CN103865473B - A kind of macromolecular material silica gel adhesive - Google Patents
A kind of macromolecular material silica gel adhesive Download PDFInfo
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- CN103865473B CN103865473B CN201410035224.6A CN201410035224A CN103865473B CN 103865473 B CN103865473 B CN 103865473B CN 201410035224 A CN201410035224 A CN 201410035224A CN 103865473 B CN103865473 B CN 103865473B
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- silica gel
- gel adhesive
- macromolecular material
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Abstract
The present invention relates to a kind of macromolecular material silica gel adhesive, this silica gel adhesive is by acid silicones, tetraethyl orthosilicate, inhibitor, organo-tin compound, titanate esters, polyoxy silane, ethyl acetate, Silicon Containing Hydrogen oil content, vinyl polysiloxane and cross-linking agent composition, the preparation method of this adhesive is simple, the most available by mix homogeneously after weighing each raw material successively, it is high that the silica gel adhesive of gained not only has traditional intrinsic viscosity, the most also there is high light transmittance, can be widely used for the material surface such as emulsion paint wall and glass, rustless steel, plank and paste, easy to use.
Description
Technical field
The present invention relates to a kind of adhesive, especially relate to a kind of high viscosity high transmission rate silica gel adhesive.
Background technology
Presently commercially available adhesive is still based on formaldehyde system adhesive, chloroprene rubber adhesive agent etc., owing to formaldehyde system adhesive is bonding
Product can discharge free formaldehyde during producing and using, the solvent toxicity of chloroprene rubber adhesive agent is big, this all serious harm people
Body is healthy, and therefore, in the case of consumer's environmental consciousness strengthens day by day, the use of formaldehyde system and chloroprene rubber adhesive agent is increasingly subject to
To limiting.For exported product, use conventional toxic to be harmful to adhesive and will be unable to enter overseas market.Silica gel viscose glue
Agent is a kind of novel tool adhesive with broad prospects for development, and it has good viscose properties, also has many special performances,
It can be not only used for emulsion paint wall and can be used for again the material surface such as glass, rustless steel, plank and paste, but have simultaneously high viscosity and
The silica gel adhesive of high transmission rate does not the most occur.
Summary of the invention
It is an object of the invention to overcome the above-mentioned deficiency of prior art, it is provided that a kind of have high viscosity and high transmission rate simultaneously
Macromolecular material silica gel adhesive.
For realizing object above, the present invention provides following technical scheme:
A kind of high viscosity high transmission rate silica gel adhesive, it is characterised in that: its component and parts by weight are:
Acid silicones 20 30 parts, tetraethyl orthosilicate 5 10 parts, inhibitor 15 parts, organo-tin compound 15 parts, titanate esters 5 10
Part, 0.5 1 parts of polyoxy silane, ethyl acetate 40 60 parts, containing hydrogen silicone oil 15 25 parts, vinyl polysiloxane 10 15 parts, hand over
Connection agent 38 parts.
Wherein said organo-tin compound is dibutyl tin, triphenyltin, stannous methide, dioctyl tin, dibutyl tin osmanthus
Any one in acid stannum.
Wherein said acid silicones be acid methyl phenyl silicone resin, methyl silicon resin, epoxy modified silicone resin and
Any one in amino silicone.
The preparation method of the silica gel adhesive of gained of the present invention is easy and simple to handle, particularly as follows: weigh successively in following ratio and mix former
Described silica gel adhesive, wherein acid silicones 20 30 parts, tetraethyl orthosilicate 5 10 parts, inhibitor 15 is obtained after material
Part, organo-tin compound 15 parts, titanate esters 5 10 parts, 0.5 1 parts of polyoxy silane, ethyl acetate 40 60 parts, Silicon Containing Hydrogen
Oil 15 25 parts, vinyl polysiloxane 10 15 parts, cross-linking agent 38 parts.
The invention has the beneficial effects as follows: the silica gel adhesive of the present invention not only has annual high characteristic, the most also has high printing opacity
Property, low cost, high-performance, be an important advance for prior art.
Detailed description of the invention
Below presently preferred embodiments of the present invention is described in detail, so that advantages and features of the invention can be easier to by this area
Artisans understand that, thus protection scope of the present invention is made apparent clear and definite defining.
Embodiment 1
Weigh acid silicones 20g, tetraethyl orthosilicate 5g, Methanamide 1g, dibutyl tin dilaurate 1g, titanate esters successively
5g, polyoxy silane 0.5g, ethyl acetate 40g, containing hydrogen silicone oil 15g, vinyl polysiloxane 10g, benzoyl peroxide 3g,
Mix homogeneously the most in addition.
Embodiment 2
Weigh acidic methylene phenyl polysiloxane 30g, tetraethyl orthosilicate 10g, acetamide 5g, two fourth stannum 5g successively, titanate esters 10g,
Polyoxy silane 1g, ethyl acetate 60g, containing hydrogen silicone oil 25g, vinyl polysiloxane 15g, benzoyl peroxide 5g, then add
With mix homogeneously.
Embodiment 3
Weigh acid epoxy modified silicone resin 25g, tetraethyl orthosilicate 5g, DMF and acetamide 5g, dibutyl tin osmanthus successively
Acid stannum 1g, titanate esters 6g, polyoxy silane 0.5g, ethyl acetate 50g, containing hydrogen silicone oil 15g, vinyl polysiloxane 10g, mistake
BP 8g, the most in addition mix homogeneously.
The technical scope of the present invention is not imposed any restrictions by above-described embodiment.The technical staff of the industry, in the technical program
Under inspiration, can make some deformation and amendment, what above embodiment was made by every technical spirit according to the present invention any repaiies
Change, equivalent variations and modification, all still fall within the range of technical solution of the present invention.
Claims (4)
1. a macromolecular material silica gel adhesive, it is characterised in that: its component and parts by weight are:
Acid silicones 20 30 parts, tetraethyl orthosilicate 5 10 parts, inhibitor 15 parts, organo-tin compound 15 parts, titanate esters 5 10 parts,
0.5 1 parts of polyoxy silane, ethyl acetate 40 60 parts, containing hydrogen silicone oil 15 25 parts, vinyl polysiloxane 10 15 parts, cross-linking agent 38 parts,
Described organo-tin compound is in dibutyl tin, triphenyltin, stannous methide, dioctyl tin, dibutyl tin dilaurate
Any one.
2. a kind of macromolecular material silica gel adhesive as claimed in claim 1, it is characterised in that: described cross-linking agent is benzoyl peroxide
Formyl.
3. macromolecular material silica gel adhesive as claimed in claim 1 a kind of, it is characterised in that: described inhibitor be Methanamide,
One or more in acetamide, hydrocinnamamide and DMF.
4. the preparation method of an a kind of macromolecular material silica gel adhesive as claimed in claim 1, it is characterised in that: claim in following ratio
Described silica gel adhesive is obtained: wherein acid silicones 20 30 parts, tetraethyl orthosilicate 5 10 parts, suppression after taking and mixing raw material
Agent 15 parts, organo-tin compound 15 parts, titanate esters 5 10 parts, 0.5 1 parts of polyoxy silane, ethyl acetate 40 60 parts, Silicon Containing Hydrogen
Oil 15 25 parts, vinyl polysiloxane 10 15 parts, cross-linking agent 38 parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410035224.6A CN103865473B (en) | 2014-01-26 | 2014-01-26 | A kind of macromolecular material silica gel adhesive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410035224.6A CN103865473B (en) | 2014-01-26 | 2014-01-26 | A kind of macromolecular material silica gel adhesive |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103865473A CN103865473A (en) | 2014-06-18 |
| CN103865473B true CN103865473B (en) | 2016-10-12 |
Family
ID=50904502
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410035224.6A Active CN103865473B (en) | 2014-01-26 | 2014-01-26 | A kind of macromolecular material silica gel adhesive |
Country Status (1)
| Country | Link |
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| CN (1) | CN103865473B (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PT2616248E (en) * | 2010-09-19 | 2015-10-09 | Reinhard Bühler | Method for producing a photographic picture |
| CN104673178A (en) * | 2015-02-05 | 2015-06-03 | 东莞新东方科技有限公司 | Silicone adhesive for sticking stainless steel material and preparation method thereof |
| CN105907338A (en) * | 2016-06-27 | 2016-08-31 | 肥西县碧涛建材有限公司 | New polymer material environment-friendly adhesive |
| CN106010387A (en) * | 2016-06-28 | 2016-10-12 | 合肥金同维低温科技有限公司 | Macromolecular new material environment-friendly adhesive |
| CN106381077A (en) * | 2016-08-30 | 2017-02-08 | 裴寿益 | High-molecular eco-friendly silica gel adhesive and preparation method thereof |
| CN107189727A (en) * | 2017-05-31 | 2017-09-22 | 安庆永大体育用品有限公司 | A kind of plank adhesive of service life length and preparation method thereof |
| CN107541177A (en) * | 2017-09-07 | 2018-01-05 | 深圳市康利邦科技有限公司 | The preparation method of silane work(graphene, antistatic silicone pressure sensitive adhesive and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102382617A (en) * | 2011-08-25 | 2012-03-21 | 江苏创景科技有限公司 | Single-component high-strength transparent organic silicon potting adhesive and preparation method thereof |
| CN102492391A (en) * | 2011-11-28 | 2012-06-13 | 上海化工研究院 | Monocomponent addition type silicone rubber packaging glue with strong cohesiveness and preparation method thereof |
| CN102898972A (en) * | 2012-10-29 | 2013-01-30 | 华南理工大学 | Preparation method of tackifier for addition type silicone pouring sealant |
| CN103102865A (en) * | 2012-12-30 | 2013-05-15 | 浙江工业大学 | Silane coupling agent for bonding addition type silicon rubber and leather material |
-
2014
- 2014-01-26 CN CN201410035224.6A patent/CN103865473B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102382617A (en) * | 2011-08-25 | 2012-03-21 | 江苏创景科技有限公司 | Single-component high-strength transparent organic silicon potting adhesive and preparation method thereof |
| CN102492391A (en) * | 2011-11-28 | 2012-06-13 | 上海化工研究院 | Monocomponent addition type silicone rubber packaging glue with strong cohesiveness and preparation method thereof |
| CN102898972A (en) * | 2012-10-29 | 2013-01-30 | 华南理工大学 | Preparation method of tackifier for addition type silicone pouring sealant |
| CN103102865A (en) * | 2012-12-30 | 2013-05-15 | 浙江工业大学 | Silane coupling agent for bonding addition type silicon rubber and leather material |
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| Publication number | Publication date |
|---|---|
| CN103865473A (en) | 2014-06-18 |
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Effective date of registration: 20160901 Address after: Room 1018, international document building, Shennan Middle Road, Futian District, Guangdong, Shenzhen 518000 Applicant after: Shenzhen Kang Libang Science and Technology Ltd. Address before: 518000 room 1019, Shenzhen international culture building, Futian Road, Shenzhen, Guangdong, Futian District Applicant before: Yue Shengwu |
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