CN103922870A - Active liquid crystal repair agent and preparation and application methods - Google Patents
Active liquid crystal repair agent and preparation and application methods Download PDFInfo
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Abstract
The invention relates to a self-reinforcing repair agent applied to biological or abiological porous materials as well as a preparation method and an application method. The active liquid crystal repair agent mainly comprises the following components in parts by weight: 30-50 parts of fat, 5-10 parts of pulp, 5-30 parts of scabs, 20-30 parts of auxiliaries, 5-10 parts of proteins and 5-10 parts of carbohydrate, wherein the fat is a mixture of animal and vegetable fat and mineral oil; the pulp is animal living body liquid and/or vegetable living body pulp; the scabs are animal scabs and/or vegetable viscose; the auxiliaries are phospholipids and/or lipoids; the proteins are animal proteins and/or vegetable proteins. The non-pressure dropping penetration application method of the active liquid crystal repair agent is characterized by piercing surface skin layers of porous materials, directly sending the active liquid crystal repair agent to the subcutaneous body tissues and enabling the active liquid crystal repair agent to actively moisten and penetrate the subcutaneous body tissues by virtue of the unique activity of the active liquid crystal repair agent.
Description
Technical field
The present invention relates to a kind of self-enhancement renovation agent that is applied to biological or abiotic porous material, and preparation method and using method.
Background technology
Biological field extensively exists special phase material, materialogy called after: liquid crystal; Phytology claims: juice; Zoology claims: body fluid.Liquid crystal is the basic substance of metabolism and circulation food chain.Metabolism is exactly the renewal process that orderly liquid crystal phase circulation develops.Food chain is: solid phase liquid crystal (food) through Digestive tract decompose disappear moltenly after being delivered to biopsy cell, develop into active liquid crystal (overcritical body) for liquefaction liquid crystal (Digestive system), absorption system are converted into liquid liquid crystal (slurries), circulation, penetration cell wall film becomes liquid phase lcp (endochylema) and is reduced to the oppositely approach excretion of solid phase liquid crystal (more new organization), waste.Living body biological transforms by the orderly phase of liquid crystal, completes distinctive material cycle course.After biological loss of activity, in body, liquid crystal circulating system stops, develops Disability, enters irreversible biological process.Under physical environment, biological body wind erosion liquefaction, oxygenolysis, biochemistry are polymerized to polymer viscose, develop into incrustation thing after viscose synersis.
Liquid crystal belongs to polymer organic-biological material, has the features such as carbon center's network architecture, capsule cell shape, the phase of taking advantage of a situation differentiation.At present synthetic liquid crystal is still located the primary stage of simple structure, small molecules amount, single two-pack, and limitation is applied to medical carrier and photoelectric display field, belongs to the jejune type material of research.
Nature extensively exists porous biological or non-biological material (being called for short: porous material), and biological species is as the biological body of bamboo wood etc.; Abiotic class is as concrete, ceramic sandstone etc.Porous material has close skin and myoplasm symbiosis texture.Skin is the surface covering contacting with the external world, by smooth exquisiteness, closely knit firm, multiple-layer stacked organizational composition; In skin, be enclosed with coarse, the loose fragile accumulation myoplasm of hole.Porous material has: the defects such as the general character such as proportion is light, elasticity weakening, heat preservation and soundproof and seepage cracking, erosion are festered, aging is rotten.
Porous material need rely on circulation selfreparing renewal just can resist erosion and feeble and decaying, disappearance must adopt spray trowelling brush, pouring and filling after regeneration system rapidly, apply and serve as a contrast foreign matter, cover the maintenance enhancements such as anticorrosion, by pressure high pressure or mechanical external force just can reach repair tissue, the object such as strengthen the property, delay senility.Deposit principle according to material phase patibhaga-nimitta, foreign peoples's storeroom there are differences person's character, and passing in time calmodulin binding domain CaM must occur: bubbling flakes, chap and the material such as peel off and repel divorced phenomenon, causes occurring the protection repair process of circulation.
At present adopt liquid crystal material and with no pressure to ooze the self-enhancement restorative procedure of mode to porous material, there is not yet documents and materials or patent report.
Summary of the invention
The object of the invention is to provide a kind of active liquid crystal renovation agent with self-enhancement repairing effect being combined by pure natural components.
Another object of the present invention is to provide the preparation method of this liquid crystal active renovation agent.
A further object of the present invention is to provide with no pressure of this liquid crystal active renovation agent and oozes application method.
Liquid crystal active renovation agent of the present invention is mainly grouped into by the one-tenth of following weight proportion: grease 30～50, slurries 5～10, incrustation 5～30, auxiliary agent 20～30, protein 5～10, carbohydrate 5～10; Described grease is the mixture of animal and plant grease and mineral oil; Described slurries are living animal body and/or liquid plant living body juice; Described incrustation is animal incrustation and/or mucilaginous gum thing; Described auxiliary agent is phosphatide and/or lipoid; Described protein is animal proteinum and/or vegetable-protein.
Grease of the present invention comprises: animal-plant oil and mineral oil.Described animal grease is as chicken pig, cattle and sheep fat and grease; Vegetable oil lipoprotein is the siccative oil that iodine number is greater than 130, as: paulownia, flax, Viscotrol C, and the semi-drying oil of iodine number approximately 130, as: beans, chaff, Sunflower Receptacle wet goods; Mineral oil comprises crude oil and hydro carbons overhead product.
Described slurry package contains: living animal body fluid, as: whey, egg white etc.; And plant living body juice, as: the quick frozen products such as mill base, latex.
Described incrustation comprises: animal incrustation, as: shellac, propolis etc.; And mucilaginous gum thing, as: peach gum, frankincense, rosin etc.
Described auxiliary agent comprises: phosphatide, lipoid and derivative etc.
Described protein comprises: animal proteinum, as: the proteolysates such as ovum, breast, silk; And vegetable-protein, as: hydrolytic soya bean protein, modified soy protein etc.
Described carbohydrate comprises: starch, cellulose hydrolysis material etc., as: glucose, dextrin, maltose etc.
Except above-mentioned composition, also can add tracer level antioxidant and perfume compound, as: vitamin-E, alcohol ketone, naphthalene anthracene and derivative etc., it adds weight is 0.001～0.01.
The preparation method of liquid crystal active renovation agent of the present invention is made up of following steps:
One, natural fats and oils is heated melt and dissolved, temperature is 60 ~ 80 DEG C, and high-speed stirring, is mixed to the state of dissolving, and obtains the oily mixing solutions intermediate of normal temperature liquid state;
Two, by suddenly to slurries, the incrustation degree of depth freezing, moment is expanded, vibrate and be milled to micronic dusts more than 1000 orders at-20 ~-25 DEG C, obtains being suspended colloidal sol after thawing;
Three, by adding auxiliary agent after step () and the mixing of step (two) products therefrom, under TRANSIENT HIGH TEMPERATURE, frequency conversion agitation condition, fully mix and make mixed solution colloidal sol;
Four, mixed solution colloidal sol is milled, pulse homogeneous, winterization growing the grain, is brokenly brilliantly separated, after isomery restructuring operation, obtains under normal temperature condition the just product of tool liquid crystal feature through colloid again;
Five, after the product anoxic packaging of above-mentioned just tool liquid crystal feature, be statically placed in and stop light and shake interference environment to hold crystalline substance, hold in brilliant process according to phase-state change trend, tremble in good time or stir, change crystalline phase growth trend, deposit more than three～six months, obtain dormant state liquid crystal active renovation agent product.
The above-mentioned degree of depth is anxious freezes, moment is expanded, vibrate mill, TRANSIENT HIGH TEMPERATURE, frequency conversion stirring, colloid are milled, pulse homogeneous, winterization growing the grain, brokenly brilliantly separate, isomery restructuring is this area current techique.
In described preparation method, step 1 grease component heating (60～80 DEG C) dissolves, speed change stirs (15～180rpm), be fully to mix each component raw material grease to carry out transesterify isomerization reaction, adjust isomery grease zero pour and iodine value, reach the object of modification isomery grease; After the liquid nitrogen of step 2 slurries, incrustation raw material and same volume or dry ice mix in enclosed high pressure still, reach degree of depth urgency and freeze (196～-78.5 DEG C) and instantaneous high pressure state.After environmental stress balance in pressure and still in raw cell, make environment instantaneous loss of pressure in still by blow-off valve, cell inner equilibrium high pressure gas expand, and moment breaks through cell wall, the active born of the same parents' juice of drainage and retains active object.It is under far below moisture zero pour (20 ~-25 DEG C) condition that low temperature is smashed to pieces, utilizes ice crystal gravel and the mechanical force of the vibrating expanded loose cell wall tissue of milling, and obtains the colloidal sol that is suspended of superelevation dispersity after thawing; Step 3 is by abundant to above-mentioned products therefrom and protein, carbohydrate, auxiliary agent, antioxidant and perfume compound melt and dissolved mixing, and the object that adds auxiliary agent is the intergranular repulsive force that is reduced or eliminated foreign peoples's raw material by emulsification.In this process, be suspended colloidal sol and contact with the microbial population of environment space, complete aerobian inoculation diffusion process.Each phase material fully contacts and under microorganism participates in, is suspended after collosol substance produces reversible stack biochemical reaction and makes elementary lyosol; The colloid of step 4 iterative cycles is milled, pulse homogeneous, winterization growing the grain, brokenly brilliantly separate, isomery regrouping process is to cause, between elementary lyosol material, complex biochemical reaction occurs, and progressively develops the critical process of liquid crystal structure, obtains just tool liquid crystal characteristic product; Step 5 just tool liquid crystal characteristic product anoxic is packed after (perfusion nitrogen or rare gas element), enter " holding crystalline substance " process, liquid crystal slurry born of the same parents change with ambient air temperature or trickle vibration is disturbed, and automatically starch born of the same parents' parcel and engulf, melt mutually and organize the complicated non-polymeric structural evolution such as network chain, derivative variation restructuring.According to survival of the fittest rule: the mesomorphic phase like a fish out of water extinction of progressively recombinating, the liquefaction liquid crystal hyperplasia that finally conforms is retained, and obtains the product of the application's liquid crystal active renovation agent dormant state.
The product that step 5 obtains for a long time lucifuge leaves standstill storage.Before use, need to replace pack environment gas and secondary and complete happiness oxygen microbial inoculant and the use of diffusion ability activity recovery.Visual observations dormancy LCD product, is converted into muddiness by the transparent phase of halation moment and hangs newborn phase, proves to occur chain type solution and collapses reaction, and crystalline phase is cracked into the liquid liquid crystal with mobility.
It is to pierce through porous material surface skin layer that with no pressure of liquid crystal active renovation agent of the present invention oozed application method, and liquid crystal active renovation agent is directly sent to subcutaneous when injected organism tissue, and the unique activity possessing by liquid crystal active renovation agent is initiatively soaked infiltration.
Liquid crystal active renovation agent of the present invention has superfluidity, can enter peripheral hardware pipe network or myoplasm is organized tube gap by gravity with no pressure, and smooth delivery of power is to required reparation strongthener region.The continuous gravity of liquid crystal active renovation agent infiltrates flow process, and self-assembling formation chain type solution collapses and assembles contraction circulation with no pressure, manifests the distinctive flow patterns of liquid crystal such as slow wriggling immersion, transverse dispersion.When contact porous material chamber wall, moment fission is for having the active liquid crystal of overcritical body performance again for liquid crystal active renovation agent, and density is close to liquid, and viscosity is close to gas, and spread coefficient is large, viscosity is little, and diffusibleness is close to gas etc.Make it possess the porous material of walking through hole microgap as the ability of piercing the clouds and mist, can freely go around in microstructure area of space.Stop that porous material is normal staticly stays liquid crystal in particle size hole to be crystal peptone or inversion is that dormant state possesses activity for a long time, be stranded in the liquid crystal active renovation agent of porous material variation defect area except occurring anchoring infiltration phenomenon with material structure contact area, in pipe, liquid crystal active renovation agent is under segregation drive, explicit solution collapses the circulation of meeting again and drives mobile, infiltrate myoplasm open texture, the liquid crystal active renovation agent of contact tissue part is organized under the collaborative erosion of acid-alkali salt environment in microorganism participation and myoplasm, there is loss of activity, liquefaction is separated brilliant, divide and depolymerize, the complicated irreversible biochemical dead reaction such as film forming crystallization, finally develop into and infiltrate fixed " root " of myoplasm tissue film anchoring, the high molecular polymers such as the contraction nethike embrane of covering myoplasm body.Polymkeric substance is the stacking flexible fiber tissue (similar tendon hoof) that develops in the environment of adequate moisture; Wet environment moisture absorption is reversible change is the tens of extremely peptones of thousands of times of volumetric expansion; The dry environment rigid fiber organizer (similar muscles and bones) that is of dewatering; The circulation that becomes class incrustation thing after the dehydration of surface develops material.
Liquid crystal active renovation agent of the present invention is wriggled, is detained in infiltration process in slow diffusion; characteristic with no pressure guarantees to protect to greatest extent the network structure of porous material fragility, and fixed parcel is filled repair structure body to be attached to the dead liquid crystal self-assembling formation of myoplasm tissue and the anchoring of former myoplasm tissue film.Liquid liquid crystal peristaltic velocity myoplasm tissue volume slower, diffusion is larger, anchorage fixed sturcture system is more perfect.
The instillation using method with no pressure of the present invention's original creation is to pierce through porous material surface skin layer, and liquid crystal active renovation agent is directly sent to subcutaneous when injected organism tissue, and the unique activity possessing by liquid crystal active renovation agent material is initiatively soaked infiltration.Liquid liquid crystal active renovation agent is all organizing internal layer automatically to carry out to the immersion diffusion of myoplasm with repairing enhancing, disobeys the basic not damaged of subordinate list layer material and effects on surface, can reach the industry ideal expectation object that the harmless self-enhancement of porous material is repaired.Though this liquid crystal active renovation agent also can adopt the techniques such as traditional spray soaks to use, but porous material surface skin layer dense structure, complex structure and liquid crystal infiltrates, polymerization cycle is very long, its efficiency is far below ripe resin paint film, except interim Emergency use, the application does not recommend this quasi-tradition construction technology.
Embodiment
Embodiment 1: liquid crystal active renovation agent is applied to concrete impervious mending-leakage and self-enhancement reparation
Active liquid crystal renovation agent proportioning raw materials of the present invention (weight): grease 42, wherein: soya-bean oil 20, hydro carbons overhead product 10, tung oil 7, butter 5; Body fluid 11, wherein: quick-frozen latex rubber 8, quick-frozen egg liquid 3; Incrustation thing 6, wherein: peach gum 2, propolis 3, chitin 1; Auxiliary agent 30, wherein: sodium soap 10, mixed phosphatide 20; Protein 8, wherein: milk protein hydrolysate 2, silk-protein hydrolyzate 3, hydrolytic soya bean protein 3; Carbohydrate 3, wherein: dextrin 2, glucose 1; Oil antioxidant (vitamin-E) 0.001, perfume compound 0.001.
preparation technology:
Each component Lipid use negative pressure is sucked to the interlayer reactor with whipping appts, in interlayer, import lower than hot water heating (the approximately 60 DEG C) 120-180rpm of boiling point and stir as modification compound lard.
Lipid acid, alcohols or the mutual acidolysis of other lipid or alcoholysis reaction between this technological process grease, transesterify fatty acid radical produces new cis isomerism, trans-isomerism ester class and quasi-grease derivative etc. each other.By the modification compound lard after transesterify, although not forming, their total fatty acids changes, because lipid acid binding site changes, its physical properties has significant variation as crystalline phase, plasticity, activity, zero pour etc.
Body fluid and incrustation thing are dropped into autoclave, add the dry ice of same volume after closing device leave standstill.Until temperature in the kettle go up, pressure rise to space pressure balance in ICP and still, open emptier moment pressure release, the cell walls of the disintegration semi-permeable membranes character of exploding, cytolemma tissue is puffed to the crisp body of structure; The carbonic acid gas that gasifies after low temperature broken wall retains envrionment conditions in anoxic still because proportion is more still deposited in reactor, and the outflow cell juice that prolection is extremely strong, avoids loss of activity and deterioration by oxidation.Complete the low temperature broken wall of raw material, obtain the active cells juice of hypoxia protection.Active cells juice shakes stamper hammering under (20 ~-25 DEG C) condition by low temperature mills and pulverizes expanded loose cell envelope tissue, and the taking-up of thawing at ambient temperature makes the active high degree of dispersion of ultra-fine micronic dust (approximately 1800 ~ 2000 order) and is suspended colloidal sol.
Low temperature shake stamper is a kind of professional equipment for cell tissue broken wall, the superfine grinding of survival micronic dust in recent years occurring, its outer likeness in form courage, has circulation low temperature cooling system and high-frequency vibration system, places numerous column vibrating spears in courage.High-frequency vibration courage body after cellular material drops in courage, the vibrating spear in courage rocks at random under vibration source and gravity inertial; The friction rubbing that cell tissue is mixed between vibrating spear is progressively pulverized; The cell tissue that is deposited on courage body bottom is also progressively pulverized under the vibrating spear of bob knocks; Moisture in material is condensed into gravel shape ice crystal under freezing conditions low temperature simultaneously, becomes milling and dispersing material of the ultra-fine cell tissue of micronic dust; The machinery heating loss of activity phenomenon producing in process of vibrating, is got rid of by circulation low temperature cooling system; Airtight courage type structure can also effectively be avoided traditional disintegrating apparatus defect such as material loss, dust pollution.
Be suspended colloidal sol and add after protein, carbohydrate, auxiliary agent and oil antioxidant under room temperature opening condition, suck the interlayer reactor of above-mentioned splendid attire modification compound lard; After high voltage pulse, TRANSIENT HIGH TEMPERATURE, frequency conversion whipping process, become oil soluble suspension liquid, then iterative cycles developed into elementary lyosol after approximately 8 ~ 36 hours.
Elementary lyosol pumps into the brilliant growing the grain system of mill forming by organizing colloidal mill, clarifixator, whizzer, thin layer plate-type heat exchanger, winterization maturator more, and circulation develops into after approximately 8 ~ 10 weeks repeatedly preserves bioactive liquid phase lcp under normal temperature condition.Liquid phase lcp adopts and fills the filling rear vanning of nitrogen, is statically placed in and stops light and shake the environment disturbing to deposit the LCD product that obtains possessing above dormancy characteristic for three months.Environmental temperature fluctuation and logistics transportation that dormancy LCD product can be resisted in storage process rock interference, liquid crystal is under dormant state, continue perfect reversible repetitive assignment polymerization process, according to survival of the fittest principle: the good dormancy liquid crystal of the condition that finally conforms is most stored in " packing bag ".
The evolution process of Concrete Leakage:
Concrete is cement, sand, Shi Yushui, the coalescent artificial stone material of making through hydration reaction, and it is the silicate material taking calcium carbonate as aggregate that group is wanted composition.Hydration reaction is violent heat-producing chemical reaction, and liquid moisture is heated gasification volumetric expansion more than 1000 doubly, and inside concrete is steamed to bubble for aggregate structure human body; Myoplasm inside is left over and is communicated with the spongy steam honeycomb space of escaping in hydration reaction and condensing process; Space inwall adheres to fine and close skin shape film; Pellicular front is separated out complex inorganic salt catalyst bases xln; Xln filling channel space, form is just as covering with the grotto of Stalactitum or stalagmite.Normal concrete myoplasm have good water resistant refuse to ooze, rainproof every wet, heat preservation and soundproof function.
In air ambient, have micro-carbonic acid gas, industrial acid mist and steam, in hydrogenesis process, dissolve acid mist, in concrete use procedure, spongy human body space internal memory gas, varies with temperature and environment alternation of wetting and drying, and volumetric shrinkage or expansion manifest respiratory.When night or temperature reduce, acid mist or steam suck and enter myoplasm space with gas, corrode space inwall or the dissolving crystallized fluent solution that becomes; When daytime or temperature raise, the concentrated corrosion of solution evaporation space inwall, recrystallization solute cause myoplasm crystallization displacement, flow out concrete surface occurs that salt efflorescence shape leaves over that in vestige, tissue, micropore crack increases gradually, honeycomb film like inwall festers, occurs water-permeable undercurrent pipe network, directly causes the pipe network powdered of subsiding and disintegrate.The aging courses such as that buildings occurs is sombre moist, structure is loose, strength decreased, seepage drip and drop down, steel bar corrosion.
Implementation method:
First the dormant state liquid crystal active renovation agent product of the present embodiment being made, opening encapsulation enveloping cover, displacement packing material gaseous constituent, secondary are introduced a fine variety aerobian; Rock the packing bag of liquid crystal active renovation agent pushing by external force, forcing vibrates brings out liquid crystal chain type solution and collapses reaction, and active liquid crystal moment of dormant state, crystalline phase cracking chain reaction occurred, and is converted into muddy outstanding newborn state mixes mutually liquid liquid crystal by the transparent cis crystalline phase of halation.
On concrete product, use the damaged mode of apparatus, penetrating epidermal area drills micropore (diameter is more than 0.5 millimeter, direction is downward-sloping, be deep to material center for best), by outreach pipe network by liquid LCD product under gravity or non-gravity drive, with no pressure trickling to concrete porous material tissue, temporary fixed apparatus and sealing are dripped and are oozed face, carry out with no pressure and ooze construction.
When the liquid liquid crystal active renovation agent contact cellular sharp-pointed microgap of new damaged porous material chamber wall is organized, the liquid liquid crystal active renovation agent that its sharp-pointed surface of a wound can broken splash into, liquid liquid crystal active renovation agent again moment fission, for having the active liquid crystal of overcritical body performance, possesses the porous material of walking microgap through hole ability.Under segregation drive with no pressure, the aobvious active liquid crystal of liquid crystal active renovation agent and liquid liquid crystal circulant solution collapse the diffusion of reunion wriggling self-powered, laterally or downwards flow and infiltrate porosity and looseness tissue, the liquid crystal active renovation agent infiltrating microorganism participate in and the collaborative etching reaction of organizer's acid-alkali salt environment under, occur loss of activity, liquefaction separate brilliant, point depolymerize, complicated irreversible biochemical dead reaction the such as saponification calcification, film forming crystallization.Organize anchoring to take root at inside concrete, conjunctiva covers, saponification is filled up, calcification is enriched, shrink crystallization etc., form new smooth steadiness inwall conjunctiva layer and coralliform crystallization clump, repair weathering aging concrete organization internal space inwall, the damaged xln that recovers to run off, fill up the micropore crack that disappearance increases or fester subside region, stop up and cut off seepage undercurrent pipe network system etc.; The gal4 amino acid composition that liquid crystal active renovation agent is decomposed in liquefaction reacts with concrete calcium silicon ion, generates amino acid calcium silicon salt; Carbohydrate collateralization is met again and is formed high score subnet structure film; The lipid acid of generation spoiled by rancid oil or fat and calcium silicon ion saponification reaction generate the glycerol of fatty acid calcium silicon salt and moisture-absorbing moisture-keeping; Between amino acid, carbohydrate, lipid acid, class ester thing, also there are random complicated stack, crosslinked reunion etc. and become membrane stack reaction; develop into flexible fiber tissue, rigid group textured fiber body, peptone shape hygroscopic material and incrustation fabric texture etc., reach and stop up the protection of seepage undercurrent pipe network, self-reinforced material performance and recover object concrete is harmless.
Embodiment 2: liquid crystal active renovation agent is applied to the reparation of timber cracking resistance and self-enhancement maintenance
Raw material: grease 50, wherein: lacquer tree oil 20, tung oil 20, sheep oil 10; Body fluid 30, wherein: quick-frozen latex 18, quick-frozen mill base 12; Incrustation thing 5, wherein: propolis 2, frankincense 1, rosin 2; Auxiliary agent 10, wherein: soap 10, mixed phosphatide 20; Protein 3, wherein: modified soy protein 3; Carbohydrate 2, wherein: maltose 1, glucose 1; Perfume compound 0.003.
Preparation technology: with above-described embodiment 1.
The evolution process of foxy:
Timber is widely used natural porous tissue material, in live body growth, has up and down connected juice delivery conduit to organize pipe network.In healthy tissues pipeline, tube wall is all attached with film like skin, the organic-biological bases resin compounded of growing on film filling pipeline, and its structure is just as covering with the network of coral.
Timber is the biological body of loss of life, is cell tissue aggregate stack structure.Losing after the biology metabolism of circulation, the dry relict cell paste porous material of weathering suffers after erosion by wind and rain, occur that in various degree compound resin runs off and cytolemma skin is rotten festers, progressively occur that cracking is rotten, fester in cavity, subside or powdered disintegration.
Implementation method:
Liquid crystal wakes technique up: with above-described embodiment 1 awakening method.
On wood raw material or goods, use the damaged mode of apparatus, penetrating epidermal area drills micropore (diameter is more than 0.5 millimeter, direction is downward-sloping, be deep to material center for best), by outreach pipe network by liquid crystal active renovation agent product under gravity or non-gravity drive, with no pressure trickling to timber porous material tissue, temporary fixed apparatus and sealing are dripped and are oozed face, carry out with no pressure and ooze construction.
After the biology metabolism pipe network tissue that the new damaged timber porous material of liquid crystal active renovation agent contact is left over, liquid liquid crystal fission navigates within metabolic micro-pipe network for active liquid crystal.Under driving with no pressure, active liquid crystal and liquid liquid crystal circulant solution collapse the diffusion of reunion wriggling self-powered, laterally or downwards flow infiltration metabolism and leave over pipe network, the liquid crystal infiltrating microorganism participate in and the collaborative biochemical reaction of organizer's organic acid alkali salt hangover environment under, occur loss of activity, liquefaction separate brilliant, point depolymerize, complicated irreversible biochemical dead reaction the such as saponification isomery, film forming crystallization.Take root in the anchoring of timber interior tissue, conjunctiva covers, crystallization etc. is filled up, shunk in saponification, form new smooth steadiness inwall conjunctiva layer and coralliform crystallization clump, repair weathering aging texture of wood internal voids inwall, the damaged xln that recovers to run off, fill up the micropore crack that disappearance increases or fester subside region, stop up and cut off seepage undercurrent pipe network system etc.
The gal4 amino acid composition of liquid crystal active renovation agent and the alkaloid ionic reaction that timber is left over are decomposed in liquefaction, generate amino acid calcium biogenic salt; Carbohydrate collateralization is met again and is formed high score subnet structure film; The lipid acid of generation spoiled by rancid oil or fat is reassembled as glycerol and the isomer of isomery network chain membrane structures matter and moisture-absorbing moisture-keeping; Between amino acid, carbohydrate, lipid acid, class ester thing, also there are random complicated stack, crosslinked reunion etc. and become membrane stack reaction; develop into flexible fiber tissue, rigid group textured fiber body, peptone shape hygroscopic material and incrustation fabric texture etc., reach and stop up the protection of seepage undercurrent pipe network, self-reinforced material performance and recover object timber is harmless.
Embodiment 3: liquid crystal active renovation agent is applied to sandstone weathering reparation and self-enhancement maintenance
Raw material: grease 30, wherein: butter 10, crude oil 20; Slurries 10, wherein: quick-frozen latex 2, whey 1, egg white 7; Incrustation thing 30, wherein: propolis 25, frankincense 2, rosin 3; Auxiliary agent 25, wherein: soap 5, mixed phosphatide 20; Protein 3, wherein: modified soy protein 3; Carbohydrate 2, wherein: dextrin 2; Perfume compound 0.003.
Preparation technology: with above-described embodiment 1.
The evolution process that sandstone weathering is rotten:
Sandstone is widely used natural abiotic porous organization material, has the weathering pipe network tissue running through up and down in material.In healthy tissues pipeline, tube wall is all attached with symbiotic microorganism film like skin, and on film, apposition growth organic microbial complex body filling pipeline, and its structure is just as covering with the network of coral.
Sandstone is abiotic silicate deposit body, is silicate aggregate stack structure.Under weathering wet condition, symbiote cell residue body suffers after erosion by wind and rain, occurs that in various degree the residual body of biomass cells runs off and silicate granules weathering is festered, and progressively occurs that cavity is rotten, subside or powdered is disintegrated.
Implementation method:
Liquid crystal wakes technique up: with above-described embodiment 1 awakening method.
On sandstone, use the micro-damaged mode of apparatus, penetrating epidermal area drills micropore (diameter is more than 0.5 millimeter, direction is downward-sloping, be deep to material center for best), by outreach pipe network by liquid crystal active renovation agent product under gravity or non-gravity drive, with no pressure trickling to sandstone porous material inside, temporary fixed apparatus and sealing are dripped and are oozed face, carry out with no pressure and ooze construction.
After the weathering Erosion pipe network that the new damaged sandstone porous material of liquid liquid crystal active renovation agent contact is left over, liquid liquid crystal active renovation agent fission navigates within the micro-pipe network of weathering Erosion for active liquid crystal.Under driving with no pressure, active liquid crystal and liquid liquid crystal circulant solution collapse the diffusion of reunion wriggling self-powered, laterally or downwards flow infiltration weathering Erosion and leave over pipe network, the liquid crystal infiltrating microorganism participate in and the inorganic or organic acid alkali salt hangover concerted reaction of weathering Erosion material under, occur loss of activity, liquefaction separate brilliant, point depolymerize, complicated irreversible biochemical dead reaction the such as saponification silication, film forming crystallization.Weathering Erosion interior tissue anchoring at sandstone is taken root, conjunctiva covers, saponification is filled up, calcification is enriched, shrink crystallization etc., form new smooth steadiness inwall conjunctiva layer and coralliform crystallization clump, repair weathering aging sandstone organization internal space inwall, the damaged xln that recovers to run off, fill up the micropore crack that disappearance increases or fester subside region, stop up and cut off seepage undercurrent pipe network system etc.
The alkaline silicon ion that the gal4 amino acid composition of liquefaction decomposition liquid crystal active renovation agent is left over sandstone reacts, and generates amino acid silicon salt; Carbohydrate collateralization is met again and is formed high score subnet structure film; The lipid acid of generation spoiled by rancid oil or fat is reassembled as glycerol and the isomer of isomery network chain membrane structures matter and moisture-absorbing moisture-keeping; Between amino acid, carbohydrate, lipid acid, class ester thing, also there are random complicated stack, crosslinked reunion etc. and become membrane stack reaction; develop into flexible fiber tissue, rigid group textured fiber body, peptone shape hygroscopic material and incrustation fabric texture etc., reach and stop up the protection of seepage undercurrent pipe network, self-reinforced material performance and recover object sandstone is harmless.
Claims (4)
1. a liquid crystal active renovation agent, is characterized in that being mainly grouped into by the one-tenth of following weight proportion: grease 30～50, slurries 5～10, incrustation 5～30, auxiliary agent 20～30, protein 5～10, carbohydrate 5～10; Described grease is the mixture of animal and plant grease and mineral oil; Described slurries are living animal body and/or liquid plant living body juice; Described incrustation is animal incrustation and/or mucilaginous gum thing; Described auxiliary agent is phosphatide and/or lipoid; Described protein is animal proteinum and/or vegetable-protein.
2. liquid crystal active renovation agent as claimed in claim 1, is characterized in that containing antioxidant and perfume compound, and it adds weight is 0.001～0.01.
3. the preparation method of liquid crystal active renovation agent as claimed in claim 1, is characterized in that being made up of following steps:
One, natural fats and oils is heated melt and dissolved, temperature is 60 ~ 80 DEG C, and high-speed stirring, is mixed to the state of dissolving, and obtains the oily mixing solutions intermediate of normal temperature liquid state;
Two, by suddenly to slurries, the incrustation degree of depth freezing, moment is expanded, vibrate and be milled to micronic dusts more than 1000 orders at-20 ~-25 DEG C, obtains being suspended colloidal sol after thawing;
Three, by adding auxiliary agent after step () and the mixing of step (two) products therefrom, under TRANSIENT HIGH TEMPERATURE, frequency conversion agitation condition, fully mix and make mixed solution colloidal sol;
Four, mixed solution colloidal sol is milled, pulse homogeneous, winterization growing the grain, is brokenly brilliantly separated, after isomery restructuring operation, obtains under normal temperature condition the just product of tool liquid crystal feature through colloid again;
Five, after the product anoxic packaging of above-mentioned just tool liquid crystal feature, be statically placed in and stop light and shake interference environment to hold crystalline substance, hold in brilliant process according to phase-state change trend, tremble in good time or stir, change crystalline phase growth trend, deposit more than three～six months, obtain dormant state liquid crystal active renovation agent product.
4. the using method of liquid crystal active renovation agent as claimed in claim 1, it is characterized in that it is to pierce through porous material surface skin layer that with no pressure of liquid crystal active renovation agent oozed application method, liquid crystal active renovation agent is directly sent to subcutaneous when injected organism tissue, initiatively soak infiltration by the activity of liquid crystal active renovation agent.
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| CN107281769A (en) * | 2017-06-24 | 2017-10-24 | 侯梦斌 | A kind of method for directly harvesting plant extract solids |
| CN114349534A (en) * | 2019-11-05 | 2022-04-15 | 重庆地质矿产研究院 | Application of repairing agent in protecting and repairing stalactite and method for repairing stalactite by inducing mineralization through microorganisms |
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| CN101954373A (en) * | 2010-09-21 | 2011-01-26 | 上海大学 | Method for restoring oil polluted wet land by combination of plant and microorganism |
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| CN107281769B (en) * | 2017-06-24 | 2019-08-13 | 侯梦斌 | A kind of method directly harvesting plant extract solids |
| CN114349534A (en) * | 2019-11-05 | 2022-04-15 | 重庆地质矿产研究院 | Application of repairing agent in protecting and repairing stalactite and method for repairing stalactite by inducing mineralization through microorganisms |
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Application publication date: 20140716 Assignee: Kunming crystal Biotechnology Co.,Ltd. Assignor: Wang Jiwei Contract record no.: 2016530000010 Denomination of invention: Active liquid crystal repair agent and preparation and application methods Granted publication date: 20150826 License type: Common License Record date: 20160325 |
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