CN103877978B - 类Fenton法深度处理印染废水催化剂的制备和应用 - Google Patents
类Fenton法深度处理印染废水催化剂的制备和应用 Download PDFInfo
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- CN103877978B CN103877978B CN201210563943.6A CN201210563943A CN103877978B CN 103877978 B CN103877978 B CN 103877978B CN 201210563943 A CN201210563943 A CN 201210563943A CN 103877978 B CN103877978 B CN 103877978B
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- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 10
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- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 2
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- VCJMYUPGQJHHFU-UHFFFAOYSA-N iron(3+);trinitrate Chemical compound [Fe+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O VCJMYUPGQJHHFU-UHFFFAOYSA-N 0.000 claims 2
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- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 238000007172 homogeneous catalysis Methods 0.000 description 3
- MVFCKEFYUDZOCX-UHFFFAOYSA-N iron(2+);dinitrate Chemical compound [Fe+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MVFCKEFYUDZOCX-UHFFFAOYSA-N 0.000 description 3
- 235000015110 jellies Nutrition 0.000 description 3
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Abstract
Description
反应时间 | 原水COD | 原水色度 | 出水COD | 出水色度 | COD去除率 |
h | mg/L | 倍 | mg/L | 倍 | % |
4 | 302 | 250 | 87.01 | 25 | 71.19 |
8 | 294 | 250 | 132.01 | 25 | 55.10 |
12 | 294 | 250 | 166.99 | 30 | 43.20 |
16 | 294 | 250 | 159.11 | 40 | 45.88 |
20 | 286 | 250 | 137.88 | 50 | 51.79 |
24 | 309 | 250 | 77.99 | 40 | 74.76 |
28 | 332 | 250 | 69.85 | 35 | 78.96 |
32 | 317 | 250 | 101.22 | 65 | 68.07 |
36 | 302 | 250 | 103.83 | 35 | 65.62 |
40 | 333 | 250 | 124.34 | 35 | 62.66 |
44 | 291 | 250 | 74.21 | 40 | 74.50 |
48 | 296 | 250 | 99.54 | 45 | 66.37 |
52 | 310 | 250 | 85.22 | 40 | 72.51 |
56 | 304 | 250 | 81.53 | 25 | 73.18 |
60 | 315 | 250 | 86.44 | 40 | 72.56 |
64 | 367 | 250 | 106.25 | 25 | 71.05 |
68 | 334 | 250 | 146.33 | 20 | 56.19 |
72 | 329 | 250 | 108.47 | 25 | 67.03 |
76 | 340 | 250 | 94.66 | 80 | 72.16 |
80 | 304 | 250 | 73.93 | 25 | 75.68 |
84 | 280 | 250 | 114.46 | 30 | 59.12 |
88 | 311 | 250 | 66.49 | 25 | 78.62 |
92 | 313 | 250 | 127.95 | 25 | 59.12 |
96 | 299 | 250 | 63.93 | 25 | 78.62 |
100 | 316 | 250 | 102.64 | 30 | 67.52 |
Claims (7)
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CN201210563943.6A CN103877978B (zh) | 2012-12-21 | 2012-12-21 | 类Fenton法深度处理印染废水催化剂的制备和应用 |
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CN201210563943.6A CN103877978B (zh) | 2012-12-21 | 2012-12-21 | 类Fenton法深度处理印染废水催化剂的制备和应用 |
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Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105060457A (zh) * | 2015-09-02 | 2015-11-18 | 常州市长宇实用气体有限公司 | 一种利用气相自由混合基处理印染废水的方法 |
CN106698780A (zh) * | 2015-11-18 | 2017-05-24 | 中国科学院大连化学物理研究所 | 一种垃圾渗滤液组合处理工艺 |
CN105772052B (zh) * | 2016-03-03 | 2018-03-13 | 中国科学院生态环境研究中心 | 一种固体芬顿催化剂及其制备方法与应用 |
CN110102319A (zh) * | 2019-05-07 | 2019-08-09 | 华东理工大学 | 成型固体载体负载氧基氯化铁的方法及其应用 |
CN111420665B (zh) * | 2020-04-26 | 2022-09-20 | 万华化学集团股份有限公司 | 改性类芬顿催化剂及制备方法和应用 |
CN114762827B (zh) * | 2021-01-15 | 2023-12-22 | 万华化学集团股份有限公司 | 一种催化剂、制备方法和在处理含过氧化物的po/chp废水中的应用 |
CN114392745A (zh) * | 2021-12-13 | 2022-04-26 | 鲁东大学 | 一种制备Fe-过渡金属-Al复合金属氧化物的方法及其应用 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1243561A2 (de) * | 2001-03-23 | 2002-09-25 | Degussa AG | Verfahren zur Aufbereitung von schadstoffhaltigen Wässern mit Hilfe eines Eisen(III)-Katalysators |
CN101259412A (zh) * | 2006-11-24 | 2008-09-10 | 哈尔滨工业大学 | Fe/无机载体催化剂的制备方法 |
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Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1243561A2 (de) * | 2001-03-23 | 2002-09-25 | Degussa AG | Verfahren zur Aufbereitung von schadstoffhaltigen Wässern mit Hilfe eines Eisen(III)-Katalysators |
CN101259412A (zh) * | 2006-11-24 | 2008-09-10 | 哈尔滨工业大学 | Fe/无机载体催化剂的制备方法 |
Non-Patent Citations (2)
Title |
---|
"Fe2O3/γ-Al2O3催化剂用于降解苯酚的非均相Fenton反应研究";万家峰等;《工业水处理》;20120229;第32卷(第2期);第28页右栏第1.2节、第29页左栏第1.3节、右栏1.2、2.1.3节 * |
"The degradation of Isophorone by catalytic wet air oxidation on Ru/TiZrO4";Huangzhao Wei等;《Journal of Hazardous Materials》;20121105;第244-245卷;第479页第1栏第3段、第480页左栏第2.4节 * |
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