CN103865396B - Anticorrosion and antifouling paint for ships and preparation method of paint - Google Patents
Anticorrosion and antifouling paint for ships and preparation method of paint Download PDFInfo
- Publication number
- CN103865396B CN103865396B CN201410124987.8A CN201410124987A CN103865396B CN 103865396 B CN103865396 B CN 103865396B CN 201410124987 A CN201410124987 A CN 201410124987A CN 103865396 B CN103865396 B CN 103865396B
- Authority
- CN
- China
- Prior art keywords
- parts
- anticorrosion
- resin
- water
- polyacrylate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 230000003373 anti-fouling effect Effects 0.000 title claims abstract description 17
- 238000002360 preparation method Methods 0.000 title claims abstract description 7
- 239000003973 paint Substances 0.000 title abstract description 8
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims abstract description 33
- 239000011347 resin Substances 0.000 claims abstract description 27
- 229920005989 resin Polymers 0.000 claims abstract description 27
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 16
- 150000004676 glycans Chemical class 0.000 claims abstract description 14
- 229910052582 BN Inorganic materials 0.000 claims abstract description 13
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 13
- 239000000843 powder Substances 0.000 claims abstract description 13
- 229920000058 polyacrylate Polymers 0.000 claims abstract description 12
- 239000000839 emulsion Substances 0.000 claims abstract description 4
- 238000001914 filtration Methods 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims abstract description 4
- 238000010521 absorption reaction Methods 0.000 claims abstract 3
- 239000012188 paraffin wax Substances 0.000 claims abstract 3
- 150000003904 phospholipids Chemical class 0.000 claims abstract 3
- 239000011248 coating agent Substances 0.000 claims description 19
- 238000000576 coating method Methods 0.000 claims description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 12
- 239000002250 absorbent Substances 0.000 claims description 7
- 230000002745 absorbent Effects 0.000 claims description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- 239000001993 wax Substances 0.000 claims 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims 1
- 210000000481 breast Anatomy 0.000 claims 1
- 238000004945 emulsification Methods 0.000 claims 1
- 239000004816 latex Substances 0.000 claims 1
- 229920000126 latex Polymers 0.000 claims 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 abstract description 3
- 229910000278 bentonite Inorganic materials 0.000 abstract description 3
- 239000000440 bentonite Substances 0.000 abstract description 3
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 abstract description 3
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 abstract 4
- 229920001282 polysaccharide Polymers 0.000 abstract 2
- 239000005017 polysaccharide Substances 0.000 abstract 2
- 239000004408 titanium dioxide Substances 0.000 abstract 2
- 239000011787 zinc oxide Substances 0.000 abstract 2
- 230000001804 emulsifying effect Effects 0.000 abstract 1
- 230000007613 environmental effect Effects 0.000 abstract 1
- 231100000252 nontoxic Toxicity 0.000 abstract 1
- 230000003000 nontoxic effect Effects 0.000 abstract 1
- 230000007797 corrosion Effects 0.000 description 11
- 238000005260 corrosion Methods 0.000 description 11
- 239000013535 sea water Substances 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 3
- 229920002125 Sokalan® Polymers 0.000 description 2
- 239000002519 antifouling agent Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000004584 polyacrylic acid Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- -1 and wherein Substances 0.000 description 1
- 238000004500 asepsis Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- XYIBRDXRRQCHLP-UHFFFAOYSA-N ethyl acetoacetate Chemical compound CCOC(=O)CC(C)=O XYIBRDXRRQCHLP-UHFFFAOYSA-N 0.000 description 1
- 125000004494 ethyl ester group Chemical group 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 230000002906 microbiologic effect Effects 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 238000007634 remodeling Methods 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- DPJRMOMPQZCRJU-UHFFFAOYSA-M thiamine hydrochloride Chemical compound Cl.[Cl-].CC1=C(CCO)SC=[N+]1CC1=CN=C(C)N=C1N DPJRMOMPQZCRJU-UHFFFAOYSA-M 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention discloses an anticorrosion and antifouling paint for ships. The anticorrosion and antifouling paint contains the following components in parts by weight: 20-40 parts of modified natural polysaccharide type high-water-absorption resin, 10-15 parts of water-soluble fluoride resin, 0.3-4 parts of emulsified paraffin, 1-3 parts of phospholipid emulsifiers, 6-12 parts of nanometer titanium dioxide, 4-8 parts of nanometer zinc oxide, 1-2 parts of organic bentonite, 0.8-2 parts of polyacrylate, 2-10 parts of ethyl acetate, and 1-5 parts of boron nitride powder. A preparation method of the paint comprises the following steps: emulsifying modified natural polysaccharide type high-water-absorption resin, water-soluble fluoride resin and emulsified paraffin together for 60-80 minutes; adding phospholipid emulsifiers to obtain a water-soluble emulsion for later use; then adding nanometer titanium dioxide, nanometer zinc oxide, organic bentonite, polyacrylate, ethyl acetate and boron nitride powder at one step; stirring for 10-15 minutes at the temperature of 95-100 DEG C; and filtering to obtain finished products. The anticorrosion and antifouling paint is nontoxic and environmental friendly, thereby causing no pollution to operators and environment.
Description
Technical field
The present invention relates to a kind of coating, particularly to a kind of marine ship anticorrosion and antifouling coating, further relate to this coating
Preparation method.
Background technology
Marine corrosion refers to the corrosion that hardware occurs in marine environment.Marine environment is a kind of complicated corrosion ring
Border.In this environment, seawater is a kind of strong corrosive medium in itself, ripple simultaneously, and wave, tide, stream produce low again to hardware
Frequency reciprocating force and impact, add marine microorganism, aufwuch and their metabolin etc. all corrosion process is produced directly or
Person's indirectly acceleration.Marine corrosion is mainly local corrosion, from the beginning of the surface building, occurs rotten in the region of very little
Erosion.In addition with low frequency corrosion fatigue, stress corrosion and microbiologic(al) corrosion etc..Generally hardware is comprehensive in Sea Water Splashing Zone
Corrosion rate highest.The housing changing the underwaters such as ripple harbour is corroded by seawater with contact with sea water for a long time, marine organisms
Attachment make ship the speed of a ship or plane decline shell corrosion rate accelerate.As shown by data, when marine biofouling rate is 5%, ship hinders
Power is equivalent to 2 times of clean surface, and dyestuff consumption increases by 10%.
In the technology preventing marine organisms apposition growth having developed at present, brushing antifouling paint has economy because of it
Property, the advantages of validity and ease for operation, develop in recent years is the fastest, is most widely used.Antifouling paint is mainly by resin, anti-
Dirty agent, auxiliary material, inserts become to be grouped into for 5 kinds with solvent, and wherein, anti-fouling agent is that aufwuch is risen with the main of toxic action
Poison, and resin is bonding and the important carrier of dispersion anti-fouling agent, both are the key components determining nonpolluting coating performance.
At present, there is following defect in the anticorrosion and antifouling coating that ship is used：1）Can not preferably meet prevents seawater, sea
The attachment of foreign air and the requirement of halobiontic attachment；2）Coating can discharge organic molten in construction usage and solidification process
Agent, constitutes serious threat to environment and health of human body.
Content of the invention
The technical problem to be solved in the present invention is to provide a kind of ship anticorrosion and antifouling coating, without toxicity, significantly subtracts
Lack and operating personnel and marine environment have been polluted.
For solving above-mentioned technical problem, the technical solution used in the present invention is：A kind of ship anticorrosion and antifouling coating, this painting
The parts by weight of the component of material and each component are as follows：Modified natural glycan super absorbent resin 20-40, soluble fluoride
Resin 10-15, emulsified wax 0.3-4, phosphatide emulsifier 1-3, nano titanium oxide 6-12, nano zine oxide 4-8, organic bentonite
The native 1-2 of profit, polyacrylate 0.8-2, ethyl acetate 2-10, boron nitride powder 1-5.
Preferably, the parts by weight of the component of this coating and each component are as follows：Modified natural glycan high-hydroscopicity tree
Fat 28-35, water soluble fluoridized resin 12-13, emulsified wax 1.2-1.6, phosphatide emulsifier 2-2.5, nano titanium oxide
7-9, nano zine oxide 3-5, organobentonite 1.4-1.7, polyacrylate 1-1.2, ethyl acetate 4-6, boron nitride powder 3-
4.
Preferably, the parts by weight of the component of this coating and each component are as follows：Modified natural glycan high-hydroscopicity tree
Fat 32, water soluble fluoridized resin 12.3, emulsified wax 1.4, phosphatide emulsifier 2.6, nano titanium oxide 7.8, nano oxygen
Change zinc 3.7, organobentonite 1.5, polyacrylate 1.2, ethyl acetate 4.6, boron nitride powder 3.7.
The present invention also provides a kind of preparation method of ship anticorrosion and antifouling coating：By modified natural glycan high-hydroscopicity
Resin, water soluble fluoridized resin emulsify 60-80 minute together with emulsified wax, add phosphatide emulsifier, make water-soluble
Property emulsion is stand-by；Again by nano titanium oxide, nano zine oxide, organobentonite, polyacrylate, ethyl acetate and boron nitride
Powder once adds, and stirs 10-15 minute at 95-100 DEG C, and filtration gets product.
Beneficial effects of the present invention：The coating asepsis environment-protecting of the present invention, reduces to the murder by poisoning of operator and to environment
Pollution, improve the antifouling stain resistance of ship, be marine organisms can not adhere to hull on.
Specific embodiment
With reference to specific embodiment, technical scheme is elaborated.
A kind of ship of present invention preparation method of anticorrosion and antifouling coating：By modified natural glycan high-hydroscopicity tree
Fat, water soluble fluoridized resin emulsify 60-80 minute together with emulsified wax, add phosphatide emulsifier, make water solubility
Emulsion is stand-by；Again by nano titanium oxide, nano zine oxide, organobentonite, polyacrylate, ethyl acetate and boron nitride powder
End once adds, and stirs 10-15 minute at 95-100 DEG C, and filtration gets product.
Embodiment 1
32 parts of modified natural glycan super absorbent resin, 12.3 parts of water soluble fluoridized resin, 1.4 parts of emulsified wax,
2.6 parts of phosphatide emulsifier, 7.8 parts of nano titanium oxide, 3.7 parts of nano zine oxide, 1.5 parts of organobentonite, polyacrylic acid
1.2 parts of ester, 4.6 parts of ethyl acetate, 3.7 parts of boron nitride powder.
Embodiment 2
20 parts of modified natural glycan super absorbent resin, 10 parts of water soluble fluoridized resin, 0.3 part of emulsified wax, phosphorus
1 part of lipid emulsifiers, 6 parts of nano titanium oxide, 4 parts of nano zine oxide, 1 part of organobentonite, 0.8 part of polyacrylate, second
2 parts of acetoacetic ester, 1 part of boron nitride powder.
Embodiment 3
40 parts of modified natural glycan super absorbent resin, 15 parts of water soluble fluoridized resin, 4 parts of emulsified wax, phosphatide
3 parts of class emulsifying agent, 12 parts of nano titanium oxide, 8 parts of nano zine oxide, 2 parts of organobentonite, 2 parts of polyacrylate, acetic acid
10 parts of ethyl ester, 5 parts of boron nitride powder.
Embodiment 4
29 parts of modified natural glycan super absorbent resin, 12.5 parts of water soluble fluoridized resin, 1.4 parts of emulsified wax,
2.35 parts of phosphatide emulsifier, 8.3 parts of nano titanium oxide, 4.2 parts of nano zine oxide, 1.6 parts of organobentonite, polyacrylic acid
1.15 parts of ester, 5.2 parts of ethyl acetate, 3.7 parts of boron nitride powder.
The above is only presently preferred embodiments of the present invention, is not the restriction that the present invention is made with other forms, appoints
What those skilled in the art possibly also with the disclosure above technology contents changed or be modified as equivalent variations etc.
Effect embodiment.But every without departing from technical solution of the present invention content, according to the present invention technical spirit to above example institute
Any simple modification, equivalent variations and the remodeling made, still falls within the protection domain of technical solution of the present invention.
Claims (3)
1. a kind of ship with anticorrosion and antifouling coating it is characterised in that：The parts by weight of the component of this coating and each component are as follows：
Modified natural glycan super absorbent resin 20-40, water soluble fluoridized resin 10-15, emulsified wax 0.3-4, phospholipid breast
Agent 1-3, nano titanium oxide 6-12, nano zine oxide 4-8, organobentonite 1-2, polyacrylate 0.8-2, acetic acid second
Ester 2-10, boron nitride powder 1-5.
2. a kind of ship according to claim 1 with anticorrosion and antifouling coating it is characterised in that：The component of this coating and each
The parts by weight of component are as follows：Modified natural glycan super absorbent resin 28-35, water soluble fluoridized resin 12-13, emulsification
Paraffin 1.2-1.6, phosphatide emulsifier 2-2.5, nano titanium oxide 7-9, nano zine oxide 4-5, organobentonite 1.4-
1.7th, polyacrylate 1-1.2, ethyl acetate 4-6, boron nitride powder 3-4.
3. the preparation method of anticorrosion and antifouling coating of the ship described in a kind of claim 1：By modified natural glycan high water absorption
Property resin, water soluble fluoridized resin emulsify 60-80 minute together with emulsified wax, add phosphatide emulsifier, make water
Latex emulsion of solubleness is stand-by；Again by nano titanium oxide, nano zine oxide, organobentonite, polyacrylate, ethyl acetate and nitridation
Boron powder once adds, and stirs 10-15 minute at 95-100 DEG C, and filtration gets product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410124987.8A CN103865396B (en) | 2014-03-31 | 2014-03-31 | Anticorrosion and antifouling paint for ships and preparation method of paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410124987.8A CN103865396B (en) | 2014-03-31 | 2014-03-31 | Anticorrosion and antifouling paint for ships and preparation method of paint |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103865396A CN103865396A (en) | 2014-06-18 |
| CN103865396B true CN103865396B (en) | 2017-02-15 |
Family
ID=50904433
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410124987.8A Expired - Fee Related CN103865396B (en) | 2014-03-31 | 2014-03-31 | Anticorrosion and antifouling paint for ships and preparation method of paint |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103865396B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106010181B (en) * | 2016-06-20 | 2018-04-06 | 上海理工大学 | The preparation method of metal conditioner and its corrosion-resistant finishes containing nm-class boron nitride |
| CN107135988A (en) * | 2017-04-01 | 2017-09-08 | 浙江海洋大学 | A kind of fish features monitor system |
| CN109321043A (en) * | 2018-09-25 | 2019-02-12 | 海南大学 | A kind of seawater pipeline anticorrosive paint and preparation method thereof |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6357674A (en) * | 1986-08-28 | 1988-03-12 | Nippon Paint Co Ltd | Treating material and method used in forming hydrophilic coating film |
| JPH04306269A (en) * | 1989-12-29 | 1992-10-29 | D & D Kk | Antifouling paint |
| CN1261506C (en) * | 2003-11-17 | 2006-06-28 | 中国科学院化学研究所 | Water moistening type non-toxic antifouling paint and its preparation method |
| TW200540238A (en) * | 2004-05-26 | 2005-12-16 | Nippon Paint Co Ltd | Coating composition, coating film, and method of reducing underwater friction |
| CN1923932A (en) * | 2005-11-02 | 2007-03-07 | 中科纳米涂料技术(苏州)有限公司 | Nano modified alkyd paint for ship and preparation method thereof |
| CN101423678A (en) * | 2008-10-29 | 2009-05-06 | 国家纳米科学中心 | Light curing nano composite coating |
| CN103589257A (en) * | 2013-09-03 | 2014-02-19 | 刘岩玉 | Antifouling paint for ships |
-
2014
- 2014-03-31 CN CN201410124987.8A patent/CN103865396B/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN103865396A (en) | 2014-06-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1086406C (en) | Coating composition | |
| CN103865396B (en) | Anticorrosion and antifouling paint for ships and preparation method of paint | |
| CN101701120B (en) | Nanometer ZnO anti-bacterial and anti-fouling coating and method for preparing same | |
| JP2014503646A (en) | Antifouling paint composition | |
| CN107400421B (en) | A kind of corrosion resistant metal coating layer material and preparation method thereof | |
| CN101696340B (en) | Strippable anti-fouling paint | |
| CN107384084A (en) | A kind of high-strength anti-corrosion water paint and preparation method thereof | |
| CN105209557A (en) | Novel polysiloxane-based fouling-release coats | |
| CN102702880A (en) | Anti-fouling paint composition | |
| CN104449249A (en) | Epoxy resin coating in marine steel pipe 3PE anticorrosive coating and preparation method thereof | |
| CN102838914A (en) | Water-based rust transformation primer for coating surface with rust | |
| CN104327650B (en) | The preparation method of methyl silicate water nano antirust agent | |
| CN104277694B (en) | Preparation method of polyurethane paint for marine wind power blades | |
| CN102504697B (en) | High-efficiency tin-free self-polishing antifouling paint composition and application thereof | |
| CN104559579A (en) | Environment-friendly type self-polishing anti-fouling paint with high adhesive force | |
| CN106349928B (en) | A kind of one pack system propeller strippable anti-fouling paint and preparation method thereof | |
| Manoj et al. | Review of biofouling paints on the marine vessel | |
| CN106281020A (en) | A kind of Wuxi, without the environment-friendly type marine antifouling coating of copper and preparation method and application | |
| CN107141968A (en) | A kind of resin base ceramic coating composition and preparation method thereof | |
| CN108546483A (en) | A kind of maritime concrete Super hydrophobic anticorrosive paint and preparation method thereof | |
| CN103788812A (en) | Marine antifouling nano paint | |
| CN106497414A (en) | A kind of low-surface-energy is from polishing type antifouling paint and its application on the cuprous anti-fouling paint of non-oxidation | |
| CN102702913A (en) | Anti-fouling coating composition | |
| CN1772828A (en) | Antifouling Coating for marine nesh cage cover | |
| CN105778696A (en) | Efficient antifouling paint for fishing gear |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20170215 |