This application claims the priority of U.S. Provisional Patent Application 61/737512 submitted on December 14th, 2012.With
The complete disclosure of the application of upper reference is merged into herein by reference.
Description of the drawings
Fig. 1 is the top view of traditional RRAM.
Fig. 2 is the side cross-sectional view by the section line A-A of Fig. 1.
Fig. 3 illustrates the manufacturing method of the RRAM of multiple embodiments according to the present invention, which includes corresponding resistive
Element and conducting element.
Fig. 4 is the top view of the part RRAM after resistive layer, conductive layer and hard mask layer is initially formed.
Fig. 5 is the side cross-sectional view by the section line B-B of Fig. 4.
Fig. 6 is the top view of the first mask and part RRAM after the first film layer is formed.
Fig. 7 is the side cross-sectional view by the section line C-C of Fig. 6.
Fig. 8 is the top view to form the part RRAM after the second film layer.
Fig. 9 is the side cross-sectional view by the section line D-D of Fig. 8.
Figure 10 be etch the second film layer after part RRAM top view.
Figure 11 is the side cross-sectional view by the section line E-E of Figure 10.
Figure 12 be etch hard mask layer after part RRAM top view.
Figure 13 is the side cross-sectional view by the section line F-F of Figure 12.
Figure 14 is the top view of part RRAM after removing the second film layer remainder to provide the first spacer.
Figure 15 is the side cross-sectional view by the section line G-G of Figure 14.
Figure 16 is the top view of the second mask and part RRAM after forming third film layer.
Figure 17 is the side cross-sectional view by the section line H-H of Figure 16.
Figure 18 is to form the 4th film layer to provide the top view of the part RRAM after the second spacer.
Figure 19 is the side cross-sectional view by the section line I-I of Figure 18.
Figure 20 is the top view for etching the 4th film layer and removing the part RRAM after third film layer.
Figure 21 is the side cross-sectional view by the section line J-J of Figure 20.
Figure 22 be etch hard mask layer remainder after part RRAM top view.
Figure 23 is the side cross-sectional view by the section line K-K of Figure 22.
Figure 24 is part after etching the 4th film layer to provide the remainder of hard mask layer in the form of the body of island
The top view of RRAM.
Figure 25 is the side cross-sectional view by the section line L-L of Figure 24.
Figure 26 is the top view for etching the part RRAM after resistive layer and conductive layer.
Figure 27 is the side cross-sectional view by the section line M-M of Figure 26.
Figure 28 is the top view using the part RRAM after separation layer.
Figure 29 is the side cross-sectional view by the section line N-N of Figure 28.
Figure 30 is the thick view of part RRAM after removing part separation layer and removing mask layer island body.
Figure 31 is the side cross-sectional view by the section line O-O of Figure 30.
Figure 32 is the top view to form the part RRAM after interconnecting.
Figure 33 is the side cross-sectional view by the section line P-P of Figure 32.
In the accompanying drawings, reference numeral may be reused to refer to similar and/or identical element.
Specific embodiment
Disclosed herein is the formation of resistance element (or stacking) and conducting element (such as through-hole or contact) including RRAM
Method.This method includes forming spacer and in a single step graphical (or etching) resistive layer and conductor layer.It uses
The mask of single formation, resistive layer and conductive layer is graphical together.Formed spacer is used to provide mask.Then make
With mask come graphical resistive layer and conductive layer.This graphically provides the Subresolution feature to resistance element and conducting element
Control.Subresolution feature refers to the feature of the resolution ratio limitation less than feature patterning tool.Resistance element and conducting element
Subresolution feature can include size, shape and the roughness on side of such as resistance element and conducting element.This method packet
It includes etching and chemical vapor deposition (CVD) rather than uses conventional lithography and photolithographic techniques.This just minimizes and/or eliminates
Element misalignment and component mismatch.As a result, resistance element and conducting element contraposition and contact surface matching.This is just minimum
Change the resistance of corresponding RRAM, improve the reliability of RRAM and improve the performance of RRAM.
Fig. 3 illustrates the manufacturing method of the RRAM including corresponding resistance element and conducting element.Although to following task
Description primarily with regard to Fig. 4-33 embodiment, thus it is possible to vary the task is to be applied to other embodiments of the present invention.
This method is since 100.
According to fig. 3, Fig. 4-5 shows the top view and sectional view of the state of the part 90 of the RRAM after task 102.
102, in access device 112, (each box for being identified as 112 can include more in figs. 4-5 and in following chart
A access device) array 110 on form resistive layer 104, conductive layer 106 and hard mask layer 108.Access device 112 can wrap
Such as transistor (such as CMOS transistor and/or BJT transistors), diode, wordline, conducting element are included (for example, conducting wire, logical
Hole, contact, etc.) or other electronic units.This is further described in Figure 32-33.
It can be set on access device and application resistive layer 104 is stacked with being formed.Resistive layer can include the first (or bottom
Portion) electrode layer 114, variable resistive layer 116, collecting layer 118 and second (or top) electrode layer 120.Electrode layer 114,120 can be with
It is formed by such as titanium nitride TiN and/or including such as titanium nitride TiN.In one embodiment, second is etched in subsequent task
For electrode layer 120 to provide electrode, which may be coupled to bit line.Variable resistive layer 116 can be by such as transiting metal oxidation
Object (such as hafnium oxide HfO2) formed and/or including such as transition metal oxide (such as hafnium oxide HfO2).Collecting layer
118 can be formed by such as active metal (such as Ti) and/or including such as active metal (such as Ti).Conductive layer 106 can be with
The heap for being deposited on resistive layer 104 is stacked on, and can be W-shaped into and/or including such as Ti, aluminium by such as Ti, aluminium Al and/or tungsten
Al and/or tungsten W.Hard mask layer 108 can be deposited on conductive layer 106, and can be by such as silicon nitride Si3N4And/or TiN
It is formed and/or including such as silicon nitride Si3N4And/or TiN.Conductive layer 106 can mask harder than (i) resistive layer 104 and (ii)
It is one or more thicker in layer 108.Hard mask layer 108 can be than one in (i) resistive layer 104 and (ii) conductive layer 106
It is a or more thinner.
Although conductive layer 106 is shown as being arranged between resistive layer 104 and hard mask layer 108, conductive layer 106 can be set
It puts between access device 112 and resistive layer 104.When conductive layer 106 is arranged between resistive layer 104 and hard mask layer 108,
In order to provide through-hole, conductive layer 106 can be etched in subsequent task.When conductive layer 106 is arranged on resistive layer 104 and covers firmly
When between film layer 108, conductive layer 106 can be etched in subsequent task to provide contact.
According to fig. 3, Fig. 6-7 shows the top view and sectional view of the state of the part 90 of the RRAM after task 130.Figure
6-7 shows resistive layer 104, conductive layer 106, hard mask layer 108, access device 112,134 and first mask of the first film layer
134.130, the first film layer 132 is formed.First mask 134 has opening 136 and can be used to form and graphical described the
One film layer 132.Can the memory cell layout based on scheduled RRAM and provide or formed the first mask 134.It can make
The first film layer 132 is deposited on hard mask layer 108 with the first mask 134.CVD or other deposition techniques can be used (such as
Physical vapour deposition (PVD) (PVD)) form the first film layer 132.The first film layer 132 can be by such as silica SiO2And/or
Silicon carbide SiC is formed and/or including such as silica SiO2And/or silicon carbide SiC.
According to fig. 3, Fig. 8-9 shows the top view and sectional view of the state of the part 90 of the RRAM after task 140.Figure
8-9 shows resistive layer 104, conductive layer 106, hard mask layer 108, access device 112,132 and second film of the first film layer
Layer 142.140, the second film layer 142 is applied in the top of the first film layer 132 and hard mask layer 108.Can use CVD,
PVD or other suitable deposition techniques deposit the second film layer 142 on the first film layer 132 and hard mask layer 108.Second is thin
Film layer 142 is formed by the material for being different from the first film layer 132.Second film layer 142 can be by such as carbon doped silicon nitride
Si3N4 is formed and/or including such as carbon doped silicon nitride Si3N4.As what is carried out in following task 150, by by with
The different material of the first film layer 132 forms the second film layer 142, can be in at least part for retaining the second film layer 142
While remove the first film layer 132.
According to fig. 3, Figure 10-11 shows the top view and sectional view of the state of the part 90 of the RRAM after task 150.
Figure 10-11 show resistive layer 104, conductive layer 106, hard mask layer 108,112 and second film layer 142 of access device residue
Part 152.150, the first film layer 132 and the second film layer 142 are etched to provide 152 (i.e. the second film of the first spacer
The remainder of layer 142).First spacer 152 is the remainder of the second film layer 142 after the second film layer 142 is etched
Point.The first film layer 132 is removed.As a result, the first spacer 152 is ring-shaped, and with central opening
154, previous the first film layer 132 is located at central opening 154.The first film layer can be removed using anisotropic etching
132 and the part of the second film layer 142 is etched away, to provide the first spacer 152.It can be wrapped in the etching that 150 perform
Include wet etching or dry ecthing.
According to fig. 3, Figure 12-13 shows the top view and sectional view of the state of the part 90 of the RRAM after task 160.
Figure 12-13 is shown between resistive layer 104, conductive layer 106, the remainder 162 of hard mask layer 108, access device 112 and first
Spacing body 152. etches hard mask layer 108, to provide remainder 162 160 using the first spacer 152 as mask.It is surplus
Remaining part point has central opening 164.Remainder 162 is ring-shaped and matches the circular pattern of the first spacer 152.It can
A part for hard mask layer 108 is etched away to use anisotropic etching, to provide remainder 162.In the erosion that 162 perform
Quarter can include dry ecthing.
According to fig. 3, Figure 14-15 shows the top view and sectional view of the state of the part 90 of the RRAM after task 160.Figure
14-15 shows resistive layer 104, conductive layer 106, the remainder 162 of hard mask layer 108 and access device 112.170, move
In addition to the first spacer 152.The first spacer 152 can be etched away using anisotropic etching.It can in the etching that 170 perform
To include wet etching or dry ecthing.
According to fig. 3, Figure 16-17 shows the top view or sectional view of the state of the part 90 of the RRAM after task 180.Figure
16-17 shows resistive layer 104, conductive layer 106, the remainder 162 of hard mask layer 108, access device 112, third film
Layer 182,182 and second mask 184 of third film layer.180, third film layer 182 is formed.Can use has opening 186
The second mask 184 to be formed and graphical third film layer 182.It can be provided based on the layout of scheduled memory cell
Or form the second mask 184.The second mask 184 can be used on conductive layer 106 and in the remainder of hard mask layer 108
Deposition third film layer 182 in 162 central opening 154.Third film layer 182 can be with the remainder of hard mask layer 108
162 are folded.Third film layer 182 can be formed using CVD or other deposition techniques (such as physical vapour deposition (PVD) (PVD)).
Third film layer 182 can be by such as silica SiO2And/or silicon carbide SiC is formed and/or comprising such as silica
SiO2And/or silicon carbide SiC.
According to fig. 3, Figure 18-19 shows the top view and sectional view of the state of the part 90 of the RRAM after task 190.Figure
18-19 shows that resistive layer 104, conductive layer 106, the remainder 162 of hard mask layer 108, third film layer 182 and the 4th are thin
Film layer 192.190, the 4th film layer 192 is formed.CVD, PVD or other suitable deposition technique can be used in third film
The 4th film layer 192 is deposited on layer 182 and conductive layer 106.4th film layer 192 is by the material different from third film layer 182
It is formed.4th film layer 192 can be by such as carbon doped silicon nitride Si3N4It is formed and/or including such as carbon doped silicon nitride
Si3N4.As what is carried out in following task 200, by by forming the 4th film layer with 182 different materials of third film layer
192, third film layer 182 can be removed while at least part for retaining the 4th film layer 192.4th film layer
192 include raised profile region 194, raised profile region 194 be due to the 4th film layer be covered in third film layer 182 with
Caused by the part that 108 remainder 162 of hard mask layer overlaps.
According to fig. 3, Figure 20-21 shows the top view and sectional view of the state of the part 90 of the RRAM after task 200.Figure
20-21 shows resistive layer 104, conductive layer 106, the remainder 162 of hard mask layer 108, access device 112, third film
The remainder 202 of 201 and the 4th film layer 192 of remainder of layer 182.200, etching third film layer 182 and the 4th
For film layer 192 to provide the second spacer 203, the second spacer 203 includes the remainder 201 and the of third film layer 182
The remainder 202 of four film layers 192.Second spacer 203 is ring-shaped.Each in spacer 162,203 is rectangle
's.The remainder 162 of hard mask layer 108 extends in a first direction.Second spacer 203 is perpendicular to the of first direction
Two sides upwardly extend.182 and the 4th film layer 192 of third film layer can be etched to provide second using anisotropic etching
Spacer 203.It can include dry ecthing in the etching that 200 perform.
According to fig. 3, Figure 22-23 shows the top view and sectional view of the state of the part 90 of the RRAM after task 210.Figure
22-23 shows resistive layer 104, conductive layer 106, access device 112, the second spacer 203 and hard mask layer island body 212.
210, the remainder of (as shown in Figure 20 and Figure 21) hard mask layer 108 is etched using the second spacer 203 as mask
Divide 162, to provide hard mask layer island body 212.The one of remainder 162 can be etched away using anisotropic etching
Point, to provide hard mask layer island body 212.It can include wet etching or dry ecthing in the etching that 210 perform.
According to fig. 3, Figure 24-25 shows the top view and sectional view of the state of the part 90 of the RRAM after task 220.Figure
24-25 shows resistive layer 104, conductive layer 106, access device 112 and hard mask layer island body 212.220, remove or (erosion
Carve) the second spacer 203 is so that remaining element on conductive layer 106 is hard mask layer island body 212.Due to previous more
The use of a etching step 160 and 210 and spacer 162,203, the side 222 of hard mask layer island body 212 is smooth.
According to fig. 3, Figure 26-27 shows the top view and sectional view of the state of the part 90 of the RRAM after task 230.Figure
26-27 shows the remainder 232 of resistive layer 104, the remainder 234 of conductive layer 106, access device 112 and hard mask
Layer island body 212.230, resistive layer 104 and conductive layer 106 are etched using hard mask layer island body 212 as mask.It can
The expose portion of resistive layer 104 is removed to use anisotropic etching, to provide remainder 232,234.It is performed 230
Etching can include wet etching or dry ecthing.Which provides resistance element 236 (the i.e. stacking of remainder 232, each stackings
All be resistance element) and conducting element (i.e. remainder 234), cross section be mutually matched and with hard mask layer island body
237 cross section matching.Each in resistance element includes first electrode 235, variable resistance element 237, hardware
238 and second electrode 239.Second electrode 239 may be coupled to bit line.
Resistance element 236 and conducting element 234 are provided to the etching of resistive layer 104 and conductive layer 106 as described above,
Resistance element 236 and conducting element 234 have the contact surface for being mutually matched and being mutually aligned accordingly.The one of resistance element
A exemplary contact surface is defined as 241.One exemplary contact surface of conducting element is defined as 243.Due to the use of
Identical correspondence mask, the patterns of the shape and size including each pair of contact surface (such as 241,243 pairs of contact surface), phase
Mutually match and be aligned.Occurs the etching to resistive layer 104 and conductor layer 106 in single task role.Therefore, to resistive layer
101 etching and the etching of conductor layer 106 is appeared in same time period.Contact surface with corresponding contact surface region
Size it is identical.
According to fig. 3, Figure 28-29 shows the top view and sectional view of the state of the part 90 of the RRAM after task 240.Figure
28-29 shows resistance element 236, conducting element 234, access device 112, hard mask layer island body 212 and dielectric isolation
Film (or isolation) layer 242.240, in 234 disposed thereon dielectric isolation film of resistance element 236 and conducting element, to carry
For separation layer 242.The part of resistance element 236 and the part of conducting element 234 are encapsulated in dielectric isolation film, will
The conducting element and resistance element being connected with each stacking are kept apart from other conducting elements and resistance element of other stackings.
According to fig. 3, Figure 30-31 shows the top view and sectional view of the state of the part 90 of the RRAM after task 250.Figure
30-31 shows resistance element 236, conducting element 234, access device 112 and dielectric isolation layer (or isolation) layer 242.
250, remove hard mask layer island body 212.Hard mask island body 212 can be removed using anisotropic etching.The etching
It can include wet etching or dry ecthing.The top surface of RRAM can be etched and/or polished using chemical-mechanical planarization, with sudden and violent
Reveal conducting element 234.
According to fig. 3, Figure 32-33 shows the top view and sectional view of the state of the part 90 of the RRAM after task 260.Figure
32-33 shows resistance element 236, conductive layer 234, access device 112, separation layer 242 and interconnection 262.260, formed mutual
Connect 262.Metallization can be performed to interconnect to be formed on the part of top surface.The interconnection by two in conducting element 234 or
More conducting elements are connected with each other.The interconnection can include metal such as Ti, aluminium Al and/or tungsten W.This method can be 270
Terminate.
The electrode 235 of resistive layer 236 may be coupled to transistor.Only make example, single transistor 280 is shown with leakage
Pole 282, source electrode 284 and grid 286.Drain electrode 282 is connected to one in electrode 235.Source electrode 284, which may be coupled to, to be for example grounded
With reference to 288.Grid 286 may be coupled to wordline 290.
In above-mentioned task, the straight smooth side of the remainder 162 of hard mask layer 108 and the second spacer 203
Straight smooth side provide the mask used in etching task, to provide the straight smooth of resistance element and conducting element
Side.Resistance element is aligned in corresponding with conducting element.
The other aspects of the present invention are related to one or more of following content content.
This document describes a kind of method, this method includes:Resistive layer is formed to stack;Formed resistive layer stack before or it
Afterwards, conductive layer is formed;Mask layer is applied in (i) resistive layer stacking or (ii) conductive layer;The first interval is formed on mask layer
Part;And the first part of mask layer is etched away using the first spacer as the first mask, remainder is configured.The party
Method further includes:In (i) resistive layer stacking or the remainder of conductive layer and (ii) mask layer, the second spacer is formed;Erosion
Carve the second part of the remainder of mask layer, to form island body;And island body is used as the second mask, (i) erosion
It carves resistive layer stacking and forms the conducting element of memory to form the resistance element of memory and (ii) etching conductive layer.
The formation of first spacer can include:The first film layer is applied on mask layer;And etch the first film layer
To provide the first spacer.The formation of second spacer can include:In (i) mask layer and (ii) resistive layer stacks or conductive layer
The second film layer of upper application;And the second film layer is etched to provide the second spacer.In first spacer and the second spacer
Each spacer can be ring-shaped.
The formation of second spacer can include:Using thin on (i) mask layer and (ii) resistive layer stacking or conductive layer
Film layer;And etch thin film layer, to provide the second spacer.
This method can also include:The second part of the remainder of mask layer is etched away, to form island body;And make
By the use of island body as mask, (i) etching resistive layer is stacked to form resistance element, and (ii) etches conductive layer to form conduction
Element.
This method can also include:In resistance element and overlying conductive elements depositing isolation material, to encapsulate (i) resistive member
The part and the part of (ii) conducting element that part stacks;By one that etches away (i) island body and (ii) isolated material
Divide and expose conducting element;And metallization is performed, two or more conducting elements in conducting element are connected to be formed
Interconnection.
This method can also include:In resistance element and overlying conductive elements depositing isolation material to encapsulate (i) resistive member
A part for a part for part and (ii) conducting element;And by etching away the part of (i) isolated material and (ii) island
Body and expose conducting element.
As an example, resistive layer stacking can be formed on access device.Access device can include transistor and
Wordline.Resistance element includes first electrode and second electrode.First electrode is connected to the drain electrode of transistor.Second electrode is connected to
Bit line.
As another example, conductive layer is formed before resistive layer is formed;And conductive unit is contact.
As an example, conductive layer is formed after resistive layer is stacked and to be formed;And conducting element is through-hole.
The invention discloses a kind of method, and this method includes:Resistive layer is formed on access device to stack;Resistive
Heap is stacked on to apply conductive layer;Mask layer is applied on the electrically conductive;Spacer is formed on mask layer;Using spacer as first
Mask carrys out etch mask layer to provide island body;And using island body, (i) etching resistive layer is stacked with shape as the second mask
Into resistance element and (ii) etching conductive layer to form conducting element, wherein resistance element provides memory cell.
This method can also include:The first film layer is formed on mask layer;The first film layer is etched to be formed between first
Spacing body;The first part of mask layer is etched away using the first spacer as mask, to provide remainder;It is thin to form second
Film layer on the remainder of (i) conductive layer and (ii) mask layer to form the second spacer;And etch away the surplus of mask layer
The second part of remaining part point, to form island body.
This method can also include:In resistance element stacking and overlying conductive elements depositing isolation material, hindered with encapsulating (i)
Property element a part and (ii) conducting element a part;And by etching away (i) island body and (ii) isolated material
A part and expose conducting element;And metallization is performed to form the mutual of two or more elements in connection conducting element
Even.
The invention discloses a kind of memory, which includes resistance element and conducting element.Resistance element offer is deposited
Memory cell array, wherein resistance element include the first contact surface.Conducting element includes through-hole or contact.Conducting element includes
Second contact surface.Resistance element is in contact with corresponding electrically conductive element, to provide element pair.For each element to using
The same period of single mask, etch the element pair.As it is etching the element pair as a result, the second contact surface with it is corresponding
The first contact surface match and be aligned.
As an example, the contact surface region of the second contact surface can have and corresponding first contact surface
The identical size in contact surface region.In addition, each during resistance element stacks can include:First electrode;With the first electricity
The variable resistance of pole contact;The hardware contacted with variable resistance;And the second electrode contacted with hardware.
The memory can also include transistor, wherein:The drain electrode of transistor is connected to the first electrode of resistance element, and
And the grid of transistor is connected to wordline.Second electrode may be coupled to bit line.
The memory can also include transistor, wherein each in transistor and corresponding (i) resistance element or
(ii) contact in conducting element.Electrode in resistance element may be coupled to the grid of transistor.
The purpose of above-mentioned task is illustrated examples;According to application, which can be in the period be folded by sequentially, together
Step ground simultaneously, continuously or is executed in different order.In addition, according to implement and/or event sequence, can not perform or
Skip any task in the task.In addition, although Yi Shang task is described primarily with regard to RRAM, more than task can be applied
To other memories.
Foregoing description is substantially exemplary only, and is not intended to the limitation disclosure, its application or uses.It can be with each
Kind form realizes the extensive introduction of the disclosure.Therefore, although the present disclosure includes specific examples, the true model of the disclosure
Enclosing so to be limited, this is because after research attached drawing, specification and appended, other modifications will be apparent.
Phrase " at least one of A, B and C " used herein should be interpreted using non-exclusive logic or logic (A or B or
C).It, can be in different order (or simultaneously) execution method it should be appreciated that under the premise of the principle of the present invention is not changed
One or more steps).
Although herein phrase " first ", " second ", " third " etc. can be used for describing various layers, interconnection, element,
Access device and/or component, these projects should not necessarily be limited by these phrases.These phrases may be only used for by a project with it is another
One project difference.When phrase used herein such as " first ", " second " and other digital phrases, it is not intended to order
Or sequence, unless explicitly pointing out in the text.Therefore, the first item being discussed below can mean second item without departing from
The introduction that example is implemented.
In the following description, using various phrases to describe the physical relation between component.When first element is known as
" above ", " being engaged in ... ", " being connected to ... ", " on being arranged on ... ", " in ... upper application "
Or when " being coupled to ... ", first element can be directly in second element, be directly fixed in second element, directly
Second element is connected to, is set up directly in second element, directly applies or be directly coupled to second yuan in second element
Part or there may be intervenient elements.On the contrary, when element be known as " on directly existing ... ", " directly engagement
In ... ", " on being set up directly on ... ", " in ... upper directly application ", " being directly connected to ... " or " straight
Connect and be coupled to ... " another element when, there is no intervenient elements herein.It is other to be used to describe relationship between element
Word should explain in this way (for example, " ... between " to " between directly existing ... ", " adjacent " is to " direct phase
It is adjacent ", etc.).
Device and method described in this application can be one or more by being performed by one or more processors
A computer program and partly or be completely carried out.The computer program includes processor-executable instruction, the instruction quilt
It is stored at least one non-provisional, tangible computer readable medium.The computer program can also include and/or rely on
Stored data.