CN103897377A - Anti-aging photodiffusion PC (Poly Carbonate)-based resin and preparation method thereof - Google Patents
Anti-aging photodiffusion PC (Poly Carbonate)-based resin and preparation method thereof Download PDFInfo
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- CN103897377A CN103897377A CN201410118559.4A CN201410118559A CN103897377A CN 103897377 A CN103897377 A CN 103897377A CN 201410118559 A CN201410118559 A CN 201410118559A CN 103897377 A CN103897377 A CN 103897377A
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- aging
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- diffusing agent
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Abstract
The invention discloses an anti-aging photodiffusion PC (Poly Carbonate)-based resin which is prepared from the following raw materials in parts by mass: 95-98 parts of PC aggregates, 2-4 parts of PC powder, 0.5-2 parts of photodiffusant, 0.02-0.05 part of antioxidant and 0.005-0.01 part of UV (Ultraviolet) assistant. A preparation method of the anti-aging photodiffusion PC-based resin comprises the following steps: 1) mixing the PC powder, the photodiffusant, the antioxidant and the UV assistant for 5-10 minutes through a high mixing machine to obtain a mixture; and 2) placing the mixture obtained in the step 1) with the PC aggregates in a low mixing machine to be stirred and mixed for 5-10 minutes, and then placing in an extruder to be subjected to melt extrusion, and pelleting. The anti-aging photodiffusion PC-based resin disclosed by the invention has relatively high light transmittance, good ageing resistance and high notch impact strength, and the product obtained has good comprehensive performance.
Description
Technical field
The present invention relates to a kind of anti-aging light diffusion PC base resin and preparation method thereof.
Background technology
In present LED Lighting Industry, lampshade and fluorescent tube generally adopt PC and the blend of scattering of light auxiliary agent to form, due to problems such as disperse phase capacitives, be difficult to take into account mist degree and the light transmission of material, the shock strength of material is also lower, and after using for some time, there is flavescence phenomenon in product.Have a strong impact on lighting effects, light fixture is shortened work-ing life on the whole.
The material using now, due to problems such as disperse phase capacitives, the shock strength of material is on the low side, and melting index is little, injection moulding demoulding difficulty, production efficiency is low.
Summary of the invention
The object of the present invention is to provide a kind of anti-aging light diffusion PC base resin and preparation method thereof.
The technical solution used in the present invention is:
A kind of anti-aging light diffusion PC base resin, its raw material by following mass parts forms: the light diffusing agent of the PC pellet of 95-98 part, the PC powder of 2-4 part, 0.5-2 part, the oxidation inhibitor of 0.02-0.05 part, the UV auxiliary agent of 0.005-0.01 part.
Described light diffusing agent is at least one in esters of acrylic acid light diffusing agent, silicone based light diffusing agent, nano barium sulfate.
Described oxidation inhibitor comprises Hinered phenols antioxidant, phosphite ester kind antioxidant.
Described oxidation inhibitor is 1010,168,1076,1098,245,6921, S9228, DHT246, compound B215, compound B225,, at least one in DLTP, DSTP, TNPP, TPP, CA, BHT.
Described ultraviolet-resistant aid is at least one in UV-P, UV-326, UV-327, UV-328, UV-329, UV-770, UV-531, UV-292, UV-320, UV-360, UV-1577, UV-1164, UV-9, UV-0, UV-622, UV-783, UV-791, UV-298, UV-5411, UV-350, UV-234.
A preparation method for anti-aging light diffusion PC base resin, comprises the following steps:
1) by PC powder, light diffusing agent, oxidation inhibitor, UV auxiliary agent through high mixer mixing 5-10min, obtain mixture;
2) mixture upper step being obtained and PC pellet are placed in low mixed machine and are uniformly mixed 5-10min, then are placed in that forcing machine melt extrudes, granulation.
The temperature melt extruding is 250-270 ℃.
The screw slenderness ratio of forcing machine is 40:1.
The invention has the beneficial effects as follows: anti-aging light diffusion PC base resin of the present invention has higher transmittance, ageing resistance, higher notched Izod impact strength preferably, and the product over-all properties of gained is better.
Embodiment
A kind of anti-aging light diffusion PC base resin, its raw material by following mass parts forms: the light diffusing agent of the PC pellet of 95-98 part, the PC powder of 2-4 part, 0.5-2 part, the oxidation inhibitor of 0.02-0.05 part, the UV auxiliary agent of 0.005-0.01 part.
Described light diffusing agent is at least one in esters of acrylic acid light diffusing agent, silicone based light diffusing agent, nano barium sulfate.
Described oxidation inhibitor is at least one in Hinered phenols antioxidant, phosphite ester kind antioxidant.
Described oxidation inhibitor is 1010,168,1076,1098,245,6921, S9228, DHT246, compound B215, compound B225,, at least one in DLTP, DSTP, TNPP, TPP, CA, BHT.
Described ultraviolet-resistant aid is at least one in UV-P, UV-326, UV-327, UV-328, UV-329, UV-770, UV-531, UV-292, UV-320, UV-360, UV-1577, UV-1164, UV-9, UV-0, UV-622, UV-783, UV-791, UV-298, UV-5411, UV-350, UV-234.
A preparation method for anti-aging light diffusion PC base resin, comprises the following steps:
1) by PC powder, light diffusing agent, oxidation inhibitor, UV auxiliary agent through high mixer mixing 5-10min, obtain mixture;
2) mixture upper step being obtained and PC pellet are placed in low mixed machine and are uniformly mixed 5-10min, then are placed in that forcing machine melt extrudes, granulation.
The temperature melt extruding is 250-270 ℃.
The screw slenderness ratio of forcing machine is 40:1.
Below in conjunction with specific embodiment, formula of the present invention is described further:
embodiment 1:
A kind of anti-aging light diffusion PC base resin, its table 1 composed as follows of filling a prescription:
table 1:
embodiment 2:
A kind of anti-aging light diffusion PC base resin, its table 2 composed as follows of filling a prescription:
table 2:
embodiment 3:
A kind of anti-aging light diffusion PC base resin, its table 3 composed as follows of filling a prescription:
table 3:
Claims (8)
1. an anti-aging light diffusion PC base resin, is characterized in that: its raw material by following mass parts forms: the light diffusing agent of the PC pellet of 95-98 part, the PC powder of 2-4 part, 0.5-2 part, the oxidation inhibitor of 0.02-0.05 part, the UV auxiliary agent of 0.005-0.01 part.
2. the anti-aging light diffusion of one according to claim 1 PC base resin, is characterized in that: described light diffusing agent is at least one in esters of acrylic acid light diffusing agent, silicone based light diffusing agent, nano barium sulfate.
3. the anti-aging light diffusion of one according to claim 1 PC base resin, is characterized in that: described oxidation inhibitor comprises Hinered phenols antioxidant, phosphite ester kind antioxidant.
4. the anti-aging light diffusion of one according to claim 1 PC base resin, it is characterized in that: described oxidation inhibitor is 1010,168,1076,1098,245,6921, S9228, DHT246, compound B215, compound B225,, at least one in DLTP, DSTP, TNPP, TPP, CA, BHT.
5. the anti-aging light diffusion of one according to claim 1 PC base resin, is characterized in that: described ultraviolet-resistant aid is at least one in UV-P, UV-326, UV-327, UV-328, UV-329, UV-770, UV-531, UV-292, UV-320, UV-360, UV-1577, UV-1164, UV-9, UV-0, UV-622, UV-783, UV-791, UV-298, UV-5411, UV-350, UV-234.
6. the preparation method of a kind of anti-aging light diffusion PC base resin claimed in claim 1, is characterized in that: comprise the following steps:
1) by PC powder, light diffusing agent, oxidation inhibitor, UV auxiliary agent through high mixer mixing 5-10min, obtain mixture;
2) mixture upper step being obtained and PC pellet are placed in low mixed machine and are uniformly mixed 5-10min, then are placed in that forcing machine melt extrudes, granulation.
7. the preparation method of a kind of anti-aging light diffusion PC base resin according to claim 6, is characterized in that: the temperature melt extruding is 250-270 ℃.
8. the preparation method of a kind of anti-aging light diffusion PC base resin according to claim 6, is characterized in that: the screw slenderness ratio of forcing machine is 40:1.
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| CN201410118559.4A CN103897377B (en) | 2014-03-27 | 2014-03-27 | A kind of anti-aging light diffusion PC base resin and preparation method thereof |
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| CN201410118559.4A CN103897377B (en) | 2014-03-27 | 2014-03-27 | A kind of anti-aging light diffusion PC base resin and preparation method thereof |
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| CN103897377A true CN103897377A (en) | 2014-07-02 |
| CN103897377B CN103897377B (en) | 2015-12-30 |
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107151413A (en) * | 2017-05-05 | 2017-09-12 | 惠州市华辉信达电子有限公司 | A kind of engineering plastics with high-weatherability and preparation method thereof |
| CN107266891A (en) * | 2016-04-07 | 2017-10-20 | 广东聚石化学股份有限公司 | A kind of high fire-retardance light diffusion PC materials and preparation method thereof |
| CN107383827A (en) * | 2017-08-08 | 2017-11-24 | 宁波汉禾新材料科技有限公司 | A kind of light spreads PC materials |
| CN108342065A (en) * | 2017-05-22 | 2018-07-31 | 安徽旭升新材料有限公司 | A kind of high-effect PC photodiffusion materials of anti-flammability and preparation method thereof |
| CN108342066A (en) * | 2017-05-22 | 2018-07-31 | 安徽旭升新材料有限公司 | A kind of high-effect PC photodiffusion materials and preparation method thereof |
| CN108398497A (en) * | 2018-02-11 | 2018-08-14 | 上海市食品药品包装材料测试所 | A kind of high-efficiency liquid chromatography method for detecting of three (nonyl phenol) phosphite esters |
| CN112592515A (en) * | 2020-12-16 | 2021-04-02 | 山东荣曦新材料科技有限公司 | Multifunctional novel chlorinated paraffin liquid composite sunscreen agent and preparation method thereof |
| CN112831172A (en) * | 2021-01-14 | 2021-05-25 | 深圳力越新材料有限公司 | PC (polycarbonate) frosted material, preparation method thereof and LED (light-emitting diode) lamp |
| CN113637308A (en) * | 2021-08-17 | 2021-11-12 | 广州仕天材料科技有限公司 | Preparation method of yellowing-resistant photodiffusion PC material |
| CN116102864A (en) * | 2022-12-29 | 2023-05-12 | 中山市华洋塑胶颜料有限公司 | Preparation method of super-dispersed PC light diffusion master batch |
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| CN101805506A (en) * | 2010-04-13 | 2010-08-18 | 深圳市兴业源塑胶电子有限公司 | Polycarbonate resin composition for lighting tube material and preparation method thereof |
| CN103554863A (en) * | 2013-09-29 | 2014-02-05 | 深圳市耐明光电有限公司 | LED lampshade material polycarbonate resin composition and preparation method thereof |
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2014
- 2014-03-27 CN CN201410118559.4A patent/CN103897377B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101805506A (en) * | 2010-04-13 | 2010-08-18 | 深圳市兴业源塑胶电子有限公司 | Polycarbonate resin composition for lighting tube material and preparation method thereof |
| CN103554863A (en) * | 2013-09-29 | 2014-02-05 | 深圳市耐明光电有限公司 | LED lampshade material polycarbonate resin composition and preparation method thereof |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107266891A (en) * | 2016-04-07 | 2017-10-20 | 广东聚石化学股份有限公司 | A kind of high fire-retardance light diffusion PC materials and preparation method thereof |
| CN107151413A (en) * | 2017-05-05 | 2017-09-12 | 惠州市华辉信达电子有限公司 | A kind of engineering plastics with high-weatherability and preparation method thereof |
| CN108342065A (en) * | 2017-05-22 | 2018-07-31 | 安徽旭升新材料有限公司 | A kind of high-effect PC photodiffusion materials of anti-flammability and preparation method thereof |
| CN108342066A (en) * | 2017-05-22 | 2018-07-31 | 安徽旭升新材料有限公司 | A kind of high-effect PC photodiffusion materials and preparation method thereof |
| CN107383827A (en) * | 2017-08-08 | 2017-11-24 | 宁波汉禾新材料科技有限公司 | A kind of light spreads PC materials |
| CN108398497A (en) * | 2018-02-11 | 2018-08-14 | 上海市食品药品包装材料测试所 | A kind of high-efficiency liquid chromatography method for detecting of three (nonyl phenol) phosphite esters |
| CN112592515A (en) * | 2020-12-16 | 2021-04-02 | 山东荣曦新材料科技有限公司 | Multifunctional novel chlorinated paraffin liquid composite sunscreen agent and preparation method thereof |
| CN112831172A (en) * | 2021-01-14 | 2021-05-25 | 深圳力越新材料有限公司 | PC (polycarbonate) frosted material, preparation method thereof and LED (light-emitting diode) lamp |
| CN113637308A (en) * | 2021-08-17 | 2021-11-12 | 广州仕天材料科技有限公司 | Preparation method of yellowing-resistant photodiffusion PC material |
| CN116102864A (en) * | 2022-12-29 | 2023-05-12 | 中山市华洋塑胶颜料有限公司 | Preparation method of super-dispersed PC light diffusion master batch |
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| Publication number | Publication date |
|---|---|
| CN103897377B (en) | 2015-12-30 |
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