CN103897560A - Radiation-cured wire coating enamel - Google Patents
Radiation-cured wire coating enamel Download PDFInfo
- Publication number
- CN103897560A CN103897560A CN201310724061.8A CN201310724061A CN103897560A CN 103897560 A CN103897560 A CN 103897560A CN 201310724061 A CN201310724061 A CN 201310724061A CN 103897560 A CN103897560 A CN 103897560A
- Authority
- CN
- China
- Prior art keywords
- parts
- radiation
- radiation curing
- wire enamel
- acrylate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Macromonomer-Based Addition Polymer (AREA)
Abstract
The invention provides radiation-cured wire coating enamel. The radiation-cured wire coating enamel is characterized by comprising the components are as follows: 40-70 parts of acrylate, 30-60 parts of acrylic monomers, 3-8 parts of an initiator, and 0.1-0.3 part of auxiliaries. The invention further provides a preparation method of the radiation-cured wire coating enamel which adopts a radiation curing technology (the radiation curing technology refers to a process of forming a solid-state product from a liquid-state oligomer through cross-linking polymerization under the action of light or high-energy rays), and has higher curing speed, and does not produce harmful substances in preparation and application processes. And therefore, compared with the existing wire coating enamel and the preparation process thereof, the radiation-cured wire coating enamel has the advantages of being quick in curing speed, less in pollution, energy-saving, and the like, and is an environment-friendly green material.
Description
Technical field
The present invention relates to a kind of radiation curing wire enamel and preparation method thereof.
Background technology
Wire enamel is a kind of coating that can make to produce between wire and wire in winding good insulation layer, be mainly used in bare copper wire, alloy wire and the ferry-glass covered wire skin of all kinds of wire diameters, with the performance of raising and stable enameled wire, can meet the requirements such as thermotolerance, shock-resistance, oil-proofness.Wire enamel of a great variety, be broadly divided into the high-end paint of general applications low side paint, high temperature resistant and special purpose, but no matter be which kind of wire enamel, in its preparation and application process, need higher temperature and longer time, and can produce environment and human harmful substance.
Summary of the invention
The object of this invention is to provide a kind of preparation temperature low and can not produce wire enamel of pollution and preparation method thereof.
In order to solve the problems of the technologies described above, a technical scheme of the present invention has been to provide a kind of radiation curing wire enamel, it is characterized in that, component is: 40～70 parts of acrylate, 30～60 parts of Acrylic Acid Monomers, 3～8 parts of initiators, 0.1～0.3 part of auxiliary agent.
Preferably, described acrylate is the one in modified epoxy acrylic ester, urethane acrylate, polyester acrylate, acroleic acid esterification polyacrylic resin or polyether acrylate.
Preferably, described initiator is light trigger.
Preferably, described auxiliary agent is defoamer or dispersion agent.
The preparation method of a kind of above-mentioned radiation curing wire enamel of another technology of the present invention, is characterized in that, step is:
The first step, at ambient temperature in, 40～70 parts of acrylate and 20～50 parts of Acrylic Acid Monomers are added in reactor, be stirred well to evenly, obtain work in-process A;
Second step, will in work in-process A, add 3～8 parts of initiators and 0.1～0.3 part of auxiliary agent, be stirred well to evenly, obtain work in-process B;
The 3rd step, according to the viscosity of desired product, work in-process B is added to remaining Acrylic Acid Monomer, after fully stirring, obtain above-mentioned a kind of radiation curing wire enamel, put it in the container with shading, store.
Radiation curing wire enamel of the present invention both can be prepared at ambient temperature, (radiation curing technology refers under the effect of light or energetic ray to adopt radiation curing technology, the process of the solid product that liquid oligopolymer forms through crosslinking polymerization) and there is curing speed faster, and can not produce objectionable impurities in preparation and application process.
Therefore, compared with existing wire enamel and preparation technology thereof, the present invention have curing speed fast, pollute less, the advantage such as energy-conservation, be a kind of eco-friendly green material.
Embodiment
For the present invention is become apparent, be hereby described in detail below with preferred embodiment.
Embodiment 1
The present embodiment discloses a kind of radiation curing wire enamel, and its component is: 40 parts of modified epoxy acrylic esters, 60 parts of Acrylic Acid Monomers, 3 parts of light triggers, 0.1 part of defoamer.
The present embodiment also discloses the preparation method of above-mentioned radiation curing wire enamel, the steps include:
The first step, at ambient temperature in, 40 parts of modified epoxy acrylic esters and 50 parts of Acrylic Acid Monomers are added in reactor, be stirred well to evenly, obtain work in-process A;
Second step, will in work in-process A, add 3 parts of light triggers and 0.1 part of defoamer, be stirred well to evenly, obtain work in-process B;
The 3rd step, according to the viscosity of desired product, work in-process B is added to 10 parts of Acrylic Acid Monomers, after fully stirring, obtain above-mentioned a kind of radiation curing wire enamel, put it in the container with shading, store.
The present invention adopts radiation curing technology, and therefore the present invention does not need higher temperature in application process, and a light requirement can be (800～1200) mJ/cm
2light or energetic ray.
Embodiment 2
The present embodiment discloses a kind of radiation curing wire enamel, and its component is: 70 parts of polyester acrylates, 45 parts of Acrylic Acid Monomers, 8 parts of light triggers, 0.3 part of dispersion agent.
The present embodiment also discloses a kind of preparation method of above-mentioned radiation curing wire enamel, the steps include:
The first step, at ambient temperature in, 70 parts of polyester acrylates and 20 parts of Acrylic Acid Monomers are added in reactor, be stirred well to evenly, obtain work in-process A;
Second step, will in work in-process A, add 8 parts of light triggers and 0.3 part of dispersion agent, be stirred well to evenly, obtain work in-process B;
The 3rd step, according to the viscosity of desired product, work in-process B is added to 25 parts of Acrylic Acid Monomers, after fully stirring, obtain above-mentioned a kind of radiation curing wire enamel, put it in the container with shading, store.
Embodiment 3
The difference of the present embodiment and embodiment 1 is to replace modified epoxy acrylic ester with acroleic acid esterification polyacrylic resin, and other components and preparation process are identical with embodiment 1.
Claims (5)
1. a radiation curing wire enamel, is characterized in that, component is: 40～70 parts of acrylate, 30～60 parts of Acrylic Acid Monomers, 3～8 parts of initiators, 0.1～0.3 part of auxiliary agent.
2. a kind of radiation curing wire enamel as claimed in claim 1, is characterized in that: described acrylate is the one in modified epoxy acrylic ester, urethane acrylate, polyester acrylate, acroleic acid esterification polyacrylic resin or polyether acrylate.
3. a kind of radiation curing wire enamel as claimed in claim 1, is characterized in that: described initiator is light trigger.
4. a kind of radiation curing wire enamel as claimed in claim 1, is characterized in that: described auxiliary agent is defoamer or dispersion agent.
5. a preparation method for radiation curing wire enamel as claimed in claim 1, is characterized in that, step is:
The first step, at ambient temperature in, 40～70 parts of acrylate and 20～50 parts of Acrylic Acid Monomers are added in reactor, be stirred well to evenly, obtain work in-process A;
Second step, will in work in-process A, add 3～8 parts of light triggers and 0.1～0.3 part of auxiliary agent, be stirred well to evenly, obtain work in-process B;
The 3rd step, according to the viscosity of desired product, work in-process B is added to remaining Acrylic Acid Monomer, after fully stirring, obtain a kind of radiation curing wire enamel as claimed in claim 1, put it in the container with shading, store.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310724061.8A CN103897560A (en) | 2013-12-24 | 2013-12-24 | Radiation-cured wire coating enamel |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310724061.8A CN103897560A (en) | 2013-12-24 | 2013-12-24 | Radiation-cured wire coating enamel |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103897560A true CN103897560A (en) | 2014-07-02 |
Family
ID=50989149
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310724061.8A Pending CN103897560A (en) | 2013-12-24 | 2013-12-24 | Radiation-cured wire coating enamel |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103897560A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105802404A (en) * | 2016-04-26 | 2016-07-27 | 安徽康瑞鑫电子科技有限公司 | Wire-covering enamel |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2001019888A1 (en) * | 1999-09-10 | 2001-03-22 | Sartomer Company, Inc. | Coating composition and method of coating substrates |
| CN1398410A (en) * | 1998-05-07 | 2003-02-19 | Dsm有限公司 | Dielectric radiation-curable coating compsns. |
| CN1487035A (en) * | 2002-08-07 | 2004-04-07 | 珠海东诚化工有限公司 | Ultraviolet ray cured insulating paint |
| CN103080205A (en) * | 2010-08-05 | 2013-05-01 | 帝斯曼知识产权资产管理有限公司 | Radiation curable resin composition for electrical wire |
-
2013
- 2013-12-24 CN CN201310724061.8A patent/CN103897560A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1398410A (en) * | 1998-05-07 | 2003-02-19 | Dsm有限公司 | Dielectric radiation-curable coating compsns. |
| WO2001019888A1 (en) * | 1999-09-10 | 2001-03-22 | Sartomer Company, Inc. | Coating composition and method of coating substrates |
| CN1487035A (en) * | 2002-08-07 | 2004-04-07 | 珠海东诚化工有限公司 | Ultraviolet ray cured insulating paint |
| CN103080205A (en) * | 2010-08-05 | 2013-05-01 | 帝斯曼知识产权资产管理有限公司 | Radiation curable resin composition for electrical wire |
Non-Patent Citations (1)
| Title |
|---|
| 刘国杰: "《涂料树脂合成工艺》", 30 June 2012, 化学工业出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105802404A (en) * | 2016-04-26 | 2016-07-27 | 安徽康瑞鑫电子科技有限公司 | Wire-covering enamel |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104152077B (en) | A kind of ultra-thin polyester two-sided tape and by glue and preparation method | |
| EP3916064B1 (en) | Uv-crosslinked hot-melt pressure-sensitive adhesive used for polyvinyl-chloride insulated adhesive tape | |
| CN106833398B (en) | Fast-curing acrylate pressure-sensitive adhesive and preparation method thereof | |
| CN105365233B (en) | The preparation method of the compound high light film of imitative metal wire-drawing | |
| CN103524667A (en) | Water-based pressure-sensitive adhesive for polyethylene protection film and polyethylene protection film and preparation method thereof | |
| CN109251683B (en) | Single-component thermosetting acrylate structural adhesive and preparation method thereof | |
| KR20180085946A (en) | Alkali soluble resin, manufacturing method of the same and emulsion polymer including alkali soluble resin | |
| JP2012504678A (en) | Resin syrup, artificial marble containing cured product of this resin syrup, and method for producing the same | |
| CN105713540A (en) | Preparation method of ultralight strippable self-exhausting acrylate pressure-sensitive coating material | |
| CN107922808A (en) | Adhesive composition, bonding sheet and the contact panel and display device that possess the bonding sheet | |
| CN103911078A (en) | Ultraviolet curing adhesive with high light transmittance for fitting touch panel | |
| CN103320065A (en) | Emulsion pressure-sensitive adhesive for protecting adhesive tape and preparation method thereof | |
| PH12015502734A1 (en) | Adhesive sheet and method of manufacturing electronic component using the same | |
| CN104877446A (en) | Ultraviolet-thermal dual-curing glass printing ink and preparation method thereof | |
| CN104575825A (en) | Aluminum twisted wire for overhead power transmission | |
| CN103897560A (en) | Radiation-cured wire coating enamel | |
| CN105330879A (en) | Light-cured glass fiber composite material and preparation method thereof | |
| CN103665696A (en) | Self-repairing polymer | |
| CN104635285B (en) | High-stiffness coated reflecting film and preparation method thereof | |
| KR101556015B1 (en) | Infrared rays-proof hard coating composition and Infrared rays-proof film by infrared rays-proof hard coating composition | |
| CN104497925A (en) | Photothermal-based preparation method of UV-cured pressure-sensitive adhesive | |
| CN104892831B (en) | Styrene-acrylic emulsion for combining sponge and cloth and preparation method thereof | |
| JP2021504506A5 (en) | ||
| CN104312320B (en) | High-transparency composite thin film capable of adsorbing ultraviolet rays and preparation method thereof | |
| KR102044072B1 (en) | High functional Adhesive resin composition of Solvent-free type Thermal polymerization and Preparing thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20140702 |