CN106010376A - New high polymer material environment-friendly adhesive - Google Patents
New high polymer material environment-friendly adhesive Download PDFInfo
- Publication number
- CN106010376A CN106010376A CN201610502128.7A CN201610502128A CN106010376A CN 106010376 A CN106010376 A CN 106010376A CN 201610502128 A CN201610502128 A CN 201610502128A CN 106010376 A CN106010376 A CN 106010376A
- Authority
- CN
- China
- Prior art keywords
- adhesive
- environmental protection
- inhibitor
- new material
- polyacrylate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/10—Transparent films; Clear coatings; Transparent materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention relates to a new high polymer material environment-friendly adhesive. The adhesive consists of polyacrylate, tetraethoxysilane, an inhibitor, an organic tin compound, titanate, polyoxosilane, ethyl acetate, hydrogen-containing silicone oil, vinyl silicon resin and a crosslinking agent. A preparation method of the adhesive is simple, and the raw materials are sequentially weighed and uniformly mixed to obtain the adhesive; and the obtained adhesive has traditional characteristic of high viscosity as well as high light transmission and can be widely applied to the surface sticking of the materials such as emulsion paint walls, glass, stainless steel and boards and is convenient to use.
Description
Technical field
The present invention relates to a kind of adhesive, especially relate to a kind of high viscosity high transmission rate adhesive.
Background technology
Presently commercially available adhesive is still based on formaldehyde system adhesive, chloroprene rubber adhesive agent etc., due to adhesive institute of formaldehyde system
Bonding product can discharge free formaldehyde during producing and using, and the solvent toxicity of chloroprene rubber adhesive agent is big, and this is the most serious
Compromise health, therefore, in the case of consumer's environmental consciousness strengthens day by day, formaldehyde system and the use of chloroprene rubber adhesive agent
Increasingly it is restricted.For exported product, use conventional toxic to be harmful to adhesive and will be unable to enter overseas market.
Summary of the invention
It is an object of the invention to overcome the above-mentioned deficiency of prior art, it is provided that one has high viscosity and high printing opacity simultaneously
The macromolecule new material environmental protection adhesive of rate.
For realizing object above, the present invention provides following technical scheme:
A kind of high viscosity high transmission rate adhesive, it is characterised in that: its component and percentage by weight be:
Polyacrylate 20-30 part, tetraethyl orthosilicate 5-10 part, inhibitor 1-5 part, organo-tin compound 1-5 part, titanium
Acid esters 5-10 part, polyoxy silane 0.5-1 part, ethyl acetate 40-60 part, containing hydrogen silicone oil 15-25 part, vinyl polysiloxane
10-15 part, cross-linking agent 3-8 part.
Wherein said organo-tin compound is dibutyl tin, triphenyltin, stannous methide, dioctyl tin, dibutyl two
Any one in tin laurate.
Detailed description of the invention
Embodiment 1
Weigh polyacrylate 20g, tetraethyl orthosilicate 5g, Methanamide 1g, dibutyl tin dilaurate 1g, titanate esters successively
5g, polyoxy silane 0.5g, ethyl acetate 40g, containing hydrogen silicone oil 15g, vinyl polysiloxane 10g, benzoyl peroxide 3g, so
After mix homogeneously in addition.
Claims (5)
1. a macromolecule new material environmental protection adhesive, it is characterised in that: this adhesive by polyacrylate, tetraethyl orthosilicate,
Inhibitor, organo-tin compound, titanate esters, polyoxy silane, ethyl acetate, Silicon Containing Hydrogen oil content, vinyl polysiloxane and cross-linking agent
Composition.
2. as described in claim 1, each material component and percentage by weight be: polyacrylate 20-30 part, tetraethyl orthosilicate
5-10 part, inhibitor 1-5 part, organo-tin compound 1-5 part, titanate esters 5-10 part, polyoxy silane 0.5-1 part, acetic acid
Ethyl ester 40-60 part, containing hydrogen silicone oil 15-25 part, vinyl polysiloxane 10-15 part, cross-linking agent 3-8 part.
3. a kind of macromolecule new material environmental protection adhesive as claimed in claim 1, it is characterised in that: described organotin chemical combination
Thing is any one in dibutyl tin, triphenyltin, stannous methide, dioctyl tin, dibutyl tin dilaurate.
4. a kind of macromolecule new material environmental protection adhesive as claimed in claim 1, it is characterised in that: described cross-linking agent was
BP.
5. a kind of macromolecule new material environmental protection adhesive as claimed in claim 1, it is characterised in that: described inhibitor is
One or more in Methanamide, acetamide, hydrocinnamamide and DMF.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610502128.7A CN106010376A (en) | 2016-06-30 | 2016-06-30 | New high polymer material environment-friendly adhesive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610502128.7A CN106010376A (en) | 2016-06-30 | 2016-06-30 | New high polymer material environment-friendly adhesive |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106010376A true CN106010376A (en) | 2016-10-12 |
Family
ID=57105849
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610502128.7A Pending CN106010376A (en) | 2016-06-30 | 2016-06-30 | New high polymer material environment-friendly adhesive |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106010376A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107189727A (en) * | 2017-05-31 | 2017-09-22 | 安庆永大体育用品有限公司 | A kind of plank adhesive of service life length and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106010387A (en) * | 2016-06-28 | 2016-10-12 | 合肥金同维低温科技有限公司 | Macromolecular new material environment-friendly adhesive |
-
2016
- 2016-06-30 CN CN201610502128.7A patent/CN106010376A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106010387A (en) * | 2016-06-28 | 2016-10-12 | 合肥金同维低温科技有限公司 | Macromolecular new material environment-friendly adhesive |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107189727A (en) * | 2017-05-31 | 2017-09-22 | 安庆永大体育用品有限公司 | A kind of plank adhesive of service life length and preparation method thereof |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20161012 |
|
| RJ01 | Rejection of invention patent application after publication |