CN103911890A - Adhesive used for fabric, and preparation method thereof - Google Patents
Adhesive used for fabric, and preparation method thereof Download PDFInfo
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- CN103911890A CN103911890A CN201310726169.0A CN201310726169A CN103911890A CN 103911890 A CN103911890 A CN 103911890A CN 201310726169 A CN201310726169 A CN 201310726169A CN 103911890 A CN103911890 A CN 103911890A
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- butadiene
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Abstract
The invention discloses an adhesive used for a fabric. The adhesive is composed of the following components by weight: 4-8 parts of butadiene, 8-12 parts of acrylonitrile, 3-8 parts of propanediol, 3-6 parts of etherified hydroxymethyl(methyl) acrylamide, 3-6 parts of maleic anhydride, 3-8 parts of ethanol, 3-5 parts of dimethyl formamide, 40-60 parts of acetone and 3-5 parts of polysulfone. Compared with a conventional adhesive, the adhesive provided by the invention has the following beneficial effects that (1) the adhesive has relatively high adhesive force and reproducibility, can resist ageing, solvent, acid and alkali and chemical agents, and a film formed by the adhesive is clear and transparent; and (2) the adhesive does not change color or damage fibers after being printed, has relatively good elasticity, good handfeel, and can be cleared from a printing device easily.
Description
Technical field
The invention belongs to textile auxiliary technical field, more specifically relate to a kind of fabric adhesive and preparation method thereof.
Background technology
Adhesive is the key component of textile printing pigment, and it is a kind of macromolecule filming material, is formed by various monomer polymerizations, by film forming, pigment is adhered on fabric, therefore the quality of filming performance will directly affect the fastness ability of PRINTED FABRIC.
The binder performance of single type comparatively limits to, and it is more difficult requiring a kind of resin to possess above-mentioned various condition, is also unpractical simultaneously, so adopt often two kinds or two or more resin blendings in addition, make it to complement each other, thereby obtain satisfied result.
At present, the kind of adhesive with 50, the product in the sixties is different, substantially belongs to third generation adhesive (high-temperature self-crosslinking type).First generation adhesive be can not be crosslinked macromolecule filming copolymer, be suitable for low temperature and cure (100 ℃); And in second generation adhesive, contain hydroxyl, carboxyl, amino, amide groups, cyano group isoreactivity group, in heating process can with fiber on hydroxyl form covalent bond, or react with additional crosslinking agent, thereby improve every application performance; Although third generation auto crosslinking binder is also Acrylate copolymerical emulsion, but in monomer, add self-cross linking monomer, conventional self-cross linking monomer has n-methylolacrylamide, methylol (methyl) acrylamide, etherificate n-methylolacrylamide etc., Printing is in the process of curing, two methylols form crosslinked from phase condensation, form network structure by the large molecule of wire, make the film of adhesive can not expand and be difficult for washing off after running into water, thereby improved the fastness of PRINTED FABRIC.Adhesive was suitable for high temperature and cured (140~150 ℃) in generation second and third.Third generation adhesive is also applicable to dacron, can simplify dyeing and printing process, and from direct printing and resist-discharge printing technological development to slurry stamp.
Summary of the invention
The object of the invention is to overcome the deficiency that prior art exists, a kind of fabric adhesive is provided.
Another object of the present invention is to provide the preparation method of this fabric adhesive.
For achieving the above object, the present invention has taked following technical scheme:
A kind of fabric adhesive, in weight portion, composed of the following components:
Butadiene: 4~8, propylene is fine: 8~12, propylene glycol: 3~8,
Etherificate methylol (methyl) acrylamide: 3~6, maleic anhydride: 3~6,
Ethanol: 3~8, dimethyl formamide: 3~5, acetone: 40~60, polysulfones: 3~5.
As preferably, described a kind of fabric adhesive, in weight portion, composed of the following components:
Butadiene: 4, propylene is fine: 8, propylene glycol: 3,
Etherificate methylol (methyl) acrylamide: 3, maleic anhydride: 3,
Ethanol: 3, dimethyl formamide: 3, acetone: 40, polysulfones: 3.
As preferably, described a kind of fabric adhesive, in weight portion, composed of the following components:
Butadiene: 8, propylene is fine: 12, propylene glycol: 8,
Etherificate methylol (methyl) acrylamide: 6, maleic anhydride: 6,
Ethanol: 8, dimethyl formamide: 5, acetone: 60, polysulfones: 5.
As preferably, described a kind of fabric adhesive, in weight portion, composed of the following components:
Butadiene: 6, propylene is fine: 10, propylene glycol: 6,
Etherificate methylol (methyl) acrylamide: 5, maleic anhydride: 4,
Ethanol: 6, dimethyl formamide: 4, acetone: 50, polysulfones: 4.
The preparation method of adhesive for described a kind of fabric, comprises following technical step:
(1) by proportioning, fine to butadiene, propylene, polysulfones and acetone are mixed, be warming up to 40~60 ℃, dispersed with stirring is even;
(2) all the other components are mixed, be warming up to 30~50 ℃, dispersed with stirring is even;
(3) product of the product of step (1) and step (2) is mixed, dispersed with stirring is even;
(4) be cooled to after room temperature, get final product to obtain finished product.
Compared with prior art, the present invention has following beneficial effect:
(1) there is higher adhesion strength and reappearance, ageing-resistant, resistance to solvent, acid and alkali-resistance and chemically-resistant medicament, film forming is Clear & Transparent,
(2) nondiscolouring and do not damage fiber after stamp, has preferably elasticity, good hand touch, and be easy to remove from printing equipment.
The specific embodiment
Below in conjunction with specific embodiment, the invention will be further described.
Embodiment 1
A kind of fabric adhesive, in weight portion, composed of the following components:
Butadiene: 4, propylene is fine: 8, propylene glycol: 3,
Etherificate methylol (methyl) acrylamide: 3, maleic anhydride: 3,
Ethanol: 3, dimethyl formamide: 3, acetone: 40, polysulfones: 3.
Embodiment 2
A kind of fabric adhesive, in weight portion, composed of the following components:
Butadiene: 8, propylene is fine: 12, propylene glycol: 8,
Etherificate methylol (methyl) acrylamide: 6, maleic anhydride: 6,
Ethanol: 8, dimethyl formamide: 5, acetone: 60, polysulfones: 5.
Embodiment 3
A kind of fabric adhesive, in weight portion, composed of the following components:
Butadiene: 6, propylene is fine: 10, propylene glycol: 6,
Etherificate methylol (methyl) acrylamide: 5, maleic anhydride: 4,
Ethanol: 6, dimethyl formamide: 4, acetone: 50, polysulfones: 4.
The preparation method of adhesive for described a kind of fabric, comprises following technical step:
(1) by proportioning, fine to butadiene, propylene, polysulfones and acetone are mixed, be warming up to 40~60 ℃, dispersed with stirring is even;
(2) all the other components are mixed, be warming up to 30~50 ℃, dispersed with stirring is even;
(3) product of the product of step (1) and step (2) is mixed, dispersed with stirring is even;
(4) be cooled to after room temperature, get final product to obtain finished product.
Claims (5)
1. a fabric adhesive, is characterized in that, in weight portion, composed of the following components:
Butadiene: 4~8, propylene is fine: 8~12, propylene glycol: 3~8,
Etherificate methylol (methyl) acrylamide: 3~6, maleic anhydride: 3~6,
Ethanol: 3~8, dimethyl formamide: 3~5, acetone: 40~60, polysulfones: 3~5.
2. a kind of fabric adhesive according to claim 1, is characterized in that, in weight portion, composed of the following components:
Butadiene: 4, propylene is fine: 8, propylene glycol: 3,
Etherificate methylol (methyl) acrylamide: 3, maleic anhydride: 3,
Ethanol: 3, dimethyl formamide: 3, acetone: 40, polysulfones: 3.
3. a kind of fabric adhesive according to claim 1, is characterized in that, in weight portion, composed of the following components:
Butadiene: 8, propylene is fine: 12, propylene glycol: 8,
Etherificate methylol (methyl) acrylamide: 6, maleic anhydride: 6,
Ethanol: 8, dimethyl formamide: 5, acetone: 60, polysulfones: 5.
4. a kind of fabric adhesive according to claim 1, is characterized in that, in weight portion, composed of the following components:
Butadiene: 6, propylene is fine: 10, propylene glycol: 6,
Etherificate methylol (methyl) acrylamide: 5, maleic anhydride: 4,
Ethanol: 6, dimethyl formamide: 4, acetone: 50, polysulfones: 4.
5. the preparation method of adhesive for a kind of fabric claimed in claim 1, is characterized in that, comprises following technical step:
(1) by proportioning, fine to butadiene, propylene, polysulfones and acetone are mixed, be warming up to 40~60 ℃, dispersed with stirring is even;
(2) all the other components are mixed, be warming up to 30~50 ℃, dispersed with stirring is even;
(3) product of the product of step (1) and step (2) is mixed, dispersed with stirring is even;
(4) be cooled to after room temperature, get final product to obtain finished product.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201310726169.0A CN103911890A (en) | 2013-12-25 | 2013-12-25 | Adhesive used for fabric, and preparation method thereof |
Applications Claiming Priority (1)
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CN201310726169.0A CN103911890A (en) | 2013-12-25 | 2013-12-25 | Adhesive used for fabric, and preparation method thereof |
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CN103911890A true CN103911890A (en) | 2014-07-09 |
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CN201310726169.0A Pending CN103911890A (en) | 2013-12-25 | 2013-12-25 | Adhesive used for fabric, and preparation method thereof |
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Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102977800A (en) * | 2012-11-21 | 2013-03-20 | 吴江红蔷薇纺织有限公司 | Insulating glue of textile machine and preparation method thereof |
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2013
- 2013-12-25 CN CN201310726169.0A patent/CN103911890A/en active Pending
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102977800A (en) * | 2012-11-21 | 2013-03-20 | 吴江红蔷薇纺织有限公司 | Insulating glue of textile machine and preparation method thereof |
Non-Patent Citations (1)
Title |
---|
丁忠传等: "《纺织染整助剂》", 30 September 1988, 化学工业出版社 * |
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Application publication date: 20140709 |