in that specific preparation process is as follows:
(1) according to parts by weight, by 30~50 parts of ethyl acetate, 30~40 parts of polyvinyl butyral resins, 3~5 parts of levellings
Agent, 3~5 parts of light stabilizers, 1~2 part of antioxidant, 5~8 parts of low-melting alloys, 8~10 parts of modified glass-fiber powder stirrings are mixed
It closes, obtains No. 1 mixed slurry；
(2) according to parts by weight, by 30~50 parts of butyl acetates, 10~20 parts of silver powder, 10~20 parts of organic siliconresins, 8~10
Part pretreated glass microballon, 8~10 parts of modified bamboo fiber powder, 3~5 parts of light stabilizers, 0.1~0.3 part of ultraviolet absorber, 30~
50 parts of acrylic resins are stirred, and obtain No. 2 mixed slurries；
(3) No. 1 mixed slurry is coated on polyester film front, it is anti-to be coated on polyester film by baking sizing for No. 2 mixed slurries
Face, high-temperature baking is to get heat insulation type vehicle explosion-proof film.
2. a kind of preparation method of heat insulation type vehicle explosion-proof film according to claim 1, it is characterised in that: step (1) is described
Levelling agent is any one in Lauxite or melamine resin.
3. a kind of preparation method of heat insulation type vehicle explosion-proof film according to claim 1, it is characterised in that: step (1) is described
Antioxidant is butylated hydroxy anisole, any one in dibutyl hydroxy toluene or tert-butyl hydroquinone.
4. a kind of preparation method of heat insulation type vehicle explosion-proof film according to claim 1, it is characterised in that: step (1) is described
Low-melting alloy is bismuth alloy, tin alloy, any one in sodium alloy or indium alloy.
5. a kind of preparation method of heat insulation type vehicle explosion-proof film according to claim 1, it is characterised in that: step (1) is described
The preparation process of modified glass-fiber powder are as follows: by glass fibre ball milling, cross the sieve of 100 mesh, glass fiber powder is obtained, by glass fibre
Powder is stirred to react with hydrofluoric acid 1:10~1:20 in mass ratio, is filtered, and washing obtains single treatment glass fiber powder, by weight
Number meter, by 20~30 parts of single treatment glass fiber powders, 5~8 parts of potato starch, 0.1~0.2 part of biogas slurry, 30~40 parts of water
0.5~0.8 times of potato starch quality of ferric chloride solution and potato starch quality 0.2~0.3 is then added dropwise in mixed fermentation
Fluorinse again, is stirred, and is concentrated under reduced pressure, dry, and charing heats up step by step, pyroreaction, cools down to get glass is modified
Glass fiber powder.
6. a kind of preparation method of heat insulation type vehicle explosion-proof film according to claim 1, it is characterised in that: step (2) is described
Organic siliconresin is poly- methylsiloxane resin, any one in poly- ethyl organic siliconresin or poly- aryl organic siliconresin.
7. a kind of preparation method of heat insulation type vehicle explosion-proof film according to claim 1, it is characterised in that: step (2) is described
The preparation process of pretreated glass microballon are as follows: glass microballoon and dopamine solution 1:10~1:20 in mass ratio are stirred,
Filtering is to get pretreated glass microballon.
8. a kind of preparation method of heat insulation type vehicle explosion-proof film according to claim 1, it is characterised in that: step (2) is described
The preparation process of modified bamboo fiber powder are as follows: bamboo fibre is crushed, the sieve of 80 mesh is crossed, bamboo fibre powder is obtained, according to parts by weight, by 10
~20 bamboo fibre powder, 2~3 parts of biogas slurries, 20~30 parts of water mixed fermentations, filtering, drying to moisture content are 5~8%, obtain and once locate
Bamboo fibre powder is managed, single treatment bamboo fibre powder and ethyl orthosilicate 1:10~1:20 in mass ratio are stirred, is filtered, liquid nitrogen
Freezing, ball milling obtains secondary treatment bamboo fibre powder, by secondary treatment bamboo fibre powder and sodium hydroxide solution 1:10~1 in mass ratio:
20 constant temperature are stirred to react, and are filtered, and are washed, dry, obtain modified bamboo fiber powder.
9. a kind of preparation method of heat insulation type vehicle explosion-proof film according to claim 1, it is characterised in that: step (2) is described
Ultraviolet absorber is resorcinol monobenzoate or 2-(2'- hydroxyl -5' t-octyl phenyl) any one in benzotriazole.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110156328A (en) * | 2019-04-28 | 2019-08-23 | 江苏华鸥玻璃有限公司 | A kind of novel fire resistant glass tube and its processing technology |
| CN116253985A (en) * | 2023-03-15 | 2023-06-13 | 山东基舜节能建材有限公司 | Glass fiber reinforced polyurethane foam plastic and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5830581A (en) * | 1996-04-17 | 1998-11-03 | Kansai Paint Co., Ltd. | Method for formation of coating film |
| CN108164726A (en) * | 2017-12-30 | 2018-06-15 | 南京陶特思软件科技有限公司 | A kind of preparation method of high temperature resistant vehicle rupture pressure disc |
-
2018
- 2018-07-28 CN CN201810849440.2A patent/CN109232944A/en not_active Withdrawn
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5830581A (en) * | 1996-04-17 | 1998-11-03 | Kansai Paint Co., Ltd. | Method for formation of coating film |
| CN108164726A (en) * | 2017-12-30 | 2018-06-15 | 南京陶特思软件科技有限公司 | A kind of preparation method of high temperature resistant vehicle rupture pressure disc |
Non-Patent Citations (1)
| Title |
|---|
| 朱美芳: "《中国战略性新兴产业-新材料 纤维复合材料》", 31 December 2017, 中国铁道出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110156328A (en) * | 2019-04-28 | 2019-08-23 | 江苏华鸥玻璃有限公司 | A kind of novel fire resistant glass tube and its processing technology |
| CN116253985A (en) * | 2023-03-15 | 2023-06-13 | 山东基舜节能建材有限公司 | Glass fiber reinforced polyurethane foam plastic and preparation method thereof |
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