CN103909210B - Preparation method of sand core material for casting copper parts - Google Patents

Preparation method of sand core material for casting copper parts Download PDF

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CN103909210B
CN103909210B CN201410134675.5A CN201410134675A CN103909210B CN 103909210 B CN103909210 B CN 103909210B CN 201410134675 A CN201410134675 A CN 201410134675A CN 103909210 B CN103909210 B CN 103909210B
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core material
sand core
casting
sand
binder
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CN103909210A (en
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王春祥
向长彬
郑火宗
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Huihuang Plumbing Group Co ltd
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Huihuang Plumbing Group Co ltd
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Abstract

The invention discloses a preparation method of a sand core material for copper casting, wherein in the method, a resin used as a main component of a binder is a modified urea-formaldehyde resin with lower price, and in the invention, the cost of the binder is about 45% of that of a binder adopting furan resin or 40% of that of a binder adopting phenolic resin, so that the sand core material for casting prepared by the method has the advantage of lower cost. On the other hand, the sand core material has better collapsibility, so that the sand core manufactured by the sand core material prepared by the method can shorten the single sand shaking time of a casting by 10-15 minutes, thereby improving the production efficiency.

Description

Preparation method of sand core material for casting copper parts
The patent application of the invention is a divisional application entitled "sand core material for casting copper parts and a preparation method thereof", with the application date of 2012/05/25 and the application number of 201210167907.8.
Technical Field
The invention relates to the field of metal casting, in particular to a preparation method of a sand core material for copper part casting.
Background
At present, in the copper casting industry, most of sand core materials use water-insoluble furan resins, additives, curing agents and the like as binders, and some of the sand core materials use phenolic resins as binders. Both the water-insoluble furan resin and the phenol resin have the following disadvantages: 1. the cost is high; 2. the collapsibility is poor, the sand shaking time of the casting is long, and the production efficiency is low. In addition, the water-insoluble furan resin can emit pungent odor in the production process, and the workshop operation environment is affected.
Disclosure of Invention
The invention aims to provide a preparation method of a sand core material for casting copper parts, which is low in cost and good in collapsibility.
In order to achieve the purpose, the invention adopts the following technical scheme:
the preparation method of the sand core material for casting the copper part is realized by the following steps:
firstly, preparing materials: respectively preparing 40-140 meshes of sea sand and a binder, wherein the binder accounts for 2-3wt% of the sea sand, and the binder mainly comprises the following components in percentage by weight:
Figure GDA0000833659880000021
respectively weighing the sea sand, the modified urea-formaldehyde resin, the water, the curing agent and the reinforcing agent according to the proportion;
mixing the modified urea-formaldehyde resin and the water together, uniformly stirring, adding the reinforcing agent, and uniformly stirring to obtain a first mixture;
thirdly, adding the curing agent into the sea sand, uniformly mixing, and standing for 1-15 minutes to obtain a second mixture;
and fourthly, uniformly mixing the first mixture and the second mixture together, and standing for 1-1.5 minutes to obtain the sand core material for casting.
The curing agent adopts Diethylenetriamine (DETA), ethylenediamine, hexamethylenediamine or dicyanodiamine.
The reinforcing agent adopts silane bonding reinforcing agent, polyacrylamide or starch modification reinforcing agent.
The modified urea-formaldehyde resin is modified by acrylic ester or vinyl acetate.
After the scheme is adopted, the resin serving as the main component of the adhesive is the low-price modified urea-formaldehyde resin, and the cost of the adhesive is about 45% of that of the adhesive adopting furan resin or 40% of that of the adhesive adopting phenolic resin, so that the sand core material for casting the copper part prepared by the method has the advantage of low cost.
On the other hand, the modified urea-formaldehyde resin as the main component of the binder has higher coking rate at the casting temperature of the copper part, so that the sand core material has better collapsibility, and multiple tests show that the sand core manufactured by the sand core material can shorten the sand shaking time of a casting piece by 10-15 minutes, thereby improving the production efficiency.
The sand core material prepared by the method can save the production cost of the sand core for a company by more than 30 ten thousand yuan per year according to the production scale of the applicant. The sand core made of the sand core material prepared by the method can shorten the single sand shaking time of a casting by 10-15 minutes, improve the production efficiency and generate considerable economic benefit.
Detailed Description
The sand core material for casting the copper part is mainly prepared from sea sand of 40-140 meshes and a bonding agent with the dosage of 2-3wt% of the sea sand; wherein, the adhesive mainly comprises the following components by weight ratio:
Figure GDA0000833659880000031
the preparation method of the sand core material for casting the copper part is realized by the following steps:
firstly, preparing materials: respectively preparing 40-140 meshes of sea sand and a binder, wherein the binder is 2-3wt% of the sea sand, and the binder mainly comprises the following components in percentage by weight (the percentage of each component is calculated by taking the total amount of the binder as a base):
Figure GDA0000833659880000032
mixing the modified urea-formaldehyde resin and the water together, uniformly stirring the mixture by a stirrer (or soaking the modified urea-formaldehyde resin in the water for 48 hours), adding the reinforcing agent, and uniformly stirring the mixture by the stirrer to obtain a first mixture;
thirdly, adding the curing agent into the sea sand, uniformly mixing, and standing for 1-15 minutes to obtain a second mixture;
and fourthly, mixing the first mixture and the second mixture together, uniformly stirring, and standing for 1-1.5 minutes to obtain the sand core material for casting. The formulated sand core material should be used up within 1 hour.
In the invention, the curing agent adopts Diethylenetriamine (DETA), ethylenediamine, hexamethylenediamine or dicyanodiamine; the reinforcing agent is a silane bonding reinforcing agent, polyacrylamide or starch modification reinforcing agent; the modified urea-formaldehyde resin is modified by acrylate or vinyl acetate. Here, Diethylenetriamine (DETA), ethylenediamine, hexamethylenediamine, dicyanodiamine, silane adhesion enhancer, polyacrylamide, starch modification enhancer and modified urea resin modified with acrylate or vinyl acetate are conventional chemical raw materials available in chemical markets. The modified urea-formaldehyde resin modified with acrylate or vinyl acetate has improved toughness and aging resistance (see the modification of urea-formaldehyde resin such as pentopaz, from "glass fiber" 2004, stage 4, P18-P20).
In the invention, because the modified urea-formaldehyde resin as the main component of the adhesive has stronger toughness, the sand core manufactured by the sand core material also has the characteristic of higher strength, thereby the damage rate of the sand core is lower, the surface smoothness is good, the inner cavity of the casting manufactured by the sand core is smoother and cleaner, air holes are not easy to generate, and the casting yield can be improved by 1-2%.

Claims (4)

1. The preparation method of the sand core material for casting the copper part is characterized by comprising the following steps of: the method is realized by the following steps:
firstly, preparing materials: respectively preparing 40-140 meshes of sea sand and a binder, wherein the binder accounts for 2-3wt% of the sea sand, and the binder mainly comprises the following components in percentage by weight:
Figure FDA0000486656160000011
respectively weighing the sea sand, the modified urea-formaldehyde resin, the water, the curing agent and the reinforcing agent according to the proportion;
mixing the modified urea-formaldehyde resin and the water together, uniformly stirring, adding the reinforcing agent, and uniformly stirring to obtain a first mixture;
thirdly, adding the curing agent into the sea sand, uniformly mixing, and standing for 1-15 minutes to obtain a second mixture;
and fourthly, uniformly mixing the first mixture and the second mixture together, and standing for 1-1.5 minutes to obtain the sand core material for casting.
2. The method for preparing a sand core material for casting copper parts as claimed in claim 1, wherein: the curing agent adopts Diethylenetriamine (DETA), ethylenediamine, hexamethylenediamine or dicyanodiamine.
3. The method for preparing a sand core material for casting copper parts as claimed in claim 1, wherein: the reinforcing agent adopts silane bonding reinforcing agent, polyacrylamide or starch modification reinforcing agent.
4. The method for preparing a sand core material for casting copper parts as claimed in claim 1, wherein: the modified urea-formaldehyde resin is modified by acrylic ester or vinyl acetate.
CN201410134675.5A 2012-05-25 2012-05-25 Preparation method of sand core material for casting copper parts Active CN103909210B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410134675.5A CN103909210B (en) 2012-05-25 2012-05-25 Preparation method of sand core material for casting copper parts

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201210167907.8A CN102989995B (en) 2012-05-25 2012-05-25 Sand core material used for casting copper part
CN201410134675.5A CN103909210B (en) 2012-05-25 2012-05-25 Preparation method of sand core material for casting copper parts

Related Parent Applications (1)

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CN201210167907.8A Division CN102989995B (en) 2012-05-25 2012-05-25 Sand core material used for casting copper part

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CN103909210A CN103909210A (en) 2014-07-09
CN103909210B true CN103909210B (en) 2020-10-27

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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5566742A (en) * 1994-04-13 1996-10-22 Nemoto; Masaru Casting method using core made of synthetic resin, core made of synthetic resin, and cast product
CN1314257A (en) * 2001-04-16 2001-09-26 赵庆华 Sand-plastic handicraft and its producing technique
JP3557430B2 (en) * 1993-04-22 2004-08-25 フォセコ インターナショナル リミテッド Metal casting mold, metal casting method, and molded article of refractory composition used therefor
CN101012360A (en) * 2007-02-01 2007-08-08 厦门大学 Artwork with modified urea-formaldehyde resin as adhesive and preparing method thereof
CN102000777A (en) * 2010-12-21 2011-04-06 潍柴动力股份有限公司 Core sand mixing process, heated core box core-making process and sand core prepared therefrom
CN102039375A (en) * 2010-11-20 2011-05-04 沈阳工业大学 Method for quickly manufacturing high-temperature alloy hollow blade casting
CN102229791A (en) * 2011-06-14 2011-11-02 王喆 Environment-friendly type urea-formaldehyde resin adhesive and production method thereof

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3557430B2 (en) * 1993-04-22 2004-08-25 フォセコ インターナショナル リミテッド Metal casting mold, metal casting method, and molded article of refractory composition used therefor
US5566742A (en) * 1994-04-13 1996-10-22 Nemoto; Masaru Casting method using core made of synthetic resin, core made of synthetic resin, and cast product
CN1314257A (en) * 2001-04-16 2001-09-26 赵庆华 Sand-plastic handicraft and its producing technique
CN101012360A (en) * 2007-02-01 2007-08-08 厦门大学 Artwork with modified urea-formaldehyde resin as adhesive and preparing method thereof
CN102039375A (en) * 2010-11-20 2011-05-04 沈阳工业大学 Method for quickly manufacturing high-temperature alloy hollow blade casting
CN102000777A (en) * 2010-12-21 2011-04-06 潍柴动力股份有限公司 Core sand mixing process, heated core box core-making process and sand core prepared therefrom
CN102229791A (en) * 2011-06-14 2011-11-02 王喆 Environment-friendly type urea-formaldehyde resin adhesive and production method thereof

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Inventor after: Wang Chunxiang

Inventor after: Xiang Changbin

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